han

Third Indian Grand Prix track and field: Another chance for many stars to stake their claim for Paris Olympics

There are no eye-popping names in the fray, perhaps because the National inter-state championship is scheduled in close proximity (June 27-30 in Panchkula, Haryana).




han

Manu under dope cloud, Paris chances hit; AFI disappointed; coach Naik too under scrutiny




han

With plenty of swimming stars at the 2024 Olympics, France's Marchand may shine brightest

With big names like Caeleb Dressel, Katie Ledecky, Ariarne Titmus and Emma McKeon, it is expected that local favourite Léon Marchand may shine in the swimming event at Paris Olympics 2024




han

Paris Olympics 2024: Team USA sending more women than men for the fourth consecutive Summer Olympics

The lineup features 314 women and 278 men, spanning ages from 16 to 59 and with 46 states represented.




han

Paris Olympics: Afghan sprinter Yousoufi tells girls not to let others make decisions for them

Competing in her third Olympics — Rio de Janeiro and Tokyo — Yousofi finished with a time of 13.42 seconds, slower than the 13.29 three years ago.




han

Neeraj Chopra reveals he took part in Diamond League final with fracture in hand

Neeraj Chopra, who added a silver to his Olympic medal tally in Paris following a historic gold at the Tokyo Games, thus ended his season on a high.




han

Sebastian Coe, multi-millionaire Johan Eliasch among seven candidates for IOC presidency

The IOC, with 111 members currently, is in charge of the Olympic Games and the multi-billion dollar industry linked to the world's biggest multi-sports event.




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PIX: Rashid Khan's grand wedding takes Kabul by storm

Afghanistan's star all-rounder, Rashid Khan, celebrated his grand wedding in Kabul on October 3, 2024. The event, held in Afghanistan's capital, quickly became a viral sensation as videos from the ceremony circulated on social media.




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India aim to gain upper hand over struggling Kiwis

India has only minor concerns, but New Zealand's troubles across batting and bowling departments are more pronounced.




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PIX: Sajid Khan's heroics save the day for Pakistan

IMAGES from Day 2 of the second Test played between Pakistan and England in Multan on Wednesday.




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PICS: Say hello to new daddy Sarfaraz Khan

The timing of the baby's arrival couldn't be more perfect as Sarfaraz turns 27 on Tuesday, October 22.




han

Sudarshan hits century but Australia A sniff victory

Flamboyant keeper-batter Ishan Kishan walked into the middle and he looked in the mood as he played some impressive shots, including pulling O'Neill for a six.




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PIX: Gill, spinners give India upper hand on Day 2

Spinners Ravindra Jadeja and Ravichandran Ashwin chipped away at the wickets to leave New Zealand reeling on 171/9 in their second innings at stumps on Day 2.




han

Dr. Mohan’s Diabetes Specialties Centre launches clinic, homecare service for the elderly

These initiatives aim to provide multidisciplinary care to senior citizens and enhance their quality of life




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Researchers document huge drop in African elephants in a half century

Fresh evidence of this comes in a study that documents alarming population declines at numerous sites across the continent over about a half century.




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Blinken says India-US working to address regional and global challenges after meeting Jaishankar

Jaishankar met Blinken on Tuesday at the Foggy Bottom headquarters of the US State Department.




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US weather agency lowers chances of La Nina’s emergence

Cuts prospects to 60%, says a weak even may last till March 2025




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Chance for La Nina to emerge has decreased, says Australia’s BoM

5 climate models point to ENSO-neutral conditions until February 2025




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Indian, Chinese troops exchange sweets at several border points on Diwali

The ties between the two Asian giants had nosedived following the clash




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Trump wants to be 'dictator', won't be good for ties with India: Congressman Shri Thanedar on US polls

He further underscored the importance of the Indian-American vote in the upcoming US Presidential elections, while noting the growing support for Kamala Harris in the crucial swing state of Michigan




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US will be more isolationist whoever wins election, Jaishankar says

"President Trump may be more articulate and expressive in that regard," he said during a panel discussion with the foreign ministers of Australia and New Zealand




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Trump victory gives Modi chance to reset India’s image with the West

Analysts and officials believe that the US under Trump will continue a years-long effort to cultivate India as a strategic partner against a more assertive Beijing, an effort that has won India big new investments from US companies like Apple Inc




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Overseas Pakistani group Al Nihang offers to acquire debt-ridden Pakistan International Airlines

Earlier, PML-N President Nawaz Sharif said that Punjab Chief Minister Maryam Nawaz advised him to buy Pakistan International Airlines (PIA) and rebrand it ‘Air Punjab’




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Villa shock Bayern in Champions League thanks to Duran's superb late strike

Duran ran onto a high ball in the 79th minute, spotted goalkeeper Manuel Neuer off his line, and scooped the ball over him to send Villa Park into delirium.




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Thomas Tuchel appointment: A German in charge of England? Nationality matters less than it used to in international football

Thomas Tuchel taking charge of England shows that, increasingly, even the top countries in the sport are abandoning the long-held belief that the national team must be led by one of their own.




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Gold prices unchanged as market awaits US economic reports

Investors are particularly focused on upcoming job data and key economic indicators to assess the health of the U.S. economy and its potential impact on future Fed decisions



  • Gold & Silver

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Jewellers woo Dhanteras buyers with attractive offers

Gold prices have been hovering above Rs ₹78,600 per 10 gm-level consistently despite weak demand due to ongoing global geopolitical turmoil in West Asia and Russia-Ukraine




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Recent advances in discrete Cu complexes for enhanced chemodynamic therapy

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02380C, Frontier
Zhao-Guo Hong, Liangliang Zhang, Hong Liang, Fu-Ping Huang
Since the concept of metal ion stimulation-mediated chemodynamic therapy was proposed by Bu and Shi 's group in 2016, increasing attention has been directed toward fabricate efficient, safe and stable...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02197E, Paper
Vandana Kardam, Vaibhav Bhatt, Kshatresh Dubey
Arylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02303J, Paper
Tao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan Wang
Ni/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02606C, Paper
Ian Dance
I describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02645D, Paper
Ketan Maru, Sarita Kalla, Ritambhara Jangir
The study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A ratiometric luminescence thermometer based on lanthanide encapsulated complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02639J, Paper
Aribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju Laishram
This paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




han

Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites

Dalton Trans., 2024, 53,18021-18026
DOI: 10.1039/D4DT02421D, Paper
Afif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki Motohashi
The oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).
The content of this RSS Feed (c) The Royal Society of Chemistry




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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




han

Writing a requiem to handwriting

The decline started with the advent of photocopiers and word processors




han

Celebrating Hanami

It’s a Japanese tradition of viewing flowers in spring




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Doctors and handwriting

A running joke is that a student with sloppy handwriting will probably become a doctor




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Nothing has changed for women in India

From Nirbhaya to Abhaya, violence continue to be perpertrated against women in the country




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A dictionary at hand

Consult it regularly to develop your own vocabulary




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Rising stars: Chani Nava and Will Chen

Interview with early-career scientists in astronomy and quantitative ecology




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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific