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Crystal structure of bis­(1-ethyl-1H-imidazole-κN3)(meso-tetra­mesitylporphyrinato-κ4N,N',N'',N''')iron(III) perchlorate chloro­benzene sesquisolvate

In the complex cation of title compound, [Fe(C56H52N4)(C5H8N2)2]ClO4·1.5C6H5Cl, the ironIII atom is coordinated in a distorted octa­hedral manner by four pyrrole N atoms of the porphyrin ring system in the equatorial plane, and by two N atoms of the 1-ethyl­imidazole ligands in the axial sites. A disordered perchlorate anion and one and a half chloro­benzene solvent mol­ecules are also present. The cationic complex exhibits a highly ruffled porphyrin core. The average Fe—Np (Np is a porphyrin N atom) bond length is 1.988 (5), and the axial Fe—NIm (NIm is an imidazole N atom) bond lengths are 1.962 (3) and 1.976 (3) Å. The two 1-ethyl­imidazole ligands are inclined to each other by a dihedral angle of 68.62 (16)°. The dihedral angles between the 1-ethyl­imidazole planes and the planes of the closest Fe—Np vector are 28.52 (18) and 43.57 (13)°. Inter­molecular C—H⋯Cl inter­actions are observed.




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Bis(μ2-4-nitro­phenolato)bis­(4-nitro­phenolato)di-μ3-oxido-octaphenyltetra­tin chloro­form sesquisolvate [+ solvate]: a tetra­nuclear stannoxane

The title tetra­nuclear stannoxane, [Sn4(C6H5)8(C6H4NO3)4O2]·1.5CHCl3·solvent, crystallized with two independent complex mol­ecules, A and B, in the asymmetric unit together with 1.5 mol­ecules of chloro­form. There is also a region of disordered electron density, which was corrected for using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18]. The oxo-tin core of each complex is in a planar `ladder' arrangement and each Sn atom is fivefold SnO3C2 coordinated, with one tin centre having an almost perfect square-pyramidal coordination geometry, while the other three Sn centres have distorted shapes. In the crystal, the complex mol­ecules are arranged in layers, composed of A or B complexes, lying parallel to the bc plane. The complex mol­ecules are linked by a number of C—H⋯O hydrogen bonds within the layers and between the layers, forming a supra­molecular three-dimensional structure.




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Smithsonian receives giant squid caught in the Gulf of Mexico

The giant squid was collected during a 60-day scientific study in which NOAA scientists were studying the availability and diversity of sperm whale prey. The squid was caught in a trawl net pulled behind a research vessel at a depth of more than 1,500 feet.

The post Smithsonian receives giant squid caught in the Gulf of Mexico appeared first on Smithsonian Insider.






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As robins disperse, West Nile mosquitoes switch diet to humans: Q&A with Smithsonian ornithologist Peter Marra

A rising spike in West Nile virus is taking health officials across the country by surprise as this year more than 2,600 people in 45 states and the District of Columbia, have been stricken with severe symptoms of this mosquito-transmitted disease.

The post As robins disperse, West Nile mosquitoes switch diet to humans: Q&A with Smithsonian ornithologist Peter Marra appeared first on Smithsonian Insider.




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As they grow some squid change dramatically, making scientists cautious about naming new species

A specimen recently pulled from deep in the southwest Atlantic may represent a new species of squid, say scientist who have studied the animal’s unusual morphology. But then again, it may not…

The post As they grow some squid change dramatically, making scientists cautious about naming new species appeared first on Smithsonian Insider.





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Vampire squid

This 1889 scientific illustration of a vampire squid from Smithsonian celebrates Halloween. The squid’s jet-black skin, the caped appearance of the webbing between its arms […]

The post Vampire squid appeared first on Smithsonian Insider.




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Discovery of new prehistoric mosquitoes reveal these blood-suckers have changed little in 46 million years

Found in well preserved shale deposits the fossils are so detailed that scientists were able to determine they represent two previously unknown species.

The post Discovery of new prehistoric mosquitoes reveal these blood-suckers have changed little in 46 million years appeared first on Smithsonian Insider.



  • Dinosaurs & Fossils
  • Science & Nature
  • insects
  • National Museum of Natural History
  • new species

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First detailed sex video of deep-sea squid resolves long-standing mysteries as to how these animals mate

Clearly visible connecting the dark-purple cephalopods was the white “terminal organ” or penis of the male, extending out through the male’s funnel.

The post First detailed sex video of deep-sea squid resolves long-standing mysteries as to how these animals mate appeared first on Smithsonian Insider.




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Blood molecules preserved for millions of years in abdomen of fossil mosquito

Sometime during the Middle Eocene a prehistoric mosquito slurped down a final blood meal then died and sank to the bottom of a pond in […]

The post Blood molecules preserved for millions of years in abdomen of fossil mosquito appeared first on Smithsonian Insider.




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Squat lobsters: colorful kings of the ocean floor

Their flavor is a unique blend of lobster and shrimp say lovers of the savory South American crustaceans called “langostinos.” Simmered with garlic, lime juice, […]

The post Squat lobsters: colorful kings of the ocean floor appeared first on Smithsonian Insider.




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What squirms inside a tiny bird? Odd new tapeworm species

Parasites such as nematodes, tapeworms, flukes, ticks and lice are normal in nature and can even be beneficial for animals, including humans, says Anna Phillips, […]

The post What squirms inside a tiny bird? Odd new tapeworm species appeared first on Smithsonian Insider.






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This Squirrel Appreciation Day we have a few surprising squirrely facts for you

Flying through the air? Check. Surviving snake bites? Check. One of the most adorable creatures on earth? Absolutely! Do you think you know everything about […]

The post This Squirrel Appreciation Day we have a few surprising squirrely facts for you appeared first on Smithsonian Insider.



  • Animals
  • Science & Nature
  • National Museum of Natural History
  • Smithsonian's National Zoo

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Rare squid “T. danae” captured in new video

No divers were in danger when two large squid (species Taningia danae) began acting aggressively toward a robot submersible operated deep in the Pacific from NOAA’s […]

The post Rare squid “T. danae” captured in new video appeared first on Smithsonian Insider.




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Basque Country & Cheese

Food is an important element of Basque life. In the Ostatua Kitchen tent at the Smithsonian’s 2016 Folklife Festival, chefs from two Basque culinary schools […]

The post Basque Country & Cheese appeared first on Smithsonian Insider.



  • History & Culture
  • Video
  • Smithsonian Folklife Festival


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Mosquito road

Jose Loaiza, a research associate at the Smithsonian Tropical Research Institute in Panama, has determined that disease carrying mosquitoes move along Panama’s highways by laying […]

The post Mosquito road appeared first on Smithsonian Insider.



  • Animals
  • Science & Nature
  • Video
  • Smithsonian Tropical Research Institute

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Squaring the EMC - how promoting membrane protein biogenesis impacts cellular functions and organismal homeostasis

Norbert Volkmar
Apr 24, 2020; 133:jcs243519-jcs243519
REVIEW




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Genetic redundancy aids competition among symbiotic bacteria in squid

Full Text:

The molecular mechanism used by many bacteria to kill neighboring cells has redundancy built into its genetic makeup, which could allow for the mechanism to be expressed in different environments, say researchers at Penn State and the University of Wisconsin-Madison. Their new study provides insights into the molecular mechanisms of competition among bacteria. "Many organisms, including humans, acquire bacteria from their environment," said Tim Miyashiro, a biochemist and molecular biologist at Penn State and the leader of the research team. "These bacteria can contribute to functions within the host organism, like how our gut bacteria help us digest food. We're interested in the interactions among bacteria cells, and between bacteria and their hosts, to better understand these mutually beneficial symbiotic relationships." Cells of the bioluminescent bacteria Vibrio fisheri take up residence in the light organ of newly hatched bobtail squid. At night, the bacteria produce a blue glow that researchers believe obscures a squid's silhouette and helps protect it from predators. The light organ has pockets, or crypts, in the squid's skin that provide nutrients and a safe environment for the bacteria. "When the squid hatches, it doesn't yet have any bacteria in its light organ," said Miyashiro. "But bacteria in the environment quickly colonize the squid's light organ." Some of these different bacteria strains can coexist, but others can't. "Microbial symbioses are essentially universal in animals, and are crucial to the health and development of both partners," says Irwin Forseth, a program director in the National Science Foundation's Division of Integrative Organismal Systems, which funded the research. "The results from this study highlight the role small genetic changes can play in microbe interactions. Increased understanding will allow us to better predict organisms' performance in changing environments."

Image credit: Andrew Cecere




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Could graphene-lined clothing prevent mosquito bites?

Full Text:

A new study shows that graphene sheets can block the signals mosquitoes use to identify a blood meal, potentially enabling a new chemical-free approach to mosquito bite prevention. Researchers showed that multilayer graphene can provide a twofold defense against mosquito bites. The ultra-thin yet strong material acts as a barrier that mosquitoes are unable to bite through. At the same time, experiments showed that graphene also blocks chemical signals mosquitoes use to sense that a blood meal is near, blunting their urge to bite in the first place. The findings suggest that clothing with a graphene lining could be an effective mosquito barrier.

Image credit: Hurt Lab/Brown University




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Square launches Online Checkout for SMEs

US-based digital payments company Square has launched...




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Square launches Online Checkout for SMEs

US-based digital payments company Square has launched Square Online Checkout, designed for SMEs looking to transition to ecommerce.




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Genetic redundancy aids competition among symbiotic bacteria in squid

Full Text:

The molecular mechanism used by many bacteria to kill neighboring cells has redundancy built into its genetic makeup, which could allow for the mechanism to be expressed in different environments, say researchers at Penn State and the University of Wisconsin-Madison. Their new study provides insights into the molecular mechanisms of competition among bacteria. "Many organisms, including humans, acquire bacteria from their environment," said Tim Miyashiro, a biochemist and molecular biologist at Penn State and the leader of the research team. "These bacteria can contribute to functions within the host organism, like how our gut bacteria help us digest food. We're interested in the interactions among bacteria cells, and between bacteria and their hosts, to better understand these mutually beneficial symbiotic relationships." Cells of the bioluminescent bacteria Vibrio fisheri take up residence in the light organ of newly hatched bobtail squid. At night, the bacteria produce a blue glow that researchers believe obscures a squid's silhouette and helps protect it from predators. The light organ has pockets, or crypts, in the squid's skin that provide nutrients and a safe environment for the bacteria. "When the squid hatches, it doesn't yet have any bacteria in its light organ," said Miyashiro. "But bacteria in the environment quickly colonize the squid's light organ." Some of these different bacteria strains can coexist, but others can't. "Microbial symbioses are essentially universal in animals, and are crucial to the health and development of both partners," says Irwin Forseth, a program director in the National Science Foundation's Division of Integrative Organismal Systems, which funded the research. "The results from this study highlight the role small genetic changes can play in microbe interactions. Increased understanding will allow us to better predict organisms' performance in changing environments."

Image credit: Andrew Cecere




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Could graphene-lined clothing prevent mosquito bites?

Full Text:

A new study shows that graphene sheets can block the signals mosquitoes use to identify a blood meal, potentially enabling a new chemical-free approach to mosquito bite prevention. Researchers showed that multilayer graphene can provide a twofold defense against mosquito bites. The ultra-thin yet strong material acts as a barrier that mosquitoes are unable to bite through. At the same time, experiments showed that graphene also blocks chemical signals mosquitoes use to sense that a blood meal is near, blunting their urge to bite in the first place. The findings suggest that clothing with a graphene lining could be an effective mosquito barrier.

Image credit: Hurt Lab/Brown University




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Mosquito pesticide causes knock on problems for birds

Pesticides that kill mosquitoes could have indirect effects on other species, according to researchers. The study indicated that a well-known mosquito insecticide led to reduced numbers of eggs and chick survival for house martin birds.




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Predicting the spread of the tiger mosquito in Europe

Researchers have identified areas of Italy that have a climate capable of sustaining a population of tiger mosquitoes, an invasive mosquito species that can carry several human diseases. The findings also indicate how these areas will expand as the climate changes in future.




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Cortex 97: The Share Square

Grey has been doing headphone testing, Myke has a big new project, and they are both dealing with sizeable disruptions.




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Sensational flavour and lively atmosphere at Thai Square in St Albans

Here in St Albans Thai Square can be found in the historical quarter of the city on the corner of George Street. The entrance of Thai Square is flanked by two stone elephants with their trunks fortuitously elevated. We open the door to a richly decorated lobby.




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Camouflage scheme: Squid glows to escape predators

Video: Learn about the bobtail squid and its interesting relationship with beneficial bacteria.




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11 natural mosquito bite remedies

Want to ditch that annoying itch from mosquito bites? These natural remedies can provide itch relief so you can get back to enjoying the great outdoors.




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Prime parking: Tesla Roadster parks in Moscow's Red Square

During the Russian leg of the Odyssey of Pioneers tour, the Tesla Roadster received clearance to park in Moscow’s famed Red Square.




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Giant squid caught on camera in U.S. waters

Researchers funded by NOAA record footage of a giant squid in U.S. waters, and the discovery is magnificent.




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Rare encounter with piglet squid leaves deep sea explorers at a loss for scientific words

Deep sea explorers capture video of a rare encounter with a piglet squid, so named because it appears to have a snout.




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Mary Ann Esposito’s Yellow Squash Salad with Grana Padano

The chef of PBS’ long running “Ciao Italia” taught me to make this flavorful, seasonal salad that would be a perfect side dish for Thanksgiving.




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The most common types of winter squash (and how they taste)

There's more to winter gourds than butternut squash. Here are just a few winter squashes and gourds you might want to consider for your dinner table.




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Deserts don't just absorb carbon dioxide, they squirrel it away for safekeeping

This surprising discovery won't be enough to stop climate change, but it will help, researchers say.



  • Climate & Weather

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How mosquitoes spread microplastics

A study found that microplastics can be kept inside water-dwelling creatures, like mosquitoes, as they age.



  • Wilderness & Resources

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The scrubbing, scouring and squeegeeing robots of CES

While they may lack a certain je ne sais quoi possessed by Rosie, there are machines out there wiling to clean your filthy windows and BBQ grill.



  • Gadgets & Electronics

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Is squatting the new standing?

Here's why you should squat instead of sitting or standing throughout the day.



  • Fitness & Well-Being

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Students revive extinct squash with 800-year-old seeds

Seeds found during an archaeological dig on First Nations land revive a long-lost varietal.



  • Organic Farming & Gardening

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5 eggnog-esque creamy holiday drinks

Shake up your holiday drink options with these creamy cocktails that aren't eggnog.




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Farm-to-Table restaurants rule Esquire's top 20 list

Eight of Esquire's top 20 new restaurants of 2010 emphasize local and sustainable foods.



  • Organic Farming & Gardening

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Why the future of West Virginia's rare flying squirrel looks bright

It's been 5 years since the West Virginia northern flying squirrel came off the Endangered Species List, and the recovery rate is encouraging.




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15 useful facts about Zika mosquitoes

The mosquitoes that transmit Zika virus are wily, but if you understand their biology, it is possible to keep them in check.



  • Fitness & Well-Being