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Reflections on Practice : Access to Health Care / directed by: Nettie Wild ; production agencies: National Film Board of Canada (Montreal), British Columbia Centre for Disease Control. Street Nurse Program (Vancouver)

Montreal : National Film Board of Canada, 2019




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Food access is about equitable agrifood systems

Addressing food inequality and ensuring that everyone has access to nutritious food are essential steps




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Reimagining access to justice

In a nation where ‘justice for all’ has long been a constitutional dream, Third-Party Litigation Funding might help turn it into reality




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Pyrrolylsulfonium salts: stable, accessible and versatile pseudohalides for Stille couplings

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01793E, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jodie L. Hann, Catherine L. Lyall, Gabriele Kociok-Köhn, Simon E. Lewis
Pyrroles functionalised with a thianthrenium or diphenylsulfonium group undergo Stille couplings with aryl or alkynyl stannanes in good yields, avoiding the issues of instability that can hamper the use of the analogous pyrrolyl halides.
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I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01801J, Research Article
Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
An I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.
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General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01698J, Research Article
Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen Xu
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
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Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01841A, Research Article
Xunhua Wang, Jianhua Wang, Xiaoxun Li
A gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.
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Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives

Org. Chem. Front., 2024, 11,6380-6384
DOI: 10.1039/D4QO01329H, Research Article
Hang Luo, Fangnian Yu, Luqing Lin
The photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.
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Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
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LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01678E, Research Article
Open Access
Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar Goreti
LiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.
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Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01844C, Research Article
Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
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DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01512F, Research Article
Rahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez Khan
A new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...
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Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01879F, Research Article
Yuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin Fan
Oxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...
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Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01734J, Research Article
Yuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing Li
Transition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...
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Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
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Empowerment campaign enhances access of differently-abled persons in Barmer

The initiative has ensured a hassle-free process of obtaining disability certificates and saved the time of differently abled persons to travel all the way to the district headquarters to appear before the Medical Board




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65% of millennials prefer digital gold over traditional for its ease of access and convenience: Moneyview survey

Digital gold can be easily converted to cash or physical gold, giving investors flexibility to trade without incurring heavy transaction costs or delays



  • Gold & Silver

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Rise in liver transplants in Kerala MCHs due to lower cost, better access

Liver transplant surgeries now available in government medical colleges in Kerala, offering affordable options for patients in need.




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Can farmers get better access to finance?

Samir Shah, MD & CEO of NCDEX, talks about commodity repository and the role it can play in lowering borrowing cost for farmers




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RBI asks banks to ensure easier accessibility for payment systems to persons with disabilities

RBI instructs banks to review payment systems for accessibility to persons with disabilities, ensuring digital payment inclusivity




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The Hindu Lit Fest 2024 | ‘Mutual funds give access to equity, debt and gold through one route,’ says Monika Halan

The author of Let’s Talk Mutual Funds on why mutual funds should be a part of the Indian investor’s portfolio




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Aadhaar biometric data access will aid forensics

While the Aadhaar Act’s provisions on core biometric information help in protecting privacy, there is a compelling case in re-evaluating these restrictions in specific contexts




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CoQ10 bioaccessibility and Caco-2 cell uptake improved with novel medium chain triglyceride encapsulation

Food Funct., 2024, 15,10981-10986
DOI: 10.1039/D4FO02844A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ziqi Li, Rachel E. Kopec
Coenzyme Q10 (CoQ10), a key component of the electron transport chain, is better micellarized and absorbed by intestinal cells following novel encapsulation with MCTs + phospholipid.
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Corn cob and corn silk-based ingredients exhibit bioaccessible and antioxidant phenolic compounds displaying anti-inflammatory effects in vitro

Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO02968B, Paper
Yessica Rubí Hernández-García, Ivan Luzardo-Ocampo, Gaytán-Martínez Marcela, G. Loarca-Pina, Estela Vázquez Barrios, Rocio Campos-Vega
The poor disposal and lack of corncob (CC) and cornsilk (CS) utilization generate environmental problems. This research aimed to develop CC and CS-based ingredients (1:1, 1:2, and 2:1 mixtures), evaluate...
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Making higher education an accessible public good

Through interest subvention and guarantee cover for banks, PM-Vidyalaxmi should help create a more skilled workforce




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Pregnancy is still a barrier in accessing employment

The legislature must recognise that medical certifications, physical tests, and arbitrary disqualification criteria are used to deny pregnant persons their employment opportunities




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Chennai hosts Crafts Council of India’s textiles and accessories show on August 9 and 10

The two-day exhibition organised by Crafts Council of India will see a gamut of weaves from across the country on display



  • Life & Style

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Extend Madurai-Punalur Express to Nagapattinam or Karaikal for better access to Sri Lanka ferry service, railways urged




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Decathlon India partners with Zepto to expand access to sporting goods

This collaboration aims to provide quick and easy access to Decathlon’s extensive portfolio of sports products, including fitness, outdoor, water sports, team sports, and more through the Zepto platform




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Accessorise your garden

Plant coriander in your shoe, hang a fern from your window, throw in a duck or two, and there’s your unique green space.




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WazirX proposes launching decentralised exchange and recovery token as investors wait to access locked up crypto

WazirX proposed launching a decentralised exchange as well as a recovery token for outstanding debt settlement, as users are unable to access their existing crypto




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Vulnerabilities reported in Apple devices impact iPhone, iPad and Macs, attackers may access sensitive information  

CERT-In, part of MeitY, has issued a warning for high-risk vulnerabilities in multiple Apple products including iPhones, iPads, Macs Apple Watch and Safari 




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Modular access to multi-substituted allenones via environmentally friendly organocatalytic C–H allenylation of aldehydes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04550E, Paper
Xinying Hu, Ayisenbati Jialingbieke, Yuzhi Ren, Yifan Yang, Donghui Wei, Jian Gao, Ding Du
Organocatalytic direct C–H allenylation of aldehydes with propargyl bromides has provided a straightforward and step-economical strategy for allenone modular synthesis.
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High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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It’s not social constraints or access anymore — women are held back by lack of employment opportunities




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Is This Working? Assessment and Evaluation Methods Used to Build and Access Language Services in Social Services Agencies In Social Services Agencies

The enactment of President Clinton’s Limited English Proficiency (LEP) Executive Order, issued in 2000, triggered a proliferation of efforts to provide services to individuals who cannot speak, understand, read, or write English fluently. With increased service provision, state and local government agencies have expressed a strong and growing interest in assuring the quality and cost-effectiveness of language access services. This paper attempts to catalog and describe some of those tools and practices.




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Proactive Engagement: Two Strategies for Providing Language Access in Workforce Development Services

This interactive language access webinar, one in a series offered by the Migration Policy Institute's National Center on Immigrant Integration Policy, examines how New York and Illinois have broken down some of these barriers to proactively engage LEP communities to obtain workforce services.




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Proactive Engagement: Two Strategies for Providing Language Access in Workforce Development Services

This webinar examines how New York and Illinois have proactively engaged Limited English Proficient (LEP) communities to obtain workforce services.




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LEP Workers & Access to Workforce Services: Perspectives on Current Barriers to Access and Prospects for Improvements Under WIA Reauthorization

In this webinar, experts discuss barriers immigrant and LEP individuals face in accessing the WIA system, how a revitalized WIA could address these barriers, and the extent to which the current Senate Health, Education, Labor, and Pensions (HELP) Committee's WIA reauthorization proposal addresses these barriers.




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Language Access and Schools: Federal Requirements and School Experiences

This is the latest in NCIIP’s language access webinar series exploring the policy and program implementation imperatives for government and community agencies serving Limited English Proficient (LEP) populations.




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Language Access and Schools: Federal Requirements and School Experiences

This webinar from the MPI’s National Center on Immigrant Integration Policy and the U.S. Conference of Catholic Bishops’ Bridging Refugee Youth & Children’s Services program explores federal requirements for providing interpretation and translation in schools and how select school districts in Minnesota and Colorado have managed these requirements.




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Federal Update: A Conversation on Language Access with the U.S. Department of Justice

This MPI webinar features U.S. Department of Justice (DOJ) officials discussing the department’s efforts to improve communications with Limited English Proficient (LEP) communities in federal and federally-funded programs and activities.




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Federal Update: A Conversation on Language Access with the U.S. Department of Justice

This MPI webinar features U.S. Department of Justice (DOJ) officials discussing the department’s efforts to improve communications with Limited English Proficient (LEP) communities in federal and federally-funded programs and activities.




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Making It Work: Lessons in Collaboration on Language Access Contracting

A webinar on language access contracting for federal, state, and local officials, agency administrators, and community stakeholders concerned with the oversight and implementation of language access provision.




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Making It Work: Lessons in Collaboration on Language Access Contracting

A webinar on language access contracting for federal, state, and local officials, agency administrators, and community stakeholders concerned with the oversight and implementation of language access provision.




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Moving Up or Standing Still? Access to Middle-Skilled Work for Newly Arrived Migrants in the European Union

The global economic crisis and changing migration patterns in Europe bring up questions about how well immigrants are able to find employment and progress into better jobs over time. This overview report caps a series of six country case studies evaluating the employment outcomes for foreign-born workers during their first decade in the Czech Republic, France, Germany, Spain, Sweden, and the United Kingdom.




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Cross-Cutting Needs and Opportunities: Language Access, Funding, Multi-Level Partnerships, and Planning for the Long Term

Part of a series exploring issues likely to be addressed by the new National Integration Plan, this webinar, with perspectives from the cities of New York and Seattle and others delves into possible recommendations on federal coordination of local government immigrant integration initiatives, including language access. 




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Cross-Cutting Needs and Opportunities: Language Access, Funding, Multi-Level Partnerships, and Planning for the Long Term

Part of a series exploring issues likely to be addressed by the new National Integration Plan, this webinar, with perspectives from the cities of New York and Seattle and others examines possible recommendations on federal coordination of local government immigrant integration initiatives, including language access. 




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It is Time for Federal Agencies to Do More to Improve the Provision of Language Access Services

Whether driven by pragmatism, local laws, or federal civil-rights provisions, state and local governments and agencies across the United States increasingly have designed and implemented language access services (i.e. translation and interpretation) in response to growing Limited English Proficient populations. This commentary argues it is time for the federal government to follow suit.