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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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AgCare Tech launches digital marketplace for agri inputs

‘Golden Farms’ is designed to digitise the agricultural input supply chain




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Zinc futures may bounce off ₹275

Traders can buy on a dip and look for a target of ₹290 




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MCX launches cottonseed wash oil futures contract

It will offer a robust price risk management solutions for the cottonseed oil industry




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MCX to launch monthly gold option contract

MCX reduces gold option expiry to monthly, improving liquidity and attracting more participants, benefiting jewellers and increasing revenue




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Crude check: Outlook is uncertain

Traders can stay out for now




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Storage in key Indian reservoirs unchanged for 3rd week in a row

They are higher than normal, filled to 87 per cent of the 180.852 BCM capacity




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Centre launches mobile app for grievance redressal of rice millers

Move to enchance transparency, accountability




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NSRCEL launches second cohort of Circular Economy programme

Pernod Ricard India Foundation to offer continued support




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Storage in India’s key reservoirs unchanged for 4th week in a row

The 155 major reservoirs were filled to 87 per cent of capacity; level in 4 States below normal




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Blue Pearl, a new fish farmer producer company launched in Kodungallur

Highlighting the rapid growth of the fisheries sector, the Minister said the Centre has outlined several schemes dedicated to strengthening the fisheries sector




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Gujarat launches procurement of soyabean, urad & moong from farmers

Under the Price Support Scheme (PSS), purchases will be conducted over 90 days from 3.7 lakh farmers who have registered for this scheme




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Cochin International Airport announces winter schedule with 1,576 weekly operations 

As per the new winter schedule, the total number of weekly services to UAE alone will be 134




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New terminal operating system and bunching of ships disrupt truck movements at Kattupalli and Ennore container terminals

While the issue with the of TOS has been addressedsorted out, the trailers are still facing delays in the scanning centre




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IRCTC Q2 net profit up 4.5%, interim dividend announced

Revenue from operations during the period under review stood at Rs ₹1064 crore, up 7.3 per cent y-o-y




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PM Modi announces new airport near Vadhavan Port in Maharashtra

Prime Minister Maharashtraannounces new airport near Vadhavan Port in Maharashtra, valued at ₹76,220 crore, during BJP election campaign




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SpiceJet to relaunch seaplane service next year 

SpiceJet had introduced a seaplane service in October 2020, operations of which were suspended within a few months citing Covid-19 restrictions




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Odisha start-up launches fully made-in-India, autonomous logistics drone service

Air Orca is fully designed, developed and manufactured in India by Odisha-based start-up Bon V Aero and is equipped to serve as a first responder in post-disaster scenarios




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AWS launches Amazon Digital Suite to enable digital transformation for Indian SMBs

Provides a broad selection of business software for B2C and B2B customers




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Dozee launches MillionICU initiative for critical care infrastructure

Central monitoring cells allow for remote parient monitoring




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Boronic ester-templated pre-rotaxanes as versatile intermediates for rotaxane endo-functionalisation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04879B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jingjing Yu, Marius Gaedke, Satyajit Das, Daniel L. Stares, Christoph A. Schalley, Fredrik Schaufelberger
Dynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.
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Delocalization error poisons the density-functional many-body expansion

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05955G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dustin R. Broderick, John M. Herbert
Self-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.
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Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05707D, Perspective
Open Access
Naoki Ogiwara, Wei Zhou, Sayaka Uchida
Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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Triple-Function Porphyrin in Glycopolymeric Photosensitizer: From PhotoATRP to Targeted PDT

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06466F, Edge Article
Open Access
Jiahui Lin, Zhiyuan Ma, Weiwei Zuo, Meifang Zhu
Porphyrin derivatives serve as photocatalysts in reversible-deactivation radical polymerization and as photosensitizers in photodynamic therapy (PDT). Herein, a triple function porphyrin, ZnTPPC6Br, was synthesized as photocatalyst and initiator for photoATRP....
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Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05396F, Edge Article
Open Access
Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff Zaleski
Using a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...
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Landing the right punch

Andre Rodrigues test drives the latest iteration of the WWE video game and is delighted with the game’s animation and fighting system




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Axis MF launches Nifty500 Value 50 Index Fund




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Detailed probe launched into fire at commercial unit near Aluva




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Union Cabinet announces economic decisions worth over ₹2.88-lakh crore

These include the MSP hike for 14 Kharif crops, Varanasi airport expansion, and a new major port at Vadhavan




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Govt announces guidelines for funding testing facilities under National Green Hydrogen Mission

With a budget of ₹200 crore till FY26, the scheme aims to support the development of standards and regulatory frameworks in the Green Hydrogen sector.




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Oil Ministry announces plans for energy security fund

The Minister highlighted the importance of creating an energy security fund and exploring rare earth minerals




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Budget 2024: ₹5,000 monthly internship allowance announced for 1 crore youth

Internship scheme aims to create job opportunities in top 500 companies over next five years




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Andhra to announce new industrial, liquor policies soon

Pharma, automobiles, mining, energy and shipping, likely to be given special thrust by the State Government




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NFRA-ICAI tussle over key audit standard overhaul: CA Institute Council to meet on Sep 17 to discuss future strategy

ICAI to debate NFRA’s plan to overhaul audit standard SA600, fearing concentration of market in few hands




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Govt to launch another PLI scheme for speciality steel: Steel Secy

Speciality steel is an area where more needs to be done, says Steel Secretary Sandeep Poundrik




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Kawasaki Ninja ZX-6R Launched




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2024 Land Rover Discovery Sport launched




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Punching above its weight

The Tata Punch.ev looks impressive on paper, but how good is it?




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Hero Mavrick 440: Unconventional?

Hero MotoCorp’s new flagship is a bucketful of rights and only a few wrongs




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Fiat announces global revival

Fiat has revealed some futuristic concepts based on the much-loved Panda, namely a city car, a fastback, a family SUV, a camper, and a pickup truck




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BMW 620d M Sport Signature launched

Priced at ₹78.90 lakh, ex-showroom, the tech-laden car is powered by a 2-litre diesel engine




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BMW M4 Competition M xDrive launched

This all-wheel-drive version is priced at ₹1.53 crore




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MG 100-Year Limited Editions launched 

The prices of special editions start from ₹9.40 lakh for the Comet EV, ₹14.81 lakh for the Astor, ₹21.20 lakh for the Hector, and ₹24.18 lakh for the ZS EV




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Tata Altroz teaser released ahead of launch 

Powering the car is going to be a Nexon-sourced 1.2-litre turbocharged petrol engine claimed to make 118 bhp and 17.33 kg-m.




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BMW F 900 GS Series launched




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TN Health Dept to launch 25 bike ambulances with Rs 1.60 crore allocation




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Bengal Governor launches self-defence course 'Abhaya Plus' for girls




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NIH-funded scientists uncover clues to precancer and tumor biology

New studies released by NCI’s Human Tumor Atlas Network explore the role of the tumor microenvironment and the immune system in promoting the spread of cancer and its resistance to treatment. The studies appear across several Nature journals.