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A C8P monolayer with cross-sp-hybridized phosphorus atoms and ultrahigh energy density as a K-ion battery anode

J. Mater. Chem. A, 2024, 12,30842-30849
DOI: 10.1039/D4TA04961F, Paper
Xu Yan, Sheng Wang, Shicong Ding, Javed Rehman, Yong Liu, Guochun Yang
The proposed C8P monolayer and its derivatives are promising candidates as anode materials for high performance K-ion batteries.
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Highly sensitive OFET based room temperature operated gas sensors using a thieno[3,2-b]thiophene extended phthalocyanine semiconductor

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03208J, Paper
Recep Isci, Ozgur Yavuz, Sheida Faraji, Dilara Gunturkun, Mehmet Eroglu, Leszek A. Majewski, Ismail Yilmaz, Turan Ozturk
A novel thienothiophene (TT) and phthalocyanine (Pc) based conjugated material was designed, synthesized, fabricated for an organic field effect transistor (OFET) and utilized as an OFET based gas sensor for hazardous gases such as NO2 and SO2.
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Strain and U driven phase transitions in monolayer intrinsic ferrovalley NbIn2As2Se2

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03637A, Paper
Jiajun Zhu, Heyun Zhao, Wanbiao Hu
Strain and U value driven topological phase transitions in monolayer NbIn2As2Se2.
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An E/Z isomer strategy of photosensitizers with tunable generation processes of reactive oxygen species

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03028A, Paper
Xiaochun Liu, Hairong Li, Hui Tang, Ning Ma, Shiyu Wu, Wenbo Dai, Yahui Zhang, Xiaoqi Yu
An E/Z isomer strategy was designed to precisely regulate the type of ROS and enable tumor imaging and PDT.
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A strain-sensitive neuromorphic device emulating mechanoreception for different skin sensitivities

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03607G, Communication
Shubhanshi Mishra, Bhupesh Yadav, Giridhar U. Kulkarni
A strain-sensitive neuromorphic device mimics mechanoreception, adapting to skin-like sensitivities. Embedded Au microwires in PDMS detect strain and display neuromorphic functionalities, closely replicating biological mechanosensory functions.
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Synergistic bio-inspired photocatalytic hydrogen production by chlorophyll derivative sensitized Nb2CTx MXene nanosheets

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04074K, Paper
Tianfang Zheng, Lin Yang, Hai Xu, Aijun Li, Shin-ichi Sasaki, Xiao-Feng Wang
A novel bio-inspired composite system consists of chlorophyll (Chl) and Nb2CTx nanosheets is synthesized for synergistic photocatalytic hydeogen production.
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Understanding deNOx mechanisms in transition metal exchanged zeolites

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00468F, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jamal Abdul Nasir, Andrew M. Beale, C. Richard A. Catlow
Transition metal-containing zeolites have received considerable attention, owing to their application in the selective catalytic reduction of NOx. To understand their chemistry, both structural and mechanistic aspects at the atomic level are needed.
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Current development, optimisation strategies and future perspectives for lead-free dielectric ceramics in high field and high energy density capacitors

Chem. Soc. Rev., 2024, 53,10761-10790
DOI: 10.1039/D4CS00536H, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hareem Zubairi, Zhilun Lu, Yubo Zhu, Ian M. Reaney, Ge Wang
This review highlights the remarkable advancements and future trends in bulk ceramics, MLCCs and ceramic thin films for lead-free high field and high energy density capacitors.
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Experimental factors influencing the bioaccessibility and the oxidative potential of transition metals from welding fumes

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D3EM00546A, Paper
Manuella Ghanem, Laurent Y. Alleman, Davy Rousset, Esperanza Perdrix, Patrice Coddeville
Experimental conditions such as extraction methods and storage conditions induce biases on the measurement of the oxidative potential and the bioaccessibility of transition metals from welding fumes.
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A high-performance and self-powered polarization-sensitive photoelectrochemical-type Bi2O2Te photodetector based on a quasi-solid-state gel electrolyte

Mater. Horiz., 2024, 11,1710-1718
DOI: 10.1039/D3MH01882B, Communication
Song Yang, Shujie Jiao, Yiyin Nie, Yue Zhao, Shiyong Gao, Dongbo Wang, Jinzhong Wang
A quasi-solid-state photoelectrochemical-type Bi2O2Te photodetector exhibits excellent linear polarized light detection capability.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Elucidating the impact of oxygen functional groups on the catalytic activity of M–N4–C catalysts for the oxygen reduction reaction: a density functional theory and machine learning approach

Mater. Horiz., 2024, 11,1719-1731
DOI: 10.1039/D3MH02115G, Communication
Liang Xie, Wei Zhou, Yuming Huang, Zhibin Qu, Longhao Li, Chaowei Yang, Yani Ding, Junfeng Li, Xiaoxiao Meng, Fei Sun, Jihui Gao, Guangbo Zhao, Yukun Qin
While current experimental and computational studies often concentrate on introducing external structures or idealized MN4 models, we emphasize the often-overlooked impact of inherent OGs within the carbon structure of MN4 materials, presenting a new perspective on their catalytic activity origin.
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Excellent thermomagnetic power generation for harvesting waste heat via a second-order ferromagnetic transition

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH02225K, Communication
Haodong Chen, Xianliang Liu, Yao Liu, Longlong Xie, Ziyuan Yu, Kaiming Qiao, Mingze Liu, Fengxia Hu, Baogen Shen, R. V. Ramanujan, Ke Chu, Hu Zhang
NiMnIn Heusler alloys with second-order ferromagnetic transition show good thermomagnetic generation (TMG) performance with zero hysteresis and a long-term service life, enabling them to be better candidates for practical applications of TMG.
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Multicolor vision perception of flexible optoelectronic synapse with high sensitivity for skin sunburn warning

Mater. Horiz., 2024, 11,1934-1943
DOI: 10.1039/D3MH02154H, Communication
Yaqian Yang, Ying Li, Di Chen, Guozhen Shen
We propose a self-powered flexible optoelectronic synapse based on PEA2SnI4 films for multicolor vision perception and skin sunburn warning.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An ultra-soft conductive elastomer for multifunctional tactile sensors with high range and sensitivity

Mater. Horiz., 2024, 11,1975-1988
DOI: 10.1039/D3MH02074F, Communication
Ao Yin, Ruiguang Chen, Rui Yin, Shiqiang Zhou, Yang Ye, Yuxin Wang, Peike Wang, Xue Qi, Haipeng Liu, Jiang Liu, Suzhu Yu, Jun Wei
Our study shows an ultra-soft conductive material with excellent adhesive ability to solve the mismatch of the interface. With coupled microstructures, our sensor demonstrates a remarkable sensitivity and a fast response time.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A moment for just transition litigation to take wing

The core issue in the M.K. Ranjitsinh case — the protection of the Great Indian Bustard in energy projects — can be used to facilitate equitable and inclusive climate action




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Multi-purpose transit yard on the cards on Kozhikode North Beach

Kerala Maritime Board invites Expression of Interest to proceed with the public-private partnership project on its 2.5 acres of beachfront property in Kozhikode city




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Twins Support Absence of Parity-Dependent Fertility Control in Pre-Transition Western European Populations [electronic journal].




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Transition from plan to market, height and well-being [electronic journal].




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Structural Change and the Fertility Transition [electronic journal].




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The Sensitivity of Cash Savings to the Cost of Capital [electronic journal].

National Bureau of Economic Research




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The permanent-transitory confusion: Implications for tests of market efficiency and for expected inflation during turbulent and tranquil times [electronic journal].




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Pareto-improving transition to fully funded pensions under myopia [electronic journal].




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Macro Recruiting Intensity from Micro Data [electronic journal].

National Bureau of Economic Research




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Implications of the permanent-transitory confusion for New-Keynesian modeling, inflation forecasts and the post-crisis era [electronic journal].




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The impact of sanctions for young welfare recipients on transitions to work and wages and on dropping out [electronic journal].




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How Far Can Economic Incentives Explain the French Fertility and Education Transition? [electronic journal].




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Heterogeneous Tax Sensitivity of Firm-level Investments [electronic journal].




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Hedge Fund Performance: Are Stylized Facts Sensitive to Which Database One Uses? [electronic journal].




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Good for the Environment, Good for Business: Foreign Acquisitions and Energy Intensity [electronic journal].




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From Fixed-event to Fixed-horizon Density Forecasts: Obtaining Measures of Multi-horizon Uncertainty from Survey Density Forecasts [electronic journal].




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Falling Behind and Catching up: India's Transition from a Colonial Economy [electronic journal].




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Exposure to Transit Migration, Public Attitudes and Entrepreneurship [electronic journal].




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The Economics of Urban Density [electronic journal].

National Bureau of Economic Research




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Economic Transition and the Rise of Alternative Institutions: Political Connections in Putin's Russia [electronic journal].




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The economic effects of density: A synthesis [electronic journal].




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Delineating Urban Areas Using Building Density [electronic journal].

National Bureau of Economic Research




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Automobiles and urban density [electronic journal].




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Gelation-induced controlled synthesis of TiO2 with tunable phase transition for efficient photocatalytic hydrogen evolution

Inorg. Chem. Front., 2024, 11,2178-2186
DOI: 10.1039/D4QI00193A, Research Article
Wenwei Lei, Ying Wang, Hongji Wang, Norihiro Suzuki, Chiaki Terashima, Akira Fujishima
A facile gelation-assisted coordination self-assembly method for mediated fabrication of TiO2 photocatalysts with controlled phase structures and morphologies is presented, showing excellent photocatalytic hydrogen production performance.
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Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00218K, Research Article
Huajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong Lu
Benefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.
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Achieving high-sensitivity dual-mode optical thermometry via phonon-assisted cross-relaxation in a double-perovskite structured up-conversion phosphor

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00395K, Research Article
Houhe Dong, Zonghao Lei, Shikun Su, Wenhua Yang, Xuyang Zhang, Wenying Teng, Guangyue Zu, Bing Teng, Degao Zhong
By adjusting the phonon energy of the host crystal (Ca2+/Sr2+/Ba2+) LaLiTeO6:Yb3+, Tm3+ phosphor, combined with the cross-relaxation phenomenon, a high-sensitivity thermometer for dual-mode temperature measurement was constructed.
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Structural phase transition drives outright photoluminescence quenching and dielectric duple bistable switching

Inorg. Chem. Front., 2024, 11,2290-2299
DOI: 10.1039/D4QI00303A, Research Article
Open Access
Zhi-Jie Wang, Ming-Jing Shen, Zhi-Peng Rao, Pei-Zhi Huang, Meng-Meng Lun, Bo-Wen Deng, Jun-Yi Li, Chang-Feng Wang, Hai-Feng Lu, Da-Wei Fu, Yi Zhang
(TECA)PbBr3 and (TEBA)PbBr3 have a wide range of photoluminescence signals and undergo coupling of the structural phase transition and photoluminescence quenching.
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Energetic copper(II) quadridentate chelate: a novel green laser-sensitive primary explosive

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00489B, Research Article
Qi Zhang, Ruibing Lv, Ying Wang, Zhenghang Luo, Pengyang Pan, Tingwei Wang, Quancheng Liu
A copper(II)-based quadridentate chelate [Cu(BNATE)·2H2O] has been prepared and systematically studied. It has excellent near-infrared laser sensitivity and detonation performance, and low mechanical sensitivity.
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Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
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Is aromaticity loss necessary for transition-metal promoted arene–alkene cycloadditions?

Chem. Sci., 2024, 15,18093-18098
DOI: 10.1039/D4SC05337K, Edge Article
Open Access
João V. Schober, Croix J. Laconsay, Judy I. Wu
Diene- and ene-like reactivity in transition metal coordinated arenes can be expected when there is a notable degree of aromaticity loss at the complexed arene.
The content of this RSS Feed (c) The Royal Society of Chemistry




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On-demand controlled bidirectional DNAzyme path for ultra-sensitive heavy metal ion detection

Chem. Sci., 2024, 15,18170-18178
DOI: 10.1039/D4SC04404E, Edge Article
Open Access
Jing Xu, Yujin Li, Futing Wang, Xinqi Luo, Wei Zhang, Yifan Lyu, Hongfen Yang, Ren Cai, Weihong Tan
A bidirectional self-powered biosensor is constructed for the quasi-simultaneous detection of Pb2+ and Hg2+ based on MoS2@CuS heterostructures as an accelerator and hybridization chain reaction as a signal amplification strategy.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Unified enantiospecific synthesis of drimane meroterpenoids enabled by enzyme catalysis and transition metal catalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06060A, Edge Article
Open Access
Yipeng You, Xue-Jie Zhang, Wen Xiao, Thittaya Kunthic, Zheng Xiang, Chen Xu
A unified synthetic strategy for drimane meroterpenoids was developed by combining heterologous biosynthesis, enzymatic oxidation, and transition metal catalysis. Six drimane meroterpenoids were synthesized in a concise and enantiospecific manner.
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Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06820C, Review Article
Open Access
Seungwon Sun, Jisu Choe, Jaeheung Cho
In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...
The content of this RSS Feed (c) The Royal Society of Chemistry




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An ultrasensitive 2,4,6-trinitrophenol nanofluidic sensor inspired by olfactory sensory neurons in sniffer dogs

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05493H, Edge Article
Open Access
Xin Li, Zhanfang Liu, Linsen Yang, Shengyang Zhou, Yongchao Qian, Yuge Wu, Zidi Yan, Zhehua Zhang, Tingyang Li, Qingchen Wang, Congcong Zhu, Xiang-Yu Kong, Liping Wen
Inspired by sniffer dog olfactory sensory neurons, an ultrasensitive TNP detection sensor was developed by in situ growing UiO-66-NH2 layers on AAO. It exhibits a limit of detection with 6.5 × 10−16 g mL−1, offering a new method for rapid detection.
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Delocalization error poisons the density-functional many-body expansion

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05955G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dustin R. Broderick, John M. Herbert
Self-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.
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Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06403H, Edge Article
Open Access
Dan-Dan Zhou, Chun-Li Hu, Xin-Wei Zhang, Jiang-Gao Mao, Fang Kong
Successful synthesis of centrosymmetric Ga(Te3O7)Br and non-centrosymmetric M2(OH)(TeO3)(Te2O5)X (M = Al, Ga; X = Br, Cl) using a depolymerization strategy.
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