hem Christian falsely accused of blasphemy in 3 cases released on bail By www.christianpost.com Published On :: Sat, 02 Nov 2024 17:35:22 -0400 A Christian falsely charged with blasphemy in three cases was released on bail this week after prosecutors failed to produce evidence against him, his attorney said. Full Article
hem Muslim vigilantes colluding with authorities to entrap Christians in blasphemy charges By www.christianpost.com Published On :: Wed, 06 Nov 2024 01:34:01 -0500 Muslim vigilante groups are working with federal authorities to lure young people into sharing blasphemous content on social media in order to put them behind bars, according to an investigation by Pakistan’s National Commission for Human Rights Full Article
hem Lauren Daigle’s anthem 'Then I Will' brings Bonhoeffer’s faith, sacrifice to life in new film (exclusive) By www.christianpost.com Published On :: Fri, 01 Nov 2024 10:58:00 -0400 Grammy Award-winning artist Lauren Daigle has written and recorded a powerful end-title track for the new film “Bonhoeffer: Pastor. Spy. Assassin” declaring obedience to God’s calling, even in the face of death. Full Article
hem Boston Children's slashed doctors' time to assess kids before referring them for trans procedures By www.christianpost.com Published On :: Fri, 08 Nov 2024 15:12:44 -0500 A former “gender-care specialist” at Boston Children’s Hospital testified that her ex-employer slashed the time allotted for psychologists to assess minors expressing confusion about their sex before referring them for life-altering procedures. Full Article
hem Ken Burns Documentary Goes Beyond The Mythic Man of Hemingway By www.nhpr.org Published On :: Thu, 01 Apr 2021 21:18:02 +0000 A new documentary by Ken Burns and Lynn Novick is coming to PBS this month , and it's all about Ernest Hemingway. NHPR's Morning Edition host Rick Ganley sat down with both Burns and Novick to talk about the new film, their process and what makes a good documentary. [Editor's note: this is a transcript of one small part of the full interview.] Rick Ganley: But why Hemingway? Ken Burns: He's a hugely important writer and he's got a very complicated life, and we like to try to wrestled to the ground these complicated stories. And boy, this is about as wonderfully difficult as any project we've undertaken. Rick Ganley: What strikes me the most is how it goes way beyond that mythic Hemingway. This is the man's man writer image that kind of, you know, gets thrown around a lot. What surprised you most about him as you dug into the project? Lynn Novick: Kind of everything in a way, you know, in that we had some understanding of his work. We could give it like the Cliff's Notes version of his Full Article
hem Workshop 35: Jonathan Lethem By audioboom.com Published On :: Wed, 11 Jan 2017 22:22:35 -0000 Jonathan Lethem is the best-selling author of Gun, with Occasional Music, Fortress of Solitude, and other novels, including the Naitonal Book Critics' Circle award-winning Motherless Brooklyn. He's known for reanimating and remixing genres - hard-boiled crime novels, post-apocalyptic science fiction, superhero comics and even technicolor westerns. His most recent novel is called A Gambler's Anatomy. It's about a high-stakes competitive backgammon player and con artist - a character who, like Lethem, was raised in the bohemian Brooklyn of the 1970s. Episode music: "Crate Diggin" by Ari de Niro Ad music: "Joy in the Restaurant" by David Szesztay Learn more about your ad choices. Visit podcastchoices.com/adchoices Full Article
hem Russian leaders try to force themselves to like domestic cars By english.pravda.ru Published On :: Fri, 03 Aug 2018 17:12:00 +0300 Russian people will be able to learn more about the vehicles used by top officials of the country. A new book titled "First Persons' Cars" is to be released under the auspices of the Federal Guard Service (FSO). According to the author of the foreword, FSO Director, Lieutenant-General Dmitry Kochnev, readers will learn exclusive details not just about cars, but also about most protected vehicles that the Soviet Union and Russia have ever seen. It stands the reason that the vehicles that top officials use for their work play a very important role in the security of the state leader. The cars that are used today for officials taking top positions in the country were developed on the basis of decades of experience. The book is illustrated with pictures taken in the Kremlin, in the Dacha of Joseph Stalin and other prominent locations. The authors wanted to place every vehicle in the entourage for which it was created. However, the FSO director believes, all the cars that one can see in the book have one common feature: they look majestic. Full Article History traditions
hem Sanctions are working: Russia does not eat reserves, but builds them up By english.pravda.ru Published On :: Tue, 02 May 2023 20:53:00 +0300 Starting from May, Russia may start buying foreign currency for its reserves again. The country's budget has stabilized thanks to the growth of oil and gas export revenues, Bloomberg reports. The growth in revenues from the sale of energy products is already close to the target level. Since February of this year, the Russian Ministry of Finance has been selling reserves in Chinese yuan to cover the budget deficit. In April, sales collapsed by 50 percent compared to the beginning of the year. From May, purchases are likely to begin, Bloomberg notes. Such purchases can be relatively small at first — an equivalent of about $200 million in yuan. For the time being, Russia currently replenishes the National Welfare Fund only by purchasing Chinese currency. Full Article Russia
hem Wife of former San Antonio trucking magnate sentenced in multi-million-dollar fraud scheme By www.tdi.texas.gov Published On :: Tue, 16 Jul 2024 00:00:00 CDT Frances Hall, former co-owner of Bill Hall Jr. Trucking, has been sentenced for her role in a scheme to avoid $9 million in workers’ compensation premiums. Full Article
hem Common Problems with Smartphones and How to Fix Them By www.retailtechnologyreview.com Published On :: By Josh Harvey, freelance writer.In the last 15 years or so, since the first iPhone debuted all the way back in 2007, it’s not hyperbolic to suggest that smartphones have changed the very fabric of our society. The average teenager probably spends more time on their phone than off it and we all rely on them for business and pleasure, par-ticularly during those long and stressful commutes. Full Article Mobile Computers
hem Makhlai blames Uralchem for TogliattiAzot being in trouble By english.pravda.ru Published On :: Mon, 13 Sep 2021 12:26:00 +0300 The runaway owner of TogliattiAzot, Sergei Makhlai, is once again in the spotlight of Russian media. This time their interest was aroused, apparently, by the media publications sponsored by Makhlai. Recently several Russian media have suggested that the chemical giant TogliattiAzot needs a change of ownership, since the current main owners of the plant, headed by Sergei Makhlai, have ruined the enterprise and criminalized it drastically. This seriously scared Makhlai, who attempted to justify himself and lay the blame on the others. Full Article Business
hem The Solution to Death From a Fentanyl Overdose Could Lie in Its Chemical Structure By www.newswise.com Published On :: Tue, 12 Nov 2024 12:45:24 EST Scientists have identified a molecule that appears to restore normal breathing in mice following a large dose of fentanyl. Full Article
hem When Countries Hide Their True Public Debt, They Hurt Themselves, Their Citizens and Their Lenders By www.newswise.com Published On :: Thu, 07 Nov 2024 16:25:47 EST Global public debt may soon collectively catch up to the worldwide gross domestic product (GDP), likely matching it by 2030. New research from a Notre Dame economist suggests that this could happen even sooner, thanks to countries' hidden debts. This misreported debt can lead to higher interest rates for borrowers and lower recovery rates for lenders, suggesting indirect adverse effects on global financial stability and consumer welfare. Full Article
hem Media Tip: Cyberthreats Are Growing - So Are Patents for Technology to Combat Them By www.newswise.com Published On :: Tue, 12 Nov 2024 08:00:57 EST Full Article
hem 6 Common Temu Scams and How to Avoid Them By money.howstuffworks.com Published On :: Mon, 19 Aug 2024 12:12:52 -0400 Temu, the ultra-affordable online marketplace taking social media by storm, is having a huge moment. But while it’s become the go-to spot for incredible deals, the retail site is also a magnet for scammers looking to cash in on the buzz. Full Article
hem What Does a Catalytic Converter Do and Why Do People Steal Them? By auto.howstuffworks.com Published On :: Thu, 14 Mar 2024 10:49:58 -0400 Catalytic converters are one of the most important parts of a car's emissions control system. Learn about catalytic converters and catalytic converter laws. Full Article
hem 2024 BGS summer placements scheme - British Geological Survey By news.google.com Published On :: Mon, 27 May 2024 16:11:34 GMT 2024 BGS summer placements scheme British Geological Survey Full Article
hem Geochemistry and health in the Kenyan Rift Valley - British Geological Survey By news.google.com Published On :: Thu, 01 Aug 2024 11:06:32 GMT Geochemistry and health in the Kenyan Rift Valley British Geological Survey Full Article
hem A contribution to the crystal chemistry and topology of organic thiosulfates: bis(1-methylpiperazinium)·S2O3·H2O versus 1-methylpiperazinediium·S2O3·3H2O By journals.iucr.org Published On :: Crystal structure and topology of two new thiosulfates formed with mono- and diprotonated species of 1-methylpiperazine is reported. Full Article text
hem Structural and biochemical characterization of the M405S variant of Desulfovibrio vulgaris formate dehydrogenase By journals.iucr.org Published On :: 2024-05-01 Molybdenum- or tungsten-dependent formate dehydrogenases have emerged as significant catalysts for the chemical reduction of CO2 to formate, with biotechnological applications envisaged in climate-change mitigation. The role of Met405 in the active site of Desulfovibrio vulgaris formate dehydrogenase AB (DvFdhAB) has remained elusive. However, its proximity to the metal site and the conformational change that it undergoes between the resting and active forms suggests a functional role. In this work, the M405S variant was engineered, which allowed the active-site geometry in the absence of methionine Sδ interactions with the metal site to be revealed and the role of Met405 in catalysis to be probed. This variant displayed reduced activity in both formate oxidation and CO2 reduction, together with an increased sensitivity to oxygen inactivation. Full Article text
hem Open-source electrochemical cell for in situ X-ray absorption spectroscopy in transmission and fluorescence modes By journals.iucr.org Published On :: 2024-02-02 X-ray spectroscopy is a valuable technique for the study of many materials systems. Characterizing reactions in situ and operando can reveal complex reaction kinetics, which is crucial to understanding active site composition and reaction mechanisms. In this project, the design, fabrication and testing of an open-source and easy-to-fabricate electrochemical cell for in situ electrochemistry compatible with X-ray absorption spectroscopy in both transmission and fluorescence modes are accomplished via windows with large opening angles on both the upstream and downstream sides of the cell. Using a hobbyist computer numerical control machine and free 3D CAD software, anyone can make a reliable electrochemical cell using this design. Onion-like carbon nanoparticles, with a 1:3 iron-to-cobalt ratio, were drop-coated onto carbon paper for testing in situ X-ray absorption spectroscopy. Cyclic voltammetry of the carbon paper showed the expected behavior, with no increased ohmic drop, even in sandwiched cells. Chronoamperometry was used to apply 0.4 V versus reversible hydrogen electrode, with and without 15 min of oxygen purging to ensure that the electrochemical cell does not provide any artefacts due to gas purging. The XANES and EXAFS spectra showed no differences with and without oxygen, as expected at 0.4 V, without any artefacts due to gas purging. The development of this open-source electrochemical cell design allows for improved collection of in situ X-ray absorption spectroscopy data and enables researchers to perform both transmission and fluorescence simultaneously. It additionally addresses key practical considerations including gas purging, reduced ionic resistance and leak prevention. Full Article text
hem A distributed data processing scheme based on Hadoop for synchrotron radiation experiments By journals.iucr.org Published On :: 2024-04-24 With the development of synchrotron radiation sources and high-frame-rate detectors, the amount of experimental data collected at synchrotron radiation beamlines has increased exponentially. As a result, data processing for synchrotron radiation experiments has entered the era of big data. It is becoming increasingly important for beamlines to have the capability to process large-scale data in parallel to keep up with the rapid growth of data. Currently, there is no set of data processing solutions based on the big data technology framework for beamlines. Apache Hadoop is a widely used distributed system architecture for solving the problem of massive data storage and computation. This paper presents a set of distributed data processing schemes for beamlines with experimental data using Hadoop. The Hadoop Distributed File System is utilized as the distributed file storage system, and Hadoop YARN serves as the resource scheduler for the distributed computing cluster. A distributed data processing pipeline that can carry out massively parallel computation is designed and developed using Hadoop Spark. The entire data processing platform adopts a distributed microservice architecture, which makes the system easy to expand, reduces module coupling and improves reliability. Full Article text
hem Electrochemical cell for synchrotron nuclear resonance techniques By journals.iucr.org Published On :: 2024-08-16 Developing new materials for Li-ion and Na-ion batteries is a high priority in materials science. Such development always includes performance tests and scientific research. Synchrotron radiation techniques provide unique abilities to study batteries. Electrochemical cell design should be optimized for synchrotron studies without losing electrochemical performance. Such design should also be compatible with operando measurement, which is the most appropriate approach to study batteries and provides the most reliable results. The more experimental setups a cell can be adjusted for, the easier and faster the experiments are to carry out and the more reliable the results will be. This requires optimization of window materials and sizes, cell topology, pressure distribution on electrodes etc. to reach a higher efficiency of measurement without losing stability and reproducibility in electrochemical cycling. Here, we present a cell design optimized for nuclear resonance techniques, tested using nuclear forward scattering, synchrotron Mössbauer source and nuclear inelastic scattering. Full Article text
hem Bis(2-hydroxy-2,3-dihydro-1H-inden-1-aminium) tetrachloridopalladate(II) hemihydrate By journals.iucr.org Published On :: 2024-01-26 A new square-planar palladium complex salt hydrate, (C9H12NO)2[PdCl4]·0.5H2O, has been characterized. The asymmetric unit of the complex salt comprises two [PdCl4]2− dianions, four 2-hydroxy-2,3-dihydro-1H-inden-1-aminium cations, each derived from (1R,2S)-(+)-1-aminoindan-2-ol, and one water molecule of crystallization. In the crystal, a two-dimensional layer parallel to (001) features a number of O—H⋯O, N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds. Full Article text
hem Poly[[{μ2-5-[(dimethylamino)(thioxo)methoxy]benzene-1,3-dicarboxylato-κ4O1,O1':O3,O3'}(μ2-4,4'-dipyridylamine-κ2N4:N4')cobalt(II)] dimethylformamide hemisolvate monohydrate] By journals.iucr.org Published On :: 2024-06-04 In the crystal structure of the title compound, {[Co(C11H9NSO5)(C10H9N3)]0.5C3H7NO·H2O}n or {[Co(dmtb)(dpa)]·0.5DMF·H2O}n (dmtb2– = 5-[(dimethylamino)thioxomethoxy]-1,3-benzenedicarboxylate and dpa = 4,4'-dipyridylamine), an assembly of periodic [Co(C11H9NSO5)(C10H9N3)]n layers extending parallel to the bc plane is present. Each layer is constituted by distorted [CoO4N2] octahedra, which are connected through the μ2-coordination modes of both dmtb2– and dpa ligands. Occupationally disordered water and dimethylformamide (DMF) solvent molecules are located in the voids of the network to which they are connected through hydrogen-bonding interactions. Full Article text
hem μ-Chlorido-bis{[1-benzyl-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene-κC]silver(I)} chloride 1,2-dichloroethane hemisolvate By journals.iucr.org Published On :: 2024-09-10 The title compound, [Ag2(C19H20N2)4]Cl·0.5C2H4Cl2, can be readily generated by treatment of (1-benzyl-3-(2,4,6-trimethylphenyl)imidazolium chloride with sodium bis(trimethylsilyl)amide followed by silver chloride. The molecular structure of the compound was confirmed using NMR spectroscopy and single-crystal X-ray diffraction analysis. The crystal structure of the title compound at 110 K has monoclinic (P21/c) symmetry. The represented silver compound is of interest with respect to antibacterial properties and the structure displays a series of weak intermolecular hydrogen-bonding interactions with the chloride counter-anion. Full Article text
hem [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-4-isobutyl-1,2,4-triazol-5-ylidene)(triphenylphosphane)iridium(I) tetrafluoridoborate dichloromethane hemisolvate By journals.iucr.org Published On :: 2024-09-30 A new triazole-based N-heterocyclic carbene IrI cationic complex with a tetrafluoridoborate counter-anion and hemi-solvating dichloromethane, [Ir(C8H12)(C8H15N3)(C18H15P)]BF4·0.5CH2Cl2, has been synthesized and structurally characterized. There are two independent ion pairs in the asymmetric unit and one dichloromethane solvent molecule per two ion pairs. The cationic complex exhibits a distorted square-planar conformation around the IrI atom, formed by a bidentate cycloocta-1,5,diene (COD) ligand, a triphenylphosphane ligand, and an N-heterocyclic carbene (NHC). There are several close non-standard H⋯F hydrogen-bonding interactions that orient the tetrafluoridoborate anions with respect to the IrI complex molecules. The complex shows promising catalytic activity in transfer hydrogenation reactions. The structure was refined as a non-merohedral twin, and one of the COD molecules is statistically disordered. Full Article text
hem Crystallographic fragment-binding studies of the Mycobacterium tuberculosis trifunctional enzyme suggest binding pockets for the tails of the acyl-CoA substrates at its active sites and a potential substrate-channeling path between them By journals.iucr.org Published On :: 2024-07-16 The Mycobacterium tuberculosis trifunctional enzyme (MtTFE) is an α2β2 tetrameric enzyme in which the α-chain harbors the 2E-enoyl-CoA hydratase (ECH) and 3S-hydroxyacyl-CoA dehydrogenase (HAD) active sites, and the β-chain provides the 3-ketoacyl-CoA thiolase (KAT) active site. Linear, medium-chain and long-chain 2E-enoyl-CoA molecules are the preferred substrates of MtTFE. Previous crystallographic binding and modeling studies identified binding sites for the acyl-CoA substrates at the three active sites, as well as the NAD binding pocket at the HAD active site. These studies also identified three additional CoA binding sites on the surface of MtTFE that are different from the active sites. It has been proposed that one of these additional sites could be of functional relevance for the substrate channeling (by surface crawling) of reaction intermediates between the three active sites. Here, 226 fragments were screened in a crystallographic fragment-binding study of MtTFE crystals, resulting in the structures of 16 MtTFE–fragment complexes. Analysis of the 121 fragment-binding events shows that the ECH active site is the `binding hotspot' for the tested fragments, with 41 binding events. The mode of binding of the fragments bound at the active sites provides additional insight into how the long-chain acyl moiety of the substrates can be accommodated at their proposed binding pockets. In addition, the 20 fragment-binding events between the active sites identify potential transient binding sites of reaction intermediates relevant to the possible channeling of substrates between these active sites. These results provide a basis for further studies to understand the functional relevance of the latter binding sites and to identify substrates for which channeling is crucial. Full Article text
hem New copper carboxylate pyrene dimers: synthesis, crystal structure, Hirshfeld surface analysis and electrochemical characterization By journals.iucr.org Published On :: 2024-01-01 Two new copper dimers, namely, bis(dimethyl sulfoxide)tetrakis(μ-pyrene-1-carboxylato)dicopper(Cu—Cu), [Cu2(C17H9O2)4(C2H6OS)2] or [Cu2(pyr-COO−)4(DMSO)2] (1), and bis(dimethylformamide)tetrakis(μ-pyrene-1-carboxylato)dicopper(Cu—Cu), [Cu2(C17H9O2)4(C3H7NO)2] or [Cu2(pyr-COO−)4(DMF)2] (2) (pyr = pyrene), were synthesized from the reaction of pyrene-1-carboxylic acid, copper(II) nitrate and triethylamine from solvents DMSO and DMF, respectively. While 1 crystallized in the space group Poverline{1}, the crystal structure of 2 is in space group P21/n. The Cu atoms have octahedral geometries, with four oxygen atoms from carboxylate pyrene ligands occupying the equatorial positions, a solvent molecule coordinating at one of the axial positions, and a Cu⋯Cu contact in the opposite position. The packing in the crystal structures exhibits π–π stacking interactions and short contacts through the solvent molecules. The Hirshfeld surfaces and two-dimensional fingerprint plots were generated for both compounds to better understand the intermolecular interactions and the contribution of heteroatoms from the solvent ligands to the crystal packing. In addition, a Cu2+/Cu1+ quasi-reversible redox process was identified for compound 2 using cyclic voltammetry that accounts for a diffusion-controlled electron-donation process to the Cu dimer. Full Article text
hem CoII-catalysed synthesis of N-(4-methoxyphenyl)-5-(pyridin-4-yl)-1,3,4-oxadiazol-2-amine hemihydrochloride monohydrate By journals.iucr.org Published On :: 2024-03-12 The title compound, C14H12N4O2·0.5HCl·H2O or H(C14H12N4O2)2+·Cl−·2H2O, arose from the unexpected cyclization of isonicotinoyl-N-phenyl hydrazine carbothioamide catalysed by cobalt(II) acetate. The organic molecule is almost planar and a symmetric N⋯H+⋯N hydrogen bond links two of them together, with the H atom lying on a crystallographic twofold axis. The extended structure features N—H⋯O and O—H⋯Cl hydrogen bonds, which generate [001] chains. Weak C—H⋯Cl interactions cross-link the chains. The chloride ion has site symmetry 2. The major contributions to the Hirshfeld surface are from H⋯H (47.1%), Cl⋯H/H⋯Cl (total 10.8%), O⋯H/H⋯O (7.4%) and N⋯H/H⋯N (6.7%) interactions. Full Article text
hem Crystal structure and Hirshfeld surface analysis of 8-benzyl-1-[(4-methylphenyl)sulfonyl]-2,7,8,9-tetrahydro-1H-3,6:10,13-diepoxy-1,8-benzodiazacyclopentadecine ethanol hemisolvate By journals.iucr.org Published On :: 2024-03-26 The asymmetric unit of the title compound, 2C31H28N2O4S·C2H6O, contains a parent molecule and a half molecule of ethanol solvent. The main compound stabilizes its molecular conformation by forming a ring with an R12(7) motif with the ethanol solvent molecule. In the crystal, molecules are connected by C—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C—H⋯π interactions also strengthen the molecular packing. Full Article text
hem 2-Cyano-2-isonitrosoacetamide–3,4-dimethylpyrazole (1/1): a co-crystal of two molecules with agrochemical activities By journals.iucr.org Published On :: 2024-04-04 In the structure of the title co-crystal, C3H3N3O2·C5H8N2, the components are linked by a set of directional O—H⋯N, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds to yield a two-dimensional mono-periodic arrangement. The structure propagates in the third dimension by extensive π–π stacking interactions of nearly parallel molecules of the two components, following an alternating sequence. The primary structure-defining interaction is very strong oxime-OH donor to pyrazole-N acceptor hydrogen bond [O⋯N = 2.587 (2) Å], while the significance of weaker hydrogen bonds and π–π stacking interactions is comparable. The distinct structural roles of different kinds of interactions agree with the results of a Hirshfeld surface analysis and calculated interaction energies. The title compound provides insights into co-crystals of active agrochemical molecules and features the rational integration in one structure of a fungicide, C3H3N3O2, and a second active component, C5H8N2, known for alleviation the toxic effects of fungicides on plants. The material appears to be well suited for practical uses, being non-volatile, air-stable, water-soluble, but neither hygroscopic nor efflorescent. Full Article text
hem Synthesis and crystal structure of poly[[μ-chlorido-μ-(2,3-dimethylpyrazine)-copper(I)] ethanol hemisolvate], which shows a new isomeric CuCl(2,3-dimethylpyrazine) network By journals.iucr.org Published On :: 2024-09-24 Reaction of copper(I)chloride with 2,3-dimethylpyrazine in ethanol leads to the formation of the title compound, poly[[μ-chlorido-μ-(2,3-dimethylpyrazine)-copper(I)] ethanol hemisolvate], {[CuCl(C6H8N2)]·0.5C2H5OH}n or CuCl(2,3-dimethylpyrazine) ethanol hemisolvate. Its asymmetric unit consists of two crystallographically independent copper cations, two chloride anions and two 2,3-dimethylpyrazine ligands as well as one ethanol solvate molecule in general positions. The ethanol molecule is disordered and was refined using a split model. The methyl H atoms of the 2,3-dimethylpyrazine ligands are also disordered and were refined in two orientations rotated by 60° relative to each other. In the crystal structure, each copper cation is tetrahedrally coordinated by two N atoms of two bridging 2,3-dimethylpyrazine ligands and two μ-1,1-bridging chloride anions. Each of the two copper cations are linked by pairs of bridging chloride anions into dinuclear units that are further linked into layers via bridging 2,3-dimethylpyrazine coligands. These layers are stacked in such a way that channels are formed in which the disordered solvent molecules are located. The topology of this network is completely different from that observed in the two polymorphic modifications of CuCl(2,3-dimethylpyrazine) reported in the literature [Jess & Näther (2006). Inorg. Chem. 45, 7446–7454]. Powder X-ray diffraction measurements reveal that the title compound is unstable and transforms immediately into an unknown crystalline phase. Full Article text
hem Structure of 2,3,5-triphenyltetrazol-3-ium chloride hemipentahydrate By journals.iucr.org Published On :: 2024-09-30 The title hydrated molecular salt, C19H15N4+·Cl−·2.5H2O, has two triphenyltetrazolium cations, two chloride anions and five water molecules in the asymmetric unit. The cations differ in the conformations of the phenyl rings with respect to the heterocyclic core, most notably for the C-bonded phenyl ring, for which the N—C—C—C torsion angles differ by 36.4 (3)°. This is likely a result of one cation accepting an O—H⋯N hydrogen bond from a water molecule [O⋯N = 3.1605 (15) Å], while the other cation accepts no hydrogen bonds. In the extended structure, the water molecules are involved in centrosymmetric (H2O)2Cl2 rings as well as (H2O)4 chains. An unusual O—H⋯π interaction and weak C—H⋯O and C—H⋯Cl hydrogen bonds are also observed. Full Article text
hem Unlocking the surface chemistry of ionic minerals: a high-throughput pipeline for modeling realistic interfaces By journals.iucr.org Published On :: 2024-03-15 A systematic procedure is introduced for modeling charge-neutral non-polar surfaces of ionic minerals containing polyatomic anions. By integrating distance- and charge-based clustering to identify chemical species within the mineral bulk, our pipeline, PolyCleaver, renders a variety of theoretically viable surface terminations. As a demonstrative example, this approach was applied to forsterite (Mg2SiO4), unveiling a rich interface landscape based on interactions with formaldehyde, a relevant multifaceted molecule, and more particularly in prebiotic chemistry. This high-throughput method, going beyond techniques traditionally applied in the modeling of minerals, offers new insights into the potential catalytic properties of diverse surfaces, enabling a broader exploration of synthetic pathways in complex mineral systems. Full Article text
hem The AUREX cell: a versatile operando electrochemical cell for studying catalytic materials using X-ray diffraction, total scattering and X-ray absorption spectroscopy under working conditions By journals.iucr.org Published On :: 2024-09-20 Understanding the structure–property relationship in electrocatalysts under working conditions is crucial for the rational design of novel and improved catalytic materials. This paper presents the Aarhus University reactor for electrochemical studies using X-rays (AUREX) operando electrocatalytic flow cell, designed as an easy-to-use versatile setup with a minimal background contribution and a uniform flow field to limit concentration polarization and handle gas formation. The cell has been employed to measure operando total scattering, diffraction and absorption spectroscopy as well as simultaneous combinations thereof on a commercial silver electrocatalyst for proof of concept. This combination of operando techniques allows for monitoring of the short-, medium- and long-range structure under working conditions, including an applied potential, liquid electrolyte and local reaction environment. The structural transformations of the Ag electrocatalyst are monitored with non-negative matrix factorization, linear combination analysis, the Pearson correlation coefficient matrix, and refinements in both real and reciprocal space. Upon application of an oxidative potential in an Ar-saturated aqueous 0.1 M KHCO3/K2CO3 electrolyte, the face-centered cubic (f.c.c.) Ag gradually transforms first to a trigonal Ag2CO3 phase, followed by the formation of a monoclinic Ag2CO3 phase. A reducing potential immediately reverts the structure to the Ag (f.c.c.) phase. Following the electrochemical-reaction-induced phase transitions is of fundamental interest and necessary for understanding and improving the stability of electrocatalysts, and the operando cell proves a versatile setup for probing this. In addition, it is demonstrated that, when studying electrochemical reactions, a high energy or short exposure time is needed to circumvent beam-induced effects. Full Article text
hem Noteworthy Chemistry - September 27, 2013 By www.acs.org Published On :: Fri, 27 Sep 2013 01:00:00 -0400 The RSS feed for Noteworthy Chemistry has been discontinued. Questions or concerns? Email us! Full Article
hem New Report Finds Major US Metro Areas, Greater Los Angeles Among Them, Are More Segregated Now Than 30 Years Ago By www.scpr.org Published On :: Wed, 30 Jun 2021 09:31:22 -0700 People rest while riding a Los Angeles Metro Rail train amid the coronavirus pandemic on April 1, 2020 in Los Angeles, California.; Credit: Mario Tama/Getty Images AirTalkDespite the racial reckoning going on in America right now, and despite the fact that attitudes towards race, inclusion and representation are different now than they were 30 years ago, new research from UC Berkeley shows that a large majority of American metro areas are more segregated now than they were in 1990. The new report from Berkeley’s Institute covers a number of topic areas, but among the key findings were from the national segregation report component of the project, which found Los Angeles to be the sixth-most segregated metro area with more than 200,000 people. Today on AirTalk, we’ll talk with the lead researcher on the new report and a local historian to talk about how we see the findings of the report play out in Southern California. Guests: Stephen Menendian, assistant director and director of research at the Othering & Belonging Institute at UC Berkeley, which works to identify and eliminate the barriers to an inclusive, just, and sustainable society in order to create transformative change; he tweets @SMenendian Eric Avila, professor of history, urban planning, and Chicano/a studies at UCLA This content is from Southern California Public Radio. View the original story at SCPR.org. Full Article
hem In Surfside, Biden Meets Local Officials And Tells Them More Help Is On The Way By www.scpr.org Published On :: Thu, 01 Jul 2021 12:40:07 -0700 President Biden listens as Florida Governor Ron DeSantis speaks about the collapse of the 12-story Champlain Towers South condo building in Surfside, Florida.; Credit: Saul Loeb/AFP via Getty Images Alana Wise | NPRPresident Biden landed in Florida on Thursday to visit privately with families whose loved ones were in the 12-story Champlain Towers South condo when it collapsed. Biden also met with first responders to thank them for their rescue work. Search and rescue efforts paused on Thursday because of structural concerns. So far, 145 people are still unaccounted for while 18 people have been confirmed dead. During a briefing with local and state officials, Biden said the federal government would pick up 100% of the costs associated with the response to the building collapse. I think I have the power and will know shortly to be able to pick up 100% of the costs of the county and the state. I'm quite sure I can do that," Biden said. Biden sat beside Florida's Republican Governor Ron DeSantis, who thanked the president for his support, saying "we've had no bureaucracy" from the Federal Emergency Management Agency. "You recognize in each individual unit, there's an amazing story, and lives have been shattered irrevocably, as a result of this," DeSantis said. "We have families with kids missing. And we even have young newlyweds who hadn't even been married a year who were in the tower when it collapsed," he said. "What we just need now is we need a little bit of luck. We need a little bit of prayers. And you know, we would like to be able to, you know, to see some miracles happen," DeSantis said. Copyright 2021 NPR. To see more, visit https://www.npr.org. This content is from Southern California Public Radio. View the original story at SCPR.org. Full Article
hem The 5 Biggest Pains IT Faces with Telecommuting and How to Solve Them By www.itsecurity.com Published On :: Wed, 25 Nov 2009 20:44:34 +0000 On-Demand Webinar > >> Watch Now! SPONSORED BY: HP Imaging and Printing GroupBy 2013, there will be 10 million telecommuters in the U.S., according to research firm IDC¹. Watch this FREE... Full Article
hem How QR codes work and what makes them dangerous: A computer scientist explains By cio.economictimes.indiatimes.com Published On :: Fri, 08 Apr 2022 15:28:35 +0530 The data in a QR code is a series of dots in a square grid. Each dot represents a one and each blank a zero in binary code, and the patterns encode sets of numbers, letters or both, including URLs. Full Article
hem We don't expect any negative surprises from large cap IT companies: Hemang Jani By cio.economictimes.indiatimes.com Published On :: Wed, 05 Apr 2023 14:24:16 +0530 So, we think that now we are entering into earnings season with this business update and particularly the banking sector should do well, both PSU and private banks. Full Article
hem Cold War Chemical Tests Over American Cities Were Far Below Dangerous Levels By Published On :: Wed, 14 May 1997 04:00:00 GMT A series of secret tests conducted by the U.S. Army in the 1950s and 1960s did not expose residents of the United States and Canada to chemical levels considered harmful, according to a new report from a committee of the National Research Council. Full Article
hem Need Still Exists for Chemical Pesticides While Alternatives Are Sought By Published On :: Tue, 18 Jul 2000 05:00:00 GMT No justification currently exists for completely abandoning chemical pesticides, says a new report from the National Academies National Research Council. Full Article
hem Adding It Up - Helping Children Learn Mathematics By Published On :: Tue, 23 Jan 2001 06:00:00 GMT American students progress toward proficiency in mathematics requires major changes in instruction, curricula, and assessment in the nations schools, says a new report from the National Research Council of the National Academies. Full Article
hem Limited Data Suggest Possible Association Between Agent Orange Exposure And Ischemic Heart Disease And Parkinsons Disease In Vietnam Veterans By Published On :: Fri, 24 Jul 2009 05:00:00 GMT A new report from the Institute of Medicine finds suggestive but limited evidence that exposure to Agent Orange and other herbicides used during the Vietnam War is associated with an increased chance of developing ischemic heart disease and Parkinsons disease for Vietnam veterans. Full Article
hem Research Priorities for the Field of Atmospheric Chemistry – New Report By Published On :: Fri, 26 Aug 2016 05:00:00 GMT Increasing energy demands and expanding industrial and agricultural activities worldwide are changing the composition of the atmosphere and contributing to major global challenges like climate change and air pollution. The study of atmospheric chemistry plays a key role in understanding and responding to these challenges, and research in this field has been successful in guiding policies to improve air quality in urban areas and reduce acid rain and stratospheric ozone depletion. Full Article
hem New Report Lays Out Strategy to Evaluate Evidence of Adverse Human Health Effects From Endocrine-Disrupting Chemicals at Low Doses By Published On :: Tue, 18 Jul 2017 05:00:00 GMT A new report by the National Academies of Sciences, Engineering, and Medicine proposes a strategy that the U.S. Environmental Protection Agency (EPA) should use to evaluate the evidence of adverse human health effects from low doses of exposure to chemicals that can disrupt the endocrine system. Full Article
hem New Report Calls for Greater Oversight of Precursor Chemicals Sold At the Retail Level to Reduce Threats from Improvised Explosive Devices By Published On :: Tue, 14 Nov 2017 06:00:00 GMT Policymakers’ efforts to reduce threats from improvised explosive devices (IEDs) should include greater oversight of precursor chemicals sold at the retail level – especially over the Internet – that terrorists, violent extremists, or criminals use to make homemade explosives, says a new report from the National Academies of Sciences, Engineering, and Medicine. Full Article
hem FAA Should Change Its Safety Risk Assessment Approach for Drones to Effectively Integrate Them Into the Nation’s Airspace By Published On :: Mon, 11 Jun 2018 05:00:00 GMT Introducing drone operations into the nation’s airspace can provide substantial benefits to society, such as preventing derailments, inspecting cell phone towers, delivering medical devices to patients in cardiac distress, and assisting firefighters, says a new congressionally mandated report by the National Academies of Sciences, Engineering, and Medicine. Full Article