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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Post-deposition in situ passivation of AgBiS2 nanocrystal inks for high-efficiency ultra-thin solar cells

Energy Environ. Sci., 2024, 17,8885-8892
DOI: 10.1039/D4EE03266G, Paper
Jae Taek Oh, Yongjie Wang, Carmelita Rodà, Debranjan Mandal, Gaurav Kumar, Guy Luke Whitworth, Gerasimos Konstantatos
A post-deposition in situ passivation strategy using a multi-functional molecular agent is reported with enhanced colloidal dispersibility of an environmentally-friendly AgBiS2 nanocrystal ink, achieving a PCE over 10% in a solar cell.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Advancing high-temperature electrostatic energy storage via linker engineering of metal–organic frameworks in polymer nanocomposites

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04085F, Paper
Zongliang Xie, Zhiyuan Huang, He Li, Tianlei Xu, Haoyu Zhao, Yunfei Wang, Pang Xi, Zhiqiang Cao, Virginia Altoe, Liana M Klivansky, Zaiyu Wang, Steven Shelton, Shiqi Lai, Peng Liu, Chenhui Zhu, Michael D. Connolly, Corie Y. Ralston, Xiaodan Gu, Zongren Peng, Jian Zhang, Yi Liu
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00130C, Paper
Egor N. Boronin, Milena M. Svetlakova, Ilya I. Vorobyov, Yulia B. Malysheva, Yuri V. Polushtaytsev, Sergey N. Mensov, Andrey V. Vorotyntsev, Alexey Yu. Fedorov, Timothy Noël, Alexander V. Nyuchev
Photoorganocatalytic arylation of amines in continuous-flow enables scaling up including decreasing of both reaction time and catalyst loading.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Bioactive compounds regulate appetite through the melanocortin system: a review

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO04024D, Review Article
Yujia Niu, Wancong Yu, Xiaohong Kou, Shuqi Wu, Mengyi Liu, Chenlong Chen, Jiaxin Ji, Ying Shao, Zhaohui Xue
The melanocortin system is regulated by long-term and short-term regulatory hormones and nutrients. Bioactive compounds influence appetite through multiple pathways: central nervous system, peripheral hormones, and intestinal microbiota.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Aronia melanocarpa extract extends the lifespan and health-span of Caenorhabditis elegans via mitogen-activated protein kinase 1

Food Funct., 2024, 15,11020-11035
DOI: 10.1039/D4FO02479F, Paper
Huan Zhang, Zhigang Zhu, Wenjing Wei, Zekun Liu, Huiji Zhou, Yueling Gong, Xinlei Yan, Jun Du, Houkai Li, Liang Chen, Lili Sheng
Aronia melanocarpa (AM) was shown to promote the lifespan and health-span of C. elegans via the PMK-1 pathway, highlighting the potential of AM as a dietary supplement for delaying aging.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dynamic changes in the gel properties, microbial community, and volatile flavor profile of Spanish mackerel (Scomberomorus niphonius) sausages inoculated with Lactiplantibacillus plantarum CY1-2

Food Funct., 2024, 15,11060-11071
DOI: 10.1039/D4FO03841J, Paper
Xinran Lv, Wenyu Wu, Shuilin Liu, Lili Ding, Anqi Ren, Le An, Fengling Bai, Jianrong Li, Xuepeng Li, Shumin Yi
This study aimed to examine the dynamic changes in the gel properties, microbial diversity, and volatile flavor compounds (VFCs) of Spanish mackerel sausages inoculated with Lactiplantibacillus plantarum CY1-2 during fermentation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cycloaddition of CO2 with epoxides into cyclic carbonates catalyzed by a binary organocatalyst under mild conditions

Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper
Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO2 into cyclic carbonates from flue gas under atmospheric pressure.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrolysis of ammonia borane for green hydrogen production over a Pd/C3N4 nanocatalyst synthesized by electron beam irradiation

Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper
Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C3N4 catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bis-thiourea and macrocyclic polyamines as binary organocatalysts for the ROP of lactide

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00952E, Paper
Open Access
Assunta D'Amato, Maria Voccia, Filippo Bruno, Sara D'Aniello, Lucia Caporaso, Francesco De Riccardis, Irene Izzo, Giorgio Della Sala, Mina Mazzeo
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Innovations in nanocomposite photocatalysts for CO2 to CH3OH conversion

Catal. Sci. Technol., 2024, 14,6443-6465
DOI: 10.1039/D4CY00822G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shuang Deng, Nannan Wang, Yanqiu Zhu, Kunyapat Thummavichai
Nowadays, the excessive use of fossil fuels has led to a global energy shortage and exacerbated the greenhouse effect.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ni,S co-doped Cu dendrites decorated with core–shell architecture assisted by MOF and Fe0.92Co0.08S nanoflakes on nanocellulose/graphene fibers for fabrication of flexible wire-type micro-supercapacitor

Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper
Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
The content of this RSS Feed (c) The Royal Society of Chemistry




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High sensing performance flexible nanocomposite sensor with a hybrid nanostructure constructed via nanoscale confined motion of nanofibers and nanoplatelets

Nanoscale, 2024, 16,20288-20303
DOI: 10.1039/D4NR02541E, Paper
Zhenghui Xie, Feiran Meng, Junlong Yang, Yuhong Wang, Chul B. Park, Pengjian Gong, Guangxian Li
Hybrid 1D nanofiber/2D nanoplatelet nanocomposite foam sensor and Monte-Carlo modelling of complex 1D/2D sensing nanostructure.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effective enrichment of glycated proteome using ultrasmall gold nanoclusters functionalized with boronic acid

Nanoscale, 2024, 16,20147-20154
DOI: 10.1039/D4NR03283G, Paper
Hongmae Heo, Seonghyeon Cho, Yuhyeon Kim, Soomin Ahn, Jeong-hun Mok, Hookeun Lee, Dongil Lee
A novel approach was developed for the first time by combining ultrasmall Au22 nanoclusters with boronic acid (BA) affinity chemistry, achieving highly efficient enrichment of early-stage glycated peptides.
The content of this RSS Feed (c) The Royal Society of Chemistry




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N-Heterocyclic carbene-stabilized gold–copper nanoclusters: synthesis, bonding and mechanochromism

Nanoscale, 2024, 16,20228-20234
DOI: 10.1039/D4NR03320E, Paper
Dongjie Zuo, Huifang Guo, Qinghua Xu, Ayisha He, Zilin Li, Simin Li, Hui Shen
The first gold–copper alloy cluster protected by both NHC and alkyne ligands was reported. The cluster displays interesting mechanochromic properties, highlighting the bright future of NHC-functionalized metal nanoclusters in materials science.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Modulating the photodynamic modality of Au22 nanoclusters through surface conjugation of arginine for promoted healing of bacteria-infected wounds

Nanoscale, 2024, 16,20089-20099
DOI: 10.1039/D4NR03278K, Paper
Xinyue Dou, Sariah Saalah, Chel-Ken Chiam, Jianping Xie, Coswald Stephen Sipaut
An Au nanocluster (NC)-based photodynamic antibacterial is designed by conjugating arginine on the surface of Au22 NCs, achieving healing of bacteria-infected wounds via producing reactive oxygen species (ROS) and reactive nitrogen species (RNS).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Exploring size-dependent optical property alterations in fine-tuning intermetallic PdCd nanocube sizes

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03640A, Paper
Jia-Lin Li, Ting-Yu Tien, Hung-Chun Liao, Hsin-Lun Wu
Size-tuned intermetallic PdCd nanocubes, synthesized via a quantum dot-like method, reveal novel size-dependent optical properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Retarding anion exchanges in lead halide perovskite nanocrystals by ligand immobilization

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03241A, Paper
Gauri Sharma, Radha Rathod, Pralay K. Santra
Plasma treatment causes the crosslinking of passivating molecules around CsPbX3 (X = Cl, Br, I) perovskite nanocrystals (PNCs), which retards the anion exchanges.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbon-based nanocarriers for plant growth promotion: Fuelling when it needs

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03268C, Review Article
Mohammad Ashfaq, Govind Gupta, Nishith Verma
Climate change (i.e., rising temperature and precipitation) due to global warming is affecting soil fertility, thereby significantly causing a decrease in agriculture production worldwide. At the same time, increasing demands...
The content of this RSS Feed (c) The Royal Society of Chemistry




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DON encapsulated carbon dot–vesicle conjugate in therapeutic intervention of lung adenocarcinoma by dual targeting of CD44 and SLC1A5

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR00426D, Paper
Afreen Zaman, Aparajita Ghosh, Anup Kumar Ghosh, Prasanta Kumar Das
HACD–TMAV, a carbon dot–vesicle conjugate, selectively delivered glutamine inhibitor DON to CD44-enriched cancer cells, inducing ROS triggered apoptosis by dual targeting CD44 and SLC1A5 through downregulation of PI3K/AKT/mTOR signalling cascade.
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Preceramic polymer hybridized phenolic aerogels and the derived ZrC/SiC/C ceramic aerogels with ultrafine nanocrystallines

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03470H, Paper
Ding Nie, Hangyu Zhong, Hongli Hu, Zhenhua Luo, Boxing Zhang
Phenolic and carbon aerogels have important applications for thermal insulation and ablative resistance materials in aerospace areas. However, their antioxidant ability in long-term and high-temperature aerobic environments is facing serious...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrodynamic Slip in Nanoconfined Flows: A Review of Experimental, Computational, and Theoretical Progress

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03697B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Abdul Aziz Shuvo, Luis E. Paniagua-Guerra, Juseok Choi, Seong H. Kim, Bladimir Ramos Alvarado
Nanofluidics has made significant impacts and advancements in various fields, including ultrafiltration, water desalination, biomedical applications, and energy conversion. These advancements are driven by the distinct behavior of fluids at...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Macrophage membrane-camouflaged nanoclusters of ultrasmall iron oxide nanoparticles for precision glioma theranostics

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00357H, Paper
Bin Zhang, Rui Yang, Hongwei Yu, Yamin Peng, Haoyu Huang, Meera Moydeen Abdul Hameed, Han Wang, Guixiang Zhang, Mohamed EL-Newehy, Mingwu Shen, Xiangyang Shi, Shaojun Peng
Macrophage membrane-camouflaged nanoclusters of ultrasmall iron oxide nanoparticles can be developed to cross the blood–brain barrier for magnetic resonance imaging and chemo/chemodynamic therapy.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Recent advances in shape memory polymeric nanocomposites for biomedical applications and beyond

Biomater. Sci., 2024, 12,2033-2040
DOI: 10.1039/D4BM00004H, Review Article
Yifan Zheng, Yudi Du, Ling Chen, Wei Mao, Yuan Pu, Steven Wang, Dan Wang
Shape memory polymers (SMPs), which initiate shape transformation in response to environmental stimuli, have attracted significant attention in both academic research and technological innovation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Between hope and hubris: Innocence, glumness, despair, gratitude after the World Cup final

This is sport. Unexpectedness and upsets are what it thrives on.




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Nanocrystals give hematite rainbow flair

Mineral’s microstructure causes natural iridescence




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Sinochem, ChemChina merger appears likely




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Bain buys antibiotics maker DSM Sinochem




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Membrane knocks out antibiotic-resistant bacteria

Combining UV disinfection with a photocatalytic membrane helps to reduce the bacteria and their genes in wastewater




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Membrane knocks out antibiotic-resistant bacteria

Combining UV disinfection with a photocatalytic membrane helps reduce the bacteria and their genes in wastewater




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NSE awaiting NoC from SEBI before filing draft prospectus for IPO

Aims to strengthen commodities segment, predicts market cap to double in 10 years




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Modular access to multi-substituted allenones via environmentally friendly organocatalytic C–H allenylation of aldehydes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04550E, Paper
Xinying Hu, Ayisenbati Jialingbieke, Yuzhi Ren, Yifan Yang, Donghui Wei, Jian Gao, Ding Du
Organocatalytic direct C–H allenylation of aldehydes with propargyl bromides has provided a straightforward and step-economical strategy for allenone modular synthesis.
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Hypervalent iodine chemistry with a mechanochemical twist

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04903A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sayad Doobary, Miguel M. de Vries Ibáñez, Berit Olofsson
An assessment of mechanochemistry's utility with hypervalent iodine reagents highlighted its effectiveness, which showed better selectivity, reaction times and differing reactivity.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Production of nanochitins via a shell biorefinery process for self-assembly applications as photonic films and Pickering emulsions

Green Chem., 2024, 26,11222-11237
DOI: 10.1039/D4GC02680B, Paper
Open Access
Xuhai Zhu, Fuyan Peng, Hui Li, Rongjun Lin, Rui Lu, Fang Lu
A simple, environmentally friendly, and flexible shell biorefinery process for integrated utilization of all NCh products in high-value applications, such as photonic films and Pickering emulsions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Economic and environmental sustainability of bio-based HMF production and recovery from lignocellulosic biomass

Green Chem., 2024, 26,11340-11350
DOI: 10.1039/D4GC04270K, Paper
Yuyao Jia, Shraddha Maitra, Lavanya Kudli, Jeremy S. Guest, Vijay Singh
Transforming waste stream of biorefinery into high-value bioproducts.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanoenzymatic Hydrolysis of Cotton to Cellulose Nanocrystals

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05113K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sandra Kaabel, Inge Schlapp-Hackl, Eero Kontturi, Mauri A. Kostiainen
Solid-state mechanoenzymatic approaches for the production of cellulose nanocrystals from cotton were examined using three commercially available cellulase systems from Trichoderma reesei, Aspergillus niger and a Cellic CTec2 cellulase blend....
The content of this RSS Feed (c) The Royal Society of Chemistry




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DD takes on RCB in potential knockout



  • Indian Premier League

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AUS A vs IND A, 2nd Unofficial Test: Dhruv Jurel strengthens his case with another fine knock




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World Chess Championship: India’s top GMs Pravin Thipsay, Abhijit Kunte predict a Gukesh knockout win inside 12 rounds




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‘Cummins is tactically good, setting good fields; Bumrah has many more wicket-taking deliveries and can just come and knock your stumps’ – Shaun Tait




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After Jio deals, RIL valued higher than BP, Sinopec, Shell, ConocoPhillips, Vodafone, Tesco

The investor confidence shot up in RIL because of the back-to-back strategic investments in its telecom subsidiary in the last three weeks




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Venezuela’s state oil group agrees $2bn Conoco payout

Deal ends dispute over nationalisation that had disrupted PDVSA’s exports




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Materials engineering, processing, and device application of hydrogel nanocomposites

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01456G, Minireview
Gi Doo Cha, Wang Hee Lee, Chanhyuk Lim, Moon Kee Choi, Dae-Hyeong Kim
The integration of patterning technologies and functional hydrogel nanocomposites enables their advanced device applications such as sensors, actuators, energy devices, and tissue engineering scaffolds.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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UP: MSME can start first, take NOC within 3 yrs

Generation of employment and attracting foreign investment are the two mainstays of UP government’s decision to suspend a majority of its labour laws for the next three years.




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Morrisons recalls Market Street Living Herbs because of possible contamination with Listeria monocytogenes

Morrisons has taken the precautionary step of recalling Market Street Living Herbs because the products might contain Listeria monocytogenes.




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Affinity maturation, humanization, and co-crystallization of a rabbit anti-human ROR2 monoclonal antibody for therapeutic applications [Immunology]

Antibodies are widely used as cancer therapeutics, but their current use is limited by the low number of antigens restricted to cancer cells. A receptor tyrosine kinase, receptor tyrosine kinase-like orphan receptor 2 (ROR2), is normally expressed only during embryogenesis and is tightly down-regulated in postnatal healthy tissues. However, it is up-regulated in a diverse set of hematologic and solid malignancies, thus ROR2 represents a candidate antigen for antibody-based cancer therapy. Here we describe the affinity maturation and humanization of a rabbit mAb that binds human and mouse ROR2 but not human ROR1 or other human cell-surface antigens. Co-crystallization of the parental rabbit mAb in complex with the human ROR2 kringle domain (hROR2-Kr) guided affinity maturation by heavy-chain complementarity-determining region 3 (HCDR3)-focused mutagenesis and selection. The affinity-matured rabbit mAb was then humanized by complementarity-determining region (CDR) grafting and framework fine tuning and again co-crystallized with hROR2-Kr. We show that the affinity-matured and humanized mAb retains strong affinity and specificity to ROR2 and, following conversion to a T cell–engaging bispecific antibody, has potent cytotoxicity toward ROR2-expressing cells. We anticipate that this humanized affinity-matured mAb will find application for antibody-based cancer therapy of ROR2-expressing neoplasms.




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A knock at the door

A man shares his story of living with HIV at an AIDS workshop aboard Logos Hope, which opened hearts for ministry to others with HIV.




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How FIA defrauds innocent citizens and implicates them in bogus case

ISLAMABAD: In a shocking move, Federal Investigation Agency’s own internal inquiry has revealed how an official of the agency converted a business deal between two private parties into a human trafficking case and implicated innocent citizens in a bogus case.Raja Muhammad Ishaq — an...




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How FIA defrauds innocent citizens and implicate them in bogus case

ISLAMABAD: In a shocking move, Federal Investigation Agency’s own internal inquiry has revealed how an official of the agency converted a business deal between two private parties into a human trafficking case and implicated innocent citizens in a bogus case.Raja Muhammad Ishaq — an...