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The competition between dehydrogenation and dehydration reactions for primary and secondary alcohols over gallia: unravelling the effects of molecular and electronic structure via a two-pronged theoretical/experimental approach

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02603G, Paper
Lorella Izzo, Tommaso Tabanelli, Fabrizio Cavani, Paola Blair Vàsquez, Carlo Lucarelli, Massimo Mella
The relative dehydrogenation/dehydration reactivity imparted by nanostructured gallium(III) oxide on alcohols was investigated via electronic structure calculations, reactivity tests and DRIFT-IR spectroscopy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Pressure effects on lipids and bio-membrane assemblies

Pressure can play a key role in probing the structure and dynamics of membrane assemblies, and is also critical to the biology and adaptation of deep-sea organisms. This article presents an overview of the effect of pressure on the structure of membranes and recent developments in high-pressure instrumentation.





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Saturation and self-absorption effects in the angle-dependent 2p3d resonant inelastic X-ray scattering spectra of Co3+

It is shown that the 2p3d resonant inelastic X-ray scattering intensity is distorted by saturation and self-absorption effects, i.e. by incident-energy-dependent saturation and by emission-energy-dependent self-absorption.




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Takagi–Taupin dynamical X-ray diffraction simulations of asymmetric X-ray diffraction from crystals: the effects of surface undulations

Dynamical X-ray diffraction simulations of very asymmetric diffraction from single crystals of silicon were made to accompany an experimental rocking-curve topography study reported in a seperate paper. Effects on rocking curves were found and are reported. The development of Uragami [(1969), J. Phys. Soc. Jpn, 27, 147–154] for Takagi–Taupin simulations was followed and applied to the case of both convex and concave surface undulations.




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Effects of surface undulations on asymmetric X-ray diffraction: a rocking-curve topography study

Very asymmetric crystal diffraction was obtained from a finely polished silicon crystal set to reflect in Bragg diffraction at grazing incidence for the (333) reflection. The angle of incidence to achieve Bragg diffraction was varied between 1.08° and 0.33° by changing the X-ray energy from 8.100 to 8.200 keV. Topographic images obtained as the crystal was rocked were used to identify the effects of surface undulations, and the results are compared with dynamical X-ray diffraction calculations made with the Takagi–Taupin equations specialized to a surface having convex or concave features, as reported in an accompanying paper.




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Synthesis and crystallographic, spectroscopic and computational characterization of the effects of O—R substituents on the torsional[torsion] angle of 3,3',4,4'-substituted bi­phenyls

The synthesis, characterization and study of structures from a series of bi­phenyls substituted at positions 3, 3', 4 and 4' with groups connected to the bi­phenyl core through oxygen atoms are presented here. The molecular conformation is extensively studied both in the solid as well as in the liquid state, and the effect of different actors (such as packing and chain length) on the torsion angle between aromatic rings is analyzed.




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Effects of human impact are long lasting for forests in Northeast U.S.

Grow fast, die young is not a lifestyle normally associated with trees. But in the forests of the Northeastern United States the red maple follows […]

The post Effects of human impact are long lasting for forests in Northeast U.S. appeared first on Smithsonian Insider.




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Effects of congestion charging increase

Congestion charging in Stockholm has become more successful over time, according to a study by Swedish researchers. Although the total cost of a journey that enters the congestion charge zone has fallen in real terms since the charges were first introduced in 2006, there has consistently been around 29% less traffic within the zone, compared with levels in 2005.




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Research Needed to Reduce Scientific Uncertainty About Effects of Hormonally Active Agents in the Environment

Although there is evidence of harmful health and ecological effects associated with exposure to high doses of chemicals known as hormonally active agents – or endocrine disrupters – little is understood about the harm posed by exposure to the substances at low concentrations, such as those that typically exist in the environment, says a new report from a National Research Council committee.




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Oil in the Sea - Inputs, Fates, and Effects

Nearly 85 percent of the 29 million gallons of petroleum that enter North American ocean waters each year as a result of human activities comes from land-based runoff, polluted rivers, airplanes, and small boats and jet skis, while less than 8 percent comes from tanker or pipeline spills.




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Effects of Oil and Gas Development Are Accumulating On Northern Alaskas Environment and Native Cultures

The environmental effects of oil and gas exploration and production on Alaska s North Slope have been accumulating for more than three decades, says a new report from the National Academies National Research Council.




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Evidence Inconclusive About Long-Term Health Effects of Exposure to Military Burn Pits

Insufficient data on service members exposures to emissions from open-air burn pits for trash on military bases in Iraq and Afghanistan is one of the reasons why it is not possible to say whether these emissions could cause long-term health effects, says a new report from the Institute of Medicine.




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Assessing the Effects of Human-Caused Activities on Marine Mammals

Rising levels of noise in the ocean have been identified as a growing concern for the well-being of marine mammals, but other threats such as pollution, climate change, and prey depletion by fisheries may also harm marine mammals and influence their response to additional noise.




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Health Effects of Marijuana and Cannabis-Derived Products Presented in New Report

A new report from the National Academies of Sciences, Engineering, and Medicine offers a rigorous review of scientific research published since 1999 about what is known about the health impacts of cannabis and cannabis-derived products – such as marijuana and active chemical compounds known as cannabinoids – ranging from their therapeutic effects to their risks for causing certain cancers, diseases, mental health disorders, and injuries.




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New Report Lays Out Strategy to Evaluate Evidence of Adverse Human Health Effects From Endocrine-Disrupting Chemicals at Low Doses

A new report by the National Academies of Sciences, Engineering, and Medicine proposes a strategy that the U.S. Environmental Protection Agency (EPA) should use to evaluate the evidence of adverse human health effects from low doses of exposure to chemicals that can disrupt the endocrine system.




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New Report One of Most Comprehensive Studies on Health Effects of E-Cigarettes - Finds That Using E-Cigarettes May Lead Youth to Start Smoking, Adults to Stop Smoking

A new congressionally mandated report from the National Academies of Sciences, Engineering, and Medicine takes a comprehensive look at evidence on the human health effects of e-cigarettes.




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Healthy People 2030’s Leading Health Indicators Should Track Health Effects of Climate Change, Residential Segregation, Civic Engagement

Healthy People 2030 (HP2030) – which will set national objectives for improving the health of all Americans from 2020 to 2030 – should include in its Leading Health Indicators (LHIs) voting as a measure of civic engagement, the health effects of climate change, and indicators of racial and ethnic residential segregation, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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NASA, Teamed with FAA, Industry, and Academia, Should Research Effects of Increased Drone Traffic on Privacy, the Environment, and Cybersecurity

NASA should collaborate with the Federal Aviation Administration (FAA), industry, academia to research the full effects that increased unpiloted air vehicle traffic would have on society, including ramifications to sound, privacy, environmental matters, and cybersecurity, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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Determining Whether There Is a Link Between Antimalarial Drugs and Persistent Health Effects Requires More Rigorous Studies

Although the immediate side effects of antimalarial drugs are widely recognized, few studies were designed specifically to examine health problems that might occur or persist months or years after people stopped taking them.




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National Academies Completes Review of National Toxicology Program’s Draft Monograph on Fluoride and Neurodevelopmental and Cognitive Effects

Today the National Academies of Sciences, Engineering, and Medicine released its review of the National Toxicology Program’s (NTP) draft monograph Systematic Review of Fluoride Exposure and Neurodevelopmental and Cognitive Health Effects.




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Potential Effects of Seasonal and Temperature Changes on Spread of COVID-19 Examined in New Rapid Response to Government from Standing Committee on Emerging Infectious Diseases

A new rapid expert consultation from a standing committee of the National Academies of Sciences, Engineering, and Medicine responds to questions from the White House Office of Science and Technology Policy (OSTP) regarding survival of the COVID-19 virus in relation to temperature and humidity and potential for seasonal reduction and resurgence of cases.




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Effects of organochlorine pollution on animals take a long time to wear off

Populations of otters, grey seals and sea eagles are slowly recovering in Sweden, which is likely to be thanks in part to a ban on organochlorine chemicals, such as PCBs and DDT, in the 1970s, according to a new study. However, the research shows that negative effects of these chemicals on the reproductive health of female animals persisted for more than 15 years after the ban was introduced.




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Evidence for effects of chemical pollution on riverbed invertebrates

To date, it has been difficult to collect data that are robust enough to demonstrate specific effects of chemical pollution in rivers on aquatic wildlife. However, a recent study combining detailed chemical, toxicological and ecological data in three European river basins now provides evidence linking cause and effect by revealing significant differences in the effects of differently polluted sediments on the organisms living in the river basins and the riverbed biodiversity.




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Ecological effects of deep-sea mining experiment still evident 26 years later

In 1989, researchers dragged a plough harrow across the seafloor of the Peru Basin to recreate some of the effects of deep-sea mining. Twenty-six years later, a new team of researchers returned to the site to assess whether there were any long-term ecological effects. They found that the seabed ecosystem remained disrupted, with significantly fewer suspension feeder species, such as anemones and sea sponges, than in undisturbed areas of seafloor. This suggests that deep-sea mining could cause irreversible changes to marine food webs in highly disturbed areas.




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Some green behaviour policies may have negative side-effects

A recent Swiss-US study of a short-term water saving campaign found that, although the programme successfully reduced water use, there was also an overall increase in electricity consumption by participants. The researchers suggest a ‘moral licensing’ effect may be in action, whereby people ‘trade’ a positive behaviour for a negative one.




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Urban planning must account for its effects on ecosystem services

Tightly compacted cities can increase flooding risk for local residents, but sprawling, suburban development can lead to major losses in carbon stored by the land and agricultural production. These are the conclusions of a study which explored the effects of different urbanisation patterns on vital ecosystem services.




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High-yield crops have curbed agricultural land expansion, but care needed to avoid negative biodiversity effects

The widespread use of higher-yielding improved varieties of crops as part of the ‘Green Revolution’ has averted the conversion of between 18 to 27 million hectares of forests, woodlands and pastures in the period 1965 to 2004, according to a recent study. However, its authors caution that the relationship between these crops and land use change is complex, and good governance is needed to protect biodiversity from future expansion of agricultural land.




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Combination Effects of Chemicals

Outside the laboratory, living organisms are never subject to single stressors at set doses. In the real world, they face an intricate array of physical, chemical and biological environmental stressors that vary in space and time. The problem of assessing these complex risks for human health and the environment is a great challenge for scientists and regulators alike. For example, even if Maximum Permissible Concentrations (MPCs) for individual contaminants are not exceeded in water, in combination they can still be potentially hazardous to wildlife. This thematic issue reports on scientific research which can help us overcome some of the challenges associated with assessing the combination effects of chemicals.




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Possible long-term effects of aircraft noise on children’s cognition

Companies that adopt the environmental management system ISO 14000, designed to help reduce businesses’ environmental impacts, generally back this up with sincere investment in environmentally-friendly practices, research suggests. Researchers found that adoption of the ISO 14000 was not ‘greenwash’, but reflected a move towards more sustainable practices in both European and North American companies.




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Natural fertilisation of sea hints at effects of geoengineering projects

New research investigating the effects of naturally occurring iron fertilisation in the sea suggests that large scale geoengineering projects designed to sequester carbon in the deep sea could have a dramatic impact on marine ecosystems. The study found that the organic matter arriving at the sea floor and the species that live there are very different, depending on whether waters are fertilised by iron leached from nearby islands or not.




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Fukushima’s effects on nuclear policy in Germany and the UK

The Fukushima accident in Japan has sparked international debate on nuclear energy. A new study has identified five factors which may have influenced the contrasting energy policy responses to the incident in the UK and Germany. Following the disaster, the UK is continuing to back nuclear power generation, whilst Germany is withdrawing support.




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European health experts warn of climate change’s effects on disease

Climate change will affect the spread and risk of many infectious diseases in Europe, according to a recent survey of leading health experts. The results suggest that more needs to be done to prepare for the expected changes in infectious disease levels, such as improved monitoring of disease.




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Significant economic effects of climate change on European timber industry

The impact of climate change on the distribution of tree species is likely to have economic implications for the timber industry. A new study has estimated that climate-induced shifts in range could reduce the value of European forest land for the timber industry by between 14 and 50% by 2100. At the higher end of this estimate, this could equate to a potential loss of several hundred billions of euros.




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Do warming and drought have lasting effects on soil ecosystems?

Despite the substantial impacts warming and drought can have on soil bacteria and fungi, these are not sustained if external conditions re-stabilise, a new study suggests. Small-scale experiements in five countries across Europe to show that even if warming and droughts continued for over a decade, there were no lasting effects on key properties of soils, such as growth rates, when the soils were allowed to re-stabilise in a laboratory over seven days.




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Peak warming effects of today’s CO2 emissions may be as soon as 10 years from now

The benefits of CO2 cuts made now, such as avoided floods and droughts, will be felt within the lifetimes of most people alive today, new research indicates. The study’s authors say their work dispels myths that the main effects of CO2 emissions will not be felt for many decades. They estimate that it could take 10 years for the maximum warming effects of a one-off CO2 emission to occur.




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Intensive grassland farming could have deep effects: sequestering significantly less soil carbon

Huge amounts of soil carbon have been discovered up to 1 metre below grassland in a recent UK study. Yet most carbon inventories do not assess soil deeper than 30cm. Furthermore, this research suggests that intensive management of grassland, involving high rates of fertiliser use and livestock grazing, may deplete carbon at these depths.




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Microplastic pollution's effects explored for two key marine species: mussels and lugworms

Mussels exposed to high levels of microplastic pollution display signs of stress, new research has shown. However, levels of exposure were higher than found in the wild and no effect on the energy reserves of either mussels or lugworms was observed in the lab. tests. The researchers caution that longer experiments may be needed to reveal microplastics' full effects.




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Green spaces can have positive, long-term effects on mental health

Moving to an area with good access to green spaces has a positive, lasting effect on residents' mental health, new research suggests. The study shows that people who move to greener areas report considerably improved mental health three years after leaving their previous neighbourhood.




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Side effects of Covid-19: Widespread adoption of telemedicine

From driving behavioral change to encouraging doctor-patient collaboration, telemedicine’s time in the sun has proved beneficial as a collateral benefit of Covid-19.




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Personnel selection, training could mitigate effects of cognitive lock-up in automation operators

Automation failures have been the cause of such widely reported disasters as the crash of Air France Flight 447 in 2009, with most of the focus placed on deficiencies in the automated system. Although automation does help in avoiding human error in completing tasks, people are still needed to monitor how well the automated system is operating.

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  • Psychology & Sociology

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Predicting effects of electric vehicles on the electricity grid

Recent research suggests that increasing the number of private electric vehicles would have very little impact on electricity consumption in Milan, Italy. However, unless there are suitable regulations, the daily demand for power to recharge the vehicles at peak times could overload the capacity of the electric supply system.




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Climate change and transport: effects of sea-level rise on an English railway line

Climate change will have major consequences for transport networks, especially those located on coastlines. This study assessed the impact of projected sea-level rise on a vulnerable stretch of railway line on the coast of South West England. The authors say their semi-empirical modelling method could provide guidance to policymakers worldwide.




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Effects of climate change on insect pests in European forests

A recent study has assessed how climate change could affect the impact of European insect pests on forests to help develop effective forest protection strategies. Changing temperatures may cause some populations of insects to grow or move into new regions of Europe.




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Effects of international wood trade on forests: wealthier countries benefit

International trade in wood and wood products affects forest stocks around the world. A recent study examines the relationship between changes in forest cover and international timber trade at global level. If finds that some wealthier nations with low population density can maintain forest areas while exporting wood; but other, usually poorer, nations, are losing forests through domestic and global demand for wood.




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Significant economic effects of climate change on European timber industry

The impact of climate change on the distribution of tree species is likely to have economic implications for the timber industry. A new study has estimated that climate-induced shifts in range could reduce the value of European forest land for the timber industry by between 14 and 50% by 2100. At the higher end of this estimate, this could equate to a potential loss of several hundred billions of euros.




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Effects of shale gas development on water quality: experiences from the Marcellus Shale

The impact of shale gas development on surface water quality has been explored in a recent study. Focusing on the Pennsylvania portion of the Marcellus Shale formation (which stretches from West Virginia to the Canadian border), the researchers conclude that shale gas wells and the treatment of shale gas extraction waste have measurable impacts on downstream surface water quality.




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New tool assesses the effects of global change on water resources

Water resource management needs to adapt to changes in climate, water demand and land use. A new tool has been developed by the LIFE+ Water Change Project to assess these ‘global change’ impacts on water resources and inform decisions on optimal adaptation strategies. A recent study has applied the tool to a river basin in Spain.




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Nutrients in streams can mask toxic effects of pesticides on aquatic life

Moderate levels of nitrogen in streams and rivers can make it difficult to assess the effects of pesticides on aquatic wildlife, because nutrients mask the pesticides’ impacts, according to recent research. This highlights the importance of considering nutrient levels when developing measures to protect aquatic ecosystems.




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Volume of leachate and environmental impact from landfills reduced — but legacy effects remain

Landfill leachate is the liquid that seeps through or out of waste deposits in landfill sites. EU regulations, such as the Landfill Directive1, have significantly reduced the volume of leachate produced, a study on leachate management in Ireland has found. Leachate, mainly from younger landfills in Ireland is, however, stronger since implementation of the legislation, and the researchers say the future treatment of leachate under stricter environmental protection regulations will continue to be a long-term concern for landfill operators and regulators.