Electrolit's planned 600,000-sq.-ft. greenfield project is slated to open in early 2026.

The title compound [systematic name: 1,10-phenanthrolinium 6-hydroxy-5-(oxidoimino)-1,3-diazinane-2,4-dione–6-hydroxy-5-(hydroxyimino)-1,3-diazinane-2,4-dione–water (1/1/5)], C12H9N2+·C4H2N3O4−·C4H3N3O4·5H2O, is a co-crystal salt hydrate comprising 1,10-phenanthrolinium cations, violurate anions, free violuric acid as co-former and five water molecules of crystallization per formula unit. The violurate and the violuric acid residues each form distinct N—H...O hydrogen-bonded tapes with a common R22(8) hydrogen-bond motif extending parallel to (103). Solvent water molecules connect the tapes to form a tri-periodic hydrogen-bonded network with channels extending parallel to the a-axis direction, which accommodate the N—H...Owater hydrogen-bonded 1,10-phenanthrolinium cations. Direct N—H...O hydrogen bonds between the 1,10-phenanthrolinium and violurate ions are not encountered.

Carolina Hurricanes defenseman Sean Walker, who turns 30 today, went a long way to the NHL after going undrafted. But it paid off in a big way.

26-year-old recorded six points in 47 game with the Rochester Americans last season

Republicans in North Carolina plan to override Gov. Roy Cooper's veto of an immigration and school choice bill in their closing days of session.

bPembrolizumab, an immunotherapy medication/b, significantly enhanced disease-free survival when added to the standard of care for patients with advanced soft tissue sarcoma of the limb.

Discover how pembrolizumab, an immunotherapy drug, enhances disease-free survival in advanced soft tissue sarcoma, offering a promising treatment alternative.

Bingham-Koslowski, N; Grey, M; Ehrman, J M; Pufahl, P. The Atlantic Geoscience Society (AGS), 47th Colloquium and Annual Meeting, program with abstracts/La Société Géoscientifique de l'Atlantique, 47th Colloquium and Annual Meeting, program with abstracts; 2021 p. 14
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200688.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200688.jpg" title="The Atlantic Geoscience Society (AGS), 47th Colloquium and Annual Meeting, program with abstracts/La Société Géoscientifique de l'Atlantique, 47th Colloquium and Annual Meeting, program with abstracts; 2021 p. 14" height="150" border="1" /></a>

Bingham-Koslowski, N; Grey, M; Pufahl, P; Ehrman, J; Strauss, A. Geoscience Canada vol. 50, 2023 p. 118, https://doi.org/10.12789/geocanj.2023.50.20
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20220635.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20220635.jpg" title="Geoscience Canada vol. 50, 2023 p. 118, https://doi.org/10.12789/geocanj.2023.50.20" height="150" border="1" /></a>

Video: Caroline Says – “Faded and Golden”

From The Lucky One, out October 11 on Western Vinyl.

Caroline Says is Caroline Sallee and she’s moved around a lot. She was raised in Alabama. She moved to Austin. Then back to Alabama. And now she’s based in Brooklyn. That much moving, more than anything, reveals that you can’t go home again.

The house where you don’t live no more
When I drive by I still call it yours.

Nothing’s ever the same as how you left it.

When I said goodbye and said I’d see you soon
And how I keep you in my head just dies when I see you.

Sallee says, “Relationships are, first and foremost, ideas. That’s what allows relationships to persist even when we’re apart. We may yearn for an old friend or lover, especially one from our teenage years and our hometown. But there is a bittersweetness to any reunion. They may shatter the memory we’ve made of them.”

Shatter? Come on. What kind of fragile-ass memories do you have? People change.

Read more at Glorious Noise...

Cinch Home Buyers introduces an innovative cash offer service in North Carolina, empowering homeowners to sell on their terms with speed, transparency, and convenience. [PR.com]

•  Friendly staff and excellent food! (Loved the fresh orange juice and the fry jacks for breakfast) 
• Clean and comfortable room (Loved the fridge and coffee maker) 
• Beautiful surroundings and wonderful sounds of the jungle (Orange trees, flowers, howler monkeys, horses galloping, and birds, plus roosters too!) 
• Refreshing pool and relaxing hammocks…aahhhh! 
• Daytrips to the ruins, cave tubing with David, the Blue Hole to swim, and driving on the beautiful Hummingbird Highway. 
• Also, the visit to Iguana Conservation Project in San Ignacio, was lots of fun (I think I’ve already taken over 1000 photos in three days)

Fr. Joseph visits with Fr. James Guirguis and the fine folks of St Raphael Mission in Fuquay-Varina, North Carolina, on their first Family Night of 2018.

Kassiani Mamalakis interviews Caroline Retzios on her OCF Story and journey as an Orthodox Christian.

Fr. John interviews Fr. Christopher Foley of Holy Cross Orthodox Church, High Point, North Carolina.

Fr. John shares an update and prayerful reflections on the recent flooding in South Carolina.

Matthew recounts the first of many scandals that have rocked the St. Alexander Nevsky Russian Orthodox Cathedral in San Francisco and then explains why knowledge of such scandals is important. Learn more HERE.

by Dr Kim Barker (University of Stirling) & Dr Olga Jurasz (Open University) The UK Government has recently published an Online Harms White Paper: initial consultation response. It is the cornerstone of the Government’s ongoing reform package which aims to

A driver has died after going around a barricade on a hurricane-damaged North Carolina highway that became a symbol of Helene's destruction, then driving off the roadway, officials said.

South Carolina has lifted the suspension of forward Ashlyn Watkins after charges of assault and kidnapping were dismissed earlier this month.

One of 43 monkeys bred for medical research that escaped a compound in South Carolina has been recovered unharmed, officials said Saturday.

Republican Donald Trump won North Carolina, capturing one of the seven heavily contested battlegrounds while votes in six other swing states are still being counted

The post The Latest: Trump wins North Carolina and GOP wins Senate control appeared first on Boston.com.

On Oct. 7, IIBEC sent a letter to the mayor and city council of Wilmington, North Carolina, recommending that they consider establishing a building façade inspection program in light of two recent building failures.

Raleigh, NC — Three new workplace safety videos are available at the Charles H. Livengood Jr. Memorial Library in Raleigh, the North Carolina Department of Labor has announced.

Washington – After a recent visit with workers in tobacco fields and labor camps in North Carolina, members of an international delegation said they were shocked and saddened to see widespread worker abuse.

Columbia, SC — South Carolina OSHA has announced its plan to adopt a standard on infectious diseases in the workplace, including COVID-19.

Columbia, SC — To help mark its 50th anniversary as a State Plan state, South Carolina OSHA is encouraging employers to provide at least 50 minutes of additional safety training to their workers during Safety Stand Down Week – set for Dec. 5-9.

In her new leadership role, Brown will work to ensure the TMA Five Diamond designation remains current and reflective of excellence in security monitoring.

A look at new plant based meat alternatives and snacks continuing to drive growth in the plant based space.

Each 21fl-oz serving of Electrolit contains 326mg of electrolytes alongside real glucose- a natural source of energy that boosts the body's recovery from dehydration.

Versatrim employees, including CEO Keith Medick and founder Thilo Hessler, delivered three truckloads of essential supplies to Western North Carolina communities affected by Hurricane Helene. 

Avery Dennison Label and Packaging Materials EMENA has introduced AD XeroLinr DT, a new FSC-certified and phenol-free direct thermal (DT) linerless solution that drives productivity, reduces waste and advances sustainability.

The crystal structure of a pyrrolidine analogue obtained from the stereoselective reduction of the enolic form of 4-hy­droxy-2-furyl-pyrrole­carboxyl­ate is described.

Proliferating cell nuclear antigen (PCNA) plays a critical role in DNA replication by enhancing the activity of various proteins involved in replication. In this study, the crystal structure of ApePCNA1, one of three PCNAs from the thermophilic archaeon Aeropyrum pernix, was elucidated. ApePCNA1 was cloned and expressed in Escherichia coli and the protein was purified and crystallized. The resulting crystal structure determined at 2.00 Å resolution revealed that ApePCNA1 does not form a trimeric ring, unlike PCNAs from other domains of life. It has unique structural features, including a long interdomain-connecting loop and a PIP-box-like sequence at the N-terminus, indicating potential interactions with other proteins. These findings provide insights into the functional mechanisms of PCNAs in archaea and their evolutionary conservation across different domains of life. A modified medium and protocol were used to express recombinant protein containing the lac operon. The expression of the target protein increased and the total incubation time decreased when using this system compared with those of previous expression protocols.

The crystal structure of the co-crystal salt solvate 1,10-phenanthrolinium violurate violuric acid penta­hydrate features a tri-periodic hydrogen-bonded network with the violurate and violuric acid residues each assembled into tapes and the phenanthrolinium cations residing in channels.

In the title complex, [ZnCl2(C14H12N2O2)], the ZnII atom is located on a twofold rotation axis and is fourfold coordinated by two chlorido ligands and a bidentate 4,7-meth­oxy-1,10-phenanthroline ligand in a distorted tetra­hedral environment. Weak π–π stacking inter­actions between adjacent 4,7-dimeth­oxy-1,10-phenanthroline rings [centroid-to-centroid distances = 3.5969 (11) and 3.7738 (11) Å] contribute to the alignment of the complexes in layers parallel to (overline{2}01).

The title compound, [Ir(C15H10N)2(C19H12N4)]PF6·CH3OH, crystallizes in the C2/c space group with one monocationic iridium complex, one hexa­fluorido­phosphate anion, and one methanol solvent mol­ecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation via hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.

The title compound, [Ru(C12H14NO2)2(C12H8N2)]PF6 crystallizes in the tetra­gonal Sohnke space group P41212. The two bidentate chiral salicyloxazoline ligands and the phenanthroline co-ligand coordinate to the central RuIII atom through N,O and N,N atom pairs to form bite angles of 89.76 (15) and 79.0 (2)°, respectively. The octa­hedral coordination of the bidentate ligands leads to a propeller-like shape, which induces metal-centered chirality onto the complex, with a right-handed (Δ) absolute configuration [the Flack parameter value is −0.003 (14)]. Both the complex cation and the disordered PF6− counter-anion are located on twofold rotation axes. Apart from Coulombic forces, the crystal cohesion is ensured by non-classical C—H⋯O and C—H⋯F inter­actions.

A confiscated package of street drugs was characterized by the usual mass spectral (MS) and FT–IR analyses. The confiscated powder material was highly crystalline and was found to consist of two very different species, accidentally of sizes convenient for X-ray diffraction. Thus, one each was selected and redundant com­plete sets of data were collected at 100 K using Cu Kα radiation. The selected crystals contained: (a) 1,2-diphenyl-2-(pyrrolidin-1-yl)ethanone hy­dro­chloride hemihydrate or 1-(2-oxo-1,2-di­phenyl­eth­yl)pyrrolidin-1-ium chloride hemihydrate, C18H20NO+·Cl−·0.5H2O, (I), a synthetic cathinone called `α-D2PV', and (b) the sugar myo-inositol, C6H12O6, (II), probably the only instance in which the drug and its diluent have been fully characterized from a single confiscated sample. Moreover, the structural details of both are rather attractive showing: (i) inter­esting hydrogen bonding observed in pairwise inter­actions by the drug mol­ecules, mediated by the chloride counter-anions and the waters of crystallization, and (ii) π–π inter­actions in the case of the phenyl rings of the drug which are of two different types, namely, π–π stacking and edge-to-π. Finally, the inositol crystallizes with Z' = 2 and the resulting diastereoisomers were examined by overlay techniques.

The crystal structures of two coordination com­pounds, (acetato-κO)(2,2'-bi­py­ri­dine-κ2N,N')(1,10-phenanthroline-κ2N,N')copper(II) acetate hexa­hydrate, [Cu(C2H3O2)(C10H8N2)(C12H8N2)](C2H3O2)·6H2O or [Cu(bipy)(phen)Ac]Ac·6H2O, and (acetato-κO)bis­(2,2'-bi­py­ri­dine-κ2N,N')copper(II) acetate–acetic acid–water (1/1/3), [Cu(C2H3O2)(C10H8N2)2](C2H3O2)·C2H4O2·3H2O or [Cu(bipy)2Ac]Ac·HAc·3H2O, are reported and com­pared with the previously published structure of [Cu(phen)2Ac]Ac·7H2O (phen is 1,10-phenanthroline, bipy for 2,2'-bi­py­ri­dine, ac is acetate and Hac is acetic acid). The geometry around the metal centre is penta­coordinated, but highly distorted in all three cases. The coordination number and the geometric distortion are both discussed in detail, and all com­plexes belong to the space group Poverline{1}. The analysis of the geometric parameters and the Hirshfeld surface properties dnorm and curvedness provide information about the metal–ligand inter­actions in these com­plexes and allow com­parison with similar systems.

The title complex, [ZnCl(C12H15N3O2)2][ZnCl3(CH3CN)], was synthesized and its structure was fully characterized through single-crystal X-ray diffraction analysis. The complex crystallizes in the ortho­rhom­bic system, space group Pbca (61), with a central zinc atom coordinating one chlorine atom and two pyrrolidinyl-4-meth­oxy­phenyl azoformamide ligands in a bidentate manner, utilizing both the nitro­gen and oxygen atoms in a 1,3-heterodiene (N=N—C=O) motif for coordinative bonding, yielding an overall positively (+1) charged complex. The complex is accompanied by a [(CH3CN)ZnCl3]− counter-ion. The crystal data show that the harder oxygen atoms in the heterodiene zinc chelate form bonding inter­actions with distances of 2.002 (3) and 2.012 (3) Å, while nitro­gen atoms are coordinated by the central zinc cation with bond lengths of 2.207 (3) and 2.211 (3) Å. To gain further insight into the inter­molecular inter­actions within the crystal, Hirshfeld surface analysis was performed, along with the calculation of two-dimensional fingerprint plots. This analysis revealed that H⋯H (39.9%), Cl⋯H/H⋯Cl (28.2%) and C⋯H/H⋯C (7.2%) inter­actions are dominant. This unique crystal structure sheds light on arrangement and bonding inter­actions with azo­formamide ligands, and their unique qualities over similar semicarbazone and azo­thio­formamide structures.

In the title compound, C19H18BrFN2O, the pyrrolidine ring adopts an envelope conformation. In the crystal, mol­ecules are linked by inter­molecular N—H⋯O, C—H⋯O, C—H⋯F and C—H⋯Br hydrogen bonds, forming a three-dimensional network. In addition, C—H⋯π inter­actions connect mol­ecules into ribbons along the b-axis direction, consolidating the mol­ecular packing. The inter­molecular inter­actions in the crystal structure were qu­anti­fied and analysed using Hirshfeld surface analysis.

The cyclic peptide cyclo(Val-Leu-Leu-d-Phe-Pro)2 (peptide 1) was specifically designed for structural chemistry investigations, drawing inspiration from Gramicidin S (GS). Previous studies have shown that Pro residues within 1 adopt a down-puckering conformation of the pyrrolidine ring. By incorporating fluoride-Pro with 4-trans/cis-isomers into 1, an up-puckering conformation was successfully induced. In the current investigation, introducing hy­droxy­prolines with 4-trans/cis-isomer configurations (tHyp/cHyp) into 1 gave cyclo(Val-Leu-Leu-d-Phe-tHyp)2 methanol disolvate monohydrate, C62H94N10O12·2CH4O·H2O (4), and cyclo(Val-Leu-Leu-d-Phe-cHyp)2 monohydrate, C62H94N10O12·H2O (5), respectively. However, the puckering of 4 and 5 remained in the down conformation, regardless of the geometric position of the hydroxyl group. Although the backbone structure of 4 with trans-substitution was asymmetric, the asymmetric backbone of 5 with cis-substitution was unexpected. It is speculated that the anti­cipated influence of stress from the geometric positioning, which was expected to affect the puckering, may have been mitigated by inter­actions between the hydroxyl groups of hy­droxy­proline, the solvent mol­ecules, and peptides.

This study presents the synthesis, characterization and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromo­phen­yl)-1,2,3,4-tetra­hydro­quinolin-4-yl]pyrrolidin-2-one, C19H18Br2N2O. In the title compound, the pyrrolidine ring adopts a distorted envelope configuration. In the crystal, mol­ecules are linked by inter­molecular N—H⋯O, C—H⋯O and C—H⋯Br hydrogen bonds, forming a three-dimensional network. In addition, pairs of mol­ecules along the c axis are connected by C—H⋯π inter­actions. According to a Hirshfeld surface study, H⋯H (36.9%), Br⋯H/H⋯Br (28.2%) and C⋯H/H⋯C (24.3%) inter­actions are the most significant contributors to the crystal packing.

The title compound, [Sn(C6H5)Cl3(C12H8N2)], which was obtained by the reaction between 1,10-phenanthroline and phenyl­tin trichloride in methanol, exhibits intra­molecular hydrogen-bonding inter­actions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by inter­molecular C—H⋯Cl hydrogen bonds, as well as Y—X⋯π and π-stacking inter­actions involving three different aromatic rings with centroid–centroid distances of 3.6605 (13), 3.9327 (14) and 3.6938 (12) Å]. Hirshfeld surface analysis and the associated two-dimensional fingerprint plots reveal significant contributions from H⋯H (30.7%), Cl⋯H/H⋯Cl (32.4%), and C⋯H/H⋯C (24.0%) contacts to the crystal packing while the C⋯C (6.2%), C⋯Cl/Cl⋯C (4.1%), and N⋯H/H⋯N (1.7%) inter­actions make smaller contributions.

Help shape the future of greenways and trails in Catawba County! Catawba County and the Carolina Thread Trail planners ask citizens to help with planning for the trail by taking an online survey.

Colonel Michael W. Gilchrist, Commander of the Highway Patrol, presented the awards to EMT Paramedic and Crew Chief Brad Harris and EMT Paramedic Eric Jones for their role in pulling a person from a burning vehicle.

The Catawba County Building Services Division has built a web page with links to the new code.