L3-edge high-energy-resolution fluorescence-detection X-ray absorption near-edge structure (XANES) spectra for palladium and rhodium compounds are presented, with focus on their electronic structures. The data are compared with transmission XANES spectra recorded at the K-edge. A correlation between the absorption edge energy and the metal ion oxidation state is not observed. Despite the different filling of the 4d orbitals and different local coordination, the Rh and Pd compounds show remarkably similar spectral shapes. Calculation of the density of states and of the L3-XANES data reproduce the experimental results.

In situ and operando investigation of photocatalysts plays a fundamental role in understanding the processes of active phase formation and the mechanisms of catalytic reactions, which is crucial for the rational design of more efficient materials. Using a custom-made operando photocatalytic cell, an in situ procedure to follow the formation steps of Pd/TiO2 photocatalyst by synchrotron-based X-ray absorption spectroscopy (XAS) is proposed. The procedure resulted in the formation of ∼1 nm Pd particles with a much narrower size distribution and homogeneous spreading over TiO2 support compared with the samples generated in a conventional batch reactor. The combination of in situ XAS spectroscopy with high-angle annular dark-field scanning transmission electron microscopy demonstrated the formation of single-atom Pd(0) sites on TiO2 as the initial step of the photodeposition process. Palladium hydride particles were observed for all investigated samples upon exposure to formic acid solutions.

The title complex, [PdCl2(C9H13N)2], comprises a single mol­ecule in the asymmetric unit. The PdII atom is tetra­coordinated by two N atoms from two trans-aligned organic ligands and two Cl ligands, forming a square-planar metal coordination environment. The distances from the ortho-H atoms on the phenyl ring to the central PdII atom fall within the range 4.70–5.30 Å, precluding any significant intra­molecular Pd⋯H inter­actions.

In the title complex salt, [Pd(C10H8N2)(C12H12N2O2)](CF3SO3)2, the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2'-bi­pyridine and 4,4'-dimeth­oxy-2,2'-bi­pyridine, in a distorted square-planar environment. In the crystal, weak π–π stacking inter­actions between the 2,2'-bi­pyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4'-dimeth­oxy-2,2'-bi­pyridine rings [centroid-to-centroid distances = 3.747 (18) Å] contribute to the alignment of the complex cations in columns parallel to the b-axis direction.

The mol­ecule of the title NCNHCS pincer N-heterocyclic carbene palladium(II) complex, [PdBr(C21H25N3S)]Br, exhibits a slightly distorted square-planar coordination at the palladium(II) atom, with the five-membered chelate ring nearly planar. The six-membered chelate ring adopts an envelope conformation. Upon chelation, the sulfur atom becomes a stereogenic centre with an RS configuration induced by the chiral carbon of the precursor imidazolium salt. There are intra­molecular C—H⋯Br—Pd hydrogen bonds in the structure. The two inter­stitial Br atoms, as the counter-anion of the structure, are both located on crystallographic twofold axes and are connected to the complex cations via C—H⋯·Br hydrogen bonds.

The PdII complex bis­{(S)-(−)-N-[(biphenyl-2-yl)methyl­idene]1-(4-meth­oxy­phen­yl)ethanamine-κN}di­chlorido­palladium(II), [PdCl2(C22H21NO)2], crystallizes in the monoclinic Sohncke space group P21 with a single mol­ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N—Pd—Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd—Cl and Pd—N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features inter­molecular N—H⋯Cl and intramolecular C—H⋯Pd inter­actions, which lead to the formation of a supramolecular framework structure.

The reaction between the (R,S)-fixolide 4-methyl­thio­semicarbazone and PdII chloride yielded the title compound, [Pd(C20H30N3S)2]·C2H6O {common name: trans-bis­[(R,S)-fixolide 4-methyl­thio­semicarbazonato-κ2N2S]palladium(II) ethanol monosolvate}. The asymmetric unit of the title compound consists of one bis-thio­semicarbazonato PdII complex and one ethanol solvent mol­ecule. The thio­semicarbazononato ligands act as metal chelators with a trans configuration in a distorted square-planar geometry. A C—H⋯S intra­molecular inter­action, with graph-set motif S(6), is observed and the coordination sphere resembles a hydrogen-bonded macrocyclic environment. Additionally, one C—H⋯Pd anagostic inter­action can be suggested. Each ligand is disordered over the aliphatic ring, which adopts a half-chair conformation, and two methyl groups [s.o.f. = 0.624 (2):0.376 (2)]. The disorder includes the chiral carbon atoms and, remarkably, one ligand has the (R)-isomer with the highest s.o.f. value atoms, while the other one shows the opposite, the atoms with the highest s.o.f. value are associated with the (S)-isomer. The N—N—C(=S)—N fragments of the ligands are approximately planar, with the maximum deviations from the mean plane through the selected atoms being 0.0567 (1) and −0.0307 (8) Å (r.m.s.d. = 0.0403 and 0.0269 Å) and the dihedral angle with the respective aromatic rings amount to 46.68 (5) and 50.66 (4)°. In the crystal, the complexes are linked via pairs of N—H⋯S inter­actions, with graph-set motif R22(8), into centrosymmetric dimers. The dimers are further connected by centrosymmetric pairs of ethanol mol­ecules, building mono-periodic hydrogen-bonded ribbons along [011]. The Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are [atoms with highest/lowest s.o.f.s considered separately]: H⋯H (81.6/82.0%), H⋯C/C⋯H (6.5/6.4%), H⋯N/N⋯H (5.2/5.0%) and H⋯S/S⋯H (5.0/4.9%).

The (S)-(+)-1-(4-bromo­phen­yl)-N-[(4-methoxyphen­yl)methyl­idene]ethyl­amine ligand, C16H16BrNO, (I), was synthesized through the reaction of 4-meth­oxy­anisaldehyde with (S)-(−)-1-(4-bromo­phen­yl)ethyl­amine. It crystallizes in the ortho­rhom­bic space group P212121 belonging to the Sohncke group, featuring a single mol­ecule in the asymmetric unit. The refinement converged successfully, achieving an R factor of 0.0508. The PdII com­plex bis­{(S)-(+)-1-(4-bromo­phen­yl)-N-[(4-methoxyphen­yl)methyl­idene]ethyl­amine-κN}di­chlorido­pal­ladium(II), [PdCl2(C16H16BrNO)2], (II), crystallizes in the monoclinic space group P21 belonging to the Sohncke group, with two mol­ecules in the asymmetric unit. The central atom is tetra­coordinated by two N atoms and two Cl atoms, resulting in a square-planar configuration. The imine moieties exhibit a trans configuration around the PdII centre, with average Cl—Pd—N angles of approximately 89.95 and 90°. The average distances within the palladium com­plex for the two mol­ecules are ∼2.031 Å for Pd—N and ∼2.309 Å for Pd—Cl.

The new palladium(II) complex, [Pd(C16H16N4O3)2](CF3COO)2·2CF3COOH, crystallizes in the triclinic space group Poverline{1} with the asymmetric unit containing half the cation (PdII site symmetry Ci), one tri­fluoro­actetate anion and one co-crystallized tri­fluoro­acetic acid mol­ecule. Two neutral chelating 2-[5-(3,4,5-tri­meth­oxy­phen­yl)-4H-1,2,4-triazol-3-yl]pyridine ligands coordinate to the PdII ion through the triazole-N and pyridine-N atoms in a distorted trans-PdN4 square-planar configuration [Pd—N 1.991 (2), 2.037 (2) Å; cis N—Pd—N 79.65 (8), 100.35 (8)°]. The complex cation is quite planar, except for the methoxo groups (δ = 0.117 Å for one of the C atoms). The planar configuration is supported by two intra­molecular C—H⋯N hydrogen bonds. In the crystal, the π–π-stacked cations are arranged in sheets parallel to the ab plane that are flanked on both sides by the tri­fluoro­acetic acid–tri­fluoro­acetate anion pairs. Apart from classical N/O—H⋯O hydrogen-bonding inter­actions, weak C—H⋯F/N/O contacts consolidate the three-dimensional architecture. Both tri­fluoro­acetic moieties were found to be disordered over two resolvable positions with a refined occupancy ratio of 0.587 (1):0.413 (17) and 0.530 (6):0.470 (6) for the protonated and deprotonated forms, respectively.

This study presents the synthesis, characterization and Hirshfeld surface analysis of the title mononuclear complex, [PdCl2(C12H14N4)]·C3H7NO. The compound crystalizes in the P21/c space group of the monoclinic system. The asymmetric unit contains one neutral complex Pd(HLc-Pe)Cl2 [HLc-Pe is 2-(3-cyclo­pentyl-1,2,4-triazol-5-yl)pyridine] and one mol­ecule of DMF as a solvate. The Pd atom has a square-planar coordination. In the crystal, mol­ecules are linked by inter­molecular N—H⋯O and C—H⋯N hydrogen bonds, forming layers parallel to the bc plane. A Hirshfeld surface analysis showed that the H⋯H contacts dominate the crystal packing with a contribution of 41.4%. The contribution of the N⋯H/H⋯N and H⋯O/O⋯H inter­actions is somewhat smaller, amounting to 12.4% and 5%, respectively.

ing with Palladium”, running February 3-24, 2023. Guests are invited to attend a Meet-the-Artist Reception on Friday, February 3 from 5:00-7:00 p.m. Roger Matsumoto has […]

The Cadence Palladium Emulation Platform is a hardware system that implements the design, accelerating its execution and verification. Itoffers the highest performance and fastest bring-up times for pre-silicon validation of billion-gate designs, using a custom processor built by Cadence.

This Palladium Introduction course is based on the Palladium 23.03 ISR4 version and covers the following modules:

• Introduction
• Palladium flow
• Running a design on the Palladium system

This course starts with an “Introduction” module that explains Palladium and other verification platforms to show its place in the big picture. It also compares Palladium with Protium and simulation and discusses its usage and limitations.

The “Palladium Flow” module includes two stages at a high level, which are Compile and Run. Then, it covers these stages in detail. First, it covers the ICE compile flow and IXCOM compile flow steps in detail. Then it explains Run, which is common for both ICE and IXCOM modes.

The third module, “Running Design on the Palladium System,” covers all the items required for running your design on the Palladium system, including:

• Software stack requirements
• Basic concepts required to understand the flow
• Compute machine requirements

In addition, this course contains labs for both the ICE and IXCOM flows with detailed steps to exercise the features provided by the Palladium system. The lab explains a practical example of multiple counters and exercising their signals for force, monitor, and deposit features, along with frequency calculation using a real-time clock. The course is available on the Cadence support page:

There is also a Digital Badge available. You will find the Badge exam opportunity when you enroll in the Online training or after you have taken the training as "live" training.

For questions and inquiries, or issues with registration, reach out to us at Cadence Training. Want to stay up to date on webinars and courses? Subscribe to Cadence Training emails. To view our complete training offerings, visit the Cadence Training website.

Related Training Bytes

• Palladium: What Are Verification Platforms
• Palladium: What Is Processor Based Emulation
• Palladium: Comparing Emulation (Z2) and Prototyping (X2)
• Palladium: What Are ICE and IXCOM Compile Flow
• Palladium: How to Process a Design to Run on Palladium
• Palladium: XCOM Compile Flow (TB+RTL to Palladium Database)
• Palladium: ICE Compile Flow (RTL to Palladium Database)
• Palladium: Legacy ICE Compile Flow
• Palladium: Cadence Software Releases for Palladium and Protium Flow
• Palladium: Setting of PATHs for Using Palladium
• Palladium: Z2 Hardware Structure (Blade and Boards)
• Palladium: What Is Sourceless and Loadless nets
• Palladium: Design Clocks
• Palladium: Step Count and Step Clock
• Palladium: Steps for Running the Design on Palladium Z2

Related Courses

• Verilog Language and Application Training
• SystemVerilog for Design and Verification
• Xcelium Simulator

Related Blogs

• Training Insights – A New Free Online Course on the Protium System for Beginner and Advanced Users
• It’s the Digital Era; Why Not Showcase Your Brand Through a Digital Badge!
• Training Insights - Free Online Courses on Cadence Learning and Support Portal

In the mol­ecule of the title N,N'-disubstituted imidazol-2-yl­idene palladium(II) complex, [PdBr2(C21H24N4O)]·CH2Cl2, the palladium(II) atom adopts a slightly distorted square-planar coordination (r.m.s. deviation = 0.0145 Å), and the five-membered chelate ring is almost planar [maximum displacement = 0.015 (8) Å]. The mol­ecular conformation is enforced by intra­molecular C—H⋯Br hydrogen bonds. In the crystal, complex mol­ecules and di­chloro­methane mol­ecules are linked into a three-dimensional network by C—H⋯O and C—H⋯Br hydrogen bonds.

In the title compound, [Pd(C10H24N4)]I2·H2O, the PdII ion is four-coordinated in a slightly distorted square-planar coordination environment defined by four N atoms from a 1,4,8,11-tetra­aza­cyclo­tetra­decane ligand. The cationic complex, two I− anions and the solvent water mol­ecule are linked through inter­molecular hydrogen bonds into a three-dimensional network structure.

In the title compound, [Pd(C7H3NO4)(C10H8N2)]·H2O, the PdII cation is four-coordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,2'-bi­pyridine ligand, one O atom and one N atom from the pyridine-2,6-di­carboxyl­ate anion. The complex and solvent water mol­ecule are linked by inter­molecular hydrogen bonds. In the crystal, the complex mol­ecules are stacked in columns along the a axis.

Bidentate and tridentate coordination of a 2,4-di-tert-butyl-substituted bridging amine bis­(phenolate) ligand to a palladium(II) center are observed within the same crystal structure, namely di­chlorido­({6,6'-[(ethane-1,2-diylbis(methyl­aza­nedi­yl)]bis­(methyl­ene)}bis­(2,4-di-tert-butyl­phenol))palladium(II) chlorido­(2,4-di-tert-butyl-6-{[(2-{[(3,5-di-tert-butyl-2-hy­droxy­phen­yl)meth­yl](meth­yl)amino}­eth­yl)(meth­yl)amino]­meth­yl}phenolato)palladium(II) methanol 1.685-solvate 0.315-hydrate, [PdCl2(C34H56N2O2)][PdCl(C34H55N2O2)]·1.685CH3OH·0.315H2O. Both complexes exhibit a square-planar geometry, with unbound phenol moieties participating in inter­molecular hydrogen bonding with co-crystallized water and methanol. The presence of both κ2 and κ3 coordination modes arising from the same solution suggest a dynamic process in which phenol donors may coordinate or dissociate from the metal center, and offers insight into catalyst speciation throughout Pd-mediated processes. The unit cell contains di­chlorido­({6,6'-[(ethane-1,2-diylbis(methyl­aza­nedi­yl)]bis­(methyl­ene)}bis­(2,4-di-tert-butyl­phenol))palladium(II), {(L2)PdCl2}, and chlorido­(2,4-di-tert-butyl-6-{[(2-{[(3,5-di-tert-butyl-2-hy­droxy­phen­yl)meth­yl](methyl)amino}eth­yl)(meth­yl)amino]­meth­yl}phenolato)palladium(II), {(L2X)PdCl}, mol­ecules as well as fractional water and methanol solvent mol­ecules.

The present invention relates to a diesel oxidation catalyst comprising a carrier substrate, and a first washcoat layer disposed on the substrate, the first washcoat layer comprising palladium supported on a support material comprising a metal oxide, gold supported on a support material comprising a metal oxide, and a ceria comprising compound, as well as a process for the preparation of such catalyst.

A method for producing a copolymer includes reacting a first monomer with a second monomer using a Pd-based catalyst, wherein the first monomer is a first hetero cyclic compound which includes a first hetero atom selected from S, N, and O, the first hetero cyclic compound in which a carbon atom adjacent to the first hetero atom is coupled with at least one hydrogen atom, and the second monomer is a second hetero cyclic compound which includes a second hetero atom selected from S, N, and O, the second hetero cyclic compound in which the second hetero atom is coupled with a carbon atom in which a halogen group selected from Br, Cl, and I is substituted.

The Center for the Performing Arts in Carmel invites the class of 2020 from across Central Indiana to a prom this August.

Looking to learn? There's a bunch of new RAKs (Rapid Adoption Kits) available online now!

1) Indago 19.09 Better Driver Tracing and More

Are you new to Indago and not sure where to start? Luckily, there’s a new Rapid Adoption Kit for you: the Indago 19.09 Overview RAK! This neat package contains everything you need to get your debugging started through Indago. In four short labs, plus a brief introductory lab, you’ll have all the basics of Indago 19.09 down—the Indago working environment, the SmartLog, how Indago interacts with the rest of the Cadence Verification Suite, and how Indago uses HDL driver tracing.

Lab 1 discusses the various debugging tools included in Indago and teaches you how to customize your Indago windows and environment settings. Lab 2 covers the SmartLog feature and talks about analyzing and filtering its messages to suit your needs, as well as how to interact with the waveform marker. Lab 3 is an interactive Indago debugging experience—it’ll walk you through how to use Indago and its features in an actual working environment: setting breakpoints, using simulator commands in the Indago console, toolbars, switches, and more. Lab 4 is all things HDL tracing—recording debug data, an introduction to debug assertions, waveform visualizations, driving expression analysis, and single-step driver tracing, among other things.

Interested? Check out the RAK here.

2) IXCOM MSIE: Faster Palladium Build Time

Got several testbenches you want to compile with the same DUT and tests and you want to do it fast? With IXCOM, all you have to do to compile those different testbenches is use the xrun command for each after compiling your DUT. But what exactly is IXCOM, and how does one start using it? This quick RAK can help—here, you’ll learn the basics of using MSIE features with IXCOM, complete with an example to get you started. Using MSIE can vastly improve your build times with Palladium and using IXCOM is the best way to shrink that tedious rebuild time as small as it can get. Check out this RAK here.

3)  JasperGold Control and Status Register Verification App Automates UVM Register Map Verification

New to the JasperGold Control and Status Register (CSR) Verification App for your UVM testbenches? Don’t worry; there’s a RAK for that! This eponymous RAK can get you up and running with this in no time, helping you automate your checks from UVM register map specs. With this RAK, you’ll learn the basics of the JasperGold CSR, how to use JasperGold CSR’s Proof Accelerator, and more. CSR features a model-based approach to predicting a register’s expected value, supports pipeline interfaces, all IP-XACT access policies, and it can fully model any expected register value. It also supports register aliases, read and write semantics, and separate read/write data latencies in any given field.

If this functionality sounds up your alley, you can take a look at this RAK here.

The rare metal is now worth US $1,700 an ounce.

Palladium decreased 57.03 USD/t oz. or 2.94% since the beginning of 2020, according to trading on a contract for difference (CFD) that tracks the benchmark market for this commodity. Historically, Palladium reached an all time high of 2875.50 in February of 2020. Palladium is a soft silver-white metal used mostly in the production of catalytic converters for petrol cars, electronics, dentistry, medicine, hydrogen purification, chemical applications, groundwater treatment and jewelry. The biggest producers of palladium are by far Russia and South Africa (70-80% of world output) followed by United States, Canada and Zimbabwe. Palladium Futures are available for trading in London Platinum and Palladium Market and on the New York Mercantile Exchange. The standard contact weights 100 troy ounces. .

JULIA LAWRENCE: On Wednesday night at London's Palladium, Madonna remembered her manners. And painful hip and knee be damned, she dazzled, the absolute trouper she is.

Fans paid hundreds of pounds to get in as the star belatedly played the first of her UK dates after cancelling the gig on Monday and being ordered to rest by doctors.

Madonna appeared ready for her second night at the London Palladium as she arrived in her chauffeur-driven car, flanked by security on Thursday.

Madonna has furiously accused the London Palladium of trying to 'censor' her by pulling the curtain down after she ran over her curfew on Wednesday.

The singer, 61, is currently performing her Madame X show at the theatre and has accused the London Palladium of trying to 'censor' her by pulling the curtain down on her five minutes after curfew.

Recently suffering from a knee injury, the singer, held onto her walking stick for support before being bundled into a black car by her hooded helper, on Saturday night