nitrogen

Salt marshes' capacity to sink carbon may be threatened by nitrogen pollution




nitrogen

Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00140K, Research Article
Qun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin Zhang
Here, an unprecedented one-step modular construction of C2-symmetric N-PACs through  reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be  converted into  a powerful organic photocatalyst.
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nitrogen

Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst

Org. Chem. Front., 2024, 11,2313-2318
DOI: 10.1039/D4QO00116H, Research Article
Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
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nitrogen

Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00280F, Research Article
Hui Yin, Siqi Jian, Xiujuan Feng, Ming Bao, Xuan Zhang
A metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.
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nitrogen

Retraction: Nickel nanoparticles immobilized on three-dimensional nitrogen-doped graphene as a superb catalyst for the generation of hydrogen from the hydrolysis of ammonia borane

J. Mater. Chem. A, 2024, 12,9247-9247
DOI: 10.1039/D4TA90071E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mojtaba Mahyari, Ahmad Shaabani
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nitrogen

Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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nitrogen

Balancing Act: Nitrogen and Potassium Key to Boosting Apple Photosynthesis

Nitrogen and potassium are fundamental nutrients for plant growth, but imbalances frequently disrupt agricultural systems. In apple orchards, low potassium can severely limit carbon and nitrogen metabolism, impairing photosynthesis and yield. Potassium availability is often reduced by environmental factors such as soil leaching, while nitrogen is frequently over-applied due to its affordability and yield-enhancing effects. Given these challenges, optimizing nitrogen and potassium levels in apple trees warrants further research to counter the negative impact of nutrient imbalances on plant health and productivity.




nitrogen

Safe use of liquid nitrogen

Liquid nitrogen is the colorless, odorless, clear liquefied form of nitrogen. It can be extremely dangerous to work around.




nitrogen

Safety board calls for an OSHA standard on liquid nitrogen

Washington — Chemical facilities that handle hazardous gases or cryogenic asphyxiants such as liquid nitrogen should maintain atmospheric monitoring and alarm systems and educate workers on hazards.




nitrogen

uboot4extlinux-nitrogen6q 2014.07-3.1 armv7h

U-Boot with Extlinux support for Nitrogen6X/Sabre Lite




nitrogen

3600 MHz Raspberry Pi 5 with Liquid Nitrogen

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nitrogen

Nitrogen Interventions: A Key to Better Health and Environment

Implementing high-ambition nitrogen interventions can benefit the environment and medlinkpublic health/medlink, suggests a new study. h2Is Earth's




nitrogen

Commercial kitchen operations produce a diverse range of gas-phase reactive nitrogen species

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00491D, Paper
Leigh R. Crilley, Jenna C. Ditto, Melodie Lao, Zilin Zhou, Jonathan P. D. Abbatt, Arthur W. H. Chan, Trevor C. VandenBoer
Gas phase reactive nitrogen (Nr) species in a commercial kitchen are mainly composed of expected species with many additional species completing the budget.
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nitrogen

Multistage construction of Gd-doped g-C3N4/Mo15S19 composites enabled both N2 activation and multiple electron transfer for an enhanced photocatalytic nitrogen reduction reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02016B, Research Article
Xiaoyu Jiang, Boran Tao, Hongda Li
A multistage construction of the Gd-doped g-C3N4/Mo15S19 catalyst, with Gd3+ as redox centers and Mo15S19 as N2 activation sites, synergistically enhances its photocatalytic NRR performance.
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nitrogen

Ammonia and formate cosynthesis via nitrate electroreduction combined with methanol electrooxidation over nitrogen-doped carbon-encapsulated nickel iron phosphide

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article
Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO3RR and anodic MOR is a viable way to coproduce ammonia (NH3) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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nitrogen

The use of single metal atoms-based photocatalysts for the production of ammonia through photocatalytic nitrogen fixation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article
Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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nitrogen

High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon

RSC Adv., 2024, 14,13017-13026
DOI: 10.1039/D4RA01641F, Paper
Open Access
Shayan Gul, Fatima Nasim, Waheed Iqbal, Amir Waseem, Muhammad Arif Nadeem
Efficient electrocatalytic CO2 reduction reaction (eCO2RR) to various products, such as carbon monoxide (CO), is crucial for mitigating greenhouse gas emissions and enabling renewable energy storage.
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nitrogen

Backbone editing of oxidized polyethylene: insertion of oxygen and nitrogen atoms via hydroxyalkyl azide-mediated rearrangements

Polym. Chem., 2024, 15,4554-4561
DOI: 10.1039/D4PY00973H, Paper
Andrew J. King, Ryan P. Sherrier, Jeffrey Aubé, Aleksandr V. Zhukhovitskiy
Hydroxyalkyl azide-mediated rearrangement modularly inserts heteroatoms and pendent functionality into oxidized polyethylene.
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nitrogen

Electrochemical system of nitrogen-doped TiO2, Fe–N–C, and copper hexacyanoferrate electrodes for photo-assisted energy conversion in acidic wastewater treatment

Phys. Chem. Chem. Phys., 2024, 26,27498-27509
DOI: 10.1039/D4CP02063D, Paper
Bianca Tainá Ferreira, Matheus Martins, Fritz Huguenin
This study examines the electrochemical performance of nitrogen-doped TiO2, Fe–N–C, and CuHCF electrodes for energy conversion in acidic solution neutralization, capturing 62.9 kJ per mole of protons.
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nitrogen

Nitrogen-doped graphene quantum dot-intensified tungsten oxide nanosheets as a SERS substrate for antibiotics detection

Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication
Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO3 NSs) were fabricated as SERS substrates.
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nitrogen

Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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nitrogen

Ultrafine VN quantum dots modified with a nitrogen-doped reduced graphene oxide anode material for enhanced rate capability and lifespan of lithium-ion batteries

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00502C, Paper
Dong Wang, Zihan Guo, Zhiwei Wang, Yanfang Gao
The excellent electrochemistry performance is attributed to vanadium nitride quantum dots (VNQDs) offering large capacity and nitrogen-doped reduced graphene oxide (NrGO) acting as a conductive network and buffer skeleton.
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nitrogen

Design and synthesis of few-layer molybdenum oxide selenide encapsulated in a 3D interconnected nitrogen-doped carbon anode toward high-performance sodium storage

New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper
Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO3–MoSe2 encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
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nitrogen

Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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nitrogen

Functionalized molybdenum disulfide (MoS2) monolayer as an efficient nanosensor towards toxic nitrogen containing gases

Environ. Sci.: Nano, 2024, 11,1740-1754
DOI: 10.1039/D4EN00072B, Paper
Wadha Alfalasi, Tanveer Hussain, Nacir Tit
Selective detection of toxic nitrogen-containing gases (e.g. NO and NO2) is achieved when special transition metal (TM) atoms are selected in doping molybdenum disulfide (MoS2) monolayer. The change of magnetic state is the secret of that selectivity.
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nitrogen

Fundamental studies of laser ablation ICPMS using a nitrogen plasma source and helium, argon and nitrogen as carrier gas

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00327F, Paper
Open Access
Dylan Käser, Ralf Kägi, Bodo Hattendorf, Detlef Günther
Nitrogen as alternative carrier gas for LA-ICPMS showed similar sensitivities and quantification capabilities as using helium in combination with a N2 plasma. The role of the gas and of the ablation cell design on the aerosol structure was studied.
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nitrogen

Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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nitrogen

Enhancing visual luminescence detection of tetracycline antibiotics through regulation of nitrogen-containing ligand and antenna effect of Ln3+

J. Mater. Chem. C, 2024, 12,17635-17646
DOI: 10.1039/D4TC02735C, Paper
Tingting Liu, Mengna Ji, Jun Zheng, Nana Liu, Hongguo Hao, Jianmin Dou, Jingjing Jiang, Yunwu Li, Suna Wang
Two water-stable luminescent Cd-MOFs were synthesized from flexible carboxylate ligand and two N-containing ligands with different rigidity and flexibility, which demonstrated different luminescence responses toward antibiotics TC/OTC.
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nitrogen

Design, Synthesis, and Optoelectronic Properties of Benzothiadiazole-fused Sulfur and Nitrogen-containing Polycyclic Heteroaromatics

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04250F, Paper
Yuxin Yin, Rui Shi, Zhongwei Liu, Yanru Li, Ting Jiang, Lingxu Zhao, Jie Li, Deyang Ji, Liqiang Li, Zhuping Fei
The optoelectronic property of sulfur and nitrogen-containing polycyclic heteroaromatics is still low and structure-property relationships remain unclear as compared with that of acenes and sulfur-heterocyclic aromatic hydrocarbons, which is mainly...
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nitrogen

Electrodegradation of nitrogenous pollutants in sewage: from reaction fundamentals to energy valorization applications

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00517A, Review Article
Ming-Lei Sun, Hao-Yu Wang, Yi Feng, Jin-Tao Ren, Lei Wang, Zhong-Yong Yuan
This review provides a comprehensive insight into the electrodegradation processes of nitrogenous pollutants in sewage, highlighting the reaction mechanisms, theoretical descriptors, catalyst design, and energy valorization strategies.
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nitrogen

Novel magneto-electrocatalyst Cr2CO2-MXene for boosting nitrogen reduction to ammonia

Mater. Horiz., 2024, 11,1769-1778
DOI: 10.1039/D3MH01945D, Communication
Neng Li, Zhongyong Zhang, Zheng Wang, Bin Liu, Deyong Zhou, Xing Zhou, Peng Zhang, Xiujian Zhao
Gibbs free energy for electrocatalytic nitrogen reduction on Cr2CO2 with four magnetic states: NM, FM, Inter-AFM, and In-AFM.
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nitrogen

Electrochemical frontiers in the nitrogen cycle

Inorg. Chem. Front., 2024, 11,2202-2204
DOI: 10.1039/D4QI90016B, Editorial
Xuping Sun, Jieshan Qiu, Chenghua Sun
Xuping Sun, Jieshan Qiu and Chenghua Sun introduce this Inorganic Chemistry Frontiers themed collection on nitrogen cycle electrocatalysis.
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nitrogen

Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05998K, Edge Article
Open Access
Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi Guan
Utilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.
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nitrogen

Understanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water Microbubbles

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06989G, Edge Article
Open Access
Sandeep Bose, Yu Xia, Richard N. Zare
Understanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water MicrobubblesWater microbubbles containing Fe2+ ion has been found to efficiently transform nitrogen (N2) to nitrate (NO3-) by initiating...
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nitrogen

Nitrogen-doped biomass-derived carbon dots for fluorescence determination of sunset yellow

Anal. Methods, 2024, 16,2063-2070
DOI: 10.1039/D3AY01944F, Paper
Qian Zhang, Xiaoqi Wang, Lili Yuan, Lina Yu, Congying Shao, Hongxing Jia, Shun Lu
Schematic of preparation of N-CDs and their sensing mechanism for sunset yellow.
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nitrogen

18F-labelling of nitrogen-containing aryl boronates – anti-cancer drug melflufen as a case study

Org. Chem. Front., 2024, 11,6411-6417
DOI: 10.1039/D4QO01594K, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kevin Bajerke, Fredrik Lehmann, Gunnar Antoni, Kálmán J. Szabó
This study addresses the 18F-labelling of nitrogen-containing arenes via copper-mediated radiofluorination (CMRF). In this case study, derivatives/fragments of the anti-cancer drug melflufen were targeted.
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nitrogen

Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR)

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02217C, Paper
Bijoy Ghosh, Sahtaz Ahmed, Ashwini K. Phukan
Comprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.
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nitrogen

The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02606C, Paper
Ian Dance
I describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.
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nitrogen

Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting

Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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nitrogen

Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02703E, Paper
Vilakkathala U. Krishnapriya, Cherumuttathu H. Suresh
Dinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.
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nitrogen

Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets

Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830
DOI: 10.1039/D4EW00538D, Paper
Jun Li, Salma Tabassum, Hüseyin Altundag
Denitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.
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nitrogen

Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03156C, Review Article
Laiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu, Shi Xue Dou
As a self-sustaining cycle, the electrocatalytic nitrogen cycle represents an avenue for rectifying the nitrogen imbalance and for synthesizing value-added chemicals, thereby contributing to a sustainable and carbon-neutral society.
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nitrogen

Generation of nitrogen by means of electrochemical oxygen depletion

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00104D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Sachse, Basil Noha Chelachottil, Andreas Glüsen, Martin Müller, Uwe Rau, Ralf Peters
Electrochemical oxygen reduction enables a high depletion of the oxygen content with very high Faraday efficiency at the same time.
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nitrogen

In situ preparation and performance of iron-based electro-magnetic synergistic electrochemical nitrogen fixation catalysts

Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper
Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO4 solution by electrochemical technology to catalyze the reduction of N2 to NH3. It was found that the applied magnetic field can significantly increase the current density.
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nitrogen

Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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nitrogen

Oxygen electrode catalysis in N-doped graphene: the role of nitrogen coordination and solvation effects

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03645J, Paper
Junxian Liu, Yun Wang, Yuantong Gu, Liangzhi Kou
The significance of explicit solvents in describing the adsorption behaviors of ORR/OER intermediates is emphasized. A higher HOMO level of active sites enhances binding to oxygen intermediates, thereby improving ORR/OER activity.
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nitrogen

A comparative study of single-particle cryo-EM with liquid-nitrogen and liquid-helium cooling

Radiation damage is the most fundamental limitation for achieving high resolution in electron cryo-microscopy (cryo-EM) of biological samples. The effects of radiation damage are reduced by liquid-helium cooling, although the use of liquid helium is more challenging than that of liquid nitrogen. To date, the benefits of liquid-nitrogen and liquid-helium cooling for single-particle cryo-EM have not been compared quantitatively. With recent technical and computational advances in cryo-EM image recording and processing, such a comparison now seems timely. This study aims to evaluate the relative merits of liquid-helium cooling in present-day single-particle analysis, taking advantage of direct electron detectors. Two data sets for recombinant mouse heavy-chain apoferritin cooled with liquid-nitrogen or liquid-helium to 85 or 17 K were collected, processed and compared. No improvement in terms of resolution or Coulomb potential map quality was found for liquid-helium cooling. Interestingly, beam-induced motion was found to be significantly higher with liquid-helium cooling, especially within the most valuable first few frames of an exposure, thus counteracting any potential benefit of better cryoprotection that liquid-helium cooling may offer for single-particle cryo-EM.




nitrogen

Scientists find excess nitrogen favors plants that respond poorly to rising CO2

Two grass species that had been relatively rare in the plots, Spartina patens and Distichlis spicata, began to respond vigorously to the excess nitrogen. Eventually the grasses became much more abundant. Nitrogen ultimately changed the composition of the ecosystem as well as its capacity to store carbon.

The post Scientists find excess nitrogen favors plants that respond poorly to rising CO2 appeared first on Smithsonian Insider.




nitrogen

Salt marshes' capacity to sink carbon may be threatened by nitrogen pollution