ammonia

Electrochemical nitrate reduction for ammonia production: amorphous or crystalline oxidized copper catalyst?

J. Mater. Chem. A, 2024, 12,8689-8693
DOI: 10.1039/D3TA07506K, Communication
Quanxiao Peng, Dandan Xing, Liuqi Dong, Yuhan Fu, Jixue Lu, Xiaoyu Wang, Changhong Wang, Chunxian Guo
An amorphous oxidized copper (a-O–Cu) is designed to investigate for electrochemical nitrate reduction to ammonia. It is found that a-O–Cu has high capability for water dissociation and amorphous structure-enabled high catalytic activity.
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ammonia

Retraction: Nickel nanoparticles immobilized on three-dimensional nitrogen-doped graphene as a superb catalyst for the generation of hydrogen from the hydrolysis of ammonia borane

J. Mater. Chem. A, 2024, 12,9247-9247
DOI: 10.1039/D4TA90071E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mojtaba Mahyari, Ahmad Shaabani
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ammonia

A bioinspired sulfur-surrounded iron catalyst for ammonia synthesis

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00710G, Paper
Na Zhang, Yubing Si, Qiang Fu, Xing Chen
A nitrogenase-inspired inorganic compound consisting of iron (Fe) and molybdenum disulfide (MoS2) is designed with a promising capability of N2 fixation using first principles.
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ammonia

Anhydrous ammonia: Know the dangers

Anhydrous ammonia – used in manufacturing, refrigeration and agriculture – is a pungent, colorless and toxic gas or liquid that, when concentrated, is corrosive to human tissue upon contact, according to NIOSH.




ammonia

OSHA announces new emphasis program for reducing exposures to ammonium nitrate, anhydrous ammonia

Kansas City, MO — OSHA has launched a Regional Emphasis Program addressing hazards stemming from exposure to fertilizer-grade ammonium nitrate and agricultural anhydrous ammonia.




ammonia

First aid for ammonia exposure

Working with ammonia requires caution. The flammable, colorless gas has the potential to explode if heated, warns the Canadian Center for Occupational Health and Safety. It’s also extremely toxic.




ammonia

Anhydrous ammonia tank failure spurs safety advisory

Washington — Two federal safety agencies are urging owners of certain “nurse” tanks used to transport anhydrous ammonia to check the tanks for potential “catastrophic failure.”




ammonia

Ammonia detector

This detector measures ultra-high ammonia concentrations – from 10,000 to 1 million ppm (saturated) – and provides extreme accuracy, excellent repeatability and an operating life measured in decades.




ammonia

Ammonia sensor

This NH3 long-life ammonia sensor works optimally regardless of how much it has been exposed to ammonia. It’s ideal in environments where ammonia could be present 24/7 – including refrigeration facilities, fertilizer manufacturing and livestock farms.




ammonia

CO2/Ammonia Cascade System Proves Effective in Retail Settings

Ongoing and evolving U.S. Environmental Protection Agency (EPA) and Department of Energy (DOE) regulations have created a complex landscape for supermarket owners.




ammonia

Ammonia leak at Pattani ice plant sickens 18

PATTANI - Local residents were evacuated and schools closed after an ammonia leak at an ice plant sickened 18 people in Muang district of this southern border province on Wednesday.




ammonia

Adani Power Takes Up Green Ammonia Combustion Pilot Project At Mundra Plant

As the world leaders converge in the UAE for the COP28 this week to chalk out strategies for climate mitigation, Adani Power announced it has taken up a green ammonia combustion pilot project at its Mundra plant.




ammonia

From Diesel to Ammonia: Unveiling Health Hazards at Sea

As colossal container ships traverse oceans delivering cargo, their massive diesel engines emit significant air pollutants that contribute to climate change and pose health risks.




ammonia

Ammonia and formate cosynthesis via nitrate electroreduction combined with methanol electrooxidation over nitrogen-doped carbon-encapsulated nickel iron phosphide

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article
Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO3RR and anodic MOR is a viable way to coproduce ammonia (NH3) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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ammonia

The use of single metal atoms-based photocatalysts for the production of ammonia through photocatalytic nitrogen fixation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article
Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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ammonia

Ammonia Decomposition over Low-loading Ruthenium Catalyst Achieved through “Adiabatic” Plasma Reactor

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper
Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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ammonia

Synthesis and characterization of TiO2/hydrochar matrix composites for enhanced ammonia degradation

RSC Adv., 2024, 14,12131-12141
DOI: 10.1039/D4RA00671B, Paper
Open Access
Ling Zhao, Jiaxing Sun, Shuang E., Kuichuan Sheng, Kaiying Wang, Ximing Zhang
Development of a one-pot method for synthesizing TiO2/hydrochar matrix composites.
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ammonia

An ultra-sensitive ammonia sensor based on a quartz crystal microbalance using nanofibers overlaid with carboxylic group-functionalized MWCNTs

Analyst, 2024, 149,5191-5205
DOI: 10.1039/D4AN01061B, Paper
Ahmad Hasan As'ari, Rizky Aflaha, Laila Katriani, Ahmad Kusumaatmaja, Iman Santoso, Rike Yudianti, Kuwat Triyana
Utilizing the specific interaction between carboxylic groups and ammonia gas has led to the development of an ultra-sensitive ammonia sensor based on a quartz crystal microbalance using nanofibers overlaid with carboxylic group-functionalized MWCNTs.
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ammonia

Efficient reduction of nitrate to ammonia on AuPt@ZIF-8 composite film

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05045B, Communication
Yijie Yang, Guorui Tang, Xiaoyun Liu, Liu Yang, Ruimin Gao, Cheng-Peng Li
The nitrate reduction represents a sustainable strategy for water denitrification. Herein we design ZIF-8 coated porous AuPt alloy composite film for electrocatalytic nitrate reduction with superior ammonia yield of (131.5...
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ammonia

A boron nitride–carbon composite derived from ammonia borane and ZIF-8 with promises for the adsorption of carbon dioxide

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00643G, Paper
Open Access
Carlos A. Castilla-Martinez, Christophe Charmette, Jim Cartier, Umit B. Demirci
In the present study, we report the synthesis, characterization and assessment of the carbon dioxide adsorption capacity of a composite made of boron nitride and carbon.
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ammonia

Effect of ammonia addition on dispersion and activity of supported copper species on porous silica-alumina hollow spheres for catalytic decomposition of nitrous oxide

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00808A, Paper
Tetsuo Umegaki, Takeru Nakamura, Yoshiyuki Kojima
This work investigated influence of ammonia addition in the immersion process of active species on dispersion and activity of copper supported porous hollow silica-alumina spheres catalysts for decomposition of nitrous...
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ammonia

Zeolite-like ion-exchanged Cu-attapulgite catalysts for promoted selective oxidation of ammonia

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00157E, Paper
Xuebin Zhang, Tianwei Lan, Qiuying Yi, Yufei Wang, Danhong Cheng, Dengsong Zhang
Zeolite-like ion-exchanged Cu-attapulgite catalysts have been developed for selective catalytic oxidation of ammonia.
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ammonia

Polymer-confined synthesis of gram-scale high-entropy perovskite fluoride nanocubes for improved electrocatalytic reduction of nitrate to ammonia

Nanoscale Horiz., 2024, Advance Article
DOI: 10.1039/D4NH00341A, Communication
Open Access
Guohao Xue, Tianlu Wang, Hele Guo, Nan Zhang, Claire J. Carmalt, Johan Hofkens, Feili Lai, Tianxi Liu
A high-entropy perovskite fluoride with a well-defined nanocubic structure was successfully prepared via a polyvinylpyrrolidone-confined nucleation strategy, demonstrating excellent electrocatalytic activity for nitrate reduction.
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ammonia

Atomic tuning of 3D printed carbon surface chemistry for electrocatalytic nitrite oxidation and reduction to ammonia

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06800A, Paper
Wanli Gao, Jan Michalička, Martin Pumera
A bifunctional electrode integrating 3D printed carbon materials with atomic layer deposition of TiO2 is developed for electrochemical nitrite oxidation and reduction, providing effective surface engineering for nitrite monitoring and remediation.
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ammonia

Lewis acid sites and flexible active centers synergistically boost efficient electrochemical ammonia synthesis

J. Mater. Chem. A, 2024, 12,30476-30485
DOI: 10.1039/D4TA04884A, Paper
Li-Bo Chen, Tong-Hui Wang, Xing-You Lang, Qing Jiang
The Lewis acid sites enhance N2 adsorption and activation, while the flexible active center facilitates hydrogenation and NH4+ formation, regenerating the catalyst.
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ammonia

Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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ammonia

Novel magneto-electrocatalyst Cr2CO2-MXene for boosting nitrogen reduction to ammonia

Mater. Horiz., 2024, 11,1769-1778
DOI: 10.1039/D3MH01945D, Communication
Neng Li, Zhongyong Zhang, Zheng Wang, Bin Liu, Deyong Zhou, Xing Zhou, Peng Zhang, Xiujian Zhao
Gibbs free energy for electrocatalytic nitrogen reduction on Cr2CO2 with four magnetic states: NM, FM, Inter-AFM, and In-AFM.
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ammonia

Engineering a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis

Mater. Horiz., 2024, 11,2032-2040
DOI: 10.1039/D3MH01909H, Communication
Jialei Yang, Zhenyu Yang, Jiafu Li, Hao Gang, Donghai Mei, Dongming Yin, Ruiping Deng, Yifeng Zhu, Xingyun Li, Ning Wang, Sameh M. Osman, Yusuke Yamauchi
A sub-nano interfacial catalytic structure is orchestrated by tailor-designing a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis.
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ammonia

Electron-deficient Co modulated by the construction of heterojunctions Co@NC boosts the electroreduction of nitrate to ammonia

Inorg. Chem. Front., 2024, 11,2144-2151
DOI: 10.1039/D4QI00110A, Research Article
Bo Zhang, Fengshou Yu, Yaohua Hong, Yuzhuo Zhou, Yaheng Wang, Shaobo Zhang, Lu-Hua Zhang
Formation of electron-deficient Co by the construction of heterojunctions to promote the electroreduction of nitrate to ammonia.
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ammonia

High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co3O4 nanoarrays by B doping

Inorg. Chem. Front., 2024, 11,2339-2345
DOI: 10.1039/D4QI00310A, Research Article
Zhiqin Deng, Heng Liu, Huiyong Wang, Chaoqun Ma, Juan Du, Baozhan Zheng
B acts as an effective dopant to boost the catalytic activity of Co3O4 for the nitrate reduction reaction towards NH3 synthesis. Such B-Co3O4/TM achieves a high faradaic efficiency of 94.7% and a large NH3 yield rate of 407.3 μmol h−1 cm−2.
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ammonia

Superior low temperature activity over α-MnO2/β-MnOOH catalyst for selective catalytic reduction of NOx with ammonia

RSC Adv., 2024, 14,35498-35504
DOI: 10.1039/D4RA05934D, Paper
Open Access
Masanori Takemoto, Haruko Fujinuma, Yoshihiro Sugawara, Yukichi Sasaki, Kenta Iyoki, Tatsuya Okubo, Kazuya Yamaguchi, Toru Wakihara
α-MnO2/β-MnOOH catalysts were synthesized by post-synthetic planetary ball milling for OMS-2, enhancing catalytic activity in low-temperature NH3-SCR.
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ammonia

Improving the catalytic performance of Co/BaCeO3 catalyst for ammonia synthesis by Y-modification of the perovskite-type support

RSC Adv., 2024, 14,36281-36294
DOI: 10.1039/D4RA06251E, Paper
Open Access
Magdalena Zybert, Hubert Ronduda, Wojciech Patkowski, Andrzej Ostrowski, Kamil Sobczak, Wioletta Raróg-Pilecka
The beneficial effect of Y3+ ions incorporated into BaCeO3 support structure stems from the strengthening of the electron-donating ability, i.e., better charge transfer from the support to the active metal, enhancing N2 dissociation.
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ammonia

Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets

Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830
DOI: 10.1039/D4EW00538D, Paper
Jun Li, Salma Tabassum, Hüseyin Altundag
Denitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.
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ammonia

Tata Projects sees green hydrogen, green ammonia, pump storage hydro as pillars of growth

“Sustainability is a critical element for us and we see in this sustainability journey, a lot of opportunities will open up in new sectors,” said Vinayak Pai, MD & CEO, Tata Projects in an interview




ammonia

Coordination environment-tailored electronic structure of single atomic copper sites for efficient electrochemical nitrate reduction toward ammonia

Energy Environ. Sci., 2024, 17,8360-8367
DOI: 10.1039/D4EE02746A, Paper
Tianchi Huang, Taiyu Liang, Jiao You, Qihua Huo, Shuai Qi, Jingwen Zhao, Na Meng, Jinglian Liao, Chunyan Shang, Hengpan Yang, Qi Hu, Chuanxin He
A robust strategy is developed to finely tune the electronic structure of Cu by employing single atomic Cu–N–C via both first and second coordination shell engineering, thereby boosting the performance for the nitrate reduction reaction.
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ammonia

Photoelectrochemical nitrate denitrification towards acidic ammonia synthesis on copper-decorated black silicon

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04438J, Paper
Yuchan Li, Qi Zhang, Huan Dai, Dong He, Zunjian Ke, Xiangheng Xiao
This work highlights the exceptional performance and great potentials of a Cu nanoparticle decorated silicon nanowire arrays (Cu–Si NWs) for photoelectrocatalytic nitrate reduction to ammonia in acidic electrolyte and in realistic wastewater.
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ammonia

Theory-guided development of a barium-doped cobalt catalyst for ammonia decomposition

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02874K, Paper
Alexander Gunnarson, Ang Cao, Olivia F. Sloth, Miriam Varón, Ruben Bueno Villoro, Thomas Veile, Christian D. Damsgaard, Cathrine Frandsen, Jens K. Nørskov, Ib Chorkendorff
This work describes the theory-guided design and experimental validation of a barium-doped cobalt catalyst for ammonia decomposition.
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ammonia

Electrodialysis and nitrate reduction (EDNR) to enable distributed ammonia manufacturing from wastewaters

Energy Environ. Sci., 2024, 17,8787-8800
DOI: 10.1039/D4EE03002H, Paper
Open Access
Jinyu Guo, Matthew J. Liu, Chloe Laguna, Dean M. Miller, Kindle S. Williams, Brandon D. Clark, Carolina Muñoz, Sarah J. Blair, Adam C. Nielander, Thomas F. Jaramillo, William A. Tarpeh
Underutilized wastewaters containing dilute levels of reactive nitrogen (Nr) can help rebalance the nitrogen cycle.
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ammonia

Hydrolysis of ammonia borane for green hydrogen production over a Pd/C3N4 nanocatalyst synthesized by electron beam irradiation

Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper
Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C3N4 catalyst.
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ammonia

Heterostructure engineered construction of N-doped CuO@Co3O4 for highly efficient electrocatalytic reduction of nitrate to ammonia

Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper
Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH3 can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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ammonia

Unraveling the Ammonia Sensing Behavior and Degradation Pathways of Novel Lead-Free MA2CuBr4 based Ammonia Sensor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02943G, Communication
Abinash Tiwari, Arjumand Mir, Aswani Yella
We report a lead-free copper-based halide perovskite gas sensor to detect ammonia gas at ambient temperature. The sensor uses methylammonium copper bromide as the active material and can trace ammonia...
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ammonia

JGC develops new ammonia production process




ammonia

Birch reduction runs ammonia-free

Crown ethers simplify the set-up of classic reaction




ammonia

Active Hydrogen Tuning by Copper-Cobalt Bimetal Catalysts for Boosting Ammonia Electrosynthesis from Simulated Waster Water

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04120H, Paper
Chunqi Yang, Chang Liu, Jingwen Zhuang, Ziyan Yang, Aiping Chen, Yuhang Li, Chunzhong Li
Electrochemical nitrate reduction reaction (NO3RR) represents a promising approach to balance the nitrogen cycle, converting environmental pollutant NO3− to valuable ammonia (NH3). However, the whole reaction involves complex protons-coupled electron...
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ammonia

Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04640D, Tutorial Review
Guanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua Qi
This work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.
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ammonia

A binuclear CuII/CaII thio­cyanate complex with a Schiff base ligand derived from o-vanillin and ammonia

The new heterometallic complex, aqua-1κO-bis­(μ2-2-imino­methyl-6-meth­oxy­phenolato-1κ2O1,O6:2κ2O1,N)bis­(thio­cyanato-1κN)calcium(II)copper(II), [CaCu(C8H8NO2)2(NCS)2(H2O)], has been synthesized using a one-pot reaction of copper powder, calcium oxide, o-vanillin and ammonium thio­cyanate in methanol under ambient conditions. The Schiff base ligand (C8H9NO2) is generated in situ from the condensation of o-vanillin and ammonia, which is released from the initial NH4SCN. The title compound consists of a discrete binuclear mol­ecule with a {Cu(μ-O)2Ca} core, in which the Cu⋯Ca distance is 3.4275 (6) Å. The coordination geometries of the four-coordinate copper atom in the [CuN2O2] chromophore and the seven-coordinate calcium atom in the [CaO5N2] chromophore can be described as distorted square planar and penta­gonal bipyramidal, respectively. In the crystal, O—H⋯S hydrogen bonds between the coordinating water mol­ecules and thio­cyanate groups form a supra­molecular chain with a zigzag-shaped calcium skeleton.




ammonia

Ammonia emissions detected upwind from an intensive poultry farm

High levels of ammonia were observed at a Natura 2000 site nearly three kilometres upwind from an intensive poultry farm in a recent study. While downwind effects of ammonia emissions are to be expected, this study suggests that ammonia emissions could be a significant source of nitrogen pollution even upwind from the source.




ammonia

Greater efforts to reduce ammonia emissions needed to meet air pollution targets

Levels of particulate matter (PM) in the atmosphere are linked to ammonia emissions. However, reducing ammonia emissions only as far as targets set out by the Gothenburg Protocol will not necessarily ensure compliance with EU PM limits, according to a new study. Greater reductions in ammonia emissions would reduce the number of days when PM limit values are exceeded, the researchers found.




ammonia

Agricultural ammonia emissions could be reduced without affecting crop yield

Ammonia released by nitrogen fertilisers in Spanish agriculture could be reduced by up to 82% with only a very minimal impact on crop yield, finds new research. This could be achieved by combining optimised management of manure with the use of non-urea synthetic fertilisers.




ammonia

Gaseous compositions comprising hydrogen fluoride and an alkylated ammonia derivative

A method of removing at least a portion of a silicon oxide material is disclosed. The silicon oxide is removed by exposing a semiconductor structure comprising a substrate and the silicon oxide to an ammonium fluoride chemical treatment and a subsequent plasma treatment, both of which may be effected in the same vacuum chamber of a processing apparatus. The ammonium fluoride chemical treatment converts the silicon oxide to a solid reaction product in a self-limiting reaction, the solid reaction product then being volatilized by the plasma treatment. The plasma treatment includes a plasma having an ion bombardment energy of less than or equal to approximately 20 eV. An ammonium fluoride chemical treatment including an alkylated ammonia derivative and hydrogen fluoride is also disclosed.