The RM85 is the latest in Ebac’s line of rotational molded polyethylene housing dehumidifiers.

Blaze Media Pro includes a powerful audio editor feature that can be used to convert MIDI to MP3, WMA, WAV, OGG, etc. This is accomplished by recording the MIDI as it plays. Follow this link for more information.

Time in the languedoc is fluid and one needs to get accustomed to it to enjoy a languedoc life in the Midi.

Les manchettes pour le 16 Novembre, 2021

Les manchettes pour le 24 Novembre, 2021

Les manchettes pour le 30 Novembre, 2021

Les manchettes pour le 29 Décembre, 2021

Catégorie - VARIÉTÉS » Genre - Noël

1. Diabète : trois grands rendez-vous à Nîmes cette semaine  Midi Libre
2. Journée mondiale du diabète : un dépistage gratuit près du Havre ce jeudi 14 novembre  actu.fr
3. Orange. Des actions pour la journée du diabète et le mois sans tabac  Le Dauphiné Libéré
4. Santé - Diabète et bien-être : une journée de prévention organisée à Guéret  La Montagne

While wood floors are built to withstand the abuse of foot traffic and furniture, humidity is an invisible enemy that can quickly wreak havoc on even the best surfaces.

In the structure of the title complex, [Zn(C4H2FN2O2)(C10H24N4)]ClO4, the zinc(II) ion forms coordination bonds with the four nitro­gen atoms of cyclam (1,4,8,11-tetra­aza­cyclo­tetra­decane or [14]aneN4) as well as with the nitro­gen atom of a deprotonated 5-fluoro­uracil ion (FU−). Cyclam adopts a trans-I type conformation within this structure. The coordination structure of the zinc(II) ion is a square pyramid with a distorted base plane formed by the four nitro­gen atoms of the cyclam. FU− engages in inter­molecular hydrogen bonding with neighboring FU− mol­ecules and with the cyclam mol­ecule.

In the title mol­ecule, C7H7N3O, the pyrimidine ring is essentially planar, with the propynyl group rotated out of this plane by 15.31 (4)°. In the crystal, a tri-periodic network is formed by N—H⋯O, N—H⋯N and C—H⋯O hydrogen-bonding and slipped π–π stacking inter­actions, leading to narrow channels extending parallel to the c axis. Hirshfeld surface analysis of the crystal structure reveals that the most important contributions for the crystal packing are from H⋯H (36.2%), H⋯C/C⋯H (20.9%), H⋯O/O⋯H (17.8%) and H⋯N/N⋯H (12.2%) inter­actions, showing that hydrogen-bonding and van der Waals inter­actions are the dominant inter­actions in the crystal packing. Evaluation of the electrostatic, dispersion and total energy frameworks indicates that the stabilization is dominated by the electrostatic energy contributions. The mol­ecular structure optimized by density functional theory (DFT) calculations at the B3LYP/6–311 G(d,p) level is compared with the experimentally determined structure in the solid state. The HOMO–LUMO behaviour was also elucidated to determine the energy gap.

Syntheses of the acyclic amidinium salts, morpholino­formamidinium hexa­fluorido­phosphate [OC4H8N—CH=NH2]PF6 or C5H11N2O+·PF6−, 1, and pyrrolidinoformamidinium hexa­fluorido­phosphate [C4H8N—CH= NH2]PF6 or C5H11N2+·PF6−, 2, were carried out by heating either morpholine or pyrrolidine with triethyl orthoformate and ammonium hexa­fluorido­phosphate. Crystals of 1 obtained directly from the reaction mixture contain one cation and one anion in the asymmetric unit. The structure involves cations linked in chains parallel to the b axis by N—H⋯O hydrogen bonds in space group Pbca, with glide-related chains pointing in opposite directions. Crystals of 1 obtained by recrystallization from ethanol, however, showed a similar unit cell and the same basic structure, but unexpectedly, there was positional disorder [occupancy ratio 0.639 (4):0.361 (4)] in one of the cation chains, which lowered the crystal symmetry to the non-centrosymmetric space group Pca21, with two cations and anions in the asymmetric unit. In the pyrrolidino compound, 2, cations and anions are ordered and are stacked separately, with zigzag N—H⋯F hydrogen-bonding between stacks, forming ribbons parallel to (101), extended along the b-axis direction. Slight differences in the delocalized C=N distances between the two cations may reflect the inductive effect of the oxygen atom in the morpholino compound.

In the title compound, C21H15N5OS2, mol­ecular pairs are linked by N—H⋯N hydrogen bonds along the c-axis direction and C—H⋯S and C—H⋯O hydrogen bonds along the b-axis direction, with R22(12) and R22(16) motifs, respectively, thus forming layers parallel to the (10overline{4}) plane. In addition, C=S⋯π and C≡N⋯π inter­actions between the layers ensure crystal cohesion. The Hirshfeld surface analysis indicates that the major contributions to the crystal packing are H⋯H (43.0%), C⋯H/H⋯C (16.9%), N⋯H/H⋯N (11.3%) and S⋯H/H⋯S (10.9%) inter­actions.

In the ten-membered 1,3,4,6-tetra­hydro-2H-pyrido[1,2-a]pyrimidine ring system of the title compound, C17H15N5, the 1,2-di­hydro­pyridine ring is essentially planar (r.m.s. deviation = 0.001 Å), while the 1,3-diazinane ring has a distorted twist-boat conformation. In the crystal, mol­ecules are linked by N—H⋯N and C—H⋯N hydrogen bonds, forming a three-dimensional network. In addition, C—H⋯π inter­actions form layers parallel to the (100) plane. Thus, crystal-structure cohesion is ensured. According to a Hirshfeld surface study, H⋯H (40.4%), N⋯H/H⋯N (28.6%) and C⋯H/H⋯C (24.1%) inter­actions are the most important contributors to the crystal packing.

The pyrazolo­pyrimidine moiety in the title mol­ecule, C13H12N4S, is planar with the methyl­sulfanyl substituent lying essentially in the same plane. The benzyl group is rotated well out of this plane by 73.64 (6)°, giving the mol­ecule an approximate L shape. In the crystal, C—H⋯π(ring) inter­actions and C—H⋯S hydrogen bonds form tubes extending along the a axis. Furthermore, there are π–π inter­actions between parallel phenyl rings with centroid-to-centroid distances of 3.8418 (12) Å. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯H (47.0%), H⋯N/N⋯H (17.6%) and H⋯C/C⋯H (17.0%) inter­actions. The volume of the crystal voids and the percentage of free space were calculated to be 76.45 Å3 and 6.39%, showing that there is no large cavity in the crystal packing. Evaluation of the electrostatic, dispersion and total energy frameworks indicate that the cohesion of the crystal structure is dominated by the dispersion energy contributions.

There are multiple ways to dehumidify a space — mechanical, reheat and desiccant to name a few. The biggest issue has been that conventional air conditioning units are only 10% effective at removing humidity. Until now, standard de-humidification systems were expensive to purchase and install.

Your personal-use humidifier. Bliz provides moisture to the air by delivering a cool, refreshing flavored mist no matter where you are

Apres Midi Paper by Kerry Hallam is a(n) Limited Edition. The Edition is Limited to pcs

Apres Midi Canvas by Kerry Hallam is a(n) Limited Edition. The Edition is Limited to pcs

IAQ-conscious homeowners might be interested to know how humidification can preserve not only their health but the health of their home, too.

Early on in CHP’s $9-million project, the team decided to make a pretty big change: an overhaul of the HVAC design.

"Baking the cost of a humidifier or dehumidifier into a full system offering is the trend today,” said Tom Ruse.

Homeowners are seeking solutions to improve comfort and IAQ. One device that does both is the humidifier.

Grow rooms are a prominent example of the potential and the challenges of indoor agriculture.

Humidity control makes up an important facet of indoor air quality, a facet that includes reducing airborne viruses but extends far beyond it.

Homeowners are increasingly paying attention to improving their indoor air quality, and dehumidification is a big part of the IAQ equation.

Colorado researchers found that on average, more than half of the energy consumed by residential air conditioners deals with the humidity on a hot day.

Whether it be a single-family household, school, or even a grocery store, all of those spaces need clean, high-quality air — which humidification plays a role in.

Following are several of the latest dehumidification products on the market, representing residential and industrial applications alike.

Comfortable, clean air. That’s what end users on both the residential and commercial sides are looking for in the aftermath of the pandemic.

Proper indoor RH — generally between 35% and 60%, with the range leaving wiggle room for personal preferences and outdoor conditions — is vital in maintaining IAQ, the health and well-being of a home’s occupants, and the condition of its furnishings.

Getting a humidification system dialed in is crucial if customers want to reap all the benefits they have to offer.

Between health benefits, energy savings, and overall improved air quality, whole-home humidification systems are an easy sell for contractors.

For contractors in humid climates, a lot of the comfort they provide is through being able to control humidity levels, which can be aided by adding a secondary dehumidification system.

Beginning July 3, 2019, the Department of Energy is requiring a maximum fan energy rating (FER) for furnace fans.

The Endeavor Line provides tech-savvy and environmentally mindful consumers like the Horwitzes with smart home compatibility and sustainable features.

While balanced ventilation does have energy benefits, there is a misconception about its ability to reduce humidity.

Felienne talks to Diomidis Spinellis about different forms of debugging. From using print-statements to version-control systems and operating system tools. We also discuss debugging strategies for different types of programming systems.

This new cooperation will introduce the SIG MidiFit family pack to Hungarian consumers for the first time.

Zara ha lanzado un vestido midi que promete convertirse en un éxito. Este diseño versátil sirve para la oficina o un evento, y su punto fuerte es su tono verde oliva, uno de los colores más en tendencia. Leer

A real-time generative device to create evolving patterns, interesting rhythmic sequence, and someth...

Special guest: Jason Snell. Topics: Headset, headseat, headset. And no baseball talk other than how games might look in VR. Also: Final Cut Pro and Logic Pro for iPad, and GM's dumb decision to drop CarPlay.

RNase J enzymes are metallohydrolases that are involved in RNA maturation and RNA recycling, govern gene expression in bacteria, and catalyze both exonuclease and endonuclease activity. The catalytic activity of RNase J is regulated by multiple mechanisms which include oligomerization, conformational changes to aid substrate recognition, and the metal cofactor at the active site. However, little is known of how RNase J paralogs differ in expression and activity. Here we describe structural and biochemical features of two Staphylococcus epidermidis RNase J paralogs, RNase J1 and RNase J2. RNase J1 is a homodimer with exonuclease activity aided by two metal cofactors at the active site. RNase J2, on the other hand, has endonuclease activity and one metal ion at the active site and is predominantly a monomer. We note that the expression levels of these enzymes vary across Staphylococcal strains. Together, these observations suggest that multiple interacting RNase J paralogs could provide a strategy for functional improvisation utilizing differences in intracellular concentration, quaternary structure, and distinct active site architecture despite overall structural similarity.

Dihydropyrimidinase (DHP) deficiency is an autosomal recessive metabolic disorder caused by biallelic pathogenic variants of DPYS. Patients with DHP deficiency exhibit a broad spectrum of phenotypes, ranging from severe neurological and gastrointestinal involvement to cases with no apparent symptoms. The biochemical diagnosis of DHP deficiency is based on the detection of a significant amount of dihydropyrimidines in urine, plasma, and cerebrospinal fluid samples. Molecular genetic testing, specifically the identification of biallelic pathogenic variants in DPYS, has proven instrumental in confirming the diagnosis and facilitating family studies. This case study documents the diagnostic journey of an 18-yr-old patient with DHP deficiency, highlighting features at the severe end of the clinical spectrum. Notably, our patient exhibited previously unreported skeletal features that positively responded to bisphosphonate treatment, contributing valuable insights to the clinical characterization of DHP deficiency. Additionally, a novel DPYS variant was identified and confirmed pathogenicity through metabolic testing, further expanding the variant spectrum of the gene. Our case emphasizes the importance of a comprehensive diagnostic approach using genetic sequencing and metabolic testing for accurate diagnosis.