bam Obama strong, rubber match awaits By www.scpr.org Published On :: Wed, 17 Oct 2012 10:28:17 -0700 Larry MantleIn the second of the three Presidential debates, President Obama displayed the passion he lacked the first time around. He also made his arguments more concisely, and didn't shy away from direct engagement with Mitt Romney. Snap polls after the debate show most viewers and listeners though Obama won the debate, though the percentages weren't nearly as overwhelming as Romney's advantage last time out. Will the President's apparent victory show up in the polls as dramatically as Romney's previous win? What will the stakes be like for next Monday's final, tie-breaking, matchup? This content is from Southern California Public Radio. View the original story at SCPR.org. Full Article
bam ROPIBAM 0.2% Ropivacaine hydrochloride 400mg/200mL solution for injection bag (ropivacaine hydrochloride) By apps.tga.gov.au Published On :: Commercial Changes / Commercial viability Full Article
bam Pillada sangrienta de dos adolescentes en Carabanchel: "Estábamos solos en casa de ella... Y llegó su padre con un cuchillo. Me quiso cortar el cuello y la cara" By www.elmundo.es Published On :: Thu, 14 Nov 2024 00:37:16 +0100 Un joven de 16 años relata su cita frustrada que terminó en Urgencias: "Sentí que moría esa tarde" Leer Full Article Artículos Daniel Somolinos
bam Las vacaciones más polémicas de Obama By www.elmundo.es Published On :: 2011-08-12T15:54:00Z Una vez dejado atrás el debate sobre la elevación del techo de la deuda, los comentaristas políticos estadounidenses se han ocupado esta semana de un tema más liviano: ¿debería tomarse Barack Obama unas vacaciones? Full Article
bam Marco Rubio, el mayor peligro para Obama By www.elmundo.es Published On :: 2011-08-18T20:51:00Z La inclusión de Marco Rubio en una candidatura republicana como aspirante a la presidencia podría representar un gran peligro para Obama, pues podría arañarle unos votos clave en Florida, estado del que es senador, y también en estados del Oeste con una fuerte presencia hispana. Full Article
bam El doble juego de Obama en inmigración By www.elmundo.es Published On :: 2011-08-21T18:30:00Z Desde su llegada a la Casa Blanca, Obama ha intentado a la vez aplacar a los grupos de derecha que son anti-inmigrante, y mantener vivas las esperanzas de los hispanos en los cambios en la política inmigratoria. Sin embargo, esta estrategia es insostenible. En los próximos meses, Obama se tendrá que mojar. Full Article
bam Obama's Secret Service agent breached security to have an affair: Memoir By abcnews.go.com Published On :: Wed, 13 Nov 2024 08:18:14 -0500 A Secret Service agent assigned to Barack Obama was breaching security while leading a double life, according to a memoir by the agent's former girlfriend. Full Article US
bam "My Child Can't Speak Yet": Manipur Man Appeals For Safe Release Of Family Missing After Jiribam Encounter By www.ndtv.com Published On :: Wed, 13 Nov 2024 23:16:10 +0530 The father of two children - who went missing along with their mother and three others from Manipur's Jiribam after an encounter between suspected Kuki insurgents and the security forces - has appealed to the authorities to find them. Full Article
bam First Bank of Alabama taps Jack Henry for growth and innovation By thepaypers.com Published On :: Wed, 13 Nov 2024 14:25:00 +0100 Full Article
bam When the Baby Pope Broke Obama By cheezburger.com Published On :: Fri, 05 Aug 2016 14:00:00 -0700 Full Article barack obama
bam Business success of corporate and bamboo flowering By blogs.siliconindia.com Published On :: Many corporate do engage in the business of ‘seasonal bamboo flowering’ and some may find success also. The question is not whether such an approach is wrong or right? But do they know the fact... Full Article
bam How the Obama Stole Christmas! Click here By sunsetblog.blogspot.com Published On :: Sun, 26 Dec 2010 17:30:00 +0000 How the Obama Stole Christmas! Full Article
bam Supreme Court schedules ‘conference’ on Obama’s eligibility By sunsetblog.blogspot.com Published On :: Fri, 18 Feb 2011 22:30:00 +0000 Supreme Court schedules ‘conference’ on Obama’s eligibilityFebruary 18, 2011In a stunning move, the U.S. Supreme Court has scheduled another “conference” on a legal challenge to Barack Obama’s eligibility to occupy the Oval Office, but officials there are not answering questions about whether two justices given their jobs by Obama will participate.The court has confirmed that it has distributed a petition for rehearing in the case brought by attorney John Hemenway on behalf of retired Col. Gregory Hollister and it will be the subject of a conference on March 4. Full Article
bam The Obama Legacy - Click here to watch By sunsetblog.blogspot.com Published On :: Mon, 23 May 2011 01:52:00 +0000 An attempt to show that our political elite is selling us down a river by devaluing our currency, thereby initiating inflation. Prices aren't going up because of corporate greed, the political elite…00:03:57 Full Article
bam TOBAM Names New Senior Appointments in New York and Paris Goal to Enhance Management and Human Rights Expertise By www.prleap.com Published On :: Tue, 09 Jan 2024 00:00:00 PST New York and Paris For Immediate Release. Full Article
bam NEA Foundation Recognizes Alabama Educator with Prestigious NEA Member Benefits Award By www.prleap.com Published On :: Tue, 07 May 2024 00:30:00 PDT The NEA Foundation announced today that Kimberly Johnson, an interventionist, resource educator, and teacher lead at Auburn Junior High School in Auburn, Ala., is the recipient of the 2024 NEA Member Benefits Award for Teaching Excellence, one of public education's top honors. Johnson was presented with the award, which comes with $25,000, by NEA Member Benefits President and CEO Leona Lindner at the NEA Foundation Salute to Excellence in Education Gala on Friday, May 3. Full Article
bam Sweet Home Alabama – the twists and turns of a contested song By www.threemonkeysonline.com Published On :: Tue, 22 Jan 2019 07:21:00 +0000 Great songs rise above ugly intentions, and Sweet Home Alabama deserves to be listened to with a critical and attentive ear. Beneath the redneck rumble and tumbling there's a slice of American History to be discovered. The post Sweet Home Alabama – the twists and turns of a contested song appeared first on Three Monkeys Online Magazine. Full Article featured Music
bam Thompson Vs. Obama in 2008 By warmonger.mu.nu Published On :: 2007-06-24T21:17:33-05:00 Yep, that's my prediction for the primaries. I'm sure there's a dozen other scenarios people will come up with, but these are the two people I believe will be going head to head. I have absolutely no idea who their... Full Article
bam Obama, Afghanistan, and the "Long War" By essentialemmes.blogspot.com Published On :: Sun, 28 Mar 2010 19:11:00 +0000 Is it a coincidence that the same day Tom Hayden writes about The 'Long War' quagmire, Obama pops up in Afghanistan on an "unannounced trip?"Probably--but the implications of Hayden's op-ed piece are dire: in the absence of an ongoing "Cold War" to stoke the fires of unbridled defense expenses, the neocons will need to promote 80 years of undeclared war against "insurgent groups from Europe to South Asia."Of course, along with defense contractors keeping in business--big business--there is the untold correlating hardship of casualties of Americans in the field.So is Obama in Afghanistan today to reassure troops on their mission, to discuss options for the long haul with his generals? Or is he developing a way to sell the taxpayers on why they need to pay for 100,000 ground forces in a country who's biggest export is based on the opium poppy seed? Full Article
bam Voters opposed to Obamacre says it Doesn't go Far Enough! By essentialemmes.blogspot.com Published On :: Sun, 01 Jul 2012 18:48:00 +0000 Some polls showing the -for and -against Obama health care bill are misleading. In some cases, people who might have been in the "in favor" of Obama health care collumn were "opposed" but not because they were against health care reform. They simply didn't think the health care law went far enough by excluding the public option and other more equitable measures that would have caost the average taxpayer less while lessening the intrusion of for-profit health insurance companies. As it stands, and has been combed through SCOTUS, it's about as far-reaching and beneficial as anything that's come up since FDR's Social Security, and LBJ's Great Society. Don't be afraid of socialism--we live in a socialist republic. Some on the right would use smoke and mirrors to mae you think our form of government is a democracy--it's certainly not communism, but then neither is China--they are run by dictators who champion entrepreneurial capitalism. The next best move, ASAP, would be astimulus plan twice the size of the last, instituted by Obama in collabroaion with the Fed. Then we'll see happ days come here again... Full Article
bam ePartners comes to Alabama By access1000.blogspot.com Published On :: Tue, 7 Nov 2006 04:08:00 -0800 ePartners is making it's debut in Alabama in 492 cities statewide. ePartners is a nationwide relocation network that allows anyone to search for and find properties for sale in any city any time.The local cities are affiliated with an agent or team of real estate agents who work the areas and are specialists in properties in each city. They can help members of the homebuying or homeselling public find exactly what they are looking for.The ePartners network also contains specific city information on schools and neighborhoods, shopping and restaurants, and parks and recreation.Sellers can market their homes through the nationwide network and buyers can easily find them from anywhere in the United States.Some of the main sites are very easy to find: Alabamawebpage.com, Montgomerywebpage.com are examples of url's that make this network very consumer friendly.The ePartners network also allows real estate agents to easily get plugged into a nationwide relocation and referral network.ePartners is set to take off in early December 2006. We will be watching. Full Article
bam New Alabama Relocation Network makes debut By access1000.blogspot.com Published On :: Thu, 9 Nov 2006 05:14:00 -0800 A new network of websites which features the largest 494 cities in Alabama will make it's debut statewide in December. Called the ePartners Network, the statewide web will make it easier for consumers to find properties all across the state of Alabama. In particular, the major cities, Montgomery, Huntsville, Birmingham, and Mobile and their surrounding communities are linked and cross linked so consumers can easily search for homes and real estate from one single location.The state affiliate Broker, Mike Carraway (Broker, Access Realty), has already introduced the network to real estate agents in Birmingham, Huntsville, Jasper, Cullman, Hoover, Gulf Shores, Orange Beach, Montgomery, and several other Alabama cities. Each city has it's own site and weblog and an agent can elect to be the exclusive real estate agent for their city to help consumers find what they want or to market their property statewide.This is the first time in the history of real estate that geographic boundaries have been erased. In the past, agents and brokers have worked in certain geographic areas and basically limited themselves to that area, even though they were licensed to do business anywhere in the state. Now, for the first time, those boundaries are gone. An agent licensed to do business in the state can assist customers finding homes or locating a local agent from anywhere.This new network will be a plus for all real estate ancillary services as well. Mortgage companies, insurance companies, and others can now advertsie their services on the network either statewide or in a local community.The ePartners Network will change the way that the real estate business is done in other ways as well. It will serve as the first statewide, and even nationwide, platform for paperless real estate transactions.Developing... Full Article
bam Alabama Real Estate in Recovery By access1000.blogspot.com Published On :: Wed, 13 Feb 2008 06:04:00 -0800 (Birmingham, AL) The Alabama real estate market is already recovering from recent lows. Evidence is everywhere.Inventories of property on the market hit an all time high at the end of november 2007 into the first of December 2007. Since then, the inventory of property for sale has been shrinking. This is always the first sign. As property inventories decrease, the demand for property rises. This causes price support and shores up values.Mortgage applications, or new people applying for a home loan, increased 12% just last week. This is yet another sign that more buyers are entering the market to buy a home. If you combine this with the fact that inventories are shrinking, it doesn't take a genius to see that values will stop declining soon and prices will again start to rise. Full Article
bam Bamboo vipers and many-banded kraits: Experiencing Hong Kong's snake safari By www.cnn.com Published On :: Mon, 10 Oct 2022 03:26:18 GMT A fraction of a second after William Sargent's torch light catches the unmistakable glint of snake skin he roars into action, sliding on a protective glove and launching himself into the dense green jungle of northern Hong Kong. Full Article
bam CA6463 MCDANIEL, Martin - Ala-Damn-Bama By www.midi-pro.net Published On :: Sat, 06 Jul 2024 10:38:16 +0000 Catégorie - HOMMES » Genre - Country Full Article
bam How bamboo houses in Assam withstand floods and earthquakes By www.thehindu.com Published On :: Thu, 10 Oct 2024 14:56:07 +0530 Bamboo, the flexible perennial grass, to the rescue Full Article Environment
bam Obama suppressed Iran nuclear intel to get deal, U.S. counterspy says By www.washingtontimes.com Published On :: Wed, 28 Aug 2024 16:29:17 -0400 The CIA suppressed secrets from inside Iran during the Obama administration showing efforts by Tehran to build a nuclear weapon were more advanced than suspected, according to a former National Security Agency counterintelligence official. Full Article
bam Obama's singular arrogance By www.washingtontimes.com Published On :: Mon, 11 Nov 2024 14:43:34 -0500 Amid the smoldering wreckage of last Tuesday's elections, Democrats must ask themselves a simple question: Who is in charge? Full Article
bam Bam Adebayo scores 32 points to help the Heat beat the Wizards 118-98 in Mexico City By www.washingtontimes.com Published On :: Sun, 03 Nov 2024 00:21:08 -0400 Bam Adebayo scored 20 of his 32 points in the first half and the Miami Heat beat the Washington Wizards 118-98 on Saturday night in the 14th NBA regular-season game in Mexico. Full Article
bam Job Alert: ACCOBAMS Survey Initiative Project Officer By www.eubon.eu Published On :: Thu, 02 Jun 2016 10:07:00 +0300 Established under the auspices of the UNEP Convention on Migratory Species (UNEP/CMS), the Agreement on the Conservation of Cetaceans of the Black Sea, Mediterranean Sea and contiguous Atlantic area (ACCOBAMS) is an Intergovernmental Agreement aimed at achieving and maintaining a favorable conservation status for cetaceans though the implementation of coordinated measures. The Secretariat of ACCOBAMS, based in Monaco, ensures the coordination of the Agreement implementation and provides assistance to the Contracting Parties. In this context, the Secretariat is working on the development of an initiative aimed at responding to the ACCOBAMS strategic objective on improving the understanding of the conservation status of cetaceans at the Mediterranean/Black Sea macroregional level (the "ACCOBAMS Survey Initiative" – ASI). The overall coordination of the project is provided by the ACCOBAMS Secretariat, according to the mandate given by the Parties to ACCOBAMS, and under the guidance of a Steering Committee. A Scientific Coordinator will be involved in the project for specific tasks/actions related to the scientific aspects of the project. The Project Officer will ensure the overall coordination of the "ACCOBAMS Survey Initiative" project. He/she will provide operational management of the project, under the general authority of the ACCOBAMS Executive Secretary and the supervision of the ACCOBAMS Project and Fundraising Officer. He/she will also liaise with the Scientific Coordinator. Find out more about the requirements and how to apply for this position, from the job offer flyer. Full Article News
bam The Bamboos - Medicine Man By www.bbc.co.uk Published On :: Thu, 24 May 2012 00:00:00 +0100 The Australians’ hybrid soul and funk sound continues to impress. Full Article
bam Vector Security Partners With University of Alabama Athletics By www.sdmmag.com Published On :: Mon, 12 Aug 2024 17:30:00 -0400 Vector Security will receive sponsorship exclusivity in the home and business security categories in association with the Alabama University Crimson Tide football, men’s and women’s basketball, baseball and softball teams. Full Article
bam OSHA under Obama: The final year By www.safetyandhealthmagazine.com Published On :: Sun, 25 Oct 2015 00:05:00 -0400 This time next year, the nation will be electing a new president, who could move OSHA in a different direction. What can the agency accomplish in the remaining months of the Obama administration? OSHA-watchers weigh in. Full Article
bam Obama taps NTSB’s Mark Rosekind to lead NHTSA By www.safetyandhealthmagazine.com Published On :: Thu, 20 Nov 2014 00:00:00 -0500 Washington – President Barack Obama has nominated Mark Rosekind to be administrator of the National Highway Traffic Safety Administration. Full Article
bam Advocacy groups to Obama: Veto OSHA budget cuts By www.safetyandhealthmagazine.com Published On :: Wed, 05 Aug 2015 00:00:00 -0400 Washington – President Barack Obama should veto proposed funding legislation that would cut OSHA’s budget, 76 advocacy groups urged in an Aug. 5 letter. Full Article
bam Michelle Obama Launches Plezi Nutrition By www.preparedfoods.com Published On :: Fri, 12 May 2023 06:30:00 -0400 Building on her efforts in the White House with her Let's Move! initiative, Mrs. Obama is a Co-Founder and Strategic Partner with PLEZi Nutrition, working behind-the-scenes to guide the company's mission to be a driver of change and a model for how food and beverage brands can support the health of our next generation. Full Article
bam The Continuing Evolution in Bamboo Flooring By www.floortrendsmag.com Published On :: Tue, 04 Mar 2014 00:00:00 -0500 Since bamboo’s initial introduction to the U.S. flooring market in the early 1990s, it has continued to evolve into different flooring formats, which has served to increase the product’s use and demand, especially in today’s eco-conscious flooring market. Full Article
bam Alabama’s Gregerson Finds Success in Multibranding By www.floortrendsmag.com Published On :: Mon, 01 Sep 2014 00:00:00 -0400 Ted Gregerson found true love as a young man. Working for a Carpet One store in his hometown right out of high school he discovered flooring was in his blood. His love for people, integrity and helping customers create beautiful homes inspired him to his core. Full Article
bam Five Graduate from Groundbreaking Alabama Flooring Installation Course at Drake State Community & Technical College By www.floortrendsmag.com Published On :: Mon, 14 Oct 2024 15:00:00 -0400 The Floor Covering Education Foundation (FCEF), in partnership with the Alabama Community College System (ACCS) Innovation Center, Drake State Community College, and the Industry Task Force, announced the completion of its first pilot cohort for the Flooring Installation Technicians course. Full Article
bam J.M. Smucker Co. Opens Uncrustables Facility in Alabama By www.foodengineeringmag.com Published On :: Fri, 08 Nov 2024 09:17:00 -0500 The 900,000-sq.-ft. manufacturing facility will increase the company's current production capacity for its Uncrustables brand to help meet demand for the frozen sandwiches. Full Article
bam Blind Boys of Alabama By indianapublicmedia.org Published On :: 17 Nov 2024 00:30:00 GMT Buskirk-Chumley Theater Saturday, November 16, 2024, 7:30 – 10pm The Blind Boys are known for crossing multiple musical boundaries with their remarkable interpretations of everything from traditional gospel favorites to contemporary spiritual material by songwriters such as Eric Clapton, Prince, and Tom Waits. They have appeared on recordings with many artists, including Lou Reed, Peter Gabriel, Bonnie Raitt, Willie Nelson, Aaron Neville, Susan Tedeschi, Ben Harper, Patty Griffin, and Taj Mahal.Blind Boys of Alabama released 'Echoes Of The South’ on Aug 25, 2023, which finds the Gospel Music Hall of Fame inductees coming home to honor those they've lost on a bold declaration of how far they still plan to go. The eleven-song collection is a portrait of perseverance from a group well-versed in overcoming incredible odds - from singing for pocket change in the Jim Crow South to performing for three different American presidents, soundtracking the Civil Rights movement, and helping define modern gospel music as we know it. Recently, the group's decades-long mission of spreading light and love has taken on even deeper context as they've reckoned with the loss of two of their own, Paul Beasley and Benjamin Moore, both longtime members of the Blind Boys’ tight-knit family. 'Echoes Of The South' is released in their honor - as well as for the group's recently-retired leader, Jimmy Carter - and keeps the Blind Boys' long-held mission statement at its core: “As long as everybody gives all that they have to give and we sing songs that touch the heart, we'll live on forever.”In 2022, the group had a collaborative recording with Béla Fleck, nominated for a Grammy. The nominated collaboration, "I Wish I Knew How It Would Feel to Be Free," powerfully reimagines the anthem of the Civil Rights Movement, originally made famous by Nina Simone. They also have had collaborative recordings and coinciding tours with both Marc Cohn and afro-pop duo Amadou & Mariam. In 2023, Blind Boys garnered another Grammy nomination for Best Americana Single for 'The Message' featuring Black Violin. 2024 started off the year with a return to the GRAMMY® Awards with three nominations and one win for Best Roots Gospel Album - 'Echoes Of The South.’ This was followed by a sold-out tour in Australia and a sizzling performance with Sir Tom Jones during the Bluesfest Byron Bay (Australia), where video of their rehearsal reached 750K + views in 48 hours on social platforms. The definitive book, titled Spirit of the Century, was released in March 2024. It’s an insider history of the Blind Boys of Alabama, the longest-running group in American music, and the untold story of their world written with band members and key musical colleagues. Contact: BCT Box Office, boxoffice@buskirkchumley.org Cost: $40 - $65 Ticket Phone: 812-323-3020 Ticket Web Link: buskirkchumley.org… Communities: Bloomington Full Article 2024/11/16 (Sat)
bam Basic Black LIVE: President Obama, Same-Sex Marriage, and the Black Vote By www.wgbh.org Published On :: Sat, 12 May 2012 00:00:00 EST (Originally broadcast May 11, 2012) President Obama surprised the world yesterday when his stance on same-sex marriage finished "evolving" and he came out in support of it. Will his position hurt or help his chances at re-election? How will it affect his relationship with black clergy? Will it alter his support in the black community? Our panelists: - Callie Crossley, host and executive editor, The Callie Crossley Show - Kim McLarin, author and assistant professor of creative writing, Emerson College - Phillip Martin, senior reporter, 89.7 WGBH Radio - Lionel McPherson, associate professor of philosophy, Tufts University Full Article
bam Basic Black Live: President Barack Obama Re-Elected By www.wgbh.org Published On :: Mon, 12 Nov 2012 00:00:00 EST Originally broadcast November 9, 2012. November 9, 2012: Election 2012 came to a close on November 6 as President Barack Obama was elected for a second term. The turnout numbers rivaled those of 2008, despite long lines at the polls and court cases challenging early voting rules. In addition to the huge percentage of African Americans who voted for him, Obama was swept to victory by the youth and Latino votes, as well as large contingents of women, working class, and educated white voters. Our panel: - Callie Crossley, host and moderator, Boston Public Radio, 89.7 WGBH Radio - Peniel Joseph, professor of history, Tufts University - Phillip Martin, senior reporter, 89.7 WGBH Radio - Robert Fortes, Republican strategist Related links: Transcript of President Obama's acceptance speech Transcript of Mitt Romney's concession speech (Photo: President Barack Obama, first lady Michelle Obama, Vice President Joe Biden and Jill Biden acknowledge the crowd at his election night party on Wednesday, November 7, 2012. Source: Associated Press.) Full Article
bam Basic Black Live: Looking Ahead to the Second Obama Administration By www.wgbh.org Published On :: Sat, 26 Jan 2013 00:00:00 EST January 25, 2013 President Obama officially began his second term of office on January 20th. In his inaugural address to the nation the following day, his focus was on the strengths and promises of America. In this Basic Black conversation, we explore the challenges, the goals, and the demands for the second Obama administration. Our panel this week: - Callie Crossley, host and moderator, Boston Public Radio, WGBH - Kim McLarin, assistant professor of writing, literature and publishing, Emerson College - Phillip Martin, senior reporter, 89.7 WGBH Radio - Peniel Joseph, professor of history, Tufts University - Robert Fortes, Republican strategist and political consultant Photo: Supreme Court Chief Justice John Roberts administers the oath of office to President Barack Obama during the inaugural swearing-in ceremony at the U.S. Capitol in Washington, D.C., Jan. 21, 2013. (Official White House Photo by Sonya N. Hebert) Full Article
bam Selective Acceleration and Inhibition of Crystal Growth of Glass Carbamazepine by Low-Concentration Poly(ethylene oxide):Effects of Drug Polymorph By journals.iucr.org Published On :: Low-concentration poly(ethylene oxide) exhibit the polymorph-dependent effects on both the surface and bulk crystal growth of carbamazepine polymorphs. These polymorph-dependent effects of PEO were mainly attributed to the polymer enrichment at the interface and different crystal surface-polymer interactions. Full Article text
bam Methyl N-{(1R)-2-[(methoxycarbonyl)oxy]-1-phenylethyl}carbamate By journals.iucr.org Published On :: 2024-03-21 The title molecule, C12H15NO5, is a methyl carbamate derivative obtained by reacting (R)-2-phenylglycinol and methyl chloroformate, with calcium hydroxide as heterogeneous catalyst. Supramolecular chains are formed in the [100] direction, based on N—H⋯O hydrogen bonds between the amide and carboxylate groups. These chains weakly interact in the crystal, and the phenyl rings do not display significant π–π interactions. Full Article text
bam Molecular structure and selective theophylline complexation by conformational change of diethyl N,N'-(1,3-phenylene)dicarbamate By journals.iucr.org Published On :: 2024-05-07 The receptor ability of diethyl N,N'-(1,3-phenylene)dicarbamate (1) to form host–guest complexes with theophylline (TEO) and caffeine (CAF) by mechanochemistry was evaluated. The formation of the 1–TEO complex (C12H16N2O4·C7H8N4O2) was preferred and involves the conformational change of one of the ethyl carbamate groups of 1 from the endo conformation to the exo conformation to allow the formation of intermolecular interactions. The formation of an N—H⋯O=C hydrogen bond between 1 and TEO triggers the conformational change of 1. CAF molecules are unable to form an N—H⋯O=C hydrogen bond with 1, making the conformational change and, therefore, the formation of the complex impossible. Conformational change and selective binding were monitored by IR spectroscopy, solid-state 13C nuclear magnetic resonance and single-crystal X-ray diffraction. The 1–TEO complex was characterized by IR spectroscopy, solid-state 13C nuclear magnetic resonance, powder X-ray diffraction and single-crystal X-ray diffraction. Full Article text
bam Bis[tris(diisobutyldithiocarbamato)-μ3-sulfido-tri-μ2-disulfido-trimolybdenum(IV)] sulfide tetrahydrofuran monosolvate By journals.iucr.org Published On :: 2024-04-18 The title compound, [Mo3(C9H18NS2)3(S2)3S]2S, crystallizes on a general position in the monoclinic space group P21/n (No. 14). The cationic [Mo3S7(S2CNiBu2)3]+ fragments are joined by a monosulfide dianion that forms close S⋯S contacts to each of the disulfide ligands on the side of the Mo3 plane opposite the μ32− ligand. The two Mo3 planes are inclined at an angle of 40.637 (15)°, which gives the assembly an open clamshell-like appearance. One μ6-S2−⋯S22− contact, at 2.4849 (14) Å, is appreciably shorter than the remaining five, which are in the range 2.7252 (13)–2.8077 (14) Å. Full Article text
bam Synthesis, crystal structure and Hirshfeld surface analysis of 4-{(1E)-1-[(carbamothioylamino)imino]ethyl}phenyl propanoate By journals.iucr.org Published On :: 2024-04-18 The title compound, C12H15N3O2S, adopts an E configuration with respect to the C=N bond. The propionate group adopts an antiperiplanar (ap) conformation. There are short intramolecular N—H⋯N and C—H⋯O contacts, forming S(5) and S(6) ring motifs, respectively. In the crystal, molecules are connected into ribbons extending parallel to [010] by pairs of N—H⋯S interactions, forming rings with R22(8) graph-set motifs, and by pairs of C—H⋯S interactions, where rings with the graph-set motif R21(7) are observed. The O atom of the carbonyl group is disordered over two positions, with a refined occupancy ratio of 0.27 (2):0.73 (2). The studied crystal consisted of two domains. Full Article text
bam Crystal structure of tris{N,N-diethyl-N'-[(4-nitrophenyl)(oxo)methyl]carbamimidothioato}cobalt(III) By journals.iucr.org Published On :: 2024-06-11 The synthesis, crystal structure, and a Hirshfeld surface analysis of tris{N,N-diethyl-N'-[(4-nitrophenyl)(oxo)methyl]carbamimidothioato}cobalt(III) conducted at 180 K are presented. The complex consists of three N,N-diethyl-N'-[(4-nitrobenzene)(oxo)methyl]carbamimidothioato ligands, threefold symmetrically bonded about the CoIII ion, in approximately octahedral coordination, which generates a triple of individually near planar metallacyclic (Co—S—C—N—C—O) rings. The overall geometry of the complex is determined by the mutual orientation of each metallacycle about the crystallographically imposed threefold axis [dihedral angles = 81.70 (2)°] and by the dihedral angles between the various planar groups within each asymmetric unit [metallacycle to benzene ring = 13.83 (7)°; benzene ring to nitro group = 17.494 (8)°]. The complexes stack in anti-parallel columns about the overline{3} axis of the space group (Poverline{3}), generating solvent-accessible channels along [001]. These channels contain ill-defined, multiply disordered, partial-occupancy solvent. Atom–atom contacts in the crystal packing predominantly (∼96%) involve hydrogen, the most abundant types being H⋯H (36.6%), H⋯O (31.0%), H⋯C (19.2%), H⋯N (4.8%), and H⋯S (4.4%). Full Article text