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Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06334A, Edge Article
Open Access
Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun Feng
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06324D, Edge Article
Open Access
Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. Reek
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
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Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06227B, Edge Article
Open Access
Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin Jiang
Water–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.
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Why this balanced advantage fund is a useful addition amidst rough markets

ICICI Prudential Balanced Advantage juggles stocks, bonds and derivatives smartly for optimal returns




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Why I hold a passive-only mutual fund portfolio: Vishal Jain, CEO, Zerodha Fund House

Vishal Jain of Zerodha Fund House on why he actively favours the passive route




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Insurance of bank balance: some useful perspectives

The basis of safety or comfort with a bank should not be DICGC cover but overall fundamental quality of the bank; preferably bank with institutions where you would not require this coverage




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Why this focused fund can be a worthy investment in heated markets

Mahindra Manulife Focused fund is large-cap heavy and takes moderate risks in its portfolio




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Man accused in 25 cases arrested for attempted theft at magistrate’s house in Ernakulam




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Police officer arraigned as accused in accident case




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Man accused of raping a tribal Odisha woman engaged as domestic help surrenders before police

Former managing director surrenders after raping tribal woman, sparking protests; accused hospitalised; case under investigation




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1,000 consumer clubs to be formed on campuses, says Kerala Minister




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FAME-III scheme unlikely to extend benefits to hybrid vehicles as govt focuses on EVs, cabinet note ready

Maruti Suzuki India, Toyota and Hyundai Motor have been lobbying for tax cuts on hybrid vehicles




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Govt proposes new window in NRS auctions for buying coal without end use requirement

Coal Ministry proposes new window in NRS Linkage Auction Policy for long-term coal linkages without end use restrictions




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Legislative bodies should use technology to discuss, shape welfare schemes for the poor, says LS Speaker Birla

By ensuring accountability and transparency of the Executive, democratic institutions make governance more responsible and efficient, says the Lok Sabha Speaker




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PCOS and PCOD: What's the difference? Symptoms, causes, treatment, prevention

While you can't fully prevent PCOD or PCOS, early detection and healthy lifestyle choices can help manage symptoms.




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What is saree, petticoat cancer? From causes, symptoms to prevention, all you need to know

Research shows that tight petticoats worn with sarees may increase the risk of skin cancer in women due to constant....




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Soon, consumers will have to pay first and then use power in Andhra Pradesh

The smart and prepaid metering system, for which the APCPDCL has commenced a survey, is proposed to be rolled out as part of the Revamped Distribution Sector Scheme, a Central government-sponsored initiative




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Manipur Police accuse radical outfit Arambai Tengol of extortion, assault

Terming the abduction of an officer “unprecedented”, police in valley and hill districts ask for more forces of Assam Rifles, fearing a breach of peace due to the movement of armed civilians, underground outfits  




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Ghatkopar hoarding collapse: Bombay High Court refuses to give relief to Bhavesh Bhinde

Passing the order, a Division Bench of Justices Bharati Dangre and Manjusha Deshpande said there are no merits in the case.




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Ludhiana woman raped after her brother elopes with accused's daughter

A man along with three family members allegedly gang-raped a woman after his daughter eloped with the victim's brother; they also recorded the act on their mobile phones




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New Zealand PM delivers landmark apology to survivors of state abuse

Some 2,00,000 vulnerable New Zealanders were abused in state care in the seven decades since the 1950s, according to an inquiry




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Justin Welby, Archbishop of Canterbury, resigns over abuse scandal

Archbishop Welby, the spiritual leader of 85 million Anglicans worldwide, had faced calls to resign after a report last week found he had taken insufficient action to stop a person it described as arguably the Church of England’s most prolific serial abuser




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Residents stage protest against pollution caused by Vijayawada Thermal Power Station

People residing in the colonies at Ferry, Kondapalli and Ibrahimpatnam organised a protest and appealed to the government to protect them from pollution




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YSRCP leader Kakani Govardhan Reddy placed under house arrest in Nellore

The YSRCP leader says that police prevented him from joining the protest against the alleged malpractice of TDP leader and Sarvepalli MLA Somireddy Chandra Mohan Reddy in the tendering process for works at Kanupur Canal




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Nellore police arrests auto-driver accused in minor girl rape case




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Construction of one lakh houses under PMAY 1.0 scheme to be completed by December: Kolusu Parthasarathy

During a review of the Housing Department in Chittoor and Tirupati districts, he says that construction work was not completed in certain places due to lack of sand supply or heavy rains




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An overview of electrochemical biosensors used for COVID-19 detection

Anal. Methods, 2024, 16,2164-2176
DOI: 10.1039/D3AY02042H, Minireview
Tatiana Lima Valerio, Raquel Anastácio, Stella Schuster da Silva, Carolina Camargo de Oliveira, Marcio Vidotti
This short review presents the latest advances in the field of electrochemical biosensors, focusing particularly on impedimetric biosensors for the direct measurement of analytes.
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Electroanalysis overview: additive manufactured biosensors using fused filament fabrication

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00278D, Minireview
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Robert D. Crapnell, Craig E. Banks
Additive manufacturing (3D-printing), in particular fused filament fabrication, presents a paradigm shift in the way electrochemical based biosensing platforms are produced, giving rise to a new generation of personalized and on-demand biosensors.
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NPR and Aadhaar - a confused process




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The not-so-smart use of mobiles




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It is an offence: On Supreme Court clarification on online content on child sex abuse

Court has done well to clarify law on online content showing child sex abuse




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Synthesis and biological evaluation of novel D-ring fused steroidal N(2)-substituted-1,2,3-triazoles

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00297K, Research Article
Branislava Tenjović, Sofija Bekić, Andjelka Ćelić, Edward Petri, Julia Scholda, Florian Kopp, Marija Sakač, Andrea Nikolić
In this study, a series of 13 new D-ring fused steroidal N(2)-substituted-1,2,3-triazoles were synthesized, characterized and evaluated for their biological activities.
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Metal-free synthesis of N-fused quinazolino-quinazoline-diones as a MALAT1 RNA triple helix intercalator

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00614C, Research Article
Vijay Babu Pathi, Pranotosh Das, Abhyuday Guin, Manish Debnath, Biswadip Banerji
The development of chemical scaffolds that target highly conserved MALAT1 RNA received attention due to its significance in splicing, nuclear organization, and gene expression in disease progression pathways.
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The re-use mantra

Mimicking nature’s cleaning process through DEWATS and the Vortex system.




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Reuse greywater wisely

Treating greywater rather than transferring it to an STP has numerous benefits, says Indukanth Ragade




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Make full use of wastewater

In many small and medium towns, domestic wastewater is already being put to use by farmers. A look by S. Vishwanath




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The pros and cons of spouses teaming up as co-founders

How do married co-founders navigate the personal and professional ties at work




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‘Focused on building a high-conviction portfolio’

How fund house Cactus Partners ensures its capital goes toward growth rather than just keeping operations running




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Attempts to douse Alipur warehouse fire continue on second day




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HC refuses to entertain plea to enhance funds allocated to MCD councillors

The Hight Court expressed surprise that members of the Legislative Assembly (MLAs) and Municipal Corporation of Delhi (MCD) councillors were approaching courts with their grievances and asked them to raise the issue in the House or before the public




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CVC has sought report from CPWD over CM House renovation: Delhi LoP




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IIT Delhi’s annual Open House shows AI’s potential use in health care, tech




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Accused in five-year-old case of sexual assault on minor held




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2020 Delhi riots: SC refuses to entertain Gulfisha Fatima’s bail plea, asks HC to to hear case on Nov. 25

The counsel for the acccused, Kapil Sibal said the 31-year-old woman has been awaiting trial for 4.7 years; SC asks Delhi HC to hear case on November 25




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SC notice to Centre on plea alleging overuse of pesticides on crops and food items




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Shivraj Chouhan asks scientists to visit fields, help farmers to use technology

Union Minister Rajiv Ranjan Singh said that if the country does not pay attention to the livestock and fisheries sectors then the sectors may fall down




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Centre announces 3 AI Centres of Excellence focused on healthcare, agri and sustainable cities

The Centres of Excellence will be led by top educational institutions, in consortium with industry partners and startups, Union Education Minister Dharmendra Pradhan said




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After snails, farmers in Idukki battling spotted locust infestation; experts say change in climate pattern could be a cause

Plantations of over 70 farmers severely affected by the spotted locust infestation at Konnathady and Vathikudy panchayats




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How Facebook can decide the price of your house




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E-commerce soaks up 2 m sqft of warehouse realty in 2015