num

Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Like Hanuman




num

Design and synthesis of few-layer molybdenum oxide selenide encapsulated in a 3D interconnected nitrogen-doped carbon anode toward high-performance sodium storage

New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper
Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO3–MoSe2 encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00864B, Paper
Zhiqiang Wu, Yueyi Li, Pengxi Jiang, Sisi Ma, Wenfei Dong, Hongjian Zhao, Enke Feng, Xuming Wang
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkage polymerization method. The samples underwent characterization through the X-ray diffraction (XRD), the fourier transform infrared...
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Alleviation of Cadmium-Induced Oxidative Damage through Application of Zinc Oxide Nanoparticles and Strigolactones in Solanum lycopersicum L.

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00796K, Paper
Vaseem Raja, Karanpal Singh, Sami Ullah Qadir, Jagpreet Singh, Ki-Hyun Kim
In this research, zinc oxide nanoparticles (ZnO NPs) are bio-synthesized using Mangifera indica leaf extract as a sustainable capping and stabilizing source. The spherical morphology, crystallinity, and average size (17.97...
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Mycogenic silver nanoparticles from Penicillium citrinum IB-CLP11 – their antimicrobial activity and potential toxicity effects on freshwater organisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper
Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Quantitatively differentiating foliar adhesion and absorption of different lead-based particles on Solanum melongena L.

Environ. Sci.: Nano, 2024, 11,1417-1428
DOI: 10.1039/D3EN00640A, Paper
Bing Zhao, Siyu Zhang, Xuejiao Zhang, Qing Zhao, Jason C. White, Fengchang Wu, Baoshan Xing
This study quantitatively distinguished foliar adhesion and absorption between Pb nano- and submicron particles of different chemical forms.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Molecular mechanisms of dimethylarsinic acid adsorption onto aluminum substituted ferrihydrite surfaces

Environ. Sci.: Nano, 2024, 11,1713-1723
DOI: 10.1039/D3EN00664F, Paper
Yiting Ge, Jiaqi Wang, Fayang Guo, Meng Yuan, Wentao Wang, Jiangshan Li, Jing Zhang, Xionghan Feng, Wenfeng Tan, Yupeng Wu, Hui Yin
Aluminum substitution in ferrihydrite promotes the formation of monodentate mononuclear and outer-sphere complexes of dimethylarsinic acid on the mineral surfaces at the expense of bidentate binuclear complexes at pH 6.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Functionalized molybdenum disulfide (MoS2) monolayer as an efficient nanosensor towards toxic nitrogen containing gases

Environ. Sci.: Nano, 2024, 11,1740-1754
DOI: 10.1039/D4EN00072B, Paper
Wadha Alfalasi, Tanveer Hussain, Nacir Tit
Selective detection of toxic nitrogen-containing gases (e.g. NO and NO2) is achieved when special transition metal (TM) atoms are selected in doping molybdenum disulfide (MoS2) monolayer. The change of magnetic state is the secret of that selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Monumental neglect

Mumbai does not value its rock-cut caves, which are among the country’s finest pieces of architecture and bear testimony to its rich pre-colonial history. The lack of awareness and resources are to blame




num

Extract a Number from a String with JavaScript

User input from HTML form fields is generally provided to JavaScript as a string. We’ve lived with that fact for decades but sometimes developers need to extract numbers from that string. There are multiple ways to get those numbers but let’s rely on regular expressions to extract those numbers! To employ a regular expression to […]

The post Extract a Number from a String with JavaScript appeared first on David Walsh Blog.




num

Unusual immunosuppressive pyridine-containing bisnor- (c23), tetranor- (c21) and pentanor- (c20) sesterterpenoids from Tibetan Leucosceptrum canum

Org. Biomol. Chem., 2024, 22,3019-3024
DOI: 10.1039/D4OB00334A, Paper
Man Li, Ling Feng, Han Zhang, Yan-Chun Liu, Ting-Ting Zhou, Yu Zheng, Kai Guo, Yan Liu, Sheng-Hong Li
Six unusual pyridine-containing bisnor- (C23), tetranor- (C21) and pentanor- (C20) sesterterpenoids were obtained from the medicinal plant Leucosceptrum canum of Tibetan origin. The immunosuppressive activities of these sesterterpenoids were observed.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

'Prasanth wanted Yash to play Hanuman'

'Since God was being shown in live action on such a large scale, Prasanth was initially sceptical about going with an animated character.'




num

The history of Japan. 16, Towards a more diverse society : from the Heisei era to the Reiwa era / editorial supervisor, Kaoru Iokibe ; cover and manga illustrations, Kou Yaginuma.

Chiyoda-ku, Tokyo, Japan : Japan Publishing Industry Foundation for Culture (JPIC), 2023.




num

Dual luminescence and infrared circularly polarized luminescence up to 900 nm with platinum complexes bearing a helical donor–acceptor ligand

Mater. Chem. Front., 2024, 8,3799-3806
DOI: 10.1039/D4QM00632A, Research Article
Open Access
Pablo Vázquez-Domínguez, Maher Horojat, Eva Suits, Francisco José Fernández de Córdova, Nicolas Vanthuyne, Denis Jacquemin, Abel Ros, Ludovic Favereau
Engineering the intramolecular charge transfer character of ligands in axially chiral arylisoquinolines platinum(II) complexes leads to both fluorescence and phosphorescence emissions in solution, with NIR CPL that extends up to almost 850 nm.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Behind the numbers with Opta and Audi - A Driven To Win Film | WIRED with Audi

Football is increasingly a data driven game, and clubs are looking at technology to give them the edge. Audi are developing the Audi Player Index with Opta to track players in real time. WIRED went the Audi Cup to find out how.




num

Autocomplete Interview - Fanum Answers The Web's Most Searched Questions

YouTuber, streamer and unapologetic New Yorker Fanum visits WIRED to answer his most searched for questions.




num

Correction: Enhancing the chemotherapeutic efficacy of platinum prodrug nanoparticles and inhibiting cancer metastasis by targeting iron homeostasis

Nanoscale Horiz., 2024, 9,2067-2068
DOI: 10.1039/D4NH90069C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fang Ding, Lingpu Zhang, Hao Chen, Haiqin Song, Shiguo Chen, Haihua Xiao
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Of elections and numbers

Though most of us crave for objectivity and neutrality in political analyses, these often suffer from our in-built biases, predilections



  • From the Viewsroom

num

Birders in Visakhapatnam report a drop in number of species during the Asian Waterbird Census

Habitat destruction, poaching and landfills near water sources are some of major threats faced by wetlands and birds in and around it in Visakhapatnam




num

An aluminum-based hybrid film photoresist for advanced lithography by molecular layer deposition

J. Mater. Chem. C, 2024, 12,17544-17553
DOI: 10.1039/D4TC02794A, Paper
Xingkun Wang, Taoli Guo, Yiyang Shan, Ou Zhang, Hong Dong, Jincheng Liu, Feng Luo
Al-based dry photoresists synthesized by molecular layer deposition (MLD) have good resolution and excellent etch resistance, so their application in photolithography is very promising.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Magnum force (1973) / directed by Ted Post [DVD].

[U.K.] : Warner Bros., [2009]




num

TVLF appeal to Veerashaiva Lingayats on enumeration




num

Aluminothermic reduction of CeO2: mechanism of an economical route to aluminum–cerium alloys

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00087K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alfred Amon, Emily E. Moore, Hunter B. Henderson, Jibril Shittu, Martin Kunz, Shane Kastamo, Nikolai Huotari, Adam Loukus, Ryan Ott, David Weiss, Scott K. McCall
Time-resolved X-ray diffraction enabled mechanistic insight into the aluminothermic reduction of CeO2. The environmentally friendly process enables a direct route to Al–Ce alloy production and a high-value use for excess Ce from rare earth mining.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Wynnum Herald [electronic journal].

Nationwide News Pty Limited




num

Productivity Dispersion and Persistence Among the World's Most Numerous Firms [electronic journal].

National Bureau of Economic Research




num

New Characteristics and Hedonic Price Index Numbers [electronic journal].




num

Myths and Numbers on Whistleblower Rewards [electronic journal].




num

Exploiting MIT Shocks in Heterogeneous-Agent Economies: The Impulse Response as a Numerical Derivative [electronic journal].

National Bureau of Economic Research




num

Elite Violence and Elite Numeracy in Europe from 500 to 1900 CE: A Co-Evolution? [electronic journal].




num

Distance-based social index numbers: a unifying approach [electronic journal].




num

Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00334A, Research Article
Jing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang Tong
Two magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide

Inorg. Chem. Front., 2024, 11,2272-2280
DOI: 10.1039/D4QI00344F, Research Article
Mengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang Zhu
This work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Recent progress in aluminum anodes for high-performance rechargeable aqueous Al-ion batteries

Inorg. Chem. Front., 2024, 11,2246-2259
DOI: 10.1039/D4QI00468J, Review Article
Le Li, Shaofeng Jia, Yue Shi, Conghui Wang, Hengwei Qiu, Yongqiang Ji, Minghui Cao, Dan Zhang
This review discusses the recent advances in the aluminum metal anodes, alloy anodes, and intercalated anodes used for rechargeable aqueous Al-ion batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries

Inorg. Chem. Front., 2024, 11,2300-2311
DOI: 10.1039/D4QI00391H, Research Article
Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
The introduction of Al2O3 regulates the solvation structure of Na+, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

More than just a number: A call to improve adverse event reporting

Heal the hurt: Redressal and support are critical to keep the faith in the system from breaking down




num

Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05014B, Edge Article
Open Access
Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei He
Modulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06083K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa Jung
The modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Efficient numerical modelling of magnetophoresis in millifluidic systems

Lab Chip, 2024, 24,5009-5019
DOI: 10.1039/D4LC00595C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Johannes Soika, Tobias Wanninger, Patrick Muschak, Anja Schnell, Sebastian P. Schwaminger, Sonja Berensmeier, Markus Zimmermann
Analytical system descriptions enable efficient 3D magnetophoresis modeling, where dimensions and fluid profile choices significantly impact results.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Defiant BRS MLA Mynampalli Hanumantha Rao to decide future course of action after talks with supporters

“I had not made any personal accusation against the Chief Minister K. Chandrashekhar Rao or the party. My grouse is against Mr. Harish Rao only,” he said.




num

West Asian nations hold the highest number of Indians in jails abroad | Data

Nearly 9,500 Indians are currently lodged in prison across 89 nations




num

Japan’s record number of women MPs still a minority

Japan ranks 118th of 146 in the 2024 World Economic Forum’s Global Gender Gap report




num

A novel electrophoretic assisted hydrophobic microdevice for enhancing blood cell sorting: design and numerical simulation

Anal. Methods, 2024, 16,2368-2377
DOI: 10.1039/D4AY00196F, Paper
Xinkun Chen, Xueye Chen
Microfluidic technology has great advantages in the precise manipulation of micro–nano particles, and the hybrid microfluidic separation technology has attracted much attention due to the advantages of both active and passive separation technology at the same time.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

Quantifying platinum binding on protein-functionalized magnetic microparticles using single particle-ICP-TOF-MS

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00268G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Veronica C. Bradley, Benjamin T. Manard, Lyndsey Hendriks, Daniel R. Dunlap, Amber N. Bible, Ada Sedova, Patricia Saint-Vincent, Brian C. Sanders, Hunter B. Andrews
This work describes an analytical procedure, single particle-inductively coupled plasma-time-of-flight-mass spectrometry (SP-ICP-TOF-MS), that was developed to determine the platinum binding efficiency of protein-coated magnetic microparticles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




num

In Araku, strawberry farms are drawing visitors in large numbers

Fill your baskets with juicy strawberries at the farming fields this season at Pedalabudu village near Araku in Andhra Pradesh




num

Virat Kohli's 100th Test:All The Numbers

Rajneesh Gupta presents all the numbers you need to know about Virat Kohli in Test cricket.




num

Border checkposts in Nilgiris to soon have automatic number plate recognition cameras

This comes in the wake of the Madras High Court recently expressing dissatisfaction over the implementation of the e-pass system in the Nilgiris and Kodaikanal




num

‘Your life is more than just a number on a weighing scale’

At an event to launch her book Gain to Lose, Dr. Sheela Nambiar said weight training helped women lose weight and cope better with their myriad tasks




num

The numbers that (don’t) matter

Do not go by the weighing scale. It doesn't tell you the full story about your fitness and health