ea Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6418-6425DOI: 10.1039/D4QO01298D, Research ArticleWei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun YaoA phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6426-6436DOI: 10.1039/D4QO01551G, Research ArticleMao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long ZhaoA cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6385-6392DOI: 10.1039/D4QO01243G, Research ArticleJinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian ChenA cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6319-6326DOI: 10.1039/D4QO01368A, Research ArticleYu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming WangA variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Nickel-catalysed enantioselective cross-electrophile coupling reaction with the retention of the β-fluorine atom By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6459-6469DOI: 10.1039/D4QO01555J, Research ArticleXin-Yi Shi, Xueyuan Yan, Xiaodong Tang, Shi-Jing Zhai, Genping Huang, Jun-An Ma, Fa-Guang ZhangA nickel-catalysed enantioselective reductive cross-coupling reaction of a new monofluoromethyl building block with acid chlorides is developed to give chiral α-monofluoromethyl acyloin derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6510-6517DOI: 10.1039/D4QO01517G, Research ArticleYu Sun, Yi Wang, Zhijun ZuoA novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6311-6318DOI: 10.1039/D4QO01474J, Research ArticleJiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng ChenCo-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Transition-metal-catalyzed C–Ge coupling reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6558-6572DOI: 10.1039/D4QO01637H, Review ArticleJie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan HeThis review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6534-6557DOI: 10.1039/D4QO01686F, Review ArticleJinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun XieThis review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01388C, Research ArticleShanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian CaiA two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01512F, Research ArticleRahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez KhanA new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01794C, Research ArticleXiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan YuThe mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:06:15 +0530 Full Article Telangana
ea Cong. govt cheating paddy farmers on procurement: Kishan Reddy By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:50:38 +0530 Full Article Telangana
ea GHMC official sentenced to one-year RI in ACB case By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:18:55 +0530 Full Article Telangana
ea ₹4.8 crore loan fraud scheme unearthed at SBI Sanathnagar, eight more arrested By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:26:49 +0530 Full Article Telangana
ea HYDRAA created fear among encroachers and big builders and not common people: Telangana CM By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:49:14 +0530 Full Article Telangana
ea When hope meets hurdles: stark reality of Telangana’s job market By www.thehindu.com Published On :: Fri, 08 Nov 2024 08:17:07 +0530 The State’s job crisis has come back to haunt the Congress party, which rode to power last year on promises of employment. While local youth wait, worry, and exchange dreams about securing government jobs, short-term opportunities are drawing people from other States. This dynamic has transformed Telangana into a job magnet for outsiders but a desert for its own aspirants, reports Serish Nanisetti Full Article Telangana
ea ‘Rahasyam Idham Jagath’ movie review: Earnest but far from engrossing By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:36:40 +0530 Director Komal R Bharadwaj’s Telugu indie ‘Rahasyam Idham Jagath’ is ambitious in using science, technology and stories from the Indian epics for an adventure drama, but falls short in its execution Full Article Movies
ea Congress shedding ‘çrocodile tears’ over BCs welfare: BJP leader Laxman By www.thehindu.com Published On :: Fri, 08 Nov 2024 17:55:32 +0530 Full Article Telangana
ea Raid on hospitals in Hyderabad and Secunderabad leads to seizure of controlled drugs By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:03:20 +0530 The raiding teams found substances which are are classified as controlled drugs and their sale and possession are strictly regulated under the Narcotic Drugs and Psychotropic Substances (NDPS) Act Full Article Hyderabad
ea Ugandan woman sentenced to 13 years RI for smuggling drugs to Hyderabad By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:05:50 +0530 The woman was caught attempting to smuggle 3,900 grams of heroin, worth ₹25 crore, to Hyderabad Full Article Telangana
ea 32 STPs taken up by BRS govt. to cleanse Musi: MLAs By www.thehindu.com Published On :: Sat, 09 Nov 2024 19:00:05 +0530 ₹3.8k crore STP project was to protect Nalgonda ryots’ farm fields from sewage water Full Article Telangana
ea Ponnam criticises BJP leader Laxman’s comments on caste census By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:06:17 +0530 Full Article Telangana
ea Telangana govt. urged to release caste survey forms in English and Urdu By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:26:10 +0530 Full Article Telangana
ea Mental health and resilience in higher education institutions as a mission By www.thehindu.com Published On :: Sat, 09 Nov 2024 21:10:51 +0530 A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing Full Article Telangana
ea Trust deficit exists between citizens and healthcare system: former IAS officer By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:23:49 +0530 Full Article Hyderabad
ea Telangana State Cyber Security Bureau nabbed 165 cyber criminals involved in 795 cases in last six months By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:58:22 +0530 45% fraudsters are either graduates or post-graduates; indulge in crime due to peer pressure and for easy money, says data Full Article Telangana
ea Nodal officers appointed for the caste survey in Greater Hyderabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:44:47 +0530 Full Article Telangana
ea Cyberabad police impose restrictions near exam centres on November 17 and 18 By www.thehindu.com Published On :: Tue, 12 Nov 2024 11:42:16 +0530 Full Article Hyderabad
ea Ind vs NZ 3rd Test: India hand New Zealand control after batting flop show on Day 1 By www.thehindu.com Published On :: Fri, 01 Nov 2024 10:48:39 +0530 India’s batting collapse makes a comeback as they face the horror of a clean sweep at home against New Zealand. Full Article Cricket
ea India cancel intra-squad match to prioritise net practice ahead of Border-Gavaskar Trophy By www.thehindu.com Published On :: Fri, 01 Nov 2024 13:39:48 +0530 India cancels intra-squad match with ‘A’ side in Australia tour for more net practice, focusing on Test series preparation Full Article Cricket
ea IND vs NZ third Test: Ravindra Jadeja rues worst fears having come true By www.thehindu.com Published On :: Fri, 01 Nov 2024 19:40:26 +0530 In India’s last series loss at home prior to this, Jadeja – a rookie – had featured in a solitary Test. Full Article Cricket
ea India vs New Zealand, 3rd Test, Day 2: Spinners dominate, time for batters to salvage pride; Test poised for exciting finish By www.thehindu.com Published On :: Sat, 02 Nov 2024 12:28:49 +0530 New Zealand ended day two with an overall lead of 143, which might look small but even a target in the vicinity of 150 will pose serious challenge for the Indian batters Full Article Cricket
ea Virat Kohli drops hints of completing 20 years with RCB By www.thehindu.com Published On :: Sat, 02 Nov 2024 15:52:51 +0530 Virat Kohli has been playing for RCB ever since IPL's inception in 2008 and is the leading run-scorer in the competition, amassing over 8,000 runs Full Article Cricket
ea IND vs NZ third Test Day 2: Chase won't be easy, we have to bat really well, says Ravichandran Ashwin By www.thehindu.com Published On :: Sat, 02 Nov 2024 18:03:18 +0530 What surprised Ashwin is the nature of low bounce, not exactly synonymous with red soil Mumbai surfaces which helps the ball to fly. Full Article Cricket
ea IND vs NZ third Test: India takes a narrow lead, with the Test poised on a knife’s edge By www.thehindu.com Published On :: Sat, 02 Nov 2024 19:19:18 +0530 Pant leads the way with an entertaining knock, while Gill is unlucky to miss his hundred; Azaz once again excels with a five-for to keep the Kiwis in the hunt on a turning track turning hostile for the batters with every passing hour Full Article Cricket
ea Ind vs NZ 3rd Test: New Zealand scripts history as India suffers Test series whitewash By www.thehindu.com Published On :: Sun, 03 Nov 2024 09:58:39 +0530 No team had been able to win all the Test matches in India in a series featuring three or more Test matches in nine decades. Full Article Cricket
ea BCCI to discuss New Zealand whitewash, some senior players could be phased out post-Australia series By www.thehindu.com Published On :: Sun, 03 Nov 2024 18:27:36 +0530 There is a high possibility that the five-match Test series against Australia could be the final one for at least two of the four seniors among Rohit Sharma, Virat Kohli, Ravindra Jadeja and Ravichandran Ashwin. Full Article Cricket
ea Wriddhiman Saha announces retirement from cricket after this year's Ranji Trophy By www.thehindu.com Published On :: Mon, 04 Nov 2024 11:03:14 +0530 Veteran cricketer Wriddhiman Saha announces retirement, last season in Ranji Trophy, ending a cherished journey in cricket Full Article Cricket
ea India vs New Zealand: Will Young shines in New Zealand’s historic Test series win in India By www.thehindu.com Published On :: Mon, 04 Nov 2024 14:51:37 +0530 His biggest contributions came in the third Test at Mumbai when Young’s 71 and 51 across the two innings helped New Zealand become the first team ever to beat India 3-0 in their own backyard Full Article Cricket
ea Wriddhiman Saha to retire after this season Ranji Trophy By www.thehindu.com Published On :: Mon, 04 Nov 2024 17:38:48 +0530 Full Article Cricket
ea India’s coaching staff under the scanner ahead of the Border-Gavaskar series By www.thehindu.com Published On :: Mon, 04 Nov 2024 18:27:16 +0530 Gambhir & Co. gets captain Rohit’s backing after the home Test series loss against New Zealand; the head coach says the team has to be honest and keep working hard Full Article Cricket
ea Australian pacer Boland looks to keep KL Rahul under pressure ahead of Border-Gavaskar Trophy By www.thehindu.com Published On :: Wed, 06 Nov 2024 04:53:00 +0530 Rahul made a hundred on his debut tour to Australia in 2015, a 110 at Sydney, but his overall performance Down Under remains scratchy, evidenced by an average of 20.77 across four Tests. Full Article Cricket
ea Ben Stokes missing from IPL’s list of 1,574 players ahead of mega auction By www.thehindu.com Published On :: Wed, 06 Nov 2024 11:58:05 +0530 IPL mega auction list includes marquee Indian players like Pant, Iyer, and Rahul, with a total purse of ₹120 crore Full Article Cricket
ea RANJI TROPHY | It is a Lad and Shreyas show as Mumbai tears into Odisha’s bowling By www.thehindu.com Published On :: Wed, 06 Nov 2024 18:36:13 +0530 CRICKET | Teenager Raghuvanshi sets the ball rolling at the top of the order after visiting captain Poddar’s ill-judged move to insert the home team in Full Article Cricket
ea Ranji Trophy | Bhambri leads the way as Chandigarh nudges ahead of Delhi By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:54:37 +0530 Almost all batters make handy contributions as the host takes a 48-run first-innings lead; spinners Badoni and Mathur shine with the ball for the visitor Full Article Cricket
ea Denish leads Assam’s fightback against Tamil Nadu By www.thehindu.com Published On :: Fri, 08 Nov 2024 00:06:46 +0530 The skipper compiles a patient unbeaten 54 and forges an unbroken 71-run stand with southpaw Sibsankar Roy, denying the opposition bowlers a breakthrough till close of play Full Article Cricket
ea NewGen stars have a chance to shine as Proteas challenge awaits By www.thehindu.com Published On :: Fri, 08 Nov 2024 05:37:00 +0530 It is imperative for them to shed the tag of sidekicks and establish themselves as the first-choice players in this format. Full Article Cricket
ea Ranji Trophy | Pacers put Bengal in driver’s seat against Karnataka By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:07:25 +0530 Porel’s four-for and Sindhu’s three-wicket haul help the visitor bundle out the host for 221 before reaching 127 for three in its second essay at the end of day three Full Article Cricket