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Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts

Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
The content of this RSS Feed (c) The Royal Society of Chemistry




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All-in-one Rh(III)-covalent organic framework for sustainable and regioselective C(sp2)–H bond functionalization

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper
Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp2)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of Co3O4 catalysts with different morphologies and their excellent catalytic performance for soot combustion

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01115E, Paper
Xinyu Zhang, Chunlei Zhang, Siyu Gao, Xinyu Chen, Siyuan Chen, Shengran Zhou, Di Yu, Lanyi Wang, Xiaoqiang Fan, Xuehua Yu, Zhen Zhao
A series of Co3O4 catalysts with different morphologies were prepared by a hydrothermal method. Among them, the sea urchin shaped Co3O4 catalyst exhibits the best catalytic performance for soot combustion.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Insight into the influence of Re and Cl on Ag catalysts in ethylene epoxidation

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00858H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Claudia J. Keijzer, Pim T. Weide, Kristiaan H. Helfferich, Justyna Zieciak, Marco de Ridder, Remco Dalebout, Tracy L. Lohr, John R. Lockemeyer, Peter van den Brink, Petra E. de Jongh
Crystalline AgReO4 was formed in Re-promoted Ag catalysts. The effect of Re on catalysis and EO isomerization was tested without and with the industrially relevant ethyl chloride. EO isomerization was greatly affected by both Re and Cl.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst

Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic H2O2 production with perylene(bis-imide)-doped periodic mesoporous silica using micropollutants as sacrificial donors

Catal. Sci. Technol., 2024, 14,6710-6719
DOI: 10.1039/D4CY00739E, Paper
Charlotte David, Stephane Grolleau, Denys Grekov, Aydar Rakhmatullin, Errol Blart, Valerie Hequet, Yann Pellegrin
A perylene-doped mesoporous silica material is used as a photocatalyst to produce H2O2 from aerated polluted water samples under light soaking.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Phenol Hydroxyl-Modified Imine-Based Covalent organic framework for enhanced solar-driven generation of H2O2 via Hydrogen Bonds

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper
Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Anthracene-based covalent organic framework supported palladium nanoparticles for visible-light-mediated Suzuki-Miyaura cross-coupling

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper
Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Microgels for bioprinting: recent advancements and challenges

Biomater. Sci., 2024, 12,1950-1964
DOI: 10.1039/D3BM01733H, Review Article
Mingjun Xie, Ji Wang, Sufan Wu, Sheng Yan, Yong He
This review introduces different methods used to generate microgels and the microgel-based bioink for bioprinting. Besides, the further tendency of microgel development in future is predicted.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Porphyrin-Based Covalent Organic Frameworks from Design, Synthesis to Biological Applications

Biomater. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4BM00214H, Review Article
Open Access
Xin-Gui Li, Junjian Li, Jinfeng Chen, Liangmei Rao, Libin Zheng, Fei Yu, Yijing Tang, Jie Zheng, Jie Ma
Covalent organic frameworks (COFs) constitute a class of highly functional porous materials characterized by ordered structures, high crystallinity, and a substantial specific surface area, primarily composed of light atoms such...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Some give and tech, this Valentine’s Day! 

Here are some fun features you might have missed out on — or not! — this Valentine’s Day! 




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MWC 2024: Lenovo showcases transparent laptop, new ThinkBook lineup and more

The focus is on seamless connectivity and AI-experiences 




len

Lenovo has shifted focus to solution-oriented offerings: Tom Butler

In conversation with businessline at MWC 2024, Tom Butler, Executive Director, Worldwide Commercial Portfolio and Product Management at Lenovo, has shed light on successes, disappointments, transparent tech and much more




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Lenovo Legion 5i review. Conquering new realms

The latest version of the gaming laptop adds new functionalities to up the ante




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Lenovo Tab M11 (2024) review: No frills, but some fun included!

The new budget tablet from the Chinese brand throws in a functional stylus at a great price point.




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Sleek, slender powerhouse -

Dell XPS 14: The top-of-the-line ultrabook offers great functionalities for work and play




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Lenovo Tab Plus review. An audiophile’s tablet 

If watching movies, listening to music and catching up on social media are your primary needs, then the Lenovo Tab Plus is definitely worth considering




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Lenovo launches a slew of CoPilot AI PCs  

Unveils additions to its Lenovo Yoga and Lenovo IdeaPad portfolios at Lenovo Innovation World 2024




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Twist & shout! Lenovo Auto Twist AI PC - Exclusive first glance

A concept device that shifts shape, and listens to every command you say




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Lenovo launches business and enterprise line-up

Unveils ultra-light ThinkPad laptops at Lenovo Innovation World 2024




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Lenovo Auto Twist AI PC: Twist and shout!

An exclusive hands-on first impression of a concept device that shifts shape and listens to every command




len

‘Eight out of every 10 organisations face a dearth of relevant tech talent’ 

With technology-based job roles taking on newer complexities, a growing number of organisations are acknowledging the need to work on their talent base, according to a new study




len

Domestic violence as a workplace issue

In India, a small but growing number of companies are having policies in place to extend support to employees facing this situation




len

Addressing the talent crunch in the semiconductor industry

More than ever before, companies in this sector see the need to strike a meaningful and lasting partnership with academia




len

Visakhapatnam police destroy 181 modified silencers, issue stern warning to errant motorists




len

The Lee X Suneet Varma collaboration, featuring Sara Ali Khan, blends comfort with couture

Choose from denim corsets, chic dresses, statement skirts and bell bottoms, rich with embroidery and embellishments




len

Let silence prevail

Noise pollution in residences, commercial establishments and corporate offices has become an intense stress factor. Are designers ready to tackle this issue? A look by Nandhini Sundar




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Subdued blenders demand hit tea prices in Coonoor auctions

The sales percentage in leaf was only 47 per cent out of the offered quantity of 25,83,350 kg, while in dust, it was 53 per cent out of the offered quantity of 6,14,625 kg




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Lenovo Tab P12 Pro Review: Work in ‘Pro’gress

A tablet with noteworthy specs, but not without its share of imperfections




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Lenovo M10 Plus tablet launched

The Tab M10 Plus (3rd Gen) is powered by an octa-core Qualcomm Snapdragon 680 chipset with 6GB RAM and 128GB storage​ to deliver good multimedia experience and mobile gaming performance



  • Mobiles & Tablets

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Lenovo Tab M9 review: An affordable, compact companion

Here is the low-down on where it impresses, and where it doesn’t




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In Maharashtra Polls, Gavit Family Holds Key To All Four Nandurbar Seat - A Stiff Challenge For BJP, Congress

In Nandurbar district, 70 per cent of the population is tribal and the region has consistently ranked among the lowest in Maharashtra's Human Development Index.




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Ahead Of Uttar Pradesh Bypolls, Yogi Adityanath Faces A `Youth` Challenge

UPPCS Protest: Amid the bypolls contest, the Yogi Adityanath government is facing a challenge which the BJP was not anticipating at this time.




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The silence of Narendra Modi




len

An artiste par excellence: Kishore Kumar

Today, on his 91st birthday, it is obvious that Kishore Kumar will forever win the hearts of people of all generations




len

Google Pixel 9 Pro Fold Review | Blends software expertise with AI in a new form factor

The Pixel 9 Pro Fold not only marks Google’s foray into the foldable market in India, but also aims to redefine user expectations




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Dyson OnTrac Review | Thoughtful headphones with excellent sound and long battery life

Customisation is a key aspect of OnTrac’s design philosophy. Users can personalise their headphones with customisable outer caps and ear cushions available in a range of colours and finishes




len

Infinix Zero Flip to use triple 50 MP lenses with 4K video recording and GoPro compatibility

The Chinese smartphone maker will launch the Zero Flip on October 17 in India




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Infinix’s first flip phone Zero Flip launched with 3.64 inch cover display and 50 MP selfie lens

The Infinix Zero Flip cover and displays have a similar 120 Hz refresh rate




len

Thanks to plenty of firsts and proven performers, India emerges as Paralympic power in Paris

Seven of these 29 medals are gold, which is another first for the country that started to make its presence felt only in the 2016 edition, where it won four medals




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Inside the gated glens and glades

If your heart aches for a piece of green, landscaping can be of help




len

Finding the right blend

Modular kitchens are all about ensuring maximum utility, convenience, comfort, and easy movement, says M.L. Mahesh.




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Today’s top tech news: Apple’s labour challenges; Russian trolls target U.S. elections; Microsoft’s AI users in India




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WhatsApp working on Google Lens-like feature to verify images

WABetaInfo reported that a new feature as part of the WhatsApp beta for Android 2.24.23.13 would let users look up images shared with them




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BASF, Solenis to combine water, paper chemicals




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Committee on Science: Exploring emerging scientific challenges and opportunities




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Call for nominations for Green Chemistry Challenge Awards




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EPA to ban methylene chloride in paint strippers

Agency commits to action on CH2Cl2 in consumer and commercial products




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Improved electrode efficiently converts CO<sub>2</sub> to ethylene

Electrochemical system runs 15 times as long as best previous design




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Sadara plans pipeline for ethylene and propylene oxide