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Research on preparation and related properties of macro–micro porous mullite ceramic skeletons via twice pore-forming technology

RSC Adv., 2024, 14,12624-12632
DOI: 10.1039/D4RA01277A, Paper
Open Access
Chunxia Xu, Rui Hu, Ying Liu, Zhe Chen, Zhen Liu, Wenbin Han
The macro–micro composite porous mullite ceramic skeletons were prepared using coal gangue and α-Al2O3 as main raw materials via twice pore-forming technology. The main phase of the porous ceramic skeletons is mullite.
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In situ one step growth of amorphous tin oxide electron transport layer for high-performance perovskite solar cells

RSC Adv., 2024, 14,12650-12657
DOI: 10.1039/D4RA01724B, Paper
Open Access
Wenlin Du, Zhe Wan, Jingyi Zhu, Xin Liu, Li Chen, Shuxia Li, Ning Kang, Chenglong Wang
Perovskite solar cells prepared by using amorphous Tin oxide as electron transport layer.
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Enhanced photocatalytic performance of ZnO under visible light by co-doping of Ta and C using hydrothermal method

RSC Adv., 2024, 14,12954-12965
DOI: 10.1039/D4RA00579A, Paper
Open Access
Thi Viet Ha Luu, Hong Yen Xuan Nguyen, Quoc Thang Nguyen, Quang Bac Nguyen, Thi Ha Chi Nguyen, Ngoc Chuc Pham, Xuan Dung Nguyen, Trung Kien Nguyen, Ngoc Nhiem Dao
C, Ta-co-doped ZnO nanoparticles (Eg = 2.88 eV), prepared by hydrothermal method, were used as a photocatalyst under visible light to remove organic contaminants in aquatic environments.
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High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon

RSC Adv., 2024, 14,13017-13026
DOI: 10.1039/D4RA01641F, Paper
Open Access
Shayan Gul, Fatima Nasim, Waheed Iqbal, Amir Waseem, Muhammad Arif Nadeem
Efficient electrocatalytic CO2 reduction reaction (eCO2RR) to various products, such as carbon monoxide (CO), is crucial for mitigating greenhouse gas emissions and enabling renewable energy storage.
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Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(III/II/III) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study

RSC Adv., 2024, 14,13200-13208
DOI: 10.1039/D3RA07697K, Paper
Open Access
Sovana Maity, Sudip Bhunia, Michael G. B. Drew, Rosa M. Gomila, Antonio Frontera, Shouvik Chattopadhyay
Formation of hydrogen bonding network in a trinuclear linear mixed-valence centrosymmetric cobalt(III)–cobalt(II)–cobalt(III) complex has been analyzed using DFT calculations.
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Dispersive micro solid phase extraction of glibenclamide from plasma, urine, and wastewater using a magnetic molecularly imprinted polymer followed by its determination by a high-performance liquid chromatography-photodiode array detector

RSC Adv., 2024, 14,13168-13179
DOI: 10.1039/D4RA00452C, Paper
Open Access
Najmeh Sabbaghi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani, Majid Farsadrooh
The present study describes the development of a simple and selective analytical method for dispersive micro solid phase extraction and determination of glibenclamide (GLB) using magnetic molecularly imprinted polymer (MMIP) as a sorbent.
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A multi-channel microfluidic platform based on human flavin-containing monooxygenase 3 for personalised medicine

RSC Adv., 2024, 14,13209-13217
DOI: 10.1039/D4RA01516A, Paper
Open Access
Melissa De Angelis, Silvia Schobesberger, Florian Selinger, Viktor Laurin Sedlmayr, Martin Frauenlob, Orsola Corcione, Shiman Dong, Gianfranco Gilardi, Peter Ertl, Sheila J. Sadeghi
A microfluidic platform with immobilized human flavin-containing monooxygenase for high-throughput screening of drugs with relevance to personalised medicine.
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The fabrication of the photothermal antibacterial platform for bacterial infectious skin wound healing: A review

Mol. Syst. Des. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4ME00010B, Review Article
Mei Han, Wenjing Sun, Yi Chen, Hongbin Li
Antibiotics are currently the main strategy to treat bacterial infections, but they can cause bacterial resistance, and it is urgent to solve this problem. The emergence of photothermal therapy provides...
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A facile and versatile platform for preparing uniform π-conjugated nanofibers with controlled length and varying shells

Polym. Chem., 2024, 15,4231-4243
DOI: 10.1039/D4PY00979G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bo Xiang, Hongluo Wu, Rang Chen, Xiaoyu Huang, Guolin Lu, Chun Feng
A versatile and facile platform is developed for the generation of uniform π-conjugated nanofibers with controlled length and varying shells by the combination of pentafluorophenyl ester chemistry and a self-seeding strategy.
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Materials designed to degrade: structure, properties, processing, and performance relationships in polyhydroxyalkanoate biopolymers

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00623B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jessica N. Lalonde, Ghanshyam Pilania, Babetta L. Marrone
A materials tetrahedron framework is applied to PHA biopolymers to highlight design challenges and frame potential future research exploring structure, property, processing, and performance relationships.
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Scalable design of uniform oligourethanes for impact study of chain length, sequence and end groups on thermal properties

Polym. Chem., 2024, 15,4319-4326
DOI: 10.1039/D4PY01001A, Paper
Open Access
Jens Van Hoorde, Nezha Badi, Filip E. Du Prez
A bidirectional growth-based protocol is used for the synthesis of a series of sequence-defined oligourethanes in large scale (50 g). The effect of chain length, sequence and end group functionalities on the thermal properties is evaluated.
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Effect of interfacial local conformation of polymer chains on adhesion strength

Polym. Chem., 2024, 15,4425-4432
DOI: 10.1039/D4PY00951G, Paper
Open Access
Tatsuki Abe, Satoru Yamamoto, Keiji Tanaka
The aggregation states of polymer chains at solid interfaces are strongly related to their adhesion properties.
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Rapid formation of antifouling coatings via cation–π interactions

Polym. Chem., 2024, 15,4465-4473
DOI: 10.1039/D4PY00859F, Paper
Zhicheng Huang, Kaijie Zhao, Shaoyin Wei, Yingxin Hao, Qina Yu, Jingcheng Hao, Jiwei Cui, Peiyu Zhang
Antifouling coatings can be quickly prepared on various substrates through cation–π interactions between copolymers and MPNs. In addition, block copolymers exhibited superior antifouling capabilities compared to random copolymers.
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Polymer chemistry informed neural networks (PCINNs) for data-driven modelling of polymerization processes

Polym. Chem., 2024, 15,4580-4590
DOI: 10.1039/D4PY00995A, Paper
Nicholas Ballard, Jon Larrañaga, Kiarash Farajzadehahary, José M. Asua
A method for training neural networks to predict the outcome of polymerization processes is described that incorporates fundamental chemical knowledge. This permits generation of data-driven predictive models with limited datasets.
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Structure, humidity adaptivity, and elasticity of hydrogen-bonded complexes formed by self-assembly of a triblock copolymer and a homopolymer

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00959B, Paper
Weijie Wang, Hanxin Jian, Hao Huang, Fengfeng Feng, Qingye Meng, Yuli Li, Gang Chen, Shuguang Yang
The tri-block copolymer polystyrene-b-poly(ethylene oxide)-b-polystyrene (SES) and the homopolymer poly(acrylic acid) (PAA) were applied to fabricate elastomers with multi-hierarchical architectures.
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Evaluation of Alkyl Chain Length and Photocatalytic Antibacterial Performance of Cation g-C3N4

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01118J, Paper
Junling Leng, Xuanwei Liu, Yin Xu, shien zhu, Yuefei Zhang, Zhongbing Tan, Xiaofei Yang, Jia-En Jin, YuFeng Shi, Fan Hongying, Yi Yang, Hang Yao, Yu Zhang, Hui Chong, Chengyin Wang
Several cation graphite carbon nitrides (g-C3N4-(CH2)n-ImI+) were synthesized by chemically attaching imidazolium appended alkane chains with different lengths (n = 2, 4, 8, 12 and 16) to g-C3N4. Introduction of...
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Enzymatic self-assembly of short peptides for cell spheroid formation

J. Mater. Chem. B, 2024, 12,11210-11217
DOI: 10.1039/D4TB01154F, Paper
Open Access
Jiaqi Guo, Weiyi Tan, Bing Xu
Biphenyl-capped phosphopeptides instruct cell aggregation into spheroids, with minimal effective concentrations below 10 μM. Key factors driving morphogenesis include the self-assembly ability and dynamic shapeshifting of the peptide assemblies.
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Improving the sulfite-detection performance of a fluorescent probe via post-synthetic modification with a metal–organic framework

J. Mater. Chem. B, 2024, 12,11251-11258
DOI: 10.1039/D4TB01754D, Paper
Jing-Yi Shi, Bin Wang, Xin-Yue Cui, Xiao-Wei Hu, Hai-Liang Zhu, Yu-Shun Yang
In this work, a post-synthetic modification strategy was attempted to improve the performance of the probe for sulfite detection.
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An innovative electrohydrodynamics-driven SERS platform for molecular stratification and treatment monitoring of lung cancer

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01434K, Highlight
Tuotuo Zhang, Biao Dong, Huiling Wang, Shuai Zhang
A schematic electrohydrodynamics-driven SERS platform to profile four proteins on sEVs to generate a unique molecular signature for lung cancer stratification.
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Effect of supramolecular peptide hydrogel scaffold charge on HepG2 viability and spheroid formation

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01701C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yu Xin, Cosimo Ligorio, Marie O’brien, Richard Collins, Siyuan Dong, Aline F. Miller, Alberto Saiani, Julie E. Gough
Understanding how fibre charge in self-assembling peptide hydrogel networks affect HepG2 cell fate and spheroid formation.
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MnO2-mineralized milk exosomes as a novel nanoplatform for glutathione detection

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01662A, Paper
Xudong Wang, Xue Wu, Jiuheng Shen, Xian Zhao, Peifen Gao, Wantong Zhou, Wenlin An
This study introduces a novel nanoplatform by surface manganese dioxide (MnO2) mineralization of milk exosomes and labelling with curcumin, enhancing their utility in the detection of GSH.
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Platform for empowering girls

Providence College, Coonoor, is enabling girls from the weaker sections to pursue job-oriented courses and live their dreams.




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Three apps to transform your pictures into artworks




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A transformative experience

PARAS ARORA’S internship at Teach for India helped him become an activist.




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How discovery platforms are boosting women-run enterprises

Pandemic has hit women entrepreneurs badly — but help is at hand




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A cerium-doped tungsten trioxide-functionalized sensing platform for photoelectrochemical detection of ascorbic acid with high sensitivity

Analyst, 2024, 149,5206-5212
DOI: 10.1039/D4AN01165A, Paper
Xueying Zhu, Tikai Liang, Dianping Tang
A highly efficient photoelectrochemical (PEC) strategy was proposed for the determination of ascorbic acid (AA).
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A nano-biosensing platform based on CuS-BSA for label-free fluorescence detection of Escherichia coli

Analyst, 2024, 149,5394-5400
DOI: 10.1039/D4AN01060D, Paper
Xiaoqing Zhang, Shanglin Li, Mei Liu
A fluorescence biosensing strategy was developed based on CuS-BSA for sensitive and rapid detection of Escherichia coli.
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The efficient triplet states formation of Se-modified PDI dimers and tetramers in solvents

Phys. Chem. Chem. Phys., 2024, 26,27325-27331
DOI: 10.1039/D4CP00954A, Paper
Feijun Huang, Wenli Su, Yubo Yang, Hang Wang, Zhishan Bo, Pengfei Jing, Wenkai Zhang
The Se-modified PDI oligomers experience triplet states formation in the solvents, but there are differences in the efficiency of triplet state generation due to variations in molecular structure.
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Spintronic performance of bent zigzag phosphorene nanoribbons: effects of mechanical deformation and gate voltage

Phys. Chem. Chem. Phys., 2024, 26,27363-27370
DOI: 10.1039/D4CP03470H, Paper
Rouhollah Farghadan
This study explores how bending and gate voltage tune the spintronic properties of zigzag phosphorene nanoribbons (ZPNRs) for advanced applications.
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Oxidation of fine aluminum particles: thermally induced transformations in particle shells and kinetics of oxide nucleation

Phys. Chem. Chem. Phys., 2024, 26,27602-27616
DOI: 10.1039/D4CP03355H, Paper
Andrey V. Korshunov
A submicron aluminum particle during oxidation is a shrinking spherical segment due to the growth of a single γ-Al2O3 nucleus.
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Experimental and theoretical study of the Sn–O bond formation between atomic tin and molecular oxygen

Phys. Chem. Chem. Phys., 2024, 26,27763-27771
DOI: 10.1039/D4CP03687E, Paper
Iakov A. Medvedkov, Anatoliy A. Nikolayev, Shane J. Goettl, Zhenghai Yang, Alexander M. Mebel, Ralf I. Kaiser
In this article, we combine state-of-art electronic structure calculations and crossed beam experiments to expose the reaction dynamics of 120Sn(3Pj) + 16O2(X3Σg) → 120Sn16O(X1Σ+) + 16O(3P) reaction that involve extensive ISC.
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Simulated conformality of atomic layer deposition in lateral channels: the impact of the Knudsen number on the saturation profile characteristics

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP00131A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Gonsalves, Jorge A. Velasco, Jihong Yim, Jänis Järvilehto, Ville Vuorinen, Riikka L. Puurunen
Systematic analysis of saturation profile characteristics allowed development of an extended slope method that relates the slope of the adsorption front to the sticking coefficient for any Knudsen number.
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Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum

Phys. Chem. Chem. Phys., 2024, 26,27669-27676
DOI: 10.1039/D4CP03506B, Paper
Ching-Hua Chang, Wen Chao, Cheng-Han Tsai, Mitchio Okumura, Frank A. F. Winiberg, Yasuki Endo
Pure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.
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Experimental and simulation study of reverse micelles formed by aerosol-OT and water in non-polar solvents

Phys. Chem. Chem. Phys., 2024, 26,27772-27782
DOI: 10.1039/D4CP03389B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angie Mat'usová, Georgina Moody, Peter J. Dowding, Julian Eastoe, Philip J. Camp
Small-angle neutron scattering and molecular dynamics simulations are used to characterise aerosol-OT reverse micelles. Simulations capture spontaneous self-assembly, compare favourably with experiments, and give microscopic information.
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Performance of functionalized graphene oxide with organic radical scavengers in proton exchange membranes

Phys. Chem. Chem. Phys., 2024, 26,27817-27828
DOI: 10.1039/D4CP03151B, Paper
Yu Hu, Jiaxing Wang, Shuai Wang, Yuan Feng
A diazonium salt reaction is used to prepare benzoic acid-functionalized graphene oxide as a bi-functional filler for a Nafion membrane, and the corresponding composite membrane has improved chemical durability and proton conductivity.
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Effects of oxide platforms on the dynamics and reduction characteristics of hydrogen spillover

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03093A, Paper
Kazuki Shun, Akihito Fujimoto, Kohsuke Mori, Hiromi Yamashita
The interparticle hydrogen spillover can be facilitated over TiO2 and WO3 as a consequence of the interfacial diffusion of H+ and e pairs, while the e diffusion coupled with H+ is inhibited on MgO and CeO2.
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Ballistic transport in sub-10 nm monolayer InAs transistors for high-performance applications

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03789H, Paper
Tianruo Xie, Yuliang Mao
The modelling of double gate MOSFETs of monolayer InAsH2 is shown in (a). The corresponding transfer characteristics are shown for (b) n-type and (c) p-type, in which various doping concentrations are chosen.
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A Comprehensive Guide for Accurate Conformational Energies of Microsolvated Li+ Clusters with Organic Carbonates

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03487B, Paper
Arseniy A. Otlyotov, Andrey Moshchenkov, Timofey P. Rozov, Anna A. Tuma, Alexander S. Ryzhako, Yury Minenkov
Organic carbonates and their mixtures are frequently used in electrolyte solutions in lithium-ion batteries. Rationalization and tuning of the related Li+ solvation processes are rooted in the proper identification of...
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Simulation study of the conformation and dynamics of substrate-supported ring and linear polymer films

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02794A, Paper
Jianhua Huang, Hongzhu Ji, Jin Zhang, Zhunpeng Wang
Ring polymers in substrate-supported films exhibit stronger adsorbability, less deformation, and similar dynamics suppression compared to linear polymers.
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Annealing approach to form a nanotube from graphdiyne ribbon: A theoretical prediction

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03573A, Paper
Bo Song, Kun Cai, Jiao Shi, Qinghua Qin
A precisely controllable heat treatment process is critical for nanofabrication. We developed a two-step method to fabricate a graphdiyne nanotube (GNT) through heat treatment in an argon environment. Initially, we...
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A composite of pineapple leaf-derived porous carbon integrated with ZnCo-MOF for high-performance supercapacitors

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02882A, Paper
Xiaoxiao Ma, Yunfan Bai, Shuangli Chen, Zhixian He, Pingping Wu, Yabing Qi, Sijing Zhang
Pineapple leaf-derived biochar (PLB) served as a carrier for ZnCo-MOF in the preparation of ZnCo-MOF@PLB-800. The porous structure of PLB reduced ZnCo-MOF aggregation, enhancing electron transfer and the conductivity of the electrode material.
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Anna Samuel’s hyper reality cakes come in the form of biryanis and kappa-meen curry

Anna’s cakes are customised to suit client’s tastes and each is a piece of edible art




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Chennai | Memories and mothers are the centre of this exhibition-performance by Nimi Ravindran

Nimi Ravindran decides to open her Pandora’s box to mediate on memories and mothers at this exhibition-performance 




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Unlocking the potential of metal ligand cooperation for enantioselective transformations

Chem. Soc. Rev., 2024, 53,3216-3223
DOI: 10.1039/D3CS00998J, Viewpoint
Open Access
Tizian-Frank Ramspoth, Johanan Kootstra, Syuzanna R. Harutyunyan
Metal–ligand cooperation, (MLC) is a versatile catalysis concept. Herein, we discuss the historical context, mechanisms, and applications, suggesting exploring MLC for enantioselective transformations beyond (de)hydrogenative processes.
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Towards high performance and durable soft tactile actuators

Chem. Soc. Rev., 2024, 53,3485-3535
DOI: 10.1039/D3CS01017A, Review Article
Open Access
Matthew Wei Ming Tan, Hui Wang, Dace Gao, Peiwen Huang, Pooi See Lee
This review assesses diverse strategies to enhance the actuation performance and durability of soft tactile actuators, enabling optimal functionality in real-world conditions.
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Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01050C, Review Article
Qiaoqiao Zhang, Yong Wang, Pierre Braunstein, Jian-Ping Lang
Olefinic coordination polymers were used as universal single crystal platforms for precise organic synthesis, in situ mechanism exploration and photochemical applications.
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Routes to high-performance layered oxide cathodes for sodium-ion batteries

Chem. Soc. Rev., 2024, 53,4230-4301
DOI: 10.1039/D3CS00929G, Review Article
Jingqiang Wang, Yan-Fang Zhu, Yu Su, Jun-Xu Guo, Shuangqiang Chen, Hua-Kun Liu, Shi-Xue Dou, Shu-Lei Chou, Yao Xiao
Various optimization strategies are reviewed and summarized to formulate design principles for layered oxide cathodes for sodium-ion batteries.
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Formula 4 night street car race | Madras High Court waves green flag

Justices R. Mahadevan and Mohammed Shaffiq refrain from stalling the conduct of the race, they permit TN government to conduct the race with certain conditions




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Bull runs, a Mercedes farewell tour, driver churn: Formula One storylines to keep an eye on

Racing fans will have to wait until next year to savour the tasty prospect of Lewis Hamilton turning out for Ferrari, but that doesn’t mean 2024 is merely the lull before the storm