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Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00171K, Research Article
Li-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei Wu
A method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.
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Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00265B, Research Article
Shuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping Hui
An efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.
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Spiro-centre substitution effects in the intramolecular spin–spin interactions of spirobiacridine diradicals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00419A, Research Article
Open Access
Shinichi Ogawa, Takuya Kanetomo, Masaya Enomoto
Spirodiradicals with the Si and Ge spiro atoms exhibit a S = 1 state. The magnetic interaction in the Si derivative was found to be lower than that in the Ge derivative, implying a negative effect on σ*(Si–Cα)–π* hyperconjugation.
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Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00552J, Research Article
Open Access
Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier Bourissou
Cycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...
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Iridium-catalyzed asymmetric hydrogenation of 5-hydroxypicolinate pyridinium salts under batch and flow: stereodefined access to cis-configurated hydroxypiperidine esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00322E, Research Article
Zhi Yang, Shangxian Luan, Linxi Wan, Jingxi Chen, Xiaofang Wei, Pei Tang, Fen-Er Chen
An iridium-catalyzed asymmetric hydrogenation of 2-esteryl-5-hydroxypyridinium salts is reported, providing chiral cis-5-hydroxypiperidine-2-carboxylates in excellent yields with high levels of enantioselectivities and diastereoselectivities.
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A self-adsorption molecule passivated interface enables efficient and stable lithium metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02903H, Paper
Gongxun Lu, Xinru Wu, Miaofei Huang, Mengtian Zhang, Zhihong Piao, Xiongwei Zhong, Chuang Li, Yanze Song, Chengshuai Chang, Kuang Yu, Guangmin Zhou
Self-adsorbing molecules stabilize electrode interfaces and inhibit solvent decomposition to ensure high-voltage stability of lithium metal batteries.
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Efficient Fully Textured Perovskite Silicon Tandems with Thermally Evaporated Hole Transporting Materials

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03899A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bhushan Kore, Oussama Er-raji, Oliver Fischer, Adrian Callies, Oliver Schultz-Wittmann, Patricia Samia Cerian Schulze, Martin Bivour, Stefaan De Wolf, Stefan W Glunz, Juliane Borchert
Fully textured perovskite silicon tandem solar cells effectively minimize the reflection losses and are compatible with industrial silicon production lines. To facilitate scalability and industrial deployment of perovskite silicon tandems...
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E.P. Jayarajan’s ‘autobiography’ row: publishing house remains tight lipped, refuses to clear the air

Jayarajan claims that circulating excerpts from his ‘autobiography’ are baseless nonsense and asserts that he had not granted publishing rights for his autobiography to any establishment




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‘Sea ranching’ launched off Thiruvananthapuram as follow-up to artificial reef project

Minister of State for Fisheries George Kurian launches project; 10 lakh pompano, cobia fingerlings to be deposited in 10 selected locations




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PDA will defeat BJP in bypolls, says Akhilesh

Welcoming the Supreme Court’s direction on bulldozer ‘justice’, the SP chief says from now onwards, the bulldozer will remain parked in garage forever




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MRPL honoured for excellence in AI-driven process efficiency

The award was presented at the 27th Energy Technology Meet in Bengaluru.




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Coast Guard Chief S Paramesh calls on India's High Commissioner to Sri Lanka, discusses maritime security




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Government efficiency 'czar' Musk to cut a lot of waste in US govt: Mark Mobius




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‘Unfortunate that Congress failed to rein in its rebel candidates…effect could be felt in 7-8 seats’: NCP leader Jayant Patil




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Non-equilibrium defect chemistry in oxygen-rich zinc oxide nano-tetrapods synthesized using atmospheric pressure microplasma

J. Mater. Chem. A, 2024, 12,9212-9231
DOI: 10.1039/D3TA06821H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dilli babu Padmanaban, Paul Maguire, Davide Mariotti
We demonstrate the synthesis of zinc oxide (ZnO) nanoscale tetrapods (nTPs) using an atmospheric pressure microplasma with a metal wire as a sacrificial electrode.
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Crystal reconstruction and defect healing enabled high-quality Sb2Se3 films for solar cell applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00734D, Paper
Qi Zhao, Bo Che, Haolin Wang, Xiaoqi Peng, Junjie Yang, Rongfeng Tang, Changfei Zhu, Tao Chen
A post-sulfurization technique has been developed to refine Sb2Se3 crystallization. This process enables high-quality Sb2Se3 with a smooth surface, large compact crystal grains and benign [hkl] growth orientation. It also mitigates the device VOC deficit, owing to the healed deep level defects.
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Porous carbon nitride rods as an efficient photoanode for water splitting and benzylamine oxidation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00237G, Paper
Sanjit Mondal, Gabriel Mark, Ayelet Tashakory, Michael Volokh, Menny Shalom
A polymeric carbon nitride layer with controlled directionality, morphology, and nitrogen defects serves as a photoanode to allow photoelectrochemical (PEC) water-splitting and benzylamine oxidation.
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Correction: Superhydrophobic and mechanical properties enhanced the electrospinning film with a multiscale micro-nano structure for high-efficiency radiation cooling

J. Mater. Chem. A, 2024, 12,9241-9241
DOI: 10.1039/D4TA90062F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijing Kong, Puqing Sun, Jincheng Liu, Yongxing Lin, Chao Xiao, Chao Bao, Kang Zheng, Meng Xue, Xian Zhang, Xianglan Liu, Xingyou Tian
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Prolonging exciton diffusion length via manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells over 19% efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00594E, Paper
Wang Ke, Fuwen Zhao, Yufan Zhu, Yi He, Zesheng Liu, Xiao Han, Qi Ai, Xingxing Shen, Bao Li, Jianqi Zhang, Yuze Lin, Chun-Ru Wang, Dan He
The limited exciton diffusion length (LD) of organic semiconductors constraints exciton dissociation in pseudo-planar heterojunction (PPHJ) organic solar cells (OSCs), which is deemed as the bottleneck issue hampering the further...
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Aggregation between oligomeric Ir photosensitizers promote efficient and long-lifetime photocatalytic hydrogen evolution

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07365C, Paper
Yifan Huang, Shihan Liu, Bo Wang, Ying Wang, Yifan Zhang, Pengyang Deng
In this paper, the aggregation effect between oligomeric Ir photosensitizers on photocatalytic hydrogen evolution was first discovered and investigated. Four oligomeric Ir photosensitizers were synthesized by copolymerization of [Ir(ppy)2(dabpy)](PF6) (H1)...
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Rapid in situ growth of high-entropy oxide nanoparticles with reversible spinel structures for efficient Li storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA08101J, Paper
Open Access
Siyu Zhu, Wei Nong, Lim Jun Ji Nicholas, Xun Cao, Peilin Zhang, Yu Lu, Mingzhen Xiu, Kang Huang, Gang Wu, Shuo-Wang Yang, Junsheng Wu, Zheng Liu, Madhavi Srinivasan, Kedar Hippalgaonkar, Yizhong Huang
Using laser radiation, high-entropy nanoparticles were rapidly fabricated on conductive carbon. The high-entropy nanomaterials with reversible spinel structures exhibit better cycling and rate performances in LIBs.
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From scrap metal to highly efficient electrodes: harnessing the nanotextured surface of swarf for effective utilisation of Pt and Co for hydrogen production

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00711E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Madasamy Thangamuthu, Emerson C. Kohlrausch, Ming Li, Alistair Speidel, Adam T. Clare, Richard Plummer, Paul Geary, James W. Murray, Andrei N. Khlobystov, Jesum Alves Fernandes
Atomically deposited Pt and Co on nano-grooves result in active and stable electrocatalysts for hydrogen evolution and oxygen evolution reactions.
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Oxygen vacancy-induced efficient hydrogen spillover in Ni17W3/WO3−x/MoO3−x for a superior pH-universal hydrogen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00729H, Paper
Open Access
Yiqing Sun, Yiwei Bao, Di Yin, Xiuming Bu, Yuxuan Zhang, Kaihang Yue, Xiaoshuang Qi, Ziyan Cai, Yongqiang Li, Xiulan Hu, Johnny C. Ho, Xianying Wang
By regulating the oxygen vacancy in the WO3−x/MoO3−x support synergistically, the active phase transition can be accomplished at low voltage, resulting in fast intermediate hydrogen uptake/transfer/desorption kinetics on the prepared catalyst surface and interface.
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Engineering electronic band structure of ternary thermoelectric nanocatalysts for highly efficient detection of hydrogen sulfide

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00438H, Paper
Hongyuan Shang, Xiaofei Zhang, Aiping Zhang, Jinwen Du, Ruiping Zhang
This study rationally designs a ternary thermoelectric nanocatalyst PtTeCu nanorod for the accurate detection of hydrogen sulfide in biomedical applications.
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Atomically Dispersed Ru Sites on MOF-derived NC-ZnO for Efficient Oxygen Evolution Reaction in Acid Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00586D, Paper
Sagar Varangane, Ragunath Madhu, Saad Mehmood, Bhavya Jaksani, Vidha Bhasin, Moses Abraham Abraham Bokinala, Ammavasi Nagaraj, Chandra Shobha Vennapoosa, Venkata Subba Reddy Basireddy, Subrata Kundu, Ujjwal Pal
Developing acid-stable oxygen evolution/reduction reaction (OER/ORR) electrocatalysts is essential for high-performance water splitting. Still, the slow kinetics of the ORR and OER during the discharge and charge processes seriously impede...
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Metal–support interaction triggered d–p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper
Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe2O3 catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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Achieving giant energy density/efficiency in light-metal-element-rich relaxor ferroelectric ceramic by annihilating the volatile Schottky defects

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00867G, Paper
Kunjie Lou, Yizheng Bao, Jun Chai, Jiyue Wu, Yanshuang Hao, Shaozheng Zhang, Genshui Wang
With the rapid growth of energy storage capacitors in advanced power systems, the pursuit of lightweight is gradually important despite the urgent need for device miniaturization. To reduce the weight...
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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Modulation of active metal species in MOF-derived catalysts for Efficient NO reduction by CO

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01075B, Paper
Ning-Rui Zhou, Zhen Yang, Ying Tang, Ming-Qi Zhang, Yun-Peng Zha, Min-Min Liu, Feng Yu, Jiang Liu
Transition metal oxides are usually used as one of the most excellent catalysts for NO selective catalytic reduction by CO (CO-SCR), but their catalytic activity is limited by the content...
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Multifunctional buried interface modification for efficient and stable SnO2-based perovskite solar cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00108G, Paper
Rui Wu, Junhua Meng, Yiming Shi, Zhengchang Xia, Chunxia Yan, Lisheng Zhang, Wenkang Liu, Jinliang Zhao, JinXiang Deng, Xing Wang Zhang
Buried interface modification with multiple roles is key to boost the performance of perovskite solar cells (PSCs). Herein, a multifunctional passivator, N-(2-hydroxyethyl) ethylene diamine triacetic acid trisodium salt (HEDTA-3Na), is...
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Efficient photocatalytic hydrogen evolution based on Z-scheme 2D OV-LaVO4/Mo-doped SV-ZnIn2S4 heterojunctions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00754A, Paper
Wei Guan, Lin Zhang, Peng Wang, Ying Wang, Haoyu Wang, Xingchen Dong, Liyan Yu, Zhixing Gan, Lifeng Dong, Lina Sui
The purposeful design and construction of two-dimensional (2D) semiconductor heterojunctions offers a promising avenue for achieving efficient photocatalytic activity. However, the challenge of enabling efficient charge migration at the interface...
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Highly stable photovoltaic effects in A2+–Zr4+ (A = Ca, Sr, Ba) co-doped BiFeO3 films with self-polarization

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00649F, Paper
Lei Shi, Wenyue Zhao, Zhao Wang, Wenjing Hua, Xiaoxia Yang, Weidong Fei, Yu Zhao
The photovoltaic responses and temperature stabilities of A2+–Zr4+ (A = Ca, Sr, Ba) composite doped BiFeO3 films with self-polarization were enhanced in the R to MA phase transition.
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NiFeCo–OH/NiTe nanoarrays with amorphous/crystalline interfaces for highly efficient oxygen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00772G, Paper
Jing Liu, Da Liu, Xiaoxiao Yan, Peifang Guo, Hongbin Xu, Peng Chen, Renbing Wu
One-dimensional heterostructured NiFeCo–OH/NiTe nanorod arrays with amorphous/crystalline interfaces have been rationally synthesized, exhibiting an excellent OER electrocatalytic performance.
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Configuration-entropy effects on BiFeO3–BaTiO3 relaxor ferroelectric ceramics for high-density energy storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00921E, Paper
Open Access
Rhys Montecillo, Cheng-Sao Chen, Kuei-Chih Feng, R. R. Chien, Pin-Yi Chen, Chi-Shun Tu
A high-configuration entropy results in the formation of grain boundaries and nanoclusters, which act as barriers for enhancing breakdown strength and energy-storage capability.
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Enhancing CO2 gasification-reforming of municipal solid waste with Ni/CeO2 and Ni/ZrO2 catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00665H, Paper
Shiyu Zhang, Yibing Peng, Mengna Wu, Qinghai Li, Yanguo Zhang, Hui Zhou
CO2 gasification-reforming facilitates CO2 utilization and yields CO-rich syngas for municipal waste management. Catalysts are essential for enhancing syngas production via catalytic tar reforming.
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Constructing vacancy-rich metal phosphates by the spatial effect of ionic oligomers for enhanced OER activity

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01706D, Paper
Yida Zhao, Xinyu He, Xiaoming Ma, Zhengxi Guo, Menghui Qi, Zhaoming Liu, Ruikang Tang
By rationally selecting ionic oligomers as building blocks, sub-nano-sized gaps can be constructed in the solid structure of catalysts. This can overcome the inherent limitations associated with vacancy formation of the traditional nucleation pathway.
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Harvesting solar energy with a Ni-MOF-based evaporator for efficient solar thermal storage and steam generation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00203B, Paper
You Xu, Zhengyun Wang, Xianbao Wang, Zhenzhen Guo, Muhammad Sultan Irshad, Naila Arshad, Jiang Gong, Hongfang Liu, Guangfang Li
A hybrid solar evaporator comprising a Ni-based metal–organic framework material and a phase change material composite was fabricated for high performance solar-thermal energy storage and continuous solar vapor generation.
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Efficient first principles based modeling via machine learning: from simple representations to high entropy materials

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00982G, Paper
Kangming Li, Kamal Choudhary, Brian DeCost, Michael Greenwood, Jason Hattrick-Simpers
Generalization performance of machine learning models: (upper panel) generalization from small ordered to large disordered structures (SQS); (lower panel) generalization from low-order to high-order systems.
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Giant Magnetocaloric Effect in Fe doped Rare earth Orthochromite GdCr0.5Fe0.5O3

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03873H, Paper
Abinash Prusty, Sudipta Mahana, B. Sheetal Priyadarshini, Andrei Gloskovskii, Dinesh Topwal, Unnikrishnan Manju
In this manuscript we present the magnetic and magnetocaloric property investigations of Fe doped orthochromite system GdCr0.5Fe0.5O3, along with the structural, electronic and thermal properties. Manifestations of orbital mediated electron-phonon...
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Beneficiaries receive ₹22.15 lakh in loans from TAMCO for minority welfare




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'Any relief on bank guarantee will be provided across the sector': Scindia on Vodafone Idea request for waiver of bank guarantees for spectrum




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An Efficient All-Visible Light-Activated Photoswitches Based on Diarylethenes and CdS Quantum Dots

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06110A, Edge Article
Open Access
Kezhou Chen, Jiayi Liu, Joakim Andréasson, Bo Albinsson, Tiegen Liu, Lili Hou
All-visible light-activated diarylethene (DAE) photoswitches are highly attractive for applications in smart photoresponsive materials. Photocyclization of DAE via the low-lying excited triplet state through triplet energy transfer (TET) from a...
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Gaining the Molecular Design Principles for Efficient Diarylethene Photoacid and Photohydride Generators Based on Photochemical Reaction Mechanism

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06202G, Edge Article
Open Access
Yifan Su, Dexin Zheng, Lingfeng Ge, Le Yu, David Lee Phillips, Jiani Ma, Yu Fang
Abstract: Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile protecting groups that release acid and hydride, respectively. Over the past decade, great efforts have been devoted to developing...
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Defence Space Agency hosts first ever space exercise 'Antariksha Abhyas - 2024' in Delhi




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Rajnath Singh stresses on adaptive defence to cope with Age of Grey Zone, hybrid warfare




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Union Education Minister Dharmendra Pradhan urges states to support exam reforms for zero-error entrance test




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Akashteer: Transforming India's air defence with cutting-edge technology




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Indonesia and Australia hold joint military drills after signing a new defense agreement

The Indonesian and Australian militaries are holding joint combat drills off Indonesia’s main island of Java with about 2,000 troops training in air, maritime, amphibious and land operations