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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




with

[ASAP] Reactivity of [Ce(NR<sub>2</sub>)<sub>3</sub>] (R = SiMe<sub>3</sub>) with Prospective Carbon Atom Transfer Reagents

Organometallics
DOI: 10.1021/acs.organomet.0c00186




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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




with

The One with Marc

In our first episode of 2014 I am joined by new guest co-host Marc Roberts of Neutron Creations. After a lengthy chat about his rather special coat we moved onto more web related links and finished up with a discussion on node.js. Big thanks for Marc for taking the time to come on the show.




with

Live with a Flat White

This week Kieran joins us live via a pair of Apple headphones from Coffee #1. Complete with baristas creating flat whites and the chitter chatter of remote workers typing away we throw audio fidelity to the wind and freestyle over a few links from Keir’s web site.




with

Lost with Lindberg

This week we celebrate the internet’s very own Oliver Lindberg as we get #lostwithlindberg. Given our distinct lack of direction for this episode, it seemed only right and proper that our favourite editor of the internet takes this week’s naming rights. If you are ever lost, and if you can find him, maybe you can also get “lost with Lindberg”. Cue the music.

We might not be a crack commando unit but we did our best to highlight a few choice topics from the internet underground. In this week’s show, we speak out in favour of the new Instagram logo, welcome the Lord of the .io domain to the UK’s most hipster city, discuss a big man with a new big book, see the sunset on sunrise, and finally get all excited about our new startup!




with

Back Stories with Marc Thiele

Welcome to Back Stories — a new series of one on one interviews hosted by Keir Whitaker (one-half of the team behind The Back to Front Show).

Each episode, unlike the usual show, will come in at 30 minutes and will attempt to delve into the interesting lives of people working in the web, design, tech, publishing, and creative industries.

In this first episode, Keir chats with Marc Thiele — long-time friend and the man behind the Beyond Tellerrand series of web conferences. There’s plenty of ground covered including the early 8 bit days, Flash, events, and more.

Marc Online




with

Back Stories with Craig Lockwood

Welcome to the second episode of Back Stories — a new series of one on one interviews hosted by Keir Whitaker (one-half of the team behind The Back to Front Show).

In this episode, Keir is joined by Craig Lockwood — long time friend of the show and the man behind endeavours including software, events, co-working spaces, and more. In this very open and honest account of his work and life, Craig shares his experiences of working in the web and tech industry.

Craig Online




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Back Stories with Kurt Elster

In this episode of Back Stories, Keir chats with Kurt Elster — founder of ecommerce agency Ethercycle, host of the popular Ecommerce Hacks Weekly video series, author of Ecommerce Bootcamp, and the host of The Unofficial Shopify Podcast.

Topics include the benefits of the “peacock” jacket, naming your company, specialisation, automating inbound leads, productised consulting, and much more.

Kurt Online




with

Back Stories with Oliver Lindberg

In this episode of Back Stories, Keir chats with Oliver Lindberg— founder of the new Pixel Pioneers web conference series and all round content guru. Topics covered include how to find speakers for your conference, the role of a good editor, how to improve your writing skills, and how to pitch to an editor.

Oliver Online




with

'Pvt hosp staff at par with govt medical staff'




with

Migrant workers clash with police in Surat

Demanding a return passage to their home states, hundreds of agitated migrant workers clashed with the police at Mora village in Gujarat's Surat district on Saturday, an official said.




with

Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




with

Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
The content of this RSS Feed (c) The Royal Society of Chemistry




with

Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Direct C(sp3)–H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI

Green Chem., 2020, 22,2354-2358
DOI: 10.1039/C9GC04446A, Communication
Yong-Long Zhao, Yong-Qin Tang, Xing-Hai Fei, Fen-Fen Yang, Zhuo-Xian Cao, Dong-Zhu Duan, Qing-Jie Zhao, Yuan-Yong Yang, Meng Zhou, Bin He
The first KI-catalyzed direct acyloxylation of indolin-3-ones with carboxylic acids has been developed using 30% aq. H2O2 as a green oxidant at room temperature. Moreover, mechanism studies indicated that a radical oxidation process may be involved for this transformation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of bioderived polycarbonates with adjustable molecular weights catalyzed by phenolic-derived ionic liquids

Green Chem., 2020, 22,2488-2497
DOI: 10.1039/D0GC00493F, Paper
Wei Qian, Lei Liu, Zengliang Zhang, Qian Su, Weizhen Zhao, Weiguo Cheng, Li Dong, Zifeng Yang, Ruibing Bai, Fei Xu, Yanqiang Zhang, Suojiang Zhang
Phenolic ionic liquid structure can be designed readily to control the molecular weight of isosorbide-derived polycarbonates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




with

Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainable remediation with an electroactive biochar system: mechanisms and perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00717J, Critical Review
Zhonghao Wan, Yuqing Sun, Daniel C. W. Tsang, Deyi Hou, Xinde Cao, Shicheng Zhang, Bin Gao, Yong Sik Ok
Biochar-based carbocatalysis is synergized from electroactive components including reactive-active moieties, metals, defective sites, heteroatoms, and graphitic structure for sustainable remediation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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One-step catalytic amination of naphthalene to naphthylamine with exceptional yield

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00633E, Communication
Fang Hao, Xin Wang, Linfang Huang, Wei Xiong, Pingle Liu, Hean Luo
This is the first time to synthesize naphthylamine from one-step naphthalene amination by vanadium catalysts with high yield under mild condition. It could obtain ∼70% yield of naphthylamine, with major product of valuable 1,5-diaminonaphthalene.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper–iron oxide|TiO2-cobaloxime photocathode

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00979B, Paper
C. Tapia, E. Bellet-Amalric, D. Aldakov, F. Boudoire, K. Sivula, L. Cagnon, V. Artero
H2 is an environmentally-friendly fuel that would allow for a circular economy but its sustainable production from solar energy and water using stable, efficient and scalable Earth-abundant materials, remains a challenge.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




with

Sulfonic acid modified hollow polymer nanospheres with tunable wall-thickness for improving biodiesel synthesis efficiency

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00905A, Paper
Wenliang Song, Yu Zhang, Anuraj Varyambath, Ji Su Kim, Il Kim
Precisely designing the morphology and size of nanostructures is vital in green chemistry as various advanced applications depend upon the shapes and dimensions of the functionalised materials. Herein, we report...
The content of this RSS Feed (c) The Royal Society of Chemistry




with

A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01142H, Communication
Noémie Emmanuel, Pauline Bianchi, Julien Legros, Jean-Christophe M. Monbaliu
Intensified chemical neutralization of a chemical warfare agent simulant CEES with air and light under continuous flow conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




with

Catalytic C–C coupling of diazo compounds with arylboronic acids: using surface modified sewage sludge as catalyst

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00317D, Paper
Zhipeng Zhang, Yang Yu, Yuxing Xie, Timothy Hughes, Jun Xu, Fei Huang, He Huang
A green, mild and efficient synthesis of diarylmethines using sewage sludge-derived carbonaceous materials (SW) by perchloric acid catalyzed coupling reactions between diazo compounds and arylboronic acids was developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile one-pot synthesis of self-assembled nitrogen-doped carbon dots/cellulose nanofibril hydrogel with enhanced fluorescence and mechanical properties

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00845A, Paper
Xueqi Chen, Zihui Song, Shaopeng Li, Nguyen Tat Thang, Xing Gao, Xinchao Gong, Minghui Guo
A facile one-pot method is used to synthesize and self-assemble nanofibril cellulose hydrogels with carbon dots as intensity enhancement and fluorescent emission factors.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




with

Interview: Singing in the Storm With Rain for Roots

The group’s latest album offers a timely message for this global moment.

Is a pandemic the best time or the worst time to release an album of children’s music based on the Psalms? Musicians Flo Paris Oakes, Sandra McCracken, and Katy Bowser Hutson hope that All Creatures, the fourth album from their musical collective Rain for Roots, reaches the world at just the right time and offers hope in the midst of a storm. The album explores the emotional range of Israel’s original songbook and points listeners to God’s glory made manifest in creation.

The three Nashville musicians talked with Megan Fowler about their project, which just released.

The three previous Rain for Roots albums have focused on Bible stories, parables, and Advent. What was the inspiration for All Creatures?

McCracken: We started out talking about Psalms, and then all these images of creation were so present in the themes that were coming up. So we started paying attention to that. A secondary theme that emerged was songs, loosely based on Psalms, but then creation and the creatures that we saw calling us into worship. It’s not strictly a praise album, but a praise album by way of the Psalms, by way of the owls and birds.

Hutson: When you say it that way, Sandra, the two themes that kind of run through are, one, there’s so much of seeing how God reveals who he is in the natural world; and two, yes, there’s so much beautiful praise, but there’s also lament and fear. I like that the Psalms are such a great way to display, to young ones in particular, that all of the range of emotions are okay to bring before the face of God.

Oakes: And that God is with us, not just in this spiritual realm, but in our humanity. God is with us in every bit of the physical world.

Continue reading...




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Interviews with Ybor City residents




with

Legalese with Ease - Legal Terms for Human Resources Professionals

Legalese with Ease – Legal Terms for Human Resources Professionals is the most comprehensive source available for finding clear definitions for over 400 legal terms used within the human resources profession. It is the only book of its kind to offer human resources professionals plain-language information regarding all areas of human resources law.

Today's human resources professionals are required to understand, and keep up-to-date with complex and ever-changing legal definitions and legislative requirements. Legalese with Ease – Legal Terms for Human Resources Professionals provides easy-to-understand definitions, along with practical examples, for all of the most important legal terms in the areas of employment, labour relations, human resources, and occupational health and safety.

Topics covered:

  • Absenteeism
  • Accommodation
  • Accreditation of employer's organization
  • Adoption leave
  • Adverse effects discrimination
  • Advisory council (BC)
  • Affiliated companies/unions
  • Affirmative action
  • Age
  • Assignment employees
  • Averaging agreement
  • Benefits
  • Bereavement leave
  • Burden of proof
  • Certiorari
  • Check off
  • Commission salesperson
  • Common law
  • Control and use in workplace
  • Controlled products
  • Corporation
  • Designated substance
  • Domestic worker
  • Employer duties
  • Employment, labour, and human rights laws
  • Enforcement
  • Ex post facto
  • Homeworker
  • No union choice
  • Occupational health and safety

About the Authors
Malcolm MacKillop, BA, LLB, is the author of a column on employment law in the Globe & Mail: Report on Business, a contributing columnist for HR Professional, and a member of the Editorial Board for Canadian Lawyer Magazine. He has also developed employment law videos with Canada Law Book, is a former lecturer in employment law at the University of Western Ontario, and has appeared in TV news coverages as a human rights specialist.

Adrian Miedema, BMath, LLB, is a senior associate at the Toronto office of Fraser Milner Casgrain LLP and has extensive experience in employment law and civil litigation. He regularly appears in the courts and before various tribunals, on the full range of employment-related matters, and provides strategic employment advice to both public and private sector employers.

If you would like more details about this product, or would like to order a copy online, please click here.




with

2014 Occupational Health and Safety Act with Regulations for Ontario

Bonus Feature
Your purchase includes a FREE eBook!

What's an eBook?
An eBook is a digital version of a conventional printed book. Portable and perfect for your office or home, the eBook is easy to access from wherever your business may take you. Adobe Digital Editions is a highly recommended free download eBook program designed to view and keep your eBooks organized and centralized.


Published: March 2014


Why pay more? Now you can pay less and still get the content you need and can trust!

The 2014 Occupational Health and Safety Act with Regulations for Ontario is a resource that fulfills the provincial requirement for your organization to post the Ontario Occupational Health and Safety Act and includes all applicable regulations. View the Table of Contents

This functional, easy-to-use reference provides you with:

  • A free eBook for easy searching and mobility
  • A handy and informative Workplace Safety Q&A section (exclusive)
  • A helpful index that includes page numbers

BULK DISCOUNTS ARE AVAILABLE. Click here to request a quote. No up-charge for custom print runs over 500 copies. Place your own colour scheme/logo on the cover page.

Topics covered:

  • Confined Spaces
  • Construction Projects
  • Control of Exposure to Biological or Chemical Agents
  • Critical Injury — Defined
  • Designated Substance — Asbestos on Construction Projects and in Buildings and Repair Operations
  • Designated Substances
  • Diving and Farming Operations
  • Roll-Over Protective Structures
  • Teachers
  • Firefighters — Protective Equipment
  • Health Care and Residential Facilities
  • Industrial Establishments
  • Inventory of Agents or Combinations of Agents
  • Joint Health and Safety Committees — Exemption from Requirements
  • Mines and Mining Plants
  • Needle Safety
  • Occupation

    If you would like more details about this product, or would like to order a copy online, please click here.




with

Antimicrobial resistance in bacteria from livestock and companion animals / editors: Stefan Schwarz, Lina Maria Cavaco, Jianzhong Shen, with Frank Møller Aarestrup




with

Histology : a text and atlas : with correlated cell and molecular biology / Wojciech Pawlina, Michael H. Ross

Ross, Michael H., author




with

Working with serious mental illness : a manual for clinical practice / edited by Catherine Gamble, Geoff Brennan




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Defying the enemy within / Joe Williams

Williams, Joe, 1983- author




with

Nursing adults with long term conditions

Nicol, Jane, author




with

Punjab & Haryana High Court: To stick with Manjunath’s name for CJ or not? SC yet to decide



  • DO NOT USE Punjab and Haryana
  • India

with

After leaders attend rally, JD(U) allies with INLD



  • DO NOT USE Punjab and Haryana
  • India

with

Sidhu: Ready to talk with Badal, not his puppets



  • DO NOT USE Punjab and Haryana
  • India

with

Assembly polls: Sushma asks Haryana electors to ‘Vote without fear’



  • DO NOT USE Punjab and Haryana
  • India

with

Punjab withdraws Sidhu’s security



  • DO NOT USE Punjab and Haryana
  • India

with

Congress faction says Bajwa ‘hijacked’ meet with Rahul



  • DO NOT USE Punjab and Haryana
  • India