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Non-biaryl atropisomerism at the C–B bond in sterically hindered aminoarylboranes

Org. Biomol. Chem., 2020, 18,3007-3011
DOI: 10.1039/D0OB00421A, Communication
Mélodie Birepinte, Frédéric Robert, Sandra Pinet, Laurent Chabaud, Mathieu Pucheault
Sterically hindered aminoarylboranes with atropisomerism about the C–B bond were prepared and resolved by chiral stationary phase HPLC.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Experimental results and computational insight into sequential reactions of β-(2-aminophenyl)-α,β-ynones with aryl isocyanates/benzoyl isothiocyanate

Org. Biomol. Chem., 2020, 18,3177-3189
DOI: 10.1039/D0OB00087F, Paper
Antonio Arcadi, Massimiliano Aschi, Marco Chiarini, Fabio Marinelli, Vincenzo Marsicano, Gustavo Portalone
The selective formation of quinazoline vs. benzoxazine  and benzothiazine derivatives from β-(2-aminophenyl)-α,β-ynones and aryl isocyanates/benzoyl isothiocyanate was explored. DFT calculations provide a plausible rationale.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Study on the ArI-catalyzed intramolecular oxy-cyclization of 2-alkenylbenzamides to benzoiminolactones

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00612B, Communication
Huixia Liu, Xiaojun Deng, Xie Huang, Nan Ji, Wei He
A metal-free synthetic method toward the preparation of benzoiminolactones through oxy-cyclization of 2-alkenylbenzamides mediated by a catalyst/oxidant (ArI/mCPBA) system was developed.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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The key entity of a DCAR agonist, phosphatidylinositol mannoside Ac1PIM1: its synthesis and immunomodulatory function

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/C9OB02724F, Communication
Yohei Arai, Shota Torigoe, Takanori Matsumaru, Sho Yamasaki, Yukari Fujimoto
We achieved the first synthesis of phosphatidylinositol mannoside Ac1PIM1, and a very potent agonist of an innate immune receptor DCAR is demonstrated.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Copper(I)/Ganphos catalysis: enantioselective synthesis of diverse spirooxindoles using iminoesters and alkyl substituted methyleneindolinones

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00546K, Paper
Hao Cui, Ke Li, Yue Wang, Manman Song, Congcong Wang, Donghui Wei, Er-Qing Li, Zheng Duan, François Mathey
A copper/Ganphos-catalyzed asymmetric 1,3-dipolar cycloaddition of glycine iminoesters with alkyl substituted 3-methylene-2-oxindoles is described, producing the spiro[pyrrolidin-3,3'-oxindole]s in good yields with high ee.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and photophysical properties of selenopheno[2,3-b]quinoxaline and selenopheno[2,3-b]pyrazine heteroacenes

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00718H, Paper
Amol Sonawane, Atsushi Shimozuma, Taro Udagawa, Masayuki Ninomiya, Mamoru Koketsu
In this paper, we report the novel synthesis of three different heterocycles namely 2-arylselenopheno[2,3-b]quinoxaline, 3-(aryl/alkylselanyl)-2-arylselenopheno[2,3-b]quinoxaline and 6-phenyl-7-(arylselanyl)selenopheno[2,3-b]pyrazine derivatives from the corresponding 2,3-dichloroquinoxaline and 2,3-dichloropyrazine derivatives. Further, photophysical properties were investigated...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Targeting STAT3 anti-apoptosis pathways with organic and hybrid organic–inorganic inhibitors

Org. Biomol. Chem., 2020, 18,3288-3296
DOI: 10.1039/C9OB02682G, Paper
Matthew B. Minus, Haopei Wang, Jaime O. Munoz, Alexandra M. Stevens, Alicia E. Mangubat-Medina, Michael J. Krueger, Wei Liu, Moses M. Kasembeli, Julian C. Cooper, Mikhail I. Kolosov, David J. Tweardy, Michele S. Redell, Zachary T. Ball
Recurrence and drug resistance are major challenges in the treatment of acute myeloid leukemia (AML) that spur efforts to identify new clinical targets and active agents.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthetic pathways to tetrahydrocannabinol (THC): an overview

Org. Biomol. Chem., 2020, 18,3203-3215
DOI: 10.1039/D0OB00464B, Review Article
Open Access
Victor R. L. J. Bloemendal, Jan C. M. van Hest, Floris P. J. T. Rutjes
This review summarises various synthetic pathways leading to tetrahydrocannabinol and structurally related cannabinoids.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of methylene cyclopropane-fused chromenes and dihydroquinolines by sequential [4 + 2]- and [1 + 2]-annulation

Org. Biomol. Chem., 2020, 18,3303-3311
DOI: 10.1039/D0OB00389A, Paper
Tianyu Lu, Xuange Zhang, Zhiwei Miao
A base promoted sequential [4 + 2]- and [1 + 2]-annulation of 2-hydroxychalcones or 2-tosylaminochalcones with prop-2-ynylsulfonium salts was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A domino annulation approach to 3,4-diacylpyrrolo[1,2-a]pyrazines: decoration of pyrazine units

Org. Biomol. Chem., 2020, 18,3324-3333
DOI: 10.1039/D0OB00444H, Paper
Anuradha Dagar, Yohan Seo, Wan Namkung, Ikyon Kim
A new one-pot, sequential three-component access to 3,4-diacylpyrrolo[1,2-a]pyrazine was achieved from the reaction of an α-haloketone, azide, and N-substituted pyrrole-2-carboxaldehyde under mild reaction conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Base-promoted 1,6-conjugate addition of alkylazaarenes to para-quinone methides

Org. Biomol. Chem., 2020, 18,3354-3359
DOI: 10.1039/D0OB00419G, Paper
Amritha Rayaroth, Rajat Kumar Singh, Kalyanakrishnan A. V., Krishna Hari, Alagiri Kaliyamoorthy
1,1,2-Triarylethanes embedded with an azaarene unit were prepared in a single step at ambient temperature via the sodium hexamethyldisilazide mediated 1,6-conjugate addition of unactivated alkylazaarenes on para-quinone methides (p-QMs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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KI/TBHP-promoted [3 + 2] cycloaddition of pyrrolo[1,2-a]quinoxalines and N-arylsulfonylhydrazones

Org. Biomol. Chem., 2020, 18,3360-3366
DOI: 10.1039/D0OB00494D, Paper
Zhen Yang, Jing He, Yueting Wei, Weiwei Li, Ping Liu
A series of diverse fused [1,2,4]triazolo[3,4-c]quinoxalines was obtained by an efficient KI/TBHP-promoted [3 + 2] cycloaddition of pyrrolo[1,2-a]quinoxalines and N-arylsulfonylhydrazones.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chiral bifunctional sulfide-catalyzed asymmetric bromoaminocyclizations

Org. Biomol. Chem., 2020, 18,3367-3373
DOI: 10.1039/D0OB00459F, Paper
Takumi Nakamura, Ken Okuno, Kazuma Kaneko, Masahiro Yamanaka, Seiji Shirakawa
A chiral bifunctional sulfide catalyst bearing a urea moiety promotes the enantioselective bromoaminocyclization of 2-allylanilines to produce optically active 2-substituted indolines.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Gold(III)-catalyzed azide-yne cyclization/O–H insertion cascade reaction for the expeditious construction of 3-alkoxy-4-quinolinone frameworks

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00745E, Paper
Jingjing Huang, Han Su, Ming Bao, Lihua Qiu, Yuanqing Zhang, Xinfang Xu
A gold-catalyzed cascade reaction has been developed, and it provides an expeditious access to 3-alkoxy-4-quinolines and applications in alkaloid synthesis.
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Dienaminodioate based multicomponent reactions with post-benzylic oxidative transformations mediated by DDQ

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00721H, Paper
Jaice Ravindran, Velickakathu Yadhukrishnan, Reghuvaran Asha , Ravi Shankar Lankalapalli
Multicomponent reactions (MCRs) using dienaminodioate with post-benzylic oxidative transformation by DDQ that afforded a diverse array of products is described. An unprecedented rearrangement of 1,2-dihydropyridines (1,2-DHPs), 3CR products, to 2-pyridones...
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Highly modified steroids from Inonotus obliquus

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00474J, Paper
Chun-Xin Zou, Zilin Hou, Ming Bai, Rui Guo, Bin Lin, Xiaobo Wang, Xiaoxiao Huang, Shaojiang Song
Six undescribed steroids were isolated from the fungus Inonotus obliquus. Notably, compounds 1 and 2 represented the first example of 8, 14-seco-4-methylpregnane. By spectroscopic data analyses, quantum chemical calculations and...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Five-year-old survives 40-feet fall with minor scratches

A five-year old boy here survived a 40-feet fall from a multi-storeyed building with minor scratches.




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James K. Wight: a tribute from his students and colleagues: held at the ACI Fall convention, Washington, DC, USA, 26-30 October 2014 / editors: Gustavo J. Parra-Montesinos, Mary Beth D. Hueste

Barker Library - TA439.J36 2016




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Composites with inorganic matrix for repair of concrete and masonry structures: held at the ACI Spring 2017 Convention, Detroit, Michigan, USA, 26-30 March 2017 / editors, Gianmarco de Felice, Lesley H. Sneed, Antonio Nanni

Barker Library - TA439.A57 2017




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Medical Applications of iPS Cells: Innovation in Medical Sciences / editors, Haruhisa Inoue and Yukio Nakamu

Online Resource




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Genomic medicine in emerging economies: genomics for every nation / edited by Catalina Lopez-Correa, George P. Patrinos

Hayden Library - QH447.G4666 2018




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Socially just pedagogies : posthumanist, feminist and materialist perspectives in higher education / edited by Vivienne Bozalek, Rosi Braidotti, Tamara Shefer and Michalinos Zembylas

London ; New York : Bloomsbury Academic, 2018




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Stino Da Napoli Recalls Various Meat Products Produced without Benefit of Inspection

Stino Da Napoli, a Rocky River, Ohio establishment, is recalling approximately 11,392 pounds of various meat products that were produced, packed and distributed without the benefit of federal inspection.




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[ASAP] In Vitro Phase I Metabolic Profiling of the Synthetic Cannabinoids AM-694, 5F-NNEI, FUB-APINACA, MFUBINAC, and AMB-FUBINACA

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00466




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[ASAP] Kinetics Analysis of the Reactions between Peroxynitric Acid and Amino Acids

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00408




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Ancient divination and experience / edited by Lindsay G Driediger-Murphy and Esther Eidinow.

Oxford : Oxford University Press, 2019




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Maria Del Camino: The Flying Car

When Bruce Tomb realized that flying cars weren’t on the imminent horizon, he decided to make his own.




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What Crocs on Treadmills Can Teach Us About Dinosaurs

What crocs on treadmills can teach us about dinosaurs.




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How to Hatch a Dinosaur

Scientists know how to turn a chicken into a dinosaur. What could possibly go wrong?




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Design FX - Walking With Dinosaurs: Muscle Simulation and Feathered Effects Exclusive

Find out how animation company Animal Logic used complex feather and muscle simulation systems to depict the prehistoric animals in Walking With Dinosaurs.




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Gadget Lab - A Look at Suck UK’s 3-D Dinosaur Cookie Cutters

Tykes can construct an edible Jurassic park with these 3-D cookie cutters that create easy-to-assemble dino shapes. Plus, the little ones will get a firsthand lesson in extinction once they devour the after-school treats.




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Design FX - The Amazing Spider-Man 2: Transforming Jamie Foxx into the Villainous Electro

In The Amazing Spider-Man 2, Jamie Foxx stars as Electro, the glowing antagonist to Andrew Garfield’s Spidey. In this video, learn how Sony Pictures Imageworks used a combination of makeup and CGI to turn the Academy Award winner into a blue, electrically-charged villain--with inspiration from lightning, neurological networks, and nebulas.




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Creating Jurassic World’s New Genetically Modified Dinosaur

Legendary paleontologist Jack Horner—the real-life inspiration behind original “Jurassic Park” protagonist Alan Grant—explains how they conceived the genetically modified dino, Indominus rex, in the new film “Jurassic World."




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Would Jurassic World’s New Dinosaur Win in an Epic Showdown?

Who would win in a battle of the dinos? “Jurassic World” consultant and renowned paleontologist Jack Horner gives us his picks, if the new “Jurassic World” dinosaur Indominus rex came face-to-face with a Tyrannosaurus rex and a velociraptor.




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Design FX - Jurassic World: Using Motion-Capture to Create Realistic Dinosaurs

“Jurassic World” debuted with a record-shattering opening weekend, netting nearly half a billion dollars. See how Industrial Light & Magic used motion capture to help design the complex dinosaurs, including the genetically modified Indominus rex.




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Design FX - How “The Good Dinosaur” Raised the Bar for Natural-World CGI

Find out how Pixar raised the CGI bar for ultra-realistic environments and landscapes in “The Good Dinosaur.”




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The Biggest Bro of the Insect Kingdom: The Rhino Beetle

Rhino beetles love to fight and to hump. They use huge scoops on their heads to joust, launching each other off branches to win the right to mate.




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Meet Vinobot, the Rover on a Mission to Help Feed Humanity

If a ballooning humanity wants to feed itself as global warming throws agriculture into disarray, it'll need the help of robots like Vinobot.




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Watch Steve Jobs Pitch the Cupertino City Council on Apple Park

In his last public appearance, Steve Jobs makes his pitch for Apple's new campus at a June 2011 Cupertino City Council meeting.




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Each and Every - Every Dinosaur In 'Jurassic Park' Series Explained

Dr. Nathan Smith, associate curator in the Dinosaur Institute at the Natural History Museum of Los Angeles County, talks about every dinosaur that appears in the Jurassic Park films.




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Obsessed - Meet The Domino Artist Behind These Amazing Chain Reactions

19-year-old Lily Hevesh is obsessed with dominos. She spends hours upon hours building insanely intricate designs and chain reactions before knocking them down. Sound like a strange way to spend your time? Tell that to the nearly 2 million people who've subscribed to her YouTube Channel, where she posts new domino videos every Saturday.




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WIRED Autocomplete Interviews - Winona Ryder & David Harbour Answer the Web's Most Searched Questions

Stranger Things stars Winona Ryder and David Harbour answer the internet's most searched questions about themselves. What is Winona Ryder's real name? Does David Harbour play video games? When did Winona start acting? Is David a nice guy?? The Stranger Things stars answer all these questions and more! Stranger Things season 3 is streaming now on Netflix.




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The High Luminosity Large Hadron Collider : the new machine for illuminating the mysteries of universe / editors, Oliver Brüning and Lucio Rossi (CERN)




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Mathematical thermoelastic methods for physics and engineering : analytical study for thermoelastic responses / Lalsingh Khalsa, Vinod Varghese, Dilip Kamdi

Khalsa, Lalsingh, author




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Mathematical methods for physics / H.W. Wyld (University of Illinois at Urbana-Champaign, Urbana, Illinois)

Wyld, H. W. (Henry William), 1928-




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Sōzein ta phainomena. English

Duhem, Pierre, 1861-1916, author




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El ADN de la formación para directivos [electronic resource] / Camelia Ilie y Ma. José Martín ; prólogo de Isabel Tocino

Ilie, Camelia, author




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The engaged caregiver [electronic resource] : how to build a performance-driven workforce to reduce burnout and transform care / edited by Joseph Cabral, James Merlino, MD, and Martin Wright




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The study of continental lithosphere electrical conductivity, temperature and rheology Abdullkhay A. Zhamaletdinov, Yury L. Rebetsky, editors

Online Resource




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American dinosaur abroad: a cultural history of Carnegie's plaster Diplodocus / Ilja Nieuwland

Hayden Library - QE862.S3 N54 2019