sig Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01767F, Research ArticleGui-Xiang Zhou, Cheng HouThis study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6393-6410DOI: 10.1039/D4QO01451K, Research ArticleJiaoyang Liu, Li-juan Huang, Zeang Sun, Juan LiDFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6470-6476DOI: 10.1039/D4QO01532K, Research ArticleXiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu LiA novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01734J, Research ArticleYuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing LiTransition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Vigil mounted in erstwhile Adilabad district following ‘sighting’ of a tiger By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:52:15 +0530 Full Article Telangana
sig Design, synthesis, biological evaluation, and in silico studies of novel N-substituted-2-(3,4,5-trimethoxyphenyl)-1H-benzo[d]imidazole-6-carboxamides as promising anticancer agents By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35323-35335DOI: 10.1039/D4RA04492D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Navid Dastyafteh, Manica Negahdaripour, Mohammad Hosein Sayahi, Mina Emami, Younes Ghasemi, Elham Safaei, Homa Azizian, Zahra Pakrouh Jahromi, Mehdi Asadi, Mohammad Reza Mohajeri-Tehrani, Fateme Zare, Minoo Shahidi, Zahra Pooraskari, Sayed Mahmoud Sajjadi-Jazi, Bagher Larijani, Mohammad Mahdavi, Sara RanjbarSynthesis and cytotoxicity evaluation of novel benzimidazoles were explained. The most potent derivative was subjected to cell cycle, apoptosis, and in silico investigations. Compound 5o proved to be a promising anticancer agent.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Design, synthesis, and evaluation of novel thiadiazole derivatives as potent VEGFR-2 inhibitors: a comprehensive in vitro and in silico study By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35505-35519DOI: 10.1039/D4RA04158E, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ibrahim H. Eissa, Walid E. Elgammal, Hazem A. Mahdy, Susi Zara, Simone Carradori, Dalal Z. Husein, Maymounah N. Alharthi, Ibrahim M. Ibrahim, Eslam B. Elkaeed, Hazem Elkady, Ahmed M. MetwalyThis study aims to investigate the potential of designed 2,3-dihydro-1,3,4-thiadiazole derivatives as anti-proliferative agents targeting VEGFR-2, utilizing a multidimensional approach combining in vitro and in silico analyses.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Design, synthesis, and in vitro and in vivo biological evaluation of triazolopyrimidine hybrids as multitarget directed anticancer agents By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35239-35254DOI: 10.1039/D4RA06704E, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Heba A. Adawy, Samar S. Tawfik, Abdullah A. Elgazar, Khalid B. Selim, Fatma E. GodaIn response to the urgent need for new anti-proliferative agents, four novel series of triazolopyrimidine compounds (7a–e, 9a–d, 11a–f, and 13a–e) were synthesized and evaluated for in vitro and in vivo anticancer efficacy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Bisphenol A (BPA) toxicity assessment and insights into current remediation strategies By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35128-35162DOI: 10.1039/D4RA05628K, Review Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joshua O. Ighalo, Setyo Budi Kurniawan, Banlambhabok Khongthaw, Junaidah Buhari, P. K. Chauhan, Jordana Georgin, Dison Stracke Pfingsten FrancoTo mitigate the toxic effects of BPA, there is a need to utilize hybrid remediation strategies for its removal from the aqueous environment.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Exploring heterocyclic scaffolds in carbonic anhydrase inhibition: a decade of structural and therapeutic insights By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35769-35970DOI: 10.1039/D4RA06290F, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nafeesa Naeem, Amina Sadiq, Gehan Ahmed Othman, Habab M. Yassin, Ehsan Ullah MughalHeterocyclic compounds represent a prominent class of molecules with diverse pharmacological activities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Congress flays Rajasthan Government over lack of clarity on Minister’s resignation during heavy rains By www.thehindu.com Published On :: Tue, 13 Aug 2024 03:01:00 +0530 The BJP Government in Rajasthan is yet to take a decision on Disaster Relief Minister Kirodi Lal Meena’s resignation Full Article Other States
sig Wikipedia assignments By marstonscience.blogspot.com Published On :: Fri, 14 Mar 2008 13:55:00 +0000 Following up on the article Dan sent around (http://www.infotoday.com/online/mar08/Badke.shtml) I thought this Wikipedia page was interesting (http://en.wikipedia.org/wiki/Wikipedia:School_and_university_projects). It lists universities/courses who have completed a class project using wikipedia and includes a list of suggested exercises for classes. Amy thought the idea of having students "evaluate and edit Wikipedia articles, using research from other sources as an evaluative tool" would be a great project for our ENC3254 courses. This would be a great way to introduce some information literacy considerations into a course. What do you think? Can you think of any other ways we could us wikipedia in our one shot classes? Full Article
sig Faster, higher, longer: decathlete Jashbir Nayak sets his sights on the Asian Games By www.thehindu.com Published On :: Sat, 26 Oct 2024 00:16:15 +0530 The 22-year-old has advanced swiftly in a short period, registering an overall increase of 1244 points since last May. This has both underlined his potential in athletics’ toughest discipline and propelled his ambition to excel at the prestigious continental event in two years’ time Full Article Athletics
sig Global carbon market gets green signal at COP29 under Paris Agreement's Article 6 By www.thehindu.com Published On :: Tue, 12 Nov 2024 12:18:07 +0530 It offers two pathways for countries and companies to trade carbon offsets, supporting the achievement of emission reduction targets set in their climate action plans, or nationally determined contributions Full Article Environment
sig Global carbon market gets green signal at COP29 By www.thehindu.com Published On :: Tue, 12 Nov 2024 17:29:33 +0530 Such a market would allow countries to trade carbon credits among themselves Full Article Environment
sig India-Germany sign multiple MoUs on green hydrogen, technology & trade By www.thehindubusinessline.com Published On :: Fri, 25 Oct 2024 21:15:46 +0530 Prime Minister Narendra Modi meeting with German Chancellor Olaf Scholz follows signing of multiple treaties, agreements on Mutual Legal Assistance Treaty in Criminal Matters and Indo-German Green Hydrogen Road Map Full Article National
sig Thomas Tuchel signs contract to become England’s new national team coach By www.thehindu.com Published On :: Wed, 16 Oct 2024 10:25:52 +0530 The German is set to become the third foreign manager to take charge of the England men's team Full Article Football
sig Arsenal sporting director Edu Gaspar resigns By www.thehindu.com Published On :: Tue, 05 Nov 2024 08:31:28 +0530 Edu said he was leaving to pursue “a different challenge” but did not specify what that would entail. Full Article Football
sig ISL | HFC consigns Blasters to third straight loss By www.thehindu.com Published On :: Fri, 08 Nov 2024 03:19:24 +0530 Full Article Football
sig Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450 By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02197E, PaperVandana Kardam, Vaibhav Bhatt, Kshatresh DubeyArylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02659D, PaperSunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua SunThe coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02563F, PaperChangfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu HanA bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig An insightful study on the reduction and extraction of neptunium assisted by molybdenum By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17909-17917DOI: 10.1039/D4DT02547D, PaperHuaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing ChenMo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister By www.thehindu.com Published On :: Tue, 12 Nov 2024 07:00:00 +0530 Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign. Full Article Karnataka
sig JD(S) demands Zameer’s resignation for his remarks against HDK By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:11:01 +0530 Full Article Karnataka
sig Heavy metal leaching from stormwater control measures – insights into field and lab prestressed media and road-deposited sediments By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, Advance ArticleDOI: 10.1039/D4EW00388H, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Philipp Stinshoff, Yannic Henn, Steffen H. Rommel, Brigitte HelmreichHeavy metals bound to filter media from stormwater control measures can leach out under unfavorable conditions. The potential overestimation due to different prestressing (lab vs. field) was evaluated with respect to the potential mobile fraction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig L&T bags 'significant' order for global nuclear fusion project By www.thehindu.com Published On :: Fri, 25 Oct 2024 13:53:48 +0530 The company classifies a 'significant order' as orders valued between ₹1,000 crore and ₹2,500 crore Full Article Industry
sig TCS signs multi year deal with Air France-KLM to modernise the airline group’s data By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:59:40 +0530 Over the next three years, TCS will modernise the airline group’s data by moving it to cloud, promoting the next generation of data-driven aviation. Full Article Business
sig Israel signs deal to acquire 25 F-15 fighter jets from Boeing Co By www.thehindu.com Published On :: Thu, 07 Nov 2024 13:33:25 +0530 Delivery of the F-15 aircraft will begin in 2031, with 4-6 aircraft to be supplied annually Full Article World
sig Meet Aswanth A, the visual designer behind the IFFK 2024 logo and brand identity concept By www.thehindu.com Published On :: Sat, 02 Nov 2024 13:58:24 +0530 The IFFK film festival will take place in Thiruvananthapuram from December 13 onwards Full Article Movies
sig Sharad Pawar resigns as MCA president By www.thehindu.com Published On :: Sat, 17 Dec 2016 19:31:26 +0530 Pawar was in his second innings as president of the MCA after being elected last year for a two-year term. Full Article Cricket
sig Indian service providers signal robust growth in October on strong demand conditions By www.thehindu.com Published On :: Wed, 06 Nov 2024 12:39:11 +0530 India’s services PMI rebounds to 58.5 in October, driven by strong output, new business, and job creation, signaling economic growth Full Article Economy
sig Mahindra University opens School of Design Innovation By www.thehindubusinessline.com Published On :: Thu, 18 Jul 2024 17:21:29 +0530 It will allow students to be mentored by some of the best design brains from India and abroad Full Article Education
sig Nudged out owing to current controversy: Congress on UPSC chairman resignation By www.thehindubusinessline.com Published On :: Sat, 20 Jul 2024 15:46:47 +0530 Congress president Mallikarjun Kharge alleged the BJP-RSS is systematically indulging in an institutional takeover of India's constitutional bodies Full Article Education
sig Nemetschek India and ICT Academy sign MoU to boost digital transformation in education By www.thehindubusinessline.com Published On :: Fri, 02 Aug 2024 19:50:33 +0530 The partnership aims to upskill students and professionals for the AEC industry through workshops, seminars, and certifications Full Article Education
sig Byju’s auditor BDO resigns amid financial and governance concerns By www.thehindubusinessline.com Published On :: Sat, 07 Sep 2024 16:56:23 +0530 The resignation comes amid reported issues with financial reporting and governance, raising questions about the firm’s financial transparency and management support Full Article Education
sig At Design for Change, we let children find creative solutions: Kiran Bir Sethi By www.thehindubusinessline.com Published On :: Fri, 13 Sep 2024 22:37:38 +0530 Change for Social Transformation — Design for Change Full Article Blchangemakers
sig Designing their future By www.thehindu.com Published On :: Wed, 03 Oct 2012 18:44:32 +0530 With many young designers running the fashion rat race, upcoming designers and industry experts talk about why very few actually win it. Full Article Nxg
sig Modi’s low level attack on Congress is a sign that he knows he is losing the polls, says K.C. Venugopal By www.thehindu.com Published On :: Thu, 23 May 2024 21:25:38 +0530 The PM is banking on the weapon of polarising and dividing the people of the country, says Congress general secretary (organisation); he says the Congress has conceded many seats to allies to ensure the BJP government is removed and to end the ‘anarchy of misgovernance and dictatorship’ Full Article India
sig What makes Dundee Design Festival the world’s most sustainable design event By www.thehindu.com Published On :: Sat, 21 Sep 2024 12:59:17 +0530 Set in a former factory and powered by renewable energy, here is why the upcoming Dundee Design Festival is touted to be ‘the world’s most sustainable design festival’ Full Article Environment
sig Naphtho[1,2-c:5,6-c']bis([1,2,3]thiadiazole) enables the design of efficient halogen-free polymer donors and fabrication of organic solar cells with >19% efficiency By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, 17,8593-8608DOI: 10.1039/D4EE02414A, PaperTao Jia, Yongmin Luo, Yulong Hai, Tao Lin, Xudong Qin, Ruijie Ma, Kezhou Fan, Aleksandr A. Sergeev, Top Archie Dela Peña, Yao Li, Mingjie Li, Kam Sing Wong, Gang Li, Jiaying Wu, Shengjian Liu, Fei HuangFusion and isomerization strategies are used to develop an electron-withdrawing motif naphtho[1,2-d:5,6-d']bis([1,2,3]thiadiazole) (iNT) and a halogen-free polymer donor achieving an efficiency of 19.1%.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Circular battery design: investing in sustainability and profitability By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, 17,8529-8544DOI: 10.1039/D4EE03418J, Perspective Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andreas Wolf, Felix Nagler, Philip Daubinger, Christoph Neef, Karl Mandel, Andreas Flegler, Guinevere A. GiffinThe market share of low-cost battery chemistries, which offer little to no recycling profitability with current methods, is growing. Design for circularity could be the key to reducing costs and enhancing sustainability for these batteries.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Techno-economic insights and deployment prospects of permanent carbon dioxide sequestration in solid carbonates By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, 17,8756-8775DOI: 10.1039/D4EE03166K, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andreas Mühlbauer, Dominik Keiner, Christian BreyerWhile a rapid defossilisation of the energy system is the highest priority, additional post-fossil CDR for net-negative emissions will be necessary. Routes for mineralisation (in situ-, ex situ mineralisation, enhanced rock weathering) are examined.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Development of Coimbatore North Station generates hopes for designation as originating terminal By www.thehindu.com Published On :: Tue, 12 Nov 2024 20:25:31 +0530 Full Article Coimbatore
sig Automated kinetic model identification via cloud services using model-based design of experiments By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Advance ArticleDOI: 10.1039/D4RE00047A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Emmanuel Agunloye, Panagiotis Petsagkourakis, Muhammad Yusuf, Ricardo Labes, Thomas Chamberlain, Frans L. Muller, Richard A. Bourne, Federico GalvaninIndustry 4.0 has birthed a new era for the chemical manufacturing sector, transforming reactor design and integrating digital twin into process control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Scaling-up continuous production of mesoporous silica particles at kg scale: design & operational strategies By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Advance ArticleDOI: 10.1039/D3RE00707C, PaperRajashri B. Jundale, Jayesh R. Sonawane, Anil V. Palghadmal, Hemant Kumar Jaiswal, Hital S. Deore, Amol A. KulkarniThis paper demonstrates a continuous flow pilot-scale production of highly porous mesoporous silica particles (MSPs) via a soft template based technique.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Along the gut-bone marrow signaling pathway: use of longan polysaccharides to regenerate blood cells after chemotherapy-induced myelosuppression By pubs.rsc.org Published On :: Food Funct., 2024, Advance ArticleDOI: 10.1039/D4FO03758H, PaperShiai Zeng, Lan Gao, Kai Wang, Xuwei Liu, Zhuoyan Hu, Lei ZhaoTLPL promoted the production of Lactobacillus in myelosuppressed mice, and promoted the haematopoiesis of bone marrow cells via the gut-bone marrow axis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Pentadecanoic acid (C15:0, PA) induces mild maternal glucose intolerance and promotes the growth of the offspring partly through up-regulating liver PPARα and MAPK signaling pathways By pubs.rsc.org Published On :: Food Funct., 2024, Advance ArticleDOI: 10.1039/D4FO03970J, PaperJun Wang, Shiqi Zheng, Ziying Li, Yimei Tang, Yanhua Huang, Junwen Wang, Rui Li, Jie Peng1% PA can induce a mild decrease in the maternal glucose tolerance and lipolysis mainly by activated MAPK and PPARα signaling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Unravelling the potential of yolkin for nutraceutical use: the origin, structure, and functional insights of a hen egg yolk polypeptide complex By pubs.rsc.org Published On :: Food Funct., 2024, 15,10746-10760DOI: 10.1039/D4FO03023K, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Aleksandra Zambrowicz, Katarzyna Kapczyńska, Paweł Kania, Jakub Stanisław Nowak, Marta Kaszowska, Katarzyna Szymczak-Kulus, Wioletta Kazana-Płuszka, Marta Piksa, Sabina Górska, Dominika Jakubczyk, Józefa Macała, Agnieszka ZabłockaThe nutraceutical potential of yolkin health benefits from hen egg yolk.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
sig Goat milk derived small extracellular vesicles ameliorate LPS-induced intestinal epithelial barrier dysfunction, oxidative stress, and apoptosis by inhibiting the MAPK signaling pathway By pubs.rsc.org Published On :: Food Funct., 2024, Advance ArticleDOI: 10.1039/D4FO04067H, PaperFeng Gao, Xin Zhang, Zhiming Xu, Kang Zhang, Fusheng QuanIntestinal injury is often accompanied by epithelial barrier dysfunction, oxidative stress, and apoptosis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
