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Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, 26,27669-27676
DOI: 10.1039/D4CP03506B, Paper
Ching-Hua Chang, Wen Chao, Cheng-Han Tsai, Mitchio Okumura, Frank A. F. Winiberg, Yasuki Endo
Pure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.
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Experimental and simulation study of reverse micelles formed by aerosol-OT and water in non-polar solvents

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Phys. Chem. Chem. Phys., 2024, 26,27772-27782
DOI: 10.1039/D4CP03389B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angie Mat'usová, Georgina Moody, Peter J. Dowding, Julian Eastoe, Philip J. Camp
Small-angle neutron scattering and molecular dynamics simulations are used to characterise aerosol-OT reverse micelles. Simulations capture spontaneous self-assembly, compare favourably with experiments, and give microscopic information.
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Density scaling and isodynes in glycerol-water mixtures

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP02231A, Paper
David B. Noirat, Bernhard Frick, Bo Jakobsen, Markus Appel, Kristine Niss
This paper presents dielectric and neutron spectroscopy data on two different glycerol-water mixtures at elevated pressures. Glycerol-water liquid mixtures have a high concentration of hydrogen bonds which usually is expected...
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Improved perovskite crystallization by antisolvent engineering in tin-perovskite photovoltaics

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02655A, Paper
Xin Zhang, Yu Liu, Xinyao Chen, Chunqian Zhang, Jigang Wang, Jin Cheng, Junming Li
By adding an appropriate proportion of DMS to the anti-solvent, the DMSO remaining in the tin-based perovskite films can be effectively extracted, resulting in films with better crystallography, and the devices have lower trap densities.
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Band alignment in CdS-α-Te van der Waals heterostructures for photocatalytic applications: Influence of biaxial strain and electric field

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03368J, Paper
Tejaswini G, Anjana E Sudheer , Muthu Vallinayagam, Matthias Posselt, Matthias Zschornak, Maniprakash S, D. Murali
We present a comprehensive theoretical analysis of the structural and electronic properties of a van der Waals heterostructure composed of CdS and α-Te single layers (SLs). The investigation includes an...
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Indie bands: The challenge of zeroing in on the right mix

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 15:56:47 +0530

Indie musicians fuse genres and tap into social media to capture their audience, but still struggle to record and release an album


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Organohypervalent heterocycles

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D2CS01055K, Review Article
Ravi Kumar, Toshifumi Dohi, Viktor V. Zhdankin
This review summarizes structural and synthetic aspects of heterocyclic molecules incorporating an atom of a hypervalent main-group element. The higher thermal stability of hypervalent heterocycles, as compared to their acyclic analogs, adds special feature to their chemistry.
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The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Hero Asian Champions Trophy: India beats Korea; registers fourth consecutive win

By www.thehindu.com
Published On :: Thu, 12 Sep 2024 15:24:45 +0530

Paris Olympics bronze medallist India had already defeated China 3-0, Japan 5-0 before thrashing last year's runner-up Malaysia 8-1.


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Mya McLure, the brave science girl : the toad cave / by Douglas Haddad ; illustrated by Jennifer Ball-Cordero

By darius.uleth.ca
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Haddad, Douglas, 1976- author


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I am big / written by Itah Sadu ; illustrated by Marley Berot

By darius.uleth.ca
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Sadu, Itah, 1961- author


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A ‘PA on steroids’ for the richie-rich

By www.thehindubusinessline.com
Published On :: Sun, 28 Jul 2024 21:25:00 +0530

Concierge service startup Indulge Global sells convenience to Indians who crave the luxe life


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CO insertion enabled γ-C(sp3)–H heteroarylative carbonylation of tertiary alcohols via heteroaryl migration

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05361C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xin Qi, Yuanrui Wang, Xiao-Feng Wu
A carbonylative γ-C(sp3)–H functionalization of alcohols via migration of heteroaryl groups to produce 1,4-diketones has been developed.
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Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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Composition tunable and stable spontaneous emission and lasing in Cd-alloyed perovskite microdisks

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04488F, Communication
Dmitry A. Tatarinov, Elizaveta V. Sapozhnikova, Daria Khmelevskaia, Yangyang Ju, Dmitriy M. Dolgintsev, Elena V. Bodyago, Alexandr A. Marunchenko, Alexey E. Zhukov, Haizheng Zhong, Ivan G. Scheblykin, Anatoly P. Pushkarev
All-inorganic Cd-alloyed perovskite microdisks were synthesized by pressure-assisted high temperature recrystallization. The microdisks showed composition tunable and temporally stable photoluminescence.
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From one to two: In-site constructing C3N5-Poly (triazine imide) heterojunction for enhanced O2 activation

By pubs.rsc.org
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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05077K, Communication
Shiling Xu, Ziheng Yang, Laiqing Zhang, Xiaorui Zhang, Zikang Zeng, Wenxuan Wang, Yujun Liang, Lan Yuan, Chuang Han
A novel C3N5-Poly (triazine imide) (PTI) heterojunction was designed and constructed by thermal polymerization process, which featured with intimated S-scheme interface coupling and exhibited a predominant performance for H2O2 production....
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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

By pubs.rsc.org
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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Generous debtors!

By www.thehindu.com
Published On :: Wed, 17 Aug 2016 01:58:49 +0530


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Merits of generosity

By www.thehindu.com
Published On :: Tue, 18 Oct 2016 00:01:52 +0530


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Ni–Co alloys via controlled pyrolysis of NiCo–MOF as heterogeneous hydrogenation catalysts

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00664J, Paper
Lidan Deng, Xingwang Liu, Chong Chen, Lu Wang, Fan Liu, Jie Zhang
The pyrolysis in H2 at lower temperatures can obtain MNP/MOF with more complete MOFs structure and dispersed Ni–Co alloy nanoparticles, which display significantly better activity for the hydrogenation of toluene to methylcyclohexane.
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From byproducts to NLO-active dyes: catalyst-free transfer hydrogenation in the modular synthesis of merocyanines

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00820K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Zou, Yi Pan, Di Zhang, Jie Zhang, Weilong Chen, Hongyan Sun, Kai-Chung Lau, Jingdong Luo
Direct transfer hydrogenation from a strong electron donor to highly polarizable hemicyanines was discovered in the synthesis of push–pull chromophores. The reaction mechanism and experimental results were elucidated using DFT calculations.
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Photocatalytic degradation of tetracycline hydrochloride by BiVO4/MIL-88B(Fe) heterojunction

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01500B, Paper
Ziwei Zhao, Qi Ling, Shangkun Deng, Ziliang Li, Jianguo Lv, Lei Yang, Chunbin Cao, Zhaoqi Sun, Miao Zhang
A type II heterostructured BiVO4/MIL-88B(Fe) composite was successfully synthesised for the photocatalytic degradation of tetracycline hydrochloride (TC-HCl) by a simple hydrothermal method. Thin film materials avoid secondary pollution of powder...
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Impact of Cr doping on the structural and optoelectronic properties of a CsPbIBr2 perovskite solar cell

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New J. Chem., 2024, 48,7205-7212
DOI: 10.1039/D4NJ00681J, Paper
M. I. Khan, Ali Mujtaba, Saddam Hussain, Asif Hussain, Dalil Bulayis N AlResheedi, Zainab Mufarreh Elqahtani, El Sayed Yousef, Norah Alwadai
The Cr–CsPbIBr2 device showed enhanced performance, with increased grain size, reduced energy band gap, and elevated efficiency from 9.64% to 12.06%.
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Ambient temperature-prepared BiOBr-supported zero-pretreatment coal gasification fine slag for organic pollutant removal

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New J. Chem., 2024, 48,7256-7264
DOI: 10.1039/D3NJ05906E, Paper
Hele Hua, Jing Yang, Rui Li, Yunfang Wang, Caimei Fan, Jianxin Liu, Yawen Wang
The BiOBr/CGFS photocatalysts were synthesized at ambient temperature by a simple hydrolysis method with zero pre-treatment of CGFS. CGFS led to the improvement of the quantum efficiency of BiOBr and further promoted the photocatalytic performance.
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In situ fabrication of a robust P–N heterojunction based on Mn–Zn–S–ethylenediamine hybrid nanorods for boosting photocatalytic performance

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New J. Chem., 2024, 48,7287-7299
DOI: 10.1039/D3NJ05879D, Paper
Zhi-Yu Liang, Wang-Jun Huang, Er-Da Zhan, Peng Yang, Ren-Kun Huang, Ying Wang, Gui-Yang Yan
Multifarious novel photocatalysts based on hybrid nanocomposites have been developed to boost photocatalytic efficiency.
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Tannic acid induced in situ growth of an underwater superoleophobic ZIF-8 composite membrane for emulsion separation

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New J. Chem., 2024, 48,7384-7393
DOI: 10.1039/D4NJ00623B, Paper
Wanyu Lu, Qijin Tang, Huajing Cheng, Shudi Li, Cailong Zhou, Hao Yang
Tannic acid induced in situ growth of ZIF-8 crystals on a nylon membrane, creating a multifunctional composite membrane that exhibits remarkable underwater superhydrophobicity and resistance to oil adhesion.
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High proficiency Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst for the actuation of C(OH)–H bond

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New J. Chem., 2024, 48,7430-7438
DOI: 10.1039/D4NJ00395K, Paper
Fereshteh Zolfi, Mahdieh Ghobadifard, Sajjad Mohebbi
Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst was prepared for the actuation of the C(OH)–H bond with a mechanistic point of view.
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A novel CuAl2O4/MoS2/BaFe12O19 magnetic photocatalyst simultaneously coupling type I and Z-scheme heterojunctions for the sunlight-driven removal of tetracycline hydrochloride

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00970J, Paper
Mengjun Han, Shifa Wang, Xinmiao Yu, Xianlun Yu, Huajing Gao, Xianju Zhou, Dengfeng Li, Leiming Fang, Jagadeesha Angadi V., Mohd Ubaidullah, Bidhan Pandit
A novel CuAl2O4/MoS2/BaFe12O19 photocatalyst is synthesized that simultaneously couples type I and Z-scheme heterojunctions and exhibits high photocatalytic activity for the degradation of TC under simulated sunlight irradiation.
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

By pubs.rsc.org
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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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A multi-technique analysis of gelatin biodegradation on the surface of core–shell nanoparticles by Alteromonas macleodii extracellular proteases

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Environ. Sci.: Nano, 2024, 11,1429-1441
DOI: 10.1039/D3EN00523B, Paper
Sergio Fernández-Castillo Suárez, Cécile Courrèges, Javier Jiménez-Lamana, Simon Godin, Sophie Nolivos, Régis Grimaud, Luisa Ronga, Joanna Szpunar, Joachim Allouche
Multi-technique characterization at the nanoscale of gelatin biodegradation on the surface of core–shell nanoparticles by extracellular proteases.
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Selective metal recovery by mucin: turning gold from wastewater into a peroxymonosulfate-activated catalyst

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Environ. Sci.: Nano, 2024, 11,1487-1498
DOI: 10.1039/D3EN00699A, Paper
Open Access
Shira Gavriely, Shachar Richter, Ines Zucker
This study explores mucin's ability to selectively recover gold (Au) from metal wastewater. The Au, in the form of a nanoparticle, was utilized in peroxymonosulfate activation for the degradation of bisphenol A.
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Core–shell magnetic zinc-based molecularly imprinted polymer: a robust heterogeneous catalytic nanoreactor toward the CO2 fixation reaction

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Environ. Sci.: Nano, 2024, 11,1622-1635
DOI: 10.1039/D3EN00554B, Paper
Tahereh Nasiriani, Neda Adabi Nigjeh, Ahmad Shaabani
This study deals with the synthesis of a core–shell magnetic zinc-based molecularly imprinted polymer (M-Zn-MIP) as a robust heterogeneous catalytic nanoreactor. The catalytic activity of the M-Zn-MIP was explored in the CO2 fixation reaction.
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Sulfur-doped porous carbon sheets embedded with rich iron sites for 1O2 dominated peroxymonosulfate activation

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00971H, Paper
Yadan Song, Yalong Liu, Yangju Li, Haipeng Hu, Kexin Huang, Zhe Zhang, Zhongxian Li, Wanning Cao, Kai Jiang, Dapeng Wu
Porous carbon films co-doped with iron, nitrogen, and sulfur were synthesized via a one-step pyrolysis process, which have multiple active sites and can produce bulk 1O2 through PMS activation, which is effective in phenol degradation.
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Construction of CsPbBr3/carboxyl-modified rGO heterostructures for efficient photocatalytic reduction of CO2 to methanol

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CrystEngComm, 2024, 26,1994-2002
DOI: 10.1039/D4CE00036F, Paper
Meng Li, Jingtao Xu, Yang Song, Yuanyuan Li, Jin Wang, Feiyong Chen
Construction of monodispersed CsPbBr3 NCs and carboxyl-modified rGO composites led to the production of CO and CH3OH with an Relectron of 359 μmol g−1 h−1 by photocatalytic CO2 reduction.
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“Feather-duster” like ZnIn2S4/TiO2 heterostructured nanocomposites with enhanced visible-light photocatalytic performance

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CrystEngComm, 2024, 26,2025-2032
DOI: 10.1039/D3CE01239E, Paper
Wenjie Liu, Lei Li, Jingru Li, Fang Wang, Chun-Shuai Cao, Jianzhou Gui, Alex T. Kuvarega, Bhekie B. Mamba, Dan Liu
The ZnIn2S4/TiO2 heterostructures show an increased surface area and strengthened interface contacts, facilitating efficient photogenerated carrier separation and leading to high photocatalytic performance under visible light irradiation.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

By pubs.rsc.org
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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

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CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
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Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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First-principles prediction of a direct Z-scheme WSe2/HfS2 van der Waals heterostructure for overall photocatalytic water decomposition

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00267A, Paper
Yan Zhang, Zhi-Bo Qiang, Jian-Xin Ding, Kang-Xin Xie, Li Duan, Lei Ni
The direct Z-scheme heterostructures photocatalyst has been validated as an efficacious approach for addressing the energy source issues and environmental challenges. This manuscript employs the first-principles to scrutinize singular-layer WSe2...
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Evolution of fractal patterns in lead-free, zero-dimensional perovskite Cs2InBr5(H2O)

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00204K, Paper
Wanyin Ge, Yang Maohao, Masaki Saruyama, Kenshi Matsumoto, Ryota Sato, Haruka Takekuma , Ryo Takahata, Toshiharu Teranishi
The crystallization behavior of halide perovskites is of great significance. Fractal structures, featured by self-similarity between local morphology and global structures, have consistently captivated scientists’ interest across diverse disciplines. In...
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S-scheme heterojunction based on CuWO4/WO3 microspheres with improved photocatalytic property under visible light

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00301B, Paper
Yangang Sun, Jianhua Ge, jiaqi xu, Jinguo Wang
Dye wastewater green treatment has always been one of the research hotspots in the environmental protection and remediation field. The photocatalytic degradation and mineralization of organic dyes are considered to...
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A perturbational approach for approximating heterogeneous agent models [electronic resource] / Anmol Bhandari, Thomas Bourany, David Evans, Mikhail Golosov

By darius.uleth.ca
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Cambridge, MA. : National Bureau of Economic Research, 2023


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Forest fires [electronic resource] : why the large year-to-year variation in forests burned? / Jerome Apt, Dennis Epple, Fallaw Sowell

By darius.uleth.ca
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Cambridge, MA.: National Bureau of Economic Research, 2023


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Lessons to be learnt on the march to net zero

By www.thehindubusinessline.com
Published On :: Sun, 23 Jul 2023 15:30:12 +0530

A World Resources Institute paper presents five case studies that are worthy of replication


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The G20 Summit and the big push towards achieving net zero

By www.thehindubusinessline.com
Published On :: Sun, 17 Sep 2023 18:44:05 +0530

Climate finance gets much-needed focus at the Delhi meet under India’s Presidency


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Towards net zero via the reduction of methane emissions

By www.thehindubusinessline.com
Published On :: Sun, 10 Dec 2023 19:10:04 +0530

Remediation of landfills and scientific waste management could make a considerable difference in India


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Cyient DLM secures 16-year aerospace contract with Honeywell 

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 14:53:45 +0530

The shares of Cyient DLM Limited were trading at ₹644.85 up by ₹11.80 or 1.86 per cent on the NSE today at 1.40 pm


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Exploring the self-assembly dynamics of novel steroid–coumarin conjugates: a comprehensive spectroscopic and solid-state investigation

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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00192C, Paper
Open Access
Claudia M. Ramírez-Lozano, Ma. Eugenia Ochoa, Pablo Labra-Vázquez, Arturo Jiménez-Sánchez, Norberto Farfán, Rosa Santillan
The design, synthesis, and characterization of seven novel steroid–coumarin conjugates with diverse steroidal nuclei as lipophilic fluorescent materials for bioimaging applications are presented.
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