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45,000 US dockworkers set to strike at midnight, impacting East and Gulf Coast ports

The strike by members of the International Longshoremen's Association could cause 36 ports to shutter operations




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FACTBOX-Who are the candidates running in the US presidential election?

The upcoming elections in the United States on November 5 have the world on the edge of their seats as they heat up, here is a brief overview of who they are




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AAPI Chief Dr Kathula suggests fast-track green cards for Indian physicians in the US

Voices concerns that there are many physicians who are still on H-1B work visas even after staying in the US for over 15-20 years.




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Starboard Value takes $1 billion stake in Pfizer in activist push

The activist has found that investors and research analysts are frustrated by the company’s sustained post-pandemic struggles




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Nobel Peace Prize awarded to Japanese atomic bombing survivors’ group Nihon Hidankyo

We wish to honour all survivors who, despite physical suffering and painful memories, have chosen to use their costly experience to cultivate hope and engagement for peace, says Jørgen Watne Frydnes, chair of the Norwegian Nobel Committee




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Robot collects melted fuel from Fukushima nuclear reactor

Operated by Tokyo Electric Power Company Holdings, the robot collected a fragment measuring approximately 5 millimetres in size




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Netanyahu’s office is accused of leaks to thwart Gaza cease-fire

Many in Israel’s security establishment dismissed the demand and accused Netanyahu of avoiding a deal to keep the war going




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Trump takes early electoral lead as race with Harris takes shape

Polls have closed in key swing states of Georgia, North Carolina, Pennsylvania and Michigan




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As Trump makes historic return, world braces for new era

People hope Trump will address jobs, economy issues; Trump has vowed to crackdown on illegal immigration




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Elon Musk’s India entry with Tesla and Starlink may get easier with Trump’s backing

Similarly, Musk is keen to launch his satellite broadband services firm Starlink in India and has been asking for lower entry barriers




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Overseas Pakistani group Al Nihang offers to acquire debt-ridden Pakistan International Airlines

Earlier, PML-N President Nawaz Sharif said that Punjab Chief Minister Maryam Nawaz advised him to buy Pakistan International Airlines (PIA) and rebrand it ‘Air Punjab’




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COP29 Climate Summit Day 2 Live: Azerbaijan is victim of ‘well-orchestrated campaign of slander and blackmail’, says President Aliyev

COP29 World Climate Action Summit Live Updates: At the COP29 climate summit in Baku, Azerbaijan, countries approved vital carbon credit quality standards essential for facilitating a U.N.-backed global carbon market aimed at funding greenhouse gas reduction projects. This early agreement marks a significant step forward, despite concerns about the upcoming U.S. administration under President-elect Donald Trump, who has indicated intentions to withdraw from the Paris Agreement. Experts suggest that the endorsement might help operationalize the market by next year, enabling countries and companies to purchase carbon credits for climate initiatives worldwide. However, while the approved standards seek to address the credibility of projects, campaigners have raised concerns about their adequacy, especially regarding human rights protections. Criticism also arose regarding the decision-making process, with some nations feeling excluded from discussions. Moving forward, negotiators aim to establish further rules to ensure the market’s integrity, which could potentially yield $250 billion annually and cut carbon emissions significantly by 2030.




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2024 on track to become the warmest year on record, says WMO

2015-2024 will be the warmest decade on glacier meltdowns, rise in sea levels and ocean heating




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Gabbia ends AC Milan's derby pain with late winner against Inter

Defender Gabbia rose highest to thump home Tijjani Reijnders' free-kick in the 89th minute and give Milan a Serie A win which pulls them out of a miserable early season slump




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Manchester City's Rodri 'out for season' after ACL injury: reports

Rodri's loss would be a huge blow to City's hopes of winning a fifth consecutive Premier League title and ambitions of reclaiming the Champions League.




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ISL | We want to make sure we do our very best at home: CFC head coach Coyle




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Serhou Guirassy scores twice in Dortmund's 4-2 comeback win over local rival Bochum

In five minutes, Matus Bero scored off a smartly executed one-two through the center, then Dani de Wit made it 2-0 after teammate Myron Boadu had snatched the ball off Dortmund's goalkeeper Gregor Kobel




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BBFS ties up with Southampton FC for coaches’ education




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Mohun Bagan considered withdrawn from ACL 2: AFC

Mohun Bagan Super Giant had last month decided against travelling to Iran for the October 2 match owing to the volatile situation that prevailed in the west Asian nation at that time




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Belfort’s brace sees Calicut down Malappuram

The victory, its first at home, helped Calicut jump over Kannur Warriors and move to the top of the table with 13 points from seven matches.




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Thomas Tuchel signs contract to become England’s new national team coach

The German is set to become the third foreign manager to take charge of the England men's team




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ISL: Bengaluru rides on Mendez’s brace against Kerala Blasters, ends two-year wait for a win in Kochi

Bengaluru FC defeated Kerala Blasters 3-1 in the Indian Super League match




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ISL: Majcen nets brace as Punjab come from behind to beat Chennaiyin

Luka Majcen, donning a mask after fracturing his jaw in its opening game versus Kerala Blasters, scored twice in three minutes while Asmir Suljic put the result beyond doubt with a third goal in the 70th minute




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ISL: Majcen nets brace as Punjab comes from behind to beat Chennaiyin




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ISL | Goa finally gets it act together in big win over Bengaluru




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Neymar picks up another injury in second game back from ACL tear

Neymar has time to recover before his next game, however, as he is not registered for the team’s matches in the Saudi Pro League and the next fixture in the AFC competition is on Nov. 25.




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Ancelotti calls for Real Madrid’s positive reaction after consecutive losses

Ancelotti's side sit second in the league standings with 24 points from 11 matches, nine points behind leaders Barcelona, who have played a game more




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Gold ETF gains traction as prices hit new high

The asset under management of gold ETF has gone up 33 per cent to ₹28,530 crore as of February against ₹21,400 crore in February, 2023



  • Gold & Silver

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Jewellery retailers fear a lacklustre Akshaya Tritiya this year due to soaring gold prices

Akshaya Tritiya, which falls on May 10 this year, is considered auspicious to buy gold



  • Gold & Silver

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RBI’s gold holding increases by 27.46 metric tonnes in FY24, reaching 822.10 metric tonnes mark

The report noted that the ratio of short-term debt to reserves has decreased, and foreign exchange reserves covering imports have increased to 11 months



  • Gold & Silver

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Malabar Gold achieves 50% cost reduction from automation as gold prices go through the roof

The high prices may detract price-sensitive customers away, but he pins his hopes on the digital-savvy new generation to invest more in the gold



  • Gold & Silver

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RBI brings back 100 tonnes of gold reserves from UK vaults

Most countries keep their gold in the vaults of the Bank of England or some such location and pay a fee for the privileges



  • Gold & Silver

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RBI moves 100 tonnes of gold back home amid global uncertainty

Since late last year, all the major central banks are moving their gold reserves back home given the volatile global developments, including the unrest in West Asia and conflict between Iran and Iraq



  • Money & Banking

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Budget 2024: Duty cut to lower gold prices. How will it impact jewellery stocks?

A drop in gold price can lead to increased jewellery demand, improving their revenue and profits Market experts believe the price of yellow metal could drop between ₹300 and ₹500 per gram going ahead



  • Gold & Silver

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65% of millennials prefer digital gold over traditional for its ease of access and convenience: Moneyview survey

Digital gold can be easily converted to cash or physical gold, giving investors flexibility to trade without incurring heavy transaction costs or delays



  • Gold & Silver

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Jewellers woo Dhanteras buyers with attractive offers

Gold prices have been hovering above Rs ₹78,600 per 10 gm-level consistently despite weak demand due to ongoing global geopolitical turmoil in West Asia and Russia-Ukraine




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Cuisine of Macau

Abstract: The cooking of the Macanese, an ethnic group originating in Macau, represents one of the earliest examples of creole cooking. What can be seen on the dining plates of these people reflects history and culture dating back to the seafaring discoveries of the Portuguese. Macanese cuisine demonstrates how Portuguese culinary traditions have been

The post Cuisine of Macau appeared first on Berkshire Publishing.




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Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR)

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02217C, Paper
Bijoy Ghosh, Sahtaz Ahmed, Ashwini K. Phukan
Comprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.
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LDH-derived Co0.5Ni0.5Te2 Dispersed in 3D Carbon Sheets as Separator Modifier to Enable Kinetics-Accelerated Lithium-Sulfur Batteries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02619E, Paper
Chunmei Li, kan Mi, Kai Xu, Zhuo Jia, Xiaolei Jiang, Huili Peng, Xiuwen Zheng, Hongjiao Nie
Lithium-sulfur battery is considered as a powerful candidate for the next generation of advanced energy storage systems relying on its high energy density and theoretical specific capacity. However, its practical...
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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
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Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02303J, Paper
Tao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan Wang
Ni/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.
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Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02659D, Paper
Sunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua Sun
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
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Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02274B, Paper
Emilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-Żyrek
Histatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.
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Syntheses, structures and characterization of noncentrosymmetric MZnPO4 (M = K, NH4)

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02530J, Paper
Jiawei Zhao, Wei Wei, Meihui Chen, Yanna Chen, Donghai An
Two phosphates, KZnPO4 and NH4ZnPO4, were successfully synthesized, and both structures show a three-way skeleton of isolated PO4 and ZnO4 tetrahedra. And NCS KZnPO4 and NH4ZnPO4 can exhibit SHG responses of 0.4 × KDP and 1 × KDP.
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Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02603A, Paper
Takeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa Mehrkhodavandi
Alkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.
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A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02734E, Paper
Hui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang Tang
A biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.
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What is the key factor affecting the cathodoluminescence intensity of europium complexes?

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02501F, Communication
Rongdeng Lu, Tinghui Huang, Alexander Goloveshkin, Dmitry Kopytov, Kseniya Orekhova, Ivan Khanbekov, Valentina V. Utochnikova
Cathodoluminescence of lanthanide coordination compounds correlates with PLQY/τ in the saturation regime and with PLQY when saturation is not reached. Understanding this, a brightly cathodoluminescent europium complex was obtained.
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Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02696A, Perspective
Ankita Sharma, Unnikrishnan Nair K, Subrata Kundu
Carbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...
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Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper
Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
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