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Ideals, varieties, and algorithms [electronic resource] : an introduction to computational algebraic geometry and commutative algebra / David A. Cox, John Little, Donal O'Shea

New York : Springer, 2007




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Geometry, Algebra, Number Theory, and Their Information Technology Applications [electronic resource] : Toronto, Canada, June, 2016, and Kozhikode, India, August, 2016 / edited by Amir Akbary, Sanoli Gun.

Cham : Springer International Publishing : Imprint: Springer, 2018.




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Geometry, algebra, number theory, and their information technology applications : Toronto, Canada, June, 2016, and Kozhikode, India, August, 2016 / Amir Akbary, Sanoli Gun, editors

Cham, Switzerland : Springer, 2018




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An introduction to the circle method [electronic resource] / M. Ram Murty, Kaneenika Sinha.

Providence, Rhode Island : American Mathematical Society, [2023]




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Passengers depending on non-Railway sources of information for timetable miss CSMT Express

Non-railway websites or apps do not immediately update changes in train timetables, say officials




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IndiaAI, Meta launch AI center in IIT Jodhpur; will promote student start-ups




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'Kutrame Thandanai' review: thoughtfully made, but something’s missing




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Metro Group eyes ₹1,000 crore revenue from Thane projects

The group plans to introduce one-of-its-kind luxury projects with modern ecosystem for the discerning professionals who prefer Thane over Mumbai




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I am…Padmakumar – Metal craftsman




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Something for everyone

Ethnic wear, jewellery, knick knacks…. this fair has it all




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Something old, something new

It is the festive season and you have all the excuses in the world to shop. Srishti brings to Coimbatore some of the best craftsmanship from the country




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Photocatalytic hydrotrichloromethylation of unactivated alkenes with chloroform

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01496K, Research Article
Dawei Gong, Caiyu Gao, Qixuan Li, Yufei Li, Lina Zhao, Degong Kong
Trichloromethyl compounds are essential constituents in synthetic and medicinal chemistry.
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Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01681E, Research Article
Lu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai Zhou
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.
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Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01488J, Research Article
Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
A photoinduced FeCl3/HCl synergistic catalytic method enables C(sp3)–S bond formation via reductive cross-coupling of activated/inert C(sp3)–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).
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General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01698J, Research Article
Heng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen Xu
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
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Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01702A, Research Article
Yiting Zhou, Bin Liu
We present a metal-free and mild three-component reaction involving vinylarenes, NHC–BH3 complexes, hydrosilanes, and 4-cyanopyridine. Remarkably, this reaction was performed with simple and inexpensive benzophenone.
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Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01841A, Research Article
Xunhua Wang, Jianhua Wang, Xiaoxun Li
A gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.
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Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01848F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tobias B. Tischer, Zulema Fernandez, Lorenz Borsdorf, Constantin Daniliuc, Shigehiro Yamaguchi, Soichiro Ogi, Gustavo Fernandez
Supramolecular polymers are often investigated for highly symmetric and planar molecules, such as typically explored BF2-substituted BODIPY dyes . However, it is surprising that the possibility of desymmetrizing the sp3...
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Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Org. Chem. Front., 2024, 11,6340-6346
DOI: 10.1039/D4QO01376J, Research Article
Qinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong Lian
We developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.
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Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction

Org. Chem. Front., 2024, 11,6426-6436
DOI: 10.1039/D4QO01551G, Research Article
Mao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long Zhao
A cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Asymmetric synthesis of (aza)flavanones by the evolution of CarOx ligands

Org. Chem. Front., 2024, 11,6444-6449
DOI: 10.1039/D4QO01345J, Research Article
Juan Yang, Wenlong Kong, Mingxin Chang, Jixing Lai, Shengkun Li
Amino-pyridine-oxazoline (NHPyOx) is conceived as an unprecedented model via the core-emulating optimization of CarOx ligands.
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Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives

Org. Chem. Front., 2024, 11,6319-6326
DOI: 10.1039/D4QO01368A, Research Article
Yu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming Wang
A variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.
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Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes

Org. Chem. Front., 2024, 11,6470-6476
DOI: 10.1039/D4QO01532K, Research Article
Xiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu Li
A novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.
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A general method for E-selective olefination of acylsilanes with isocyanides via silver catalysis

Org. Chem. Front., 2024, 11,6450-6458
DOI: 10.1039/D4QO01528B, Research Article
Xiu-Xia Liang, Dan-Ni Yang, Xiao-Hui Yan, Peng Wang, Man-Yi Han
A silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.
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Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions

Org. Chem. Front., 2024, 11,6437-6443
DOI: 10.1039/D4QO01265H, Research Article
Dabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou Cai
In this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.
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Transition-metal-catalyzed C–Ge coupling reactions

Org. Chem. Front., 2024, 11,6558-6572
DOI: 10.1039/D4QO01637H, Review Article
Jie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan He
This review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.
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Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis

Org. Chem. Front., 2024, 11,6534-6557
DOI: 10.1039/D4QO01686F, Review Article
Jinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun Xie
This review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.
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LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01678E, Research Article
Open Access
Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar Goreti
LiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.
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A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01388C, Research Article
Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01844C, Research Article
Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
This article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...
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Catalyst-free C–H methylation of heteroarenes enabled by electron donor–acceptor complex photoactivation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01309C, Research Article
Jiayang Wang, Baoer Shao, Haixia Ge, Huiyu Xue, Xiangyuan Ding, Yuqi Li, Peiyao Sheng
A visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.
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Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01963F, Highlight
Yingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie Wu
As the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...
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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01771D, Research Article
Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
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Integrating electrocatalysis with biocatalysis for asymmetric synthesis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01899K, Highlight
Yuqi Lin, Jiage Yu, Ke-Yin Ye
This highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.
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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
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Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01714E, Research Article
Ke Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang Sun
Transition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.
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PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01589D, Research Article
Xinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah Hamze
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
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66% of gamers in India are from non-metro cities: Lumikai annual report

Average weekly time spent on gaming increased by 30% to 13 hours




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Discover your true calling through psychometric tests

It is a useful tool that offers career clarity and opens up new possibilities.




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Effective BPA degradation in water: the integration of bimetallic UiO-66 Ce–Zr

RSC Adv., 2024, 14,35090-35096
DOI: 10.1039/D4RA06460G, Paper
Open Access
Leidy Marcela Gallo, Juan L. Obeso, Nora S. Portillo-Vélez, Carlos E. Garduño-Albino, Catalina V. Flores, Leonardo Herrera-Zuñiga, Alejandro Islas-Jácome, Ricardo A. Peralta, Carolina Leyva
In this work, a bimetallic MOF UiO-66 Ce–Zr to degrade bisphenol A (BPA) in water was synthesised. The material exhibited a remarkable degradation efficiency of 84.3% under UV irradiation for 240 minutes.
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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
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Design, synthesis, biological evaluation, and in silico studies of novel N-substituted-2-(3,4,5-trimethoxyphenyl)-1H-benzo[d]imidazole-6-carboxamides as promising anticancer agents

RSC Adv., 2024, 14,35323-35335
DOI: 10.1039/D4RA04492D, Paper
Open Access
Navid Dastyafteh, Manica Negahdaripour, Mohammad Hosein Sayahi, Mina Emami, Younes Ghasemi, Elham Safaei, Homa Azizian, Zahra Pakrouh Jahromi, Mehdi Asadi, Mohammad Reza Mohajeri-Tehrani, Fateme Zare, Minoo Shahidi, Zahra Pooraskari, Sayed Mahmoud Sajjadi-Jazi, Bagher Larijani, Mohammad Mahdavi, Sara Ranjbar
Synthesis and cytotoxicity evaluation of novel benzimidazoles were explained. The most potent derivative was subjected to cell cycle, apoptosis, and in silico investigations. Compound 5o proved to be a promising anticancer agent.
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Surface science studies of the coverage dependent adsorption of methyl acetate and methyl propanoate on graphite

RSC Adv., 2024, 14,35373-35385
DOI: 10.1039/D4RA04466E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jack E. Fulker, Wendy A. Brown
The adsorption of methyl acetate and methyl propanoate has been studied on a graphite surface at 28 K. TPD data show that the desorption energy of both molecules is highly coverage dependent with repulsive interactions being seen at low coverages.
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Correction: Luminescence properties of Bi3+/Sm3+ co-doped K3Gd5(PO4)6 phosphors for self-referencing optical thermometry

RSC Adv., 2024, 14,35447-35447
DOI: 10.1039/D4RA90130D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jing Wang, Mingjun Song, Junpeng Xue, Shala Bi, Hyo Jin Seo
The content of this RSS Feed (c) The Royal Society of Chemistry




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DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ag@Mg12@Ag20: a three-layer matryoshka structure with S6 symmetry

RSC Adv., 2024, 14,35553-35558
DOI: 10.1039/D4RA07046A, Paper
Open Access
Peng-Bo Liu, Jing-Jing Guo, Yi-Sha Chen, Hui-Yan Zhao, Jing Wang, Ying Liu
A novel three-layer matryoshka structure with S6 symmetry is proposed, amid the evolving landscape of carbon-based derivatives and high-symmetry architectures.
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Comparing diverse extraction methodologies to infer the performance of 1,8-cineole extraction from Eucalyptus cinerea: process optimization, kinetics, and interaction mechanisms

RSC Adv., 2024, 14,35529-35552
DOI: 10.1039/D4RA06050D, Paper
Open Access
Divya Baskaran, Madhumitha Sathiamoorthy, Ramasamy Govindarasu, Hun-Soo Byun
Different extraction techniques were used to extract 1,8-cineole from Eucalyptus cinerea leaves, and their performance efficiency was evaluated through optimization and kinetic studies.
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Statistically driven automated method for catalytic glucose conversion optimisation

RSC Adv., 2024, 14,35578-35584
DOI: 10.1039/D4RA06038E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joseph Install, Rui Zhang, Jukka Hietala, Timo Repo
A statistically driven, automated approach to optimize glucose transformations to platform chemicals, methyl lactate and levulinic acid, is reported.
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Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Harnessing the UiO-67 metal–organic framework for advanced detection of cadmium ions in water bodies

RSC Adv., 2024, 14,35618-35627
DOI: 10.1039/D4RA06811D, Paper
Open Access
Bhuvaneswari Selvaraj, Lakshmi Priya G., Selva Balasubramanian
Heavy metal ions are hazardous pollutants that pose serious threats to ecosystems and human health, making it imperative to detect and monitor their presence in water for environmental protection.
The content of this RSS Feed (c) The Royal Society of Chemistry