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Perovskite photoinitiated RAFT-mediated polymerization-induced self-assembly for organic–inorganic hybrid nanomaterials

Inorg. Chem. Front., 2024, 11,2471-2478
DOI: 10.1039/D4QI00233D, Research Article
Bingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli Lü
An efficient strategy is proposed to construct PQD/polymer organic–inorganic nanohybrids by PET-RAFT polymerization-mediated PISA and the nanohybrid assemblies can maintain excellent luminescence originating from PQDs with enhanced stability.
The content of this RSS Feed (c) The Royal Society of Chemistry




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sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds

Inorg. Chem. Front., 2024, 11,2312-2318
DOI: 10.1039/D4QI00178H, Research Article
Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties

Inorg. Chem. Front., 2024, 11,2457-2470
DOI: 10.1039/D4QI00109E, Research Article
Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
The luminescence mechanism of Te4+-doped VODPs is reported. Te4+-doped Hf-based VODPs exhibit luminescence characteristics that are more in line with those of Te4+ ions, while Te4+-doped Sn- and Zr-based VODPs have STEs emission characteristics.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical frontiers in the nitrogen cycle

Inorg. Chem. Front., 2024, 11,2202-2204
DOI: 10.1039/D4QI90016B, Editorial
Xuping Sun, Jieshan Qiu, Chenghua Sun
Xuping Sun, Jieshan Qiu and Chenghua Sun introduce this Inorganic Chemistry Frontiers themed collection on nitrogen cycle electrocatalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stable Calcium Ellagate Metal-Organic Framework as High Performance Green Memorizer Bearing High Working Temperature

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article
Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effect of -OH on the Thermal Enhancement Properties of NIR-II Lanthanide Doped Nanoparticles in Water

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00147H, Research Article
Yingping Huang, Jie Hu, Yongwei Guo, Zihao Wang, Fulin Lin, Haomiao Zhu
Thermal enhanced nanothermometry has attracted great attention due to its high thermal sensitivity, however, most of studies are focused on the upconversion nanoparticles (NPs) in forms of powder. In the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hafnia-based oxide enhanced Ga2O3-based photodetectors via band engineering with ultralarge responsivity

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00490F, Research Article
Han Wu, Jiaying Shen, Lincong Shu, Jie Dai, Shulin Sha, Zeng Liu, Weihua Tang, Yuehui Wang, Zhenping Wu, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
β-Ga2O3 photodetectors achieve ultrahigh responsivity under low supply voltage and ultralow light intensity conditions via band engineering with polar Hf0.5Zr0.5O2 as an insert layer.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni(4-MePy)4(NCS)2]

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00636D, Research Article
Open Access
Shi-Qiang Wang, Shaza Darwish, Catiucia Matos, Zicong Marvin Wong, Anjaiah Nalaparaju, Yifei Luo, Jun Zhu, Xiaofei Zhang, Zhengtao Xu, Michael Zaworotko
Shape-memory effects and stimuli-induced phase transformations are observed across many types of materials but remain understudied in molecular materials. In this contribution, we revisit the Werner complex, [Ni(4-MePy)4(NCS)2] (4-MePy =...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Row over ISMA’s suggestion to regulate khandsari units

Opposing curbs, traditional sweeteners body BHAKTI says Centre should not be swayed by false narratives




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Global Organic Textiles Standards bans 5 Indian cotton firms for faking documents

Two firms used non-existent shipping firms to show transactions, the others submitted fake transaction certificates




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Crude oil futures rise amid declining US inventories

December Brent oil futures rose to $74.37, while November WTI futures climbed to $70.59.




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Aluminium futures retain positive bias

The price region between ₹228 and ₹230 is a demand zone




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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Spinning mills in Gujarat, N. India seek quality cotton from Raichur region

Ongoing rains raise concern over quality, crop size across key producing regions




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Nickel prices likely to be under pressure on market surplus

Analysts peg its average price for 2024 at around $17,000/tonne




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Global oil prices should hopefully come down, says Oil Minister Puri

One thing that is very clear is there is no shortage of oil in the world, said Puri




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Weather experts divided over emergence of La Nina

APEC Climate Centre predicts the weather event from December




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India defers plan to hike minimum selling price of sugar, for now

The agri costs panel had recommended regular revision of the minimum price




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Crude oil trades higher as market monitors developments in West Asia 

At 9.56 am on Friday, December Brent oil futures were at $74.50, up by 0.16 per cent, and December crude oil futures on WTI (West Texas Intermediate) were at $70.28, up by 0.13 per cent




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Crude oil futures dip after Israeli attack avoids Iranian oil facilities 

November natural gas futures were trading at ₹254.50 on MCX during the initial hour of trading on Monday against the previous close of ₹258.20, down by 1.43 per cent




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India’s iron ore, manganese, aluminium output rises in H1 FY25 amid strong demand

Iron ore production rose by 5.5% to 135 million tonnes, while manganese ore output increased by 6.2% to 1.7 million tonnes




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Coconut water, evening walks & meditation




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Communities lead

The theme on World AIDS Day (December 1) is ‘Let Communities Lead’




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Golden morning, balanced diet & tennis




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Calisthenics, rock-climbing and laughter




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Immunisation turns 50

The Expanded Programme on Immunization (EPI) — an initiative of the World Health Organization (1974) turns 50 this year




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Union Budget: Hopeful of an investment blueprint for healthcare

India’s healthcare sector needs government-private sector partnerships, funding for screening and diagnostics and lower taxes to enhance services




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No turning back on the biotech super highway

Industry experts call for support to firms pursuing cutting-edge technologies as they forge ahead 




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Morning run, nutritious meals and unwinding

Prioritise mornings with running, balanced diet, revitalizing workouts and meditation for mental health, says Nishant Pitti, CEO and Co-Founder, EaseMyTrip




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Is health on your manifesto this election?

Vote for health: As India approaches election season, will health reforms become a rallying point?




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Private capital, a catalyst to Universal Health Coverage

India is committed to achieving Universal Health Coverage (UHC) for all by 2030. For India to achieve thisUHC, it is essential that both private enterprises and the government come together.




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Tennis, yoga and unwinding with a book

Ritesh Kumar’s daily routine includes yoga, a plant-based diet, contemplation, tennis, and unwinding with a good book.




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Redefining the regulatory pathway for nutraceutical and pharmaceutical products

As the nutraceutical landscape grows, experts call for clarity in the manufacturing debate




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Runing, cycling & a ‘colourful’ meal

Maya Nair, Executive Director of Elixir Consulting, on her fitness regimen, diet and love for table tennis




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Reviewing TRIPS, an opportunity for evidence-based policies

Colombia calls for review of TRIPS Agreement implementation, highlighting need for evidence-based IP law and policy




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Clinical trial waiver, a step to improve patient access, in need of guardrails

Experts call for ensuring patient safety while expanding access to new drugs




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Mindful eating, short walks and melatonin window of sleep

Founder & CEO, Khyaal, Hemanshu Jain, on his exercise routine, practising mindful eating and more.




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Companies harness pester-power to boost sales



  • Bindu D Menon

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UPL recognised as top patent applicant in agro-chemical research

This recognition comes from the Global Innovation Index (GII) 2024, which annually ranks the world’s economies based on their innovation capabilities




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Ninjacart pares losses to ₹259 cr for fiscal 2024

Operating revenues up 74 per cent % at Rs ₹2002 cr on volume growth




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6 weather models point to La Nina not emerging during Nov-Feb, says Australia’s BoM

IOD negative conditions likely by November, but may turn neutral by December