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UN COP29 climate summit: What is a carbon credit? What is Article 6 of the Paris Agreement?

Officials are keen to secure an early "win" on Article 6 at this year's climate conference in Azerbaijan




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PSG moves 6 points clear at top of French league after beating Lens 1-0

Barcola has been PSG's best attacking player this season. Near the end of the first half, he played a through ball to Marco Asensio but goalkeeper Brice Samba saved his angled shot.




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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02469A, Paper
Zhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei Qin
Heteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.
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Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02396J, Paper
Chuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo Peng
Zinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.
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Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02634A, Perspective
Mateusz Klarek, Konrad Kowalski
Article summarizes over 12 years of studies on organometallic nucleic acid components in our laboratory. It outlines synthetic chemistry, redox, photophysical and biological properties alike. It also shows directions for future development.
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Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02514H, Paper
Khalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique Lorcy
Multinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.
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One-pot facile synthesis of rod-like Bi2S3 particles in deep eutectic solvent and their ppb-level selective H2S gas detection

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT03006K, Communication
Reiko Furukawa, Takuya Hasegawa, Ayahisa Okawa, Shu Yin
Rod-like Bi2S3 particles were synthesized by one-pot reactions with choline chloride-based DESs, and showed sub-ppm level selective H2S gas detection. Acetamide-based DES yielded uniform particles with excellent gas sensitivity.
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Effect of mono- and dinuclear thiosemicarbazone platinacycles in the proliferation of a colorectal carcinoma cell line

Dalton Trans., 2024, 53,17803-17818
DOI: 10.1039/D4DT01490A, Paper
Open Access
Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes, José M. Vila
The study of the antiproliferative activity of thiosemicarbazone platinacycles puts forward their high selectivity and low IC50 values.
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Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction

Dalton Trans., 2024, 53,17772-17776
DOI: 10.1039/D4DT02595D, Communication
Zaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi Yi
Neutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
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Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction

Dalton Trans., 2024, 53,17789-17793
DOI: 10.1039/D4DT02791D, Communication
Gargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. Sen
The reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Freewheeling exploration with a bicycle

The machine was a precious possession, a symbol of hard work and determination




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Tunga Aarati held in Shivamogga as part of campaign to clean river Tungabhadra

Shivamogga MLA S.N. Channabasappa appreciated the efforts of people and students involved in the padayatra from Sringeri to Harihar as part of a campaign to keep the river clean




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Morning Digest: NSCN-IM threatens armed violence for first time since 2015 agreement; Article 370 cannot be restored by anyone, says PM Modi, and more

Here is a select list of stories to start the day




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Polyphosphazene-based hyper crosslinked polymers for efficient uranium ion removal from nuclear wastewater

Environ. Sci.: Water Res. Technol., 2024, 10,2961-2980
DOI: 10.1039/D4EW00614C, Paper
Rimsha Khalid, Isham Areej, Faiza Ashraf, Saqlain Raza, Amin Abid, Tayyab Ahsan, Bien Tan
This study focuses on the removal of uranium ions from nuclear wastewater by fabricating inorganic–organic hybrid cyclic and linear polyphosphazene based polymers.
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Ultrafiltration behavior of CuO particles synthesized without and with different surfactants using PAN and PES membranes

Environ. Sci.: Water Res. Technol., 2024, 10,2981-2996
DOI: 10.1039/D4EW00462K, Paper
Olabimpe Genevieve Badru, Ime Akanyeti
Four different CuO particles were synthesized, with no surfactant (CuO/NS) and with three surfactants: Triton X-100 (CuO/TX100), cetyltrimethylammonium bromide (CuO/CTAB) and sodium dodecyl sulfate (CuO/SDS).
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L&T bags 'significant' order for global nuclear fusion project

The company classifies a 'significant order' as orders valued between ₹1,000 crore and ₹2,500 crore




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Food delivery agents and dependents find it hard to get insurance claims cleared

Food delivery agent and their dependents have been finding it increasingly hard to get insurance claims for injuries or death caused by accidents or other reasons




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BBS Trust Circle / NewsHour Productions LLC

[Place of publication not identified] : NewsHour Productions LLC, [2024]




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Families Battle In Maharashtra: Husband Vs Wife, Uncle Vs Nephew - Key Contests To Watch Out For

Maharashtra Election 2024: Voting for the 288 legislative assembly seat will take place on November 20.




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GoM decides to cut GST on 20-litre water bottles, bicycles to 5%; raise rate on shoes, watches

The Group of Ministers on GST rate on life and health insurance decided to exempt GST on premiums paid for health insurance with coverage of ₹5 lakh for individuals other than senior citizens; final decision to be taken by the GST Council




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IIT Madras partners with ISRO to establish Research Centre to study Spacecraft & launch vehicle Thermal Management

This ‘Centre of Excellence in the area of Fluid and Thermal Sciences’ will be the Nodal Centre to study Thermal problems regarding design, analysis and testing of various components




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India will ‘commission a nuclear power reactor every year’: NPCIL chief

An interview with B.C. Pathak on India’s nuclear power plans and strategy




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WATCH | Electoral bond not poll issue; people understand intent was to ensure clean money coming to politics: Tejasvi Surya



  • Lok Sabha Elections

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Turnout in Srinagar shows it was right to revoke Article 370: Amit Shah

37% polling in Srinagar ‘greatest testament to rightness of the decision’, the Union Home Minister says; there is no doubt that the NDA is on its way to 400-plus seats, he adds; says that his party has no history of misusing a majority, and it was a Congress government that had imposed the Emergency and made changes to the Constitution



  • Lok Sabha Elections

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A high-entropy cathode catalyst with multiphase catalytic capability of Li2O2 and Li2CO3 enabling ultralong cycle life in Li–air batteries

Energy Environ. Sci., 2024, 17,8198-8208
DOI: 10.1039/D4EE02817A, Paper
Xia Li, Guoliang Zhang, Dongmei Zhang, Ruonan Yang, Han Yu, Xiuqi Zhang, Gang Lian, Hua Hou, Zhanhu Guo, Chuanxin Hou, Xiaoyang Yang, Feng Dang
High entropy design guidance enables a modulated broad d-band of cathode catalyst with efficient d–p coupling for all reactants, realizing multiphasic catalytic capability of Li2O2 and Li2CO3 and ultralong cycle life in Li–air and Li–CO2 batteries.
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Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03156C, Review Article
Laiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu, Shi Xue Dou
As a self-sustaining cycle, the electrocatalytic nitrogen cycle represents an avenue for rectifying the nitrogen imbalance and for synthesizing value-added chemicals, thereby contributing to a sustainable and carbon-neutral society.
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Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
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A Review on Organic Nanoparticle-based Optoelectronic Devices: From Synthesis to Applications

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03575E, Review Article
Zhe Liu, Chen Xie, Thomas Heumueller, Iain McCulloch, Christoph J Brabec, Fei Huang, Yong Cao, Ning Li
Over the past decades, organic optoelectronic devices have shown broad application prospects. Due to the solubility property of organic materials, the use of toxic solvent obstacles the device fabrication processing...
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Staying cool, but with clean tech, global collaborations

International cooperation on clean energy and cooling solutions is another crucial step in addressing the climate crisis




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The Musi’s clean-up: On Hyderabad’s river plan




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Palladium particle-catalyzed selective butadiene hydrogenation: effect of covalent organic framework modification

React. Chem. Eng., 2024, 9,950-958
DOI: 10.1039/D3RE00606A, Paper
Xianming Li, Yi Wang, Qiao Yuan, Xintai Chen, Xiaoling Mou, Xiangen Song, Li Yan, Ronghe Lin, Yunjie Ding
Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.
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Encapsulation of TixFeyLamOz nanoparticles into NH2-MIL-125(Ti) to fabricate a promising photocatalyst for the C–N coupling reaction

React. Chem. Eng., 2024, 9,849-860
DOI: 10.1039/D3RE00457K, Paper
Yahya Absalan, Mohammad Rafsanjani Dehghazi, Reza Samavati, Kambiz Souri, Mostafa Gholizadeh
An array of organic compounds and natural products can be synthesized through carbon–nitrogen coupling reactions.
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Selective aerobic oxidative C–C bond cleavage using a high-entropy oxide-derived multimetallic catalyst

React. Chem. Eng., 2024, 9,967-973
DOI: 10.1039/D3RE00525A, Paper
Shaoyuan Guo, Xinli Tong, Jipeng Wang, Hang Tang
A stable and efficient high entropy catalyst is developed for the selective oxidative C–C bond cleavage in the presence of O2.
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Surface treatment of magnetite nanoparticle thin films with potassium phosphate for calcium phosphate precipitation

React. Chem. Eng., 2024, 9,782-786
DOI: 10.1039/D4RE00048J, Communication
Reo Kimura, Kazuto Sugimoto, Iori Yamada, Motohiro Tagaya
The treatment of magnetite nanoparticle thin films with potassium phosphate and their surface reaction with simulated body fluid were in situ monitored by the QCM-D technique, which is suitable for the precipitation of calcium phosphate.
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High-efficiency non-thermal plasma synthesis of imine macrocycles

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00061G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Patrycja Roszkowska, Abbie M. Scholes, James L. Walsh, Timothy L. Easun, Anna G. Slater
Non-thermal plasma synthesis offers efficient access to imine macrocycles.
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Scaling-up continuous production of mesoporous silica particles at kg scale: design & operational strategies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00707C, Paper
Rajashri B. Jundale, Jayesh R. Sonawane, Anil V. Palghadmal, Hemant Kumar Jaiswal, Hital S. Deore, Amol A. Kulkarni
This paper demonstrates a continuous flow pilot-scale production of highly porous mesoporous silica particles (MSPs) via a soft template based technique.
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Miracle herbs in your garden

It takes very little effort to plant your own little herb garden at home




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Dietary Lactobacillus johnsonii-derived extracellular vesicles ameliorate acute colitis by regulating gut microbiota and maintaining intestinal barrier homeostasis

Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO04194A, Paper
Zhiguo Li, Mengyu Li, Xuexun Fang, Dahai Yu, Xin Hu
Inflammatory bowel disease (IBD) is a chronic gastrointestinal disease with intricate pathogenesis, and clinical treatment is still not ideal. The imbalance of gut microbiota is associated with IBD progression. Various...
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Goat milk derived small extracellular vesicles ameliorate LPS-induced intestinal epithelial barrier dysfunction, oxidative stress, and apoptosis by inhibiting the MAPK signaling pathway

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO04067H, Paper
Feng Gao, Xin Zhang, Zhiming Xu, Kang Zhang, Fusheng Quan
Intestinal injury is often accompanied by epithelial barrier dysfunction, oxidative stress, and apoptosis.
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Selenium-mediated alleviation of skeletal muscle atrophy through enterotype modulation in mice

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03889D, Paper
Yixin Cheng, Xiaofan Liu, Yingao Hao, Shixu Wang, FangFang Wu, Lingzhuo Zhao, Du Peng, Du Yawen, Sun Sheng, Li Jianguo, Guangxu Ren
Selenium element improves dexamethasone-induced skeletal muscle atrophy by affecting enterotype.
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Exosome-like nanoparticles from Arbutus unedo L. mitigate LPS-induced inflammation via JAK-STAT inactivation

Food Funct., 2024, 15,11280-11290
DOI: 10.1039/D4FO03646H, Paper
Cristian Martínez Fajardo, Lucía Morote, Elena Moreno-Giménez, Susana López-López, Ángela Rubio-Moraga, María José M. Díaz-Guerra, Gianfranco Diretto, Alberto J. López Jiménez, Oussama Ahrazem, Lourdes Gómez-Gómez
Exosomes have garnered attention as a potential cell-free therapy for inflammatory diseases due to their immunomodulatory and anti-inflammatory properties.
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Advances in plant-derived extracellular vesicles: isolation, composition, and biological functions

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO04321A, Review Article
Yao-Bo Zeng, Xun Deng, Li-Sha Shen, Yong Yang, Xing Zhou, Lianbao Ye, Sibao Chen, Da-Jian Yang, Guo-Qing Chen
Plant-derived extracellular vesicles (PDEVs) are nanoscale vesicles released from plant cells into the extracellular space.
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GST circulars should be clear and easy to understand

This will smoothen the assessment process and reduce the piling up of appeals at the Tribunals




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Article 370 Review

Article 370 is not as crude as some of the openly propagandist films made in recent times. It could at least open up a discussion on what is to be done to heal the wounds of the people of Kashmir, which years of shrieking TV debaters could not do, feels Deepa Gahlot.




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Will demolish all obstacles preventing people from all castes from becoming priests: CM