pti

Layer-by-layer assembly of homopolypeptide polyelectrolytes on asymmetric nanochannels for the detection of nickel ions

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00422A, Paper
Pengrong An, Jincan Yang, Tianming Wang, Saiwen Lu, Dehao Wang, Zhuoyue Wang, Chun-Lin Sun, Chuanguang Qin, Jun Li
We report PA-γ-PGA-modified asymmetric nanochannels that enable ultra-sensitive detection of Ni2+ (limit of detection is 1 × 10−8 M).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

A simple and rapid colorimetric detection of Staphylococcus Aureus relied on the distance-dependent optical properties of silver nanoparticles

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D3AY02189K, Paper
Ngoc Anh Thu Phan, Hoang Men Nguyen, Cam Duyen Thi Vo, Toi Vo Van, Phuoc Long Truong
The quick and accurate diagnosis of pathogens has appeared as a pressing issue in clinical diagnostics, environmental monitoring, and food safety. The current assays are suffering from limited capacities in...
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Growth prescription: On the latest World Economic Outlook 

The IMF’s ‘mediocre’ medium-term outlook merits policy attention




pti

Lead optimisation of OXS007417: in vivo PK profile and hERG liability modulation to optimise a small molecule differentiation agent for the potential treatment of acute myeloid leukaemia

RSC Med. Chem., 2024, 15,3495-3506
DOI: 10.1039/D4MD00275J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas J. Cogswell, Laia Josa-Culleré, David Zimmer, Sébastien R. G. Galan, Morgan Jay-Smith, Kate S. Harris, Carole J. R. Bataille, Thomas R. Jackson, Douzi Zhang, Stephen G. Davies, Paresh Vyas, Thomas A. Milne, Graham M. Wynne, Angela J. Russell
The optimisation of a class of AML differentiation agents is described to show improved potency, solubility and stability, reduced off target toxicity, and tumour regression in a murine model in vivo.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Discovery and optimisation of pyrazolo[1,5-a]pyrimidines as aryl hydrocarbon receptor antagonists

RSC Med. Chem., 2024, 15,3477-3484
DOI: 10.1039/D4MD00266K, Research Article
Raitis Bobrovs, Svetlana Terentjeva, Ninni Elise Olafsen, Zilvinas Dambrauskas, Antanas Gulbinas, Toivo Maimets, Indrek Teino, Aigars Jirgensons, Jason Matthews, Kristaps Jaudzems
The aryl hydrocarbon receptor (AHR) is a versatile ligand-dependent transcription factor involved in diverse biological processes, from metabolic adaptations to immune system regulation.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Human microbiome derived synthetic antimicrobial peptides with activity against Gram-negative, Gram-positive, and antibiotic resistant bacteria

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00383G, Research Article
Open Access
Walaa K. Mousa, Ashif Y. Shaikh, Rose Ghemrawi, Mohammed Aldulaimi, Aya Al Ali, Nour Sammani, Mostafa Khair, Mohamed I. Helal, Farah Al-Marzooq, Emilia Oueis
An AMP-derived short 15-mer peptide and its cyclic derivatives have low micromolar broad spectrum antibacterial activity, with rapid onset of bactericidal effect and a membrane-targeting mode of action.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Amides of moronic acid and morolic acid with the tripeptides MAG and GAM targeting antimicrobial, antiviral and cytotoxic effects

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00742E, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Uladzimir Bildziukevich, Lucie Cerna, Jana Trylčová, Marie Kvasnicova, Lucie Rárová, David Šaman, Petra Lovecká, Jan Weber, Zdenek Wimmer
A series of amides of the selected plant triterpenoids, moronic acid and morolic acid, with the tripeptides MAG and GAM was designed and synthesized. Two required tripeptides 5 and 10...
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

A novel approach for the synthesis of the cyclic lipopeptide globomycin

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00685B, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Samantha J. Bann, Stephen A. Cochrane
Lipid swapping: a new approach for the synthesis of globomycin that allows for facile lipid diversification.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Synthesis of cationic N-acylated thiazolidine for selective activity against Gram-positive bacteria and evaluation of N-acylation's role in membrane-disrupting activity

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00626G, Research Article
Aleena Pious, Vignesh Venkatasubramanian, Dharshini Karnan Singaravelu, Subburethinam Ramesh, Fuad Ameen, Anbazhagan Veerappan
Lipidation modulates the Gram-selective antibacterial activity of QPyNATh.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Property-based optimisation of PROTACs

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00769G, Opinion
James Scott, Iacovos Michaelides, Markus Schade
PROTACs are an emerging therapeutic approach towards targeted protein degradation. This article examines the leading examples of this modality that are in clinical development through the prism of their physicochemical...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Association holds protest against delay in Anna University’s staff absorption, promotions




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Can Chennai change its energy consumption patterns?

In creating energy-efficient cities, India will do well to model its development on its own age-old techniques, says Durganand Balsavar




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Options for hot water

Energy consumed in heating water may not appear like a major problem, compared to industries, but thousands of homes each with 2 or 3 heaters may surpass many industries in energy consumption.




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Why power from Sri Lanka is a better option than offshore wind

Wind industry sources estimate island nation has 65 GW onshore potential




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ARRL VEC Services Update During Systems Disruption

Updated 10/30/2024

ARRL previously reported that we are responding to a serious incident involving access to our network and headquarters-based systems. Several services have been affected, including those administered by the ARRL Volunteer Examiner Coordinator (ARRL VEC).

Exam Registrations and Materials. ARRL Volunteer Examiners (VEs) should continue to submit exam registrations and material re...




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2025 ARRL Foundation Scholarship Program Accepting Applications through Jan 6, 2025

The 2025 ARRL Foundation Scholarship Program will begin accepting applications on October 30, 2024. Applications will be accepted through January 6, 2025.

More than 100 scholarships ranging from $500 to $25,000 will be awarded. All applicants must be active, FCC-licensed amateur radio operators. 

Information, along with the link to the online application, can be found on ARRL’s website: https://w...




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Policy prescription for economic and political maladies

Bimal Jalan delves deep into issues that are critical to the country with suggestions on how to overcome challenges 




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SEBI issues norms for MFs’ redemption curbs




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By 2021, India to have 810 m smartphone subscriptions




pti

A macroscopic magneto-optical response resulting from local effects in ferronematic liquid crystals

Soft Matter, 2024, 20,8363-8372
DOI: 10.1039/D4SM00577E, Paper
Xiangshen Meng, Xiaowei Li, Jian Li, Yueqiang Lin, Xiaodong Liu, Zhenghong He
The dynamic rotational behavior of composite chains under a rotating magnetic field was observed. The birefringence and dichroism variations in FNLCs mainly stem from the magnetic response of the composite chains, indicating local effects.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Optimality and cooperativity in superselective surface binding by multivalent DNA nanostars

Soft Matter, 2024, 20,8515-8523
DOI: 10.1039/D4SM00704B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Linne, Eva Heemskerk, Jos W. Zwanikken, Daniela J. Kraft, Liedewij Laan
Our study shows that DNA nanostars with three binding sites (ligands) can (1) bind superselectively to surfaces based on receptor density, and (2) that interactions between ligands affect the optimum number of ligands required for superselectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Banana DNA derivatives as homeotropic alignment layers in optical devices

Soft Matter, 2024, 20,8561-8569
DOI: 10.1039/D4SM00322E, Paper
Rafał Węgłowski, Anna Spadło, Dorota Węgłowska
In this study, DNA extracted from bananas was functionalized and used as a homeotropic alignment layer for liquid crystals.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Tuning collective actuation of active solids by optimizing activity localization

Soft Matter, 2024, 20,8570-8580
DOI: 10.1039/D4SM00868E, Paper
Davi Lazzari, Olivier Dauchot, Carolina Brito
Active solids, more specifically elastic lattices embedded with polar active units, exhibit collective actuation when the elasto-active feedback, generically present in such systems, exceeds some critical value.
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Supramolecular chiroptical sensing of chiral species based on circularly polarized luminescence

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00960F, Review Article
Panyang Chen, Huahua Fan, Sifan Du, Xin Wen, Li Zhang, Minghua Liu
Chiral analytes can bind to an achiral fluorescent system to generate circularly polarized luminescence (CPL). Subsequently, the CPL signal can be employed to determine the absolute configuration of the chiral substrate.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Shape transformations in peptide-DNA coacervates driven by enzyme-catalyzed deacetylation

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM01091D, Paper
Open Access
Merlijn van Haren, Nienke Helmers, Luuk Verploegen, Viveca Beckers, Evan Spruijt
Biomolecular condensates formed by liquid-liquid phase separation (LLPS) are important organizers of biochemistry in living cells. Condensate formation can be dynamically regulated, for example by protein binding or enzymatic processes....
The content of this RSS Feed (c) The Royal Society of Chemistry




pti

Flexible Captioned Slanted Images

Eric Meyer gift wraps the most awkwardly shaped of boxes using nothing but CSS, HTML and a little curl of ribbon. No matter how well you plan and how much paper you have at your disposal, sometimes you just need to slant the gift to the side.


We have a lot of new layout tools at our disposal these days—flexbox is finally stable and interoperable, and Grid very much the same, with both technologies having well over 90% support coverage. In that light, we might think there’s no place for old tricks like negative margins, but I recently discovered otherwise.

Over at An Event Apart, we’ve been updating some of our landing pages, and our designer thought it would be interesting to have slanted images of speakers at the tops of pages. The end result looks like this.

The interesting part is the images. I wanted to set up a structure like the following, so that it will be easy to change speakers from time to time while preserving accessible content structures:

<div id="page-top">
  <ul class="monoliths">
    <li>
      <a href="https://aneventapart.com/speakers/rachel-andrew"> 
        <img src="/img/rachel-andrew.jpg" alt=""> 
        <div> 
          <strong>Rachel Andrew</strong> CSS Grid 
        </div> 
      </a>
    </li>
    <li>
      <a href="https://aneventapart.com/speakers/derek-featherstone"> 
        <img src="/img/derek-featherstone.jpg" alt=""> 
        <div> 
          <strong>Derek Featherstone</strong> Accessibility 
        </div> 
      </a>
    </li>
    <li>
      …
    </li>
    <li>
      …
    </li>
  </ul>
</div>

The id value for the div is straightforward enough, and I called the ul element monoliths because it reminded me of the memorial monoliths at the entrance to EPCOT in Florida. I’m also taking advantage of the now-ubiquitous ability to wrap multiple elements, including block elements, in a hyperlink. That way I can shove the image and text structures in there, and make the entire image and text below it one link.

Structure is easy, though. Can we make that layout fully responsive? I wondered. Yes we can. Here’s the target layout, stripped of the navbar and promo copy.

So let’s start from the beginning. The div gets some color and text styling, and the monoliths list is set to flex. The images are in a single line, after all, and I want them to be flexible for responsive reasons, so flexbox is 100% the right tool for this particular job.

#page-top { 
  background: #000; 
  color: #FFF; 
  line-height: 1; 
} 
#page-top .monoliths { 
  display: flex; 
  padding-bottom: 1em; 
  overflow: hidden; 
}

I also figured, let’s give the images a simple basis for sizing, and set up the hyperlink while we’re at it.

#page-top .monoliths li { 
  width: 25%; 
} 
#page-top .monoliths a { 
  color: inherit; 
  text-decoration: inherit; 
  display: block; 
  padding: 1px; 
}

So now the list items are 25% wide—I can say that because I know there will be four of them—and the links pick up the foreground color from their parent element. They’re also set to generate a block box.

At this point, I could concentrate on the images. They need to be as wide as their parent element, but no wider, and also match height. While I was at it, I figured I’d create a little bit of space above and below the captioning text, and make the strong elements containing speakers’ names generate a block box.

#page-top .monoliths img { 
  display: block; 
  height: 33rem; 
  width: 100%; 
} 
#page-top .monoliths div { 
  padding: 0.5em 0; 
} 
#page-top .monoliths strong { 
  display: block; 
  font-weight: 900; 
}

It looks like the speakers were all cast into the Phantom Zone or something, so that needs to be fixed. I can’t physically crop the images to be the “correct” size, because there is no correct size: this needs to work across all screen widths. So rather than try to swap carefully-sized images in and out at various breakpoints, or complicate the structure with a wrapper element set to suppress overflow of resized images, I turned to object-fit.

#page-top .monoliths img { 
  display: block; 
  height: 33rem; 
  width: 100%; 
  object-fit: cover; 
  object-position: 50% 20%; 
}

If you’ve never used object-fit, it’s a bit like background-size. You can use it to resize image content within the image’s element box without creating distortions. Here, I set the fit sizing to cover, which means all of the img element’s element box will be covered by image content. In this case, it’s like zooming in on the image content. I also set a zooming origin with object-position, figuring that 50% across and 20% down would be in the vicinity of a speaker’s face, given the way pictures of people are usually taken.

This is fairly presentable as-is—a little basic, perhaps, but it would be fine to layer the navbar and promo copy back over it with Grid or whatever, and call it a day. But it’s too square and boxy. We must go further!

To make that happen, I’m going to take out the third and fourth images temporarily, so we can see more clearly how the next part works. That will leave us with Rachel and Derek.

The idea here is to clip the images to be slanted, and then pull them close to each other so they have just a little space between them. The first part is managed with clip-path, but we don’t want to pull the images together unless their shapes are being clipped. So we set up a feature query.

@supports (clip-path: polygon(0 0)) or (-webkit-clip-path: polygon(0 0)) { 
  #page-top .monoliths li { 
    width: 37.5%; 
  } 
}

I decided to test for both the un-prefixed and WebKit-prefixed versions of clip-path because Safari still requires the prefix, and I couldn’t think of a good reason to penalize Safari’s users for the slowness of its standards advancement. Then I made the images wider, taking them from 25% to 37.5%, which makes them half again as wide.

Thanks to object fitting, the images don’t distort when I change their parent’s width; they just get wider and scale up the contents to fit. And now, it is time for clipping!

@supports (clip-path: polygon(0 0)) or (-webkit-clip-path: polygon(0 0)) { 
  #page-top .monoliths li { 
    width: 37.5%; 
    -webkit-clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
    clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
  } 
}

Each coordinate pair in the polygon() is like the position pairs in background-position or object-position: the horizontal distance first, followed by the vertical distance. So the first point in the polygon is 25% 0, which is 25% of the way across the element box, and no distance down, so right at the top edge. 100% 0 is the top right corner. 75% 100% is on the bottom edge, three-quarters of the way across the element, and 0 100% is the bottom left corner. That creates a polygon that’s a strip three-quarters the full width of the element box, and runs from bottom left to top right.

Now we just have to pull them together, and this is where old tricks come back into play: all we need is a negative right margin to bring them closer together.

#page-top .monoliths li { 
  width: 37.5%; 
  margin-right: -7.5%; 
  -webkit-clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
  clip-path: polygon(25% 0, 100% 0, 75% 100%, 0 100%); 
}

The separation between them is a little wider than we were originally aiming for, but let’s see what happens when we add the other two images back in and let flexbox do its resizing magic.

Notice how the slants actually change shape as the screen gets narrower or wider. This is because they’re still three-quarters the width of the image element’s box, but the width of that box is changing as the screen width changes. That means at narrow widths, the slant is much steeper, whereas at wide widths, the slant is more shallow. But since the clipping path’s coordinates were all set with percentage distances, they all stay parallel to each other while being completely responsive to changes in screen size. An absolute measure like pixels would have failed.

But how did the images get closer together just by adding in two more? Because the list items’ basic sizing added up to more than 100%, and they’re all set to flex-shrink: 1. No, you didn’t miss a line in the CSS: 1 is the default value for flex-shrink. Flex items will shrink by default, which after all is what we should expect from a flexible element. If you want to know how much they shrunk, and why, here’s what Firefox’s flex inspector reports.

When there were only two list items, there was space enough for both to be at their base size, with no shrinkage. Once we went to four list items, there wasn’t enough space, so they all shrank down. At that point, having a negative right margin of -7.5% was just right to pull them together to act as a unit.

So, now they’re all nicely nestled together, and fully responsive! The captions need a little work, though. Notice how they’re clipped off a bit on the left edge, and can be very much clipped off on the right side at narrower screen widths? This happens because the li elements are being clipped, and that clipping applies to all their contents, images and text alike. And we can’t use overflow to alter this: clipped is clipped, not overflowed.

Fortunately, all we really need to do is push the text over a small amount. Inside the feature query, I added:

#page-top .monoliths div { 
  padding-left: 2%;
  padding-right: 26%; 
}

This shifts the text just a bit rightward, enough to clear the clip path. On the right side, I padded the div boxes so their contents wouldn’t fall outside the clipped area and appear to slide under the next caption. We could also use margins here, but I didn’t for reasons I’ll make clear at the end.

At the last minute, I decided to make the text at least appear to follow the slants of the images. For that, I just needed to shift the first line over a bit, which I did with a bit more padding.

#page-top .monoliths strong { 
  padding-left: 1%; 
}

That’s all to the good, but you may have noticed the captions still overlap at really narrow screen widths. There are a lot of options here, from stacking the images atop one another to reverting to normal flow, but I decided to just hide the captions if things got too narrow. It reduces clutter without sacrificing too much in the way of content, and by leaving them still technically visible, they seem to remain accessible.

@media (max-width: 35rem) { 
  #page-top .monoliths div { 
    opacity: 0.01 
  } 
}

And that, as they say, is that! Fully responsive slanted images with text, in an accessible markup structure. I dig it.

I did fiddle around with the separations a bit, and found that a nice thin separator occurred around margin-right: -8%, whereas beefier ones could be found above -7%. And if you crank the negative margin value to something beyond -8%, you’ll make the images overlap entirely, no visible separation—which can be a useful effect in its own right.

I promised to say why I used padding for the caption text div rather than margins. Here’s why.

#page-top .monoliths div { 
  padding-left: 3%; 
  padding-right: 26%; 
  border-top: 2px solid transparent; 
  background: linear-gradient(100deg,hsl(292deg,50%,50%) 50%, transparent 85%); 
  background-clip: padding-box; 
}

It required a wee bit more padding on the left to look decent, and an alteration to the background clipping box in order to keep the purple from filling the transparent border area, but the end result is pretty nifty, if I do say so myself. Alternatively, we could drop the background gradient on the captions and put one in the background, with a result like this.

I have no doubt this technique could be extended, made more powerful, and generally improved upon. I really wished for subgrid support in Chrome, so that I could put everything on a grid without having to tear the markup structure apart, and there are doubtless even more interesting clipping paths and layout patterns to try out.

I hope these few ideas spark some much better ideas in you, and that you’ll share them with us!


About the author

Eric A. Meyer (@meyerweb) has been a burger flipper, a college webmaster, an early blogger, one of the original CSS Samurai, a member of the CSS Working Group, a consultant and trainer, and a Standards Evangelist for Netscape. Among other things, Eric co-wrote Design For Real Life with Sara Wachter-Boettcher for A Book Apart and CSS: The Definitive Guide with Estelle Weyl for O’Reilly, created the first official W3C test suite, assisted in the creation of microformats, and co-founded An Event Apart with Jeffrey Zeldman. Eric lives with his family in Cleveland, Ohio, which is a much nicer city than you’ve probably heard. He enjoys a good meal whenever he can and considers almost every form of music to be worthwhile.

More articles by Eric




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Sculpting muscles and dreams

Mr.Madurai contest has been shaping the ideals and aspirations of city body builders. A.SHRIKUMAR takes a peek into what goes on behind the stage




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Editorial. Right option

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Maharashtra elections 2024: Shinde-led Mahayuti government perceived as high on corruption, not bad on performance

Two in five (42%) voters believed that corruption had increased under the Mahayuti government.




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Visible-light mediated selective phosphonylation modification of tryptophan residues in oligopeptides

Org. Chem. Front., 2024, 11,6287-6292
DOI: 10.1039/D4QO01028K, Research Article
Wenfang Xiong, Junye He, Jinyao Liu, Peiru Chen, Shiqi Xu, Yipeng Liu, Shiting Chen, Yuanyuan You, Zhenyu Chen, Jinwu Zhao
A direct C2-H phosphonylation strategy driven by visible light for specific modification of tryptophan-containing peptides has been reported, providing a plethora of phosphorylated tryptophan-containing peptides
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pd-catalyzed S-glycosylation of cysteine-containing peptides at room temperature

Org. Chem. Front., 2024, 11,6347-6352
DOI: 10.1039/D4QO01389A, Research Article
Linhua Shen, Franck Le Bideau, Gong Chen, Samir Messaoudi
This study reports the synthesis of thioglycopeptides via a Pd-catalyzed coupling of cysteine-containing peptides with iodoglycals. A variety of cysteine-containing peptides and other thiol nucleophiles including thiosugars and thiophenols were used.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01832J, Research Article
Open Access
Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh Hariharan
Achieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Man, friend killed in car-bus collision after attending sister’s wedding reception




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Career options in stem cell research

The field of stem cell research offers lucrative career options for people looking for something different in the field of medical science.




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Correction: Sustainable polymeric adsorbents for adsorption-based water remediation and pathogen deactivation: a review

RSC Adv., 2024, 14,35104-35104
DOI: 10.1039/D4RA90129K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huda Alkhaldi, Sarah Alharthi, Salha Alharthi, Hind A. AlGhamdi, Yasmeen M. AlZahrani, Safwat A. Mahmoud, Lamiaa Galal Amin, Nora Hamad Al-Shaalan, Waleed E. Boraie, Mohamed S. Attia, Samera Ali Al-Gahtany, Nadiah Aldaleeli, Mohamed Mohamady Ghobashy, A. I. Sharshir, Mohamed Madani, Reem Darwesh, Sana F. Abaza
The content of this RSS Feed (c) The Royal Society of Chemistry




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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
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Surface science studies of the coverage dependent adsorption of methyl acetate and methyl propanoate on graphite

RSC Adv., 2024, 14,35373-35385
DOI: 10.1039/D4RA04466E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jack E. Fulker, Wendy A. Brown
The adsorption of methyl acetate and methyl propanoate has been studied on a graphite surface at 28 K. TPD data show that the desorption energy of both molecules is highly coverage dependent with repulsive interactions being seen at low coverages.
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Assessment of optimized FRET substrates as universal corona- and picornavirus main protease substrates for screening assays

RSC Adv., 2024, 14,35438-35446
DOI: 10.1039/D4RA06573E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Conrad Fischer, Tayla J. Van Oers, Marco J. van Belkum, Tess Lamer, Aaron Romney, Pu Chen, M. Joanne Lemieux, John C. Vederas
A short FRET peptide was identified as a universal substrate for selected coronavirus Mpros. Kinetic parameters, buffer stability and Z'-assay suggest this substrate as an excellent target for CoV-Mpro HT inhibitor screening assay development.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis, optical, electrochemical, and computational study of benzene/thiophene based D–π–A chromophores

RSC Adv., 2024, 14,35424-35437
DOI: 10.1039/D4RA02668C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michaela Babejová, Iveta Třísková, Libuše Trnková, Hugo Semrád, Markéta Munzarová, Dominik Heger, Dana Nachtigallová, Milan Potáček
Synthesis of novel (D–π–A) chromophores with one electron-donating + withdrawing group at opposite ends of terphenyl, terthiophene, or 2,5-diphenylthiophene, analysed upon results of HOMO–LUMO gaps, determined via CV and in terms of MO via DFT.
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Correction: Luminescence properties of Bi3+/Sm3+ co-doped K3Gd5(PO4)6 phosphors for self-referencing optical thermometry

RSC Adv., 2024, 14,35447-35447
DOI: 10.1039/D4RA90130D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jing Wang, Mingjun Song, Junpeng Xue, Shala Bi, Hyo Jin Seo
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Comparing diverse extraction methodologies to infer the performance of 1,8-cineole extraction from Eucalyptus cinerea: process optimization, kinetics, and interaction mechanisms

RSC Adv., 2024, 14,35529-35552
DOI: 10.1039/D4RA06050D, Paper
Open Access
Divya Baskaran, Madhumitha Sathiamoorthy, Ramasamy Govindarasu, Hun-Soo Byun
Different extraction techniques were used to extract 1,8-cineole from Eucalyptus cinerea leaves, and their performance efficiency was evaluated through optimization and kinetic studies.
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Statistically driven automated method for catalytic glucose conversion optimisation

RSC Adv., 2024, 14,35578-35584
DOI: 10.1039/D4RA06038E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joseph Install, Rui Zhang, Jukka Hietala, Timo Repo
A statistically driven, automated approach to optimize glucose transformations to platform chemicals, methyl lactate and levulinic acid, is reported.
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Syntheses of optically active monapterin, 7,8-dihydromonapterin, and 5,6,7,8-tetrahydromonapterin from L-xylose

RSC Adv., 2024, 14,35644-35649
DOI: 10.1039/D4RA07179D, Paper
Open Access
Arun K. Ghosh, Ashish Sharma, Satish Nagam, Clay Fuqua
Monapterin, 7,8-dihydromonapterin, and 5,6,7,8-tetrahydromonapterin are synthesized in optically active forms using L-xylose as the starting material.
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Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
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Porous, environment-friendly chitosan-ZIF composite fibers for dye adsorption

RSC Adv., 2024, 14,36063-36072
DOI: 10.1039/D4RA06883A, Paper
Open Access
Xuebin Hou, Wei Chen, Meihong Fan, Chen Shi
Porous, environment friendly ZIF-8@CS composite fibers were fabricated through wet spinning and self-assembly method, which effectively remove dyes from water and exhibit excellent recyclability.
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Developing Ni0.5Zn0.5Fe2O4 ferrite with controlled particle size and morphology through optimized processing conditions of low energy solid state reaction

RSC Adv., 2024, 14,36264-36272
DOI: 10.1039/D4RA07076C, Paper
Open Access
Sarah Baayyad, Fatima-Zahra Semlali, El Kébir Hlil, Tarik Mahfoud, Hassan El Moussaoui, Mounir El Achaby
Soft magnetic materials, like Ni0.5Zn0.5Fe2O4, require high temperatures and regulated environments for their manufacture and processing, which can be highly energy intensive.
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Simone Biles’ redemption song continues to silence Tokyo demons

The 27-year-old gymnast, regarded as one of the best ever, booked her ticket to Paris with a resounding victory at the US trials. Having successfully made a comeback after a two-year break to safeguard her mental health, she has the opportunity to put the 2020 Olympics firmly in her rearview mirror




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Shift in Hindi cinema’s portrayal of doctors reflects society’s evolving perception: Expert