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Research progress of Co-based spinel oxide materials for direct methanol fuel cells

New J. Chem., 2024, 48,7148-7167
DOI: 10.1039/D3NJ05431D, Paper
Zhiyang Zhong, Qinghui Zhang, Yingying Zhu, Bingyu Chen, Siyan Xu, Tianyu Shen, Aijuan Xie, Shiping Luo
With decades of research, both the synthesis and applications of spinels have achieved greatly increased development. The preparation, regulation strategies, and their application in MOR of Co based spinels are reviewed in this paper.
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3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
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Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
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Hydroquinone colorimetric sensing based on core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites as oxidase mimics

New J. Chem., 2024, 48,7323-7333
DOI: 10.1039/D4NJ00284A, Paper
Xuefang Lei, Yujin Li, Peiqing Guo, Mingzhu Qiu, Rang Meng, Shaohui Li, Dongxia Zhang, Nali Chen, Xibin Zhou
The core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites were successfully synthesized by co-precipitation method, and CeO2 was uniformly dispersed on the shell layer with the help of nitrogen-doped graphene quantum dots (N-GQDs).
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1-Butyl-3-methylimidazolium hydrogen sulfate-induced structure modification and reconstruction of nickel foams for oxygen evolution reactions

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05752F, Paper
Huamei Yang, Ziqin Chen, Kai Luo, Mengjun Yu, Yao Zhang
Surface chemical etching for the in situ growth of metal–organic materials and electrochemical reconstruction are expected to efficiently improve the catalytic performance of oxygen evolution reactions (OERs).
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Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
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Catalytic oxidative desulfurization performance of a modified nano-sized β zeolite loaded with different structural polyoxometalates

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00214H, Paper
Jinhong Li, Haonan Li, Zhimei Song, Ying Guo, Mengxiao Tai, Mei Han, Xinyao Wang, Lidong Chen, Dongmei Ren
HPW/β-T+S has the best desulfurization activity among the composite catalysts supported by polyoxometalates with different structures.
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Ultrasound-assisted ionic liquid-mediated green method for synthesis of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidines, their anti-tubercular activity, molecular docking study and ADME predictions

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00563E, Paper
Sravanthi Baddepuri, G. Rama Krishna, Jyothi Kumari, Sriram Dharmarajan, Srinivas Basavoju
The aim of the study is to develop the synthesis of a novel series of potent anti-tubercular (anti-TB) activity of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidine derivatives via an efficient green approach achieved by...
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Ahead of 2023, here are five stories that prove it’s never too late to learn something new

These people could inspire you to take up a hobby or learn a skill this New Year, no matter how old you are



  • Life & Style

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A chance to watch the celestial spectacle of Lyrids meteor shower from the foothills of Anamalai

The Coimbatore-based The Papyrus Itineraries and stargazing tour organisers Starvoirs have planned a sky-gazing event on April 22 and 23




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Queer artist Liactuallee crocheted sculptures and embroidery are on display at Method Bandra

Polish artist Liactuallee celebrates Pride Month with crocheted sculptures and embroidery




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Critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst systems

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00911D, Paper
Yang Luo, Hong Li, Hailan Yang, Zhiming Yang, Chuang Li, Shaoheng Liu, Qiang Chen, Weihua Xu, Wei Zhang, Xiaofei Tan
The critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst system was studied.
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Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Classification, uptake, translocation, and detection methods of nanoparticles in crop plants: a review

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00059E, Critical Review
He-Yi Zhang, Wen-Hao Su
Nanotechnology offers a viable solution to enhancing agricultural sustainability by supporting seed germination and crop growth.
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Silver nanoparticle doped laser-induced graphene fabrication methodology affects silver nanoparticle size, distribution, biological and electrochemical properties

Environ. Sci.: Nano, 2024, 11,1582-1596
DOI: 10.1039/D3EN00371J, Paper
Chetan Prakash Sharma, Abhishek Gupta, Meghna Khadka, Hadar Ben-Yoav, Avner Ronen, Christopher J. Arnusch
Three fabrication methods for metal-doped laser-induced graphene (LIG) are compared resulting in stable nanoparticles embedded within LIG. Variable nanoparticle size, distribution, antibacterial and electrochemical properties were observed.
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Biogenic synthesis of dual-emission chlorophyll-rich carbon quantum dots for detection of toxic heavy metal ions – Hg(II) and As(III) in water and mouse fibroblast cell line NIH-3T3

Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper
Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg2+ and As3+ in drinking water to protect human health.
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Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
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Selective metal recovery by mucin: turning gold from wastewater into a peroxymonosulfate-activated catalyst

Environ. Sci.: Nano, 2024, 11,1487-1498
DOI: 10.1039/D3EN00699A, Paper
Open Access
Shira Gavriely, Shachar Richter, Ines Zucker
This study explores mucin's ability to selectively recover gold (Au) from metal wastewater. The Au, in the form of a nanoparticle, was utilized in peroxymonosulfate activation for the degradation of bisphenol A.
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Molecular mechanisms of dimethylarsinic acid adsorption onto aluminum substituted ferrihydrite surfaces

Environ. Sci.: Nano, 2024, 11,1713-1723
DOI: 10.1039/D3EN00664F, Paper
Yiting Ge, Jiaqi Wang, Fayang Guo, Meng Yuan, Wentao Wang, Jiangshan Li, Jing Zhang, Xionghan Feng, Wenfeng Tan, Yupeng Wu, Hui Yin
Aluminum substitution in ferrihydrite promotes the formation of monodentate mononuclear and outer-sphere complexes of dimethylarsinic acid on the mineral surfaces at the expense of bidentate binuclear complexes at pH 6.
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Doped carbon dots affect heavy metal speciation in mining soil: changes of dissimilated iron reduction processes and microbial communities

Environ. Sci.: Nano, 2024, 11,1724-1739
DOI: 10.1039/D3EN00823A, Paper
Xinyi Huang, Shaobo Liu, Xuanming Liu, Xiaofei Tan, Shuai Guo, Mingyang Dai, Qiang Chen, Gaobin Chen, Chenzhi Feng
Carbon dots (CDs) inevitably accumulate in soils due to their widespread use, affecting soil enzyme activities and microbial community structure.
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Utilization of lead-based saturated adsorbents for the fabrication of battery-like hybrid asymmetric supercapacitors

Environ. Sci.: Nano, 2024, 11,1654-1670
DOI: 10.1039/D3EN00601H, Paper
Sourav Acharya, Shrabani De, Ayon Ganguly, Brijesh K. Mishra, Ganesh Chandra Nayak
In this study S-doped graphitic CN/ZIF-8 composite was fabricated to remove Pb from water which was anchored through heat treatment. This formed a composite of carbon, Zn-NCN, PbO and PbS and was used as supercapacitor anode.
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Correction: Nano-pelargonidin modulates p53/PARP/HSP 90/XRCC1 signaling axis to combat cypermethrin-induced genotoxicity and metabolic dysfunction in fish: a molecular docking predicted in vivo approach

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN90017K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Priyanka Sow, Sudatta Dey, Rishita Dey, Asmita Samadder, Sisir Nandi, Debojyoti Tarafdar, Anisur Rahman Khuda-Bukhsh
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A facile synthesis of a Ce-based MOF at room temperature for effective adsorption of methylene blue

CrystEngComm, 2024, 26,2009-2017
DOI: 10.1039/D4CE00096J, Paper
Yang Zhou, Dan Wang, Qiuxiang Feng, Qi Wu, Feng Cao, Li Jiang, Qianli Zhang, Jie Liu
Ce-UiO-66-NH2 was synthesized in water and ethanol at room temperature for effective removal of MB in aqueous solution.
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Study on growth technology and optical properties of large size and high quality methylamine lead bromide single crystals

CrystEngComm, 2024, 26,2003-2008
DOI: 10.1039/D4CE00028E, Paper
Yuanlong Sun, Yundong Ma, Xiangting Li, Ziyu Hu, Guozong Zheng
As a new generation of photoelectric materials, organic–inorganic halide perovskites have been widely used in photodetectors, solar cells and other fields, but most of the current mainstream applications are thin film materials.
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Construction of CsPbBr3/carboxyl-modified rGO heterostructures for efficient photocatalytic reduction of CO2 to methanol

CrystEngComm, 2024, 26,1994-2002
DOI: 10.1039/D4CE00036F, Paper
Meng Li, Jingtao Xu, Yang Song, Yuanyuan Li, Jin Wang, Feiyong Chen
Construction of monodispersed CsPbBr3 NCs and carboxyl-modified rGO composites led to the production of CO and CH3OH with an Relectron of 359 μmol g−1 h−1 by photocatalytic CO2 reduction.
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Polymeric polyiodo-chlorotellurates(IV): new supramolecular hybrids in halometalate chemistry

CrystEngComm, 2024, 26,2018-2024
DOI: 10.1039/D4CE00088A, Paper
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin
Reaction between TeO2 and I2 in HCl afforded a series of supramolecular hybrids Cat2{[TeCl6](I2)} (1–5) where diiodine fragments are linked to [TeCl6]2− octahedra via halogen bonds (XB).
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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals grown by travelling Te solution method

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00081A, Paper
Yuchen Song, Tingting Zhang, Jiahui Lv, Guorong Zhang, Changyou Liu, Tao Wang, Gangqiang Zha, Wanqi Jie
Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals were successfully grown by travelling Te solution method. The segregation of Mg with the growth of crystal is weaken and the as-grown crystal has high homogeneity.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
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Coral-mimetic production of aragonite films from CO2 captured by biogenic polyamines

CrystEngComm, 2024, 26,2065-2071
DOI: 10.1039/D4CE00126E, Paper
Open Access
Kohei Takashina, Hiroto Watanabe, Yuya Oaki, Yoshikazu Ohno, Ko Yasumoto, Hiroaki Imai
We designed CaCO3 films comprised of aragonite nanorods by mimicking the microstructure and the formation process of the calcareous skeleton of a stony coral in the sea.
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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Study on Raman scattering spectroscopy of Mn-doped GaN grown by the ammonothermal method

CrystEngComm, 2024, 26,2166-2171
DOI: 10.1039/D4CE00093E, Paper
Wenhao Lu, Tengkun Li, Guoqiang Ren, Zhenghui Xia, Kaihe Xie, Shaozhe Li, Liangkun Shen, Ke Xu
Mn-doped GaN crystals of a-plane and (11−22) plane were grown by the ammonothermal method.
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Meta Verified is now available in India at ₹699

Meta Verified is available for direct purchase on Instagram or Facebook.




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Meta launches more parental supervision tools for Instagram. Is it enough?

Many of the features require minors and their parents to opt in, raising questions about how effective the measures are




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Meta explains how AI influences Facebook and Instagram feeds

Meta is also expanding ‘Why Am I Seeing This?’ feature in Instagram and Facebook Reels.




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Meta takes aim at Twitter with the launch of Threads

Threads passes 5 million sign ups in four hours: CEO Zuckerberg




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Meta Threads is live now. Here’s how to register

Threads gains about 10 million signups within seven hours of the roll out




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Meta’s Threads rolls out, Mark challenges Elon with first Twitter post in decade

Mark challenges Elon with Twitter post




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Twitter threatens to sue Meta over Threads: report

Meta, which launched Threads on Wednesday, looks to take on Elon Musk's Twitter by taking advantage of Instagram's billions of users




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Meta’s Threads draws millions seeking a Twitter alternative

On Threads, people can post text and links and reply to or repost messages from others




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Why Meta’s Threads app is the biggest threat to Twitter yet

In less than 24 hours, Threads attracted some 30 million users




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Ex-Twitter CEO Jack Dorsey takes a dig at Meta over Threads

Threads app received about 30 million signups as of Thursday morning