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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02563F, Paper
Changfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu Han
A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
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Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02634A, Perspective
Mateusz Klarek, Konrad Kowalski
Article summarizes over 12 years of studies on organometallic nucleic acid components in our laboratory. It outlines synthetic chemistry, redox, photophysical and biological properties alike. It also shows directions for future development.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Two amino-functionalized metal–organic frameworks with different topologies for C2H2/C2H4 separation

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02592J, Communication
Yue Li, Mingming Xu, Hongyan Liu, Xiaokang Wang, Yutong Wang, Meng Sun, Weidong Fan, Daofeng Sun
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting

Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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Imine bond-directed assembly of polyoxometalate-based metal–organic frameworks

Dalton Trans., 2024, 53,17902-17908
DOI: 10.1039/D4DT02609H, Paper
Xiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai Yuan
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
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The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
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It's all in the interpretation




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Karnataka High Court directs Chief Secretary to form panel to examine plea for declaring Allama Prabhu Swamy temple as ancient monument  

The temple is submerged in the backwaters of Hidkal dam in Belagavi district for nearly six months in a year




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Ketamine [electronic resource] : the story of modern psychiatry's most fascinating molecule / by Keith G. Rasmussen.

Washington, DC : American Psychiatric Association Publishing, [2024]




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People have seen our work... Devendra Fadnavis exudes confidence in Mahayuti alliance retaining power in Maharashtra




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Enhanced removal efficiency of Tetradesmus obliquus for nevirapine removal via co-substrate supplementation: removal mechanisms, relative gene expression and metabolomics

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00576G, Paper
Karen Reddy, Nirmal Renuka, Muneer Ahmad Malla, Brenda Moodley, Faizal Bux, Sheena Kumari
The bioremediation of pharmaceutical wastewater by microalgae has gained scientific attention due to its cost-effectiveness and environmental friendliness.
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Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation

Environ. Sci.: Water Res. Technol., 2024, 10,2646-2654
DOI: 10.1039/D4EW00496E, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
D. Boglaienko, M. E. Bowden, N. M. Escobedo, Q. M. Collins, A. R. Lawter, T. G. Levitskaia, C. I. Pearce
Removal of pertechnetate 99TcO4 and perrhenate ReO4 during mineral transformation of the non-toxic basic bismuth subnitrate for subsurface remediation.
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Simultaneous removal of acetaminophen, sulfamethoxazole, and iohexol from real wastewater in continuous mode by an immobilized sulfur-doped Bi2O3/MnO2 photocatalyst

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00501E, Paper
Vishal Kumar Parida, Mario Vino Lincy Gnanaguru, Suneel Kumar Srivastava, Shamik Chowdhury, Ashok Kumar Gupta
The photocatalytic potential of the Z-scheme 2S-Bi2O3/MnO2 immobilized photocatalyst for the simultaneous degradation of ACT, SMX, and IOX from MBBR-sand filter treated wastewater is studied for the first time, purely from a practical perspective.
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Heavy metal leaching from stormwater control measures – insights into field and lab prestressed media and road-deposited sediments

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00388H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Philipp Stinshoff, Yannic Henn, Steffen H. Rommel, Brigitte Helmreich
Heavy metals bound to filter media from stormwater control measures can leach out under unfavorable conditions. The potential overestimation due to different prestressing (lab vs. field) was evaluated with respect to the potential mobile fraction.
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CNG price may rise ₹4-6 on input supply cuts to gas retailers

City gas retailers are forced to buy imported and costlier liquefied natural gas to make up for the shortfall, which will lead to a hike in CNG prices that varies from ₹4-6/kg




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CCI publishes detailed order approving merger of RIL, Walt Disney's media assets

As part of seeking the regulator’s approval, the parties have voluntarily agreed that they will not bundle TV ad slots for IPL, ICC and BCCI cricketing rights till the end of existing rights




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Automobile retail sales witness 64% growth in October: FADA

The convergence of major festivals (Navratri & Diwali) in October significantly boosted consumer demand, FADA said.




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Shweta upsets fifth seed Arthi




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Maharashtra Election: Who Will Be CM If Mahayuti Retains Power? BJP Keeps People Guessing

The BJP has left the 'Maharashtra CM face question' open-ended with its allies NCP and Shiv Sena maintaining a balanced stand. 




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Giuliani the favorite as Trump weighs secretary of state

Although Mr. Giuliani has little foreign policy experience, the official said there was no real competition for the job as the nation’s top diplomat.




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Nikki Haley to meet Trump, could be Secretary of State

Earlier in the day, a close aide of Mr. Trump from South Carolina said that Ms. Haley was being considered for a Cabinet position, including that of the Secretary of State.




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UK tribunal quashes Meta-Giphy deal block, regulator to reconsider ruling

The Competition Appeals Tribunal said it had quashed the CMA’s ruling and referred the matter back for a new decision




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ADB retains India's growth forecast at 7%; govt spending, agriculture to boost economy

The Indian economy grew 8.2% in the last fiscal (2023-24)




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Government retains borrowing target, to raise ₹6.61 lakh crore in H2 to fund revenue gap

The gross market borrowing of ₹6.61 lakh crore shall be completed through 21 weekly auctions.




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Government picks three new members to join RBI’s Monetary Policy Committee

The new members are Ram Singh, Saugata Bhattacharya and Nagesh Kumar. They have been appointed for a period of four years.




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No rethink on FDI curbs in multi-brand retail sector: Piyush Goyal

Piyush Goyal said there will be no rethink on the Foreign Direct Investment (FDI) curbs in the multi-brand retail sector.




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RBI Monetary Policy Committee meeting: policy rate unchanged at 6.5% for 10th time in a row

‘RBI changes stance of monetary policy to ‘neutral’ from withdrawal of accomodation,’ says Shaktikanta Das.




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36% surge in vegetable prices lifts September inflation to 9-month high

Retail inflation touches nine-month high of 5.5% in September




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Centre re-starts retail sale of pulses as prices rise ahead of festivals

Direct interventions through retail sale of basic food items such as rice, atta, dal and onion have helped maintain a stable price regime, Union Consumer Affairs and Food Minister Pralhad Joshi said




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At nearly 5-year high, 42.2% vegetable price rise propelled October retail inflation past 6.2% 

“High food inflation in October, 2024 is mainly due to increase in inflation of vegetables, fruits and oils and fats,” the National Statistical Office said




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NEET UG 2024 counselling registration to begin on August 14, confirms NMC Secretary

Additionally, the NEET UG 2024 results were revised, resulting in a decline in the number of toppers.




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‘Assamese identity has historically been secular,’ says Sangeeta Barooah Pisharoty

As the government searches for a definition, the author of ‘The Assamese: A Portrait of a Community’ unpacks the composite culture of the people by the Brahmaputra




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Budget 2024: New job schemes to kick off this year, says Finance Secretary T.V. Somanathan

For Andhra Pradesh and Bihar, funds for some projects will be only through concessional multilateral loans, which could be from World Bank, Asian Development Bank, JICA, AIIB… any of these institutions, he says




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Understanding the structure–activity relationship of additives for durable Zn metal batteries: a case study of aromatic molecules

Energy Environ. Sci., 2024, 17,8349-8359
DOI: 10.1039/D4EE03232B, Paper
Da-Qian Cai, Haiyang Cheng, Jin-Lin Yang, Huan Liu, Tao Xiao, Xin Liu, Minghua Chen, Hong Jin Fan
The Zn/electrolyte interface with parallelly adsorbed Pym molecules can efficiently suppress corrosion and HER and simultaneously accelerate Zn redox kinetics by inducing zincophilicity.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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The construction of multifunctional solid electrolyte interlayers for stabilizing Li6PS5Cl-based all-solid-state lithium metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper
Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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Quantitatively detecting and characterizing metallic lithium in lithium-based batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03468F, Review Article
Zhi Zheng, Xue Fang, Wei Deng, Peng Li, Xiaobo Zheng, Hang Zhang, Lin Li, Shulei Chou, Yuan Chen, Yongbing Tang, Jiazhao Wang
Quantitative detection and characterization methods for analysis of metallic Li and related inactive components of Li batteries and their related characteristics are discussed.
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Regulating local chemical softness of the collector to homogenize Li deposition for anode-free Li-metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03673E, Paper
Jiaming Zhu, Cong Kang, Xiangjun Xiao, Ya Mao, Ying Luo, Yuheng Wang, Quansheng Zhang, Yulin Ma, Chunyu Du, Shuaifeng Lou, Fanpeng Kong, Jingying Xie, Geping Yin
A heterogeneous collector featuring hard-base sites and soft-acid sites is proposed, which significantly reduces nucleation and growth barriers, with no dendrite formation. This finding offers a pathway to rationally design highly efficient collectors for AFLMBs.
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Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
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High-Entropy Materials for Aqueous Zinc Metal Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04442H, Review Article
Xiaomin Han, Ran Zhao, Jingjing Yang, Yahui Wang, Anqi Zhang, Zhifan Hu, Mengge Lv, Chuan Wu, Ying Bai
To meet the challenges raised by the utilization of intermittent clean energies, rechargeable aqueous zinc ion battery (AZIB) stands at the forefront due to its competitive capacity, low cost, and...
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An electric double layer regulator empowers robust solid-electrolyte interphase for potassium metal batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03978E, Paper
Xueyu Lian, Liang Xu, Zhijing Ju, Ziang Chen, Xiaopeng Chen, Yuyang Yi, Zhengnan Tian, Tao Cheng, Shi Xue Dou, Xinyong Tao, Jingyu Sun
The electric double layer (EDL) plays a key role in constructing solid electrolyte interphase (SEI) for high-energy metal anodes. Nevertheless, the significance of EDL and its associated influence remain elusive...
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