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Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02396J, Paper
Chuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo Peng
Zinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.
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A ratiometric luminescence thermometer based on lanthanide encapsulated complexes

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02639J, Paper
Aribam Rishikanta Sharma, Atom Rajiv Singh, Anju Ajayan Kongasseri, Swadhin Garain, Ann Mariella Babu, Rajkumari Lonibala, Raju Laishram
This paper describes the synthesis of various luminescent Tb and Eu complexes by encapsulation in a Ca-complex. The synthesised material was then used as a ratiometric luminescence thermometer, in which thermometric parameters could be tuned.
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Rational fabrication of an anionic zinc carboxylate framework as a fluorescent probe for 2,6-pyridinedicarboxylic acid

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02529F, Paper
Hui-Hui Xie, Hao Yu, Xiuling Xu, Si-Fu Tang
An anionic zinc carboxylate framework has been fabricated as a fluorescent sensor for the detection of 2,6-pyridinedicarboxylic acid (DPA).
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Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02563F, Paper
Changfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu Han
A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02713B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sophie C. Corner, Gemma K. Gransbury, David P. Mills
We present the synthesis and characterisation of two dysprosium metallocene complexes with bound weakly coordinating anions. Despite their similarity these complexes exhibit vastly different effective energy barriers to magnetic reversal.
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Two amino-functionalized metal–organic frameworks with different topologies for C2H2/C2H4 separation

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02592J, Communication
Yue Li, Mingming Xu, Hongyan Liu, Xiaokang Wang, Yutong Wang, Meng Sun, Weidong Fan, Daofeng Sun
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02940B, Paper
Thi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek Dereń
The increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...
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β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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Molecular Fe(II)–Ln(III) dyads for luminescence reading of spin-state equilibria at the molecular level

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17756-17765
DOI: 10.1039/D4DT01868K, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Timothée Lathion, Neel Deorukhkar, Charlotte Egger, Homayoun Nozary, Claude Piguet
Efficient and easy lanthanide(III)-based luminescence reading of iron(II) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.
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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Multi-functional biotinylated platinum(IV)–SAHA conjugate for tumor-targeted chemotherapy

By pubs.rsc.org
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Dalton Trans., 2024, 53,17829-17840
DOI: 10.1039/D4DT01571A, Paper
Ajay Gupta, Pijus K. Sasmal
Herein, we have developed a hydrolytically stable biotinylated Pt(IV) complex conjugated with a histone deacetylase inhibitor (SAHA) as a multi-functional tumour targeted chemotherapeutic agent.
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Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper
Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
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Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
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Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17989-18002
DOI: 10.1039/D4DT02195A, Paper
Jie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng Fang
A series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.
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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02589J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef Holub
The objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier
Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
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Anchored to beliefs

By www.thehindubusinessline.com
Published On :: Thu, 23 May 2013 16:48:29 +0530


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In a state of urgency

By www.thehindubusinessline.com
Published On :: Thu, 08 Aug 2013 16:28:45 +0530


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Many facets of intolerance

By www.thehindubusinessline.com
Published On :: Fri, 23 Aug 2013 16:42:24 +0530


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Samen delen across the fence

By www.thehindu.com
Published On :: Sun, 11 Aug 2024 01:16:00 +0530

Striking a rapport with neighbours in the Netherlands


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Pencilled in

By www.thehindu.com
Published On :: Sun, 11 Aug 2024 03:37:00 +0530

The writing stick has all but disappeared, flaunted only by a few sections


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The incredible matutinal drink

By www.thehindu.com
Published On :: Sun, 18 Aug 2024 01:00:00 +0530

A cup of morning ‘South Indian coffee’ is the only pick-me-up than one needs


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A trip to Panchmarhi

By www.thehindu.com
Published On :: Sun, 25 Aug 2024 02:54:00 +0530

A college tour to the picturesque destination breaks the ice


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The dark side of digital dependence

By www.thehindu.com
Published On :: Sun, 01 Sep 2024 04:35:00 +0530

The dreaded blue screen can throw life out gear in the most unlikeliest of places


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When influencers call the shots

By www.thehindu.com
Published On :: Sun, 15 Sep 2024 01:31:00 +0530

They act as symbols of beauty, success, and happiness, and their posts, stories, and videos are vehicles of meaning for the audiences


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NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy

By physicsworld.com
Published On :: 2018-01-19T14:46:48Z

Register now: 8 March 2018
A webinar sponsored by HORIBA Scientific


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Enhancing radiotherapy with MRI

By physicsworld.com
Published On :: 2018-01-25T14:58:04Z

Bas Raaymakers describes how MRI can help target tumours with improved accuracy


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Mysuru Sangeetha Sugandha concludes

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 19:51:31 +0530

Tourism Ministry to promote the event beyond State


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Digital drive soon to encourage passengers to make QR code-based payments for railway tickets

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 20:41:25 +0530

The drive will entail establishing special ‘May I Help You’ counters manned by railway staff near ticket booking counters


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Art camp in support of cancer patients in Mysuru soon

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 20:59:54 +0530


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Medical malpractice destroys profession’s nobility, says BLDE Vice-Chancellor

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 07:00:00 +0530


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KSRTC plans to launch Ashwamedha AC buses within 100-km radius of Bengaluru

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 07:13:00 +0530

In contrast to regular Ashwamedha buses, the AC version will be smaller, fully air-conditioned, and equipped with comfortable seating, and amenities like charging ports 


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Model rocketry workshop launched to inspire young innovators in Bengaluru

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 07:55:02 +0530

The workshop is aimed at promoting innovation and technical expertise


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Activists demand that govt. grant land to landless, instead of encroachers on contract

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 20:02:51 +0530

They also urged the State government to recover the hundreds of acres of land encroached upon by private company estates in the Malnad region


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Siddaramaiah to launch projects in Mysuru on November 12 and 13

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 21:06:08 +0530


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Chunchankatte Jalapatotsava to be held on Nov. 30, Dec. 1

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 21:25:36 +0530


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Karnataka High Court directs Chief Secretary to form panel to examine plea for declaring Allama Prabhu Swamy temple as ancient monument  

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 22:47:38 +0530

The temple is submerged in the backwaters of Hidkal dam in Belagavi district for nearly six months in a year


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Kalaburagi: Man sentenced to 20 years of imprisonment for sexually assaulting minor girl

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 19:17:32 +0530


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Sandur bypolls: Ballari Deputy Commissioner appeals to voters to exercise franchise

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 19:36:30 +0530


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Allocation for development works nails BJP’s lie of resource crunch in State, says Siddaramaiah

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 20:02:22 +0530


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Don’t reduce quantum of advance, Minister Shivanand Patil tells NABARD

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 21:15:47 +0530


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