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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry




state

Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




state

In a state of urgency




state

State-level mock Parliament competition for high school and PU students in Shivamogga tomorrow




state

Allocation for development works nails BJP’s lie of resource crunch in State, says Siddaramaiah




state

EAM Jaishankar says success of Central govt's policies linked to state's intentions




state

Phosphorus release from sewage sludge and digestate driven by biological sulfate reduction: effect of feed sulfate concentration and thermal hydrolysis

Environ. Sci.: Water Res. Technol., 2024, 10,2897-2905
DOI: 10.1039/D4EW00322E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Francesco Di Capua, Stefano Papirio, Silvio Matassa, Francesco Pirozzi, Giovanni Esposito
Recovering phosphorus from sewage sludge is a strategic, circular approach to ensure long-term phosphorus availability for future generations, supporting sustainability and resource preservation.
The content of this RSS Feed (c) The Royal Society of Chemistry




state

Congress takes strong exception to Kannur Collector’s ‘character statement’ about Naveen Babu

AICC general secretary, K. C. Venugopal, accused the Collector of attempting to tarnish the character of his deceased colleague at the instance of an influential coterie in the CPI(M) leadership




state

State government constitutes expert committee for Medisep revamp

The scheme’s next phase to be launched on July 1, 2025. Rates for medical and surgical packages offered under it will be revised in consultation with service and pensioners’ organisations 




state

KTU teaching appointments in limbo as Governor, State government clash over V-C appointment

KTU recently issued a notification seeking applications for six Professors, six Associate Professors and 28 Assistant Professors across the five schools offering postgraduate courses.




state

Thrissur Sahodaya takes home overall trophy in CBSE State Kalotsav

Malabar Sahodaya and Kochi Sahodaya come in second and third positions, respectively. Among schools, Silver Hills Public School, Kozhikode, became the overall champions




state

Samson wants to make a statement in Daredevils colours




state

Islamic State group flourishes and recruits in Pakistan

According to police, Afghan officials and IS media outlets, the majority of Islamic State fighters in Afghanistan are Pakistani nationals, mostly from the tribal regions.




state

Giuliani the favorite as Trump weighs secretary of state

Although Mr. Giuliani has little foreign policy experience, the official said there was no real competition for the job as the nation’s top diplomat.




state

Nikki Haley to meet Trump, could be Secretary of State

Earlier in the day, a close aide of Mr. Trump from South Carolina said that Ms. Haley was being considered for a Cabinet position, including that of the Secretary of State.




state

Islamic State killed 300 former policemen south of Mosul, HRW says

Human Rights Watch said some of the former policemen were separated from a group of about 2,000 people from nearby villages and towns who were forced to march alongside the militants last month as they retreated north to Mosul and the town of Tal Afar.




state

China state media warn Trump against renouncing free trade deals

Chinese state media has warned Mr. Trump against isolationism and interventionism, calling instead for the United States to actively work with China to maintain the international status quo.




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Post-1991, southern States emerged as leaders: EAC-PM

Punjab and West Bengal have recorded sharp declines in per capita income after a head start




state

German economy to shrink further in 2024, think-tanks issue statement




state

The job crisis undermines state legitimacy

Unemployment is not merely an economic issue, but a fundamental political challenge that strikes at the heart of how we organise our societies




state

Vision for Viksit Bharat: State-level investment competition, fresh blood in politics

Prime Minister Narendra Modi calls for State-level investment push, focus on green jobs, birth of first-generation political leaders




state

30 States, UTs come under Vidya Samiksha Kendra network: Govt

The system will allow for mapping, tracking and identifying learning gaps in students even if they move across States 




state

State can regulate madrasa education to ensure standards of excellence: SC 

The Supreme Court on Tuesday partially upheld the constitutional validity of the Uttar Pradesh Madrasa Education Board Act of 2004 while confirming that States can regulate madrasa education to ensure standards of excellence.




state

Tamil Nadu continues to be the second largest State economy: Finance Minister

Ahead of the Global Investors’ Meet, Finance Minister Thangam Thennarasu dismissed claims that Uttar Pradesh had overtaken Tamil Nadu as the second largest State economy. He also spoke about renewable energy and impact of floods on revenues. Excerpts from an interview with The Hindu:




state

States to play a critical role in next generation reforms: CEA Anantha Nageswaran

Chief Economic Advisor V. Anantha Nageswaran identifies some of the next generation reforms needed in the coming years




state

Three-step thermodynamic vs. two-step kinetics-limited sulfur reactions in all-solid-state sodium batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03160A, Paper
Tongtai Ji, Qingsong Tu, Yang Zhao, Dominik Wierzbicki, Vincent Plisson, Ying Wang, Jiwei Wang, Kenneth S. Burch, Yong Yang, Hongli Zhu
This study unveils the intrinsic three-step thermodynamic and the two-step kinetics-limited pathways in all-solid-state sodium–sulfur batteries, providing crucial insights into sulfur reaction mechanisms for high-performance energy storage solutions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The construction of multifunctional solid electrolyte interlayers for stabilizing Li6PS5Cl-based all-solid-state lithium metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper
Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




state

More coaching centres for competitive exams to be opened in State, says Higher Education Minister




state

​Solemn promise: On restoring Statehood for Jammu and Kashmir  

There can be no further delay in restoring Statehood for Jammu and Kashmir




state

States and the Centre’s fetter of ‘net borrowing ceiling’

The Centre’s NBC step and, subsequently, Kerala’s move to approach the higher judiciary on the issue, highlight the need to revisit Article 293 of the Constitution




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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Garden state

In Singapore’s Hort Park, Rupa Gopal meets gardening enthusiasts at the annual fair




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Garden state

Is it time to make kitchen gardens mandatory, asks Hema Vijay




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Relationships of dietary habits with prostate cancer risk: results from Mendelian randomization analyses and the National Health and Nutrition Examination Survey

Food Funct., 2024, 15,10823-10837
DOI: 10.1039/D4FO03859B, Paper
Zhen Zhou, Jin Xu, Yang Zhao, Yuanjie Niu
Prior investigations identified correlations between dietary habits and the risk of prostate cancer (PCa); however, the causative dynamics are unclear.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solid-state fermentation of green lentils by Lactiplantibacillus plantarum leads to formation of distinct peptides that are absorbable and enhances DPP-IV inhibitory activity in an intestinal Caco-2 cell model

Food Funct., 2024, 15,11220-11235
DOI: 10.1039/D4FO03326D, Paper
Elisa Di Stefano, Nico Hüttmann, Pieter Dekker, Monic M. M. Tomassen, Teresa Oliviero, Vincenzo Fogliano, Chibuike C. Udenigwe
In vitro gastrointestinal digestion, brush border enzyme activity, and microbial fermentation with Lactiplantibacillus plantarum influenced the peptidome of green lentils and peptide transport across the intestinal Caco-2 cell monolayer.
The content of this RSS Feed (c) The Royal Society of Chemistry




state

Which States are leading the race towards renewables in India?

India with 300 days of sunshine each year, possesses vast solar energy potential. The National Institute of Energy estimated the country’s solar potential at 748 GW, assuming solar PV modules cover 3% of the geographical surface. Solar energy is expected to be the main driver pushing India closer to its renewable energy targets. Diving deep into the state-wise push towards solar energy. Rajasthan, Gujarat, Tamil Nadu and Karnataka are the leading States in India, both in terms of installed capacities and power generation, in the solar segment. Also, with respect to solar energy projects, Rajasthan and Gujarat lead in terms of the capacities added since FY22 and projects in pipeline




state

Punjab Minister says state to meet 20 per cent fuel demand through biofuels by 2035




state

Punjab CM dedicates state-of-the-art Bhagwan Valmiki-ji Panorama




state

Govt may get rice milling outside state, says Punjab CM




state

Punjab CM seeks incentives for industry on par with hill states




state

25 venues in Thiruvananthapuram for State School Arts Festival

Nearly 15,000 students will participate in 249 competitive events at fete that will be held from January 4 to 8




state

Odisha’s panchayats witness spate of no-confidence motions after BJP’s victory in State

The trend signals a shift in the grassroots power dynamics across the State with BJP venturing to claim even more of the BJD’s political territory




state

Lokayukta police conduct raids across the State, book 8 officials




state

Bypolls LIVE: Voting begins for 31 Assembly seats in 10 States

Congress general secretary Priyanka Gandhi Vadra is making her electoral debut in Wayanad





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Gujarat State Fertilizers & Chemicals Ltd. - Unaudited Financial Results For The 1St Quarter Ended On 30Th June, 2019




state

Gujarat State Fertilizers & Chemicals Ltd. - Revised- Standalone And Consolidated Unaudited Financial Results For The 1St Quarter Ended On 30Th June, 2019.




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New insights into influences of initial oxidization states on dynamic reconstruction of Cu catalysts and C–C coupling in CO2 reduction

Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper
Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO2 reduction, resulting in the dynamic evolution of i-CuOx species. The in situ formed i-CuOx plays decisive roles in promoting C–C coupling.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metamagnetic transition and meta-stable magnetic state in Co-doped Fe3GaTe2

Nanoscale, 2024, 16,20252-20259
DOI: 10.1039/D4NR02622E, Paper
Hyo-Bin Ahn, Hyunjong Lim, Jaegu Song, Jisung Lee, Seung-Young Park, Minwoong Joe, Chang-Jong Kang, Kyoung-Whan Kim, Tae-Eon Park, Tuson Park, Changgu Lee
The phase diagram and MH curves of the metamagnetic regime of (Fe1−xCox)3GaTe2 with x = 0.19–0.26 at various temperatures were studied.
The content of this RSS Feed (c) The Royal Society of Chemistry