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A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper
Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.
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Exploring the impact of abnormal coordination in macrocyclic N-heterocyclic carbene ligands on bio-inspired iron epoxidation catalysis

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
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High-temperature calcination enhances the activity of MnOx catalysts for soot oxidation

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6278-6285
DOI: 10.1039/D4CY00983E, Paper
Open Access
Meng Wang, Jingyi Wang, Yan Zhang, Yunbo Yu, Wenpo Shan
High-temperature calcination usually induces the sintering of catalysts, thus resulting in negative effects on their performance.
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Fundamental studies of ruthenium species supported on boron nitride nanotubes: metal loading and pretreatment effects on CO oxidation

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Published On ::

Catal. Sci. Technol., 2024, 14,6198-6206
DOI: 10.1039/D4CY00945B, Paper
Jinwon Choi, Amol Pophali, Byeongseok Kim, Kwangsuk Yoon, Thomas You-Seok Kim, Hocheol Song, Sang Eun Shim, Jaewoo Kim, Taejin Kim
RuOx/BNNT catalysts were prepared with varying metal loadings and under oxidation and reduction conditions. RuOx/BNNT showed superior catalytic activity than Ru/BNNT. The catalyst will be favorable to the ER mechanism over the LH mechanism.
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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Engineering galactose oxidase for efficient cascade synthesis of L-guluronic acid from D-glucose

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00697F, Paper
Qingxiu Wang, Weisong Liu, Lijing Chang, Kuncheng Zhang, Yanbing Shen, Lingling Zhang
A synthetic pathway of L-guluronic acid and rational design of galactose oxidase.
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Mechanistic Study of DETA-Modified CdS for Carbon Dioxide Reduction

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01140F, Paper
Meiyan Guo, Wanxiang Yang, Yi Li, Yongfan Zhang, Wei Lin
Cadmium sulfide (CdS) exhibits remarkable light absorption capabilities and is widely employed in photocatalytic reduction of CO2. Nevertheless, the role of crystal facet effects on the micro-scale mechanisms governing CO2...
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Insight into the influence of Re and Cl on Ag catalysts in ethylene epoxidation

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00858H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Claudia J. Keijzer, Pim T. Weide, Kristiaan H. Helfferich, Justyna Zieciak, Marco de Ridder, Remco Dalebout, Tracy L. Lohr, John R. Lockemeyer, Peter van den Brink, Petra E. de Jongh
Crystalline AgReO4 was formed in Re-promoted Ag catalysts. The effect of Re on catalysis and EO isomerization was tested without and with the industrially relevant ethyl chloride. EO isomerization was greatly affected by both Re and Cl.
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Bioinspired copper-catalysed nitrous oxide reduction with simultaneous N–H or O–H bond oxidation

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6503-6512
DOI: 10.1039/D4CY00760C, Paper
Bruce A. Lobo Sacchelli, Suellen M. P. Onguene, Ruben S. M. Almeida, Alexandra M. M. Antunes, Dmytro S. Nesterov, Leandro H. Andrade, Elisabete C. B. A. Alegria, Martin H. G. Prechtl
Tuning selectivities with oxidants: O2 oxidises methanol to the carboxylate level and N2O oxidises it to the formaldehyde level.
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Heterogeneous oxidative upcycling of polystyrene plastics to benzoic acid under air conditions

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper
Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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Switching of selectivity from benzaldehyde to benzoic acid using MIL-100(V) as a heterogeneous catalyst in aerobic oxidation of benzyl alcohol

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper
Open Access
Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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Enhancing coking resistance of nickel-based catalysts for dry reforming of methane via nitric oxide abatement: a support study

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper
Open Access
Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

By pubs.rsc.org
Published On ::

Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Ni,S co-doped Cu dendrites decorated with core–shell architecture assisted by MOF and Fe0.92Co0.08S nanoflakes on nanocellulose/graphene fibers for fabrication of flexible wire-type micro-supercapacitor

By pubs.rsc.org
Published On ::

Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper
Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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High sensing performance flexible nanocomposite sensor with a hybrid nanostructure constructed via nanoscale confined motion of nanofibers and nanoplatelets

By pubs.rsc.org
Published On ::

Nanoscale, 2024, 16,20288-20303
DOI: 10.1039/D4NR02541E, Paper
Zhenghui Xie, Feiran Meng, Junlong Yang, Yuhong Wang, Chul B. Park, Pengjian Gong, Guangxian Li
Hybrid 1D nanofiber/2D nanoplatelet nanocomposite foam sensor and Monte-Carlo modelling of complex 1D/2D sensing nanostructure.
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Nano-sized metal oxide fertilizers for sustainable agriculture: balancing benefits, risks, and risk management strategies

By pubs.rsc.org
Published On ::

Nanoscale, 2024, 16,19998-20026
DOI: 10.1039/D4NR01354A, Review Article
Raja Muthuramalingam Thangavelu, Washington Luis da Silva, Nubia Zuverza-Mena, Christian O. Dimkpa, Jason C. White
This critical review comprehensively analyses nano-sized metal oxide fertilizers (NMOFs) and their transformative potential in sustainable agriculture.
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Advances in Flexible Ionic Thermal Sensors: Present and Perspectives

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03423F, Review Article
Zehao Zhao, Yun Shen, Run Hu, Dongyan Xu
Ionic thermal sensors (ITSs) represent a promising frontier in sensing technology, offering unique advantages over conventional electronic sensors. Comprising a polymer matrix and electrolyte, these sensors possess inherent flexibility, stretchability,...
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Mixed phase Ti3+-rich TiO2 thin films by oxide defect engineered crystallization

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03545C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lauri Palmolahti, Harri Ali-Löytty, Markku Hannula, Tuomas Tinus, Kalle Lehtola, Antti Tukiainen, Jarno Reuna, Mika Valden
Amorphous TiO2 has insufficient chemical stability that can be enhanced with annealing induced crystallization. However, the crystalline structure is already predetermined by the defect composition of the amorphous phase. In...
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Synthesis, Characterization, Genotoxicity Assessment and Antibacterial Applications of Zanthoxylum armatum Silver Nanoparticles (ZASNP) with Antibiotic Efficacy Enhancement Potential

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03608E, Paper
Open Access
Nikita Quadri, Manjunath M. Setty, Anshumali Awasthi, Usha Yogendra Nayak, Minakshi Singh, Sharad Sharma
The study aimed to develop alternative antibacterial treatments by combining traditional herbal knowledge with modern nanotechnology. This approach targets multiple bacterial strains, combats antibiotic resistance, and offers solutions for treating...
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Impact of catalyst support on water-assisted CO oxidation over PdO/MO2 (M = Sn, Ti, and Si) catalysts: experimental and theoretical investigation

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03963G, Paper
Kun Liu, Luliang Liao, Guangfu Liao
This study investigates the influence of different supports on PdO-based catalysts during CO oxidation, particularly under humid conditions.
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Highly stable and ultra-fast vibration-responsive flexible iontronic sensors for accurate acoustic signal recognition

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03370A, Paper
Yan Wang, Weiqiang Liao, Xikai Yang, Kexin Wang, Shengpeng Yuan, Dan Liu, Cheng Liu, Shiman Yang, Li Wang
A wearable acoustic vibration pressure sensor was developed based on an interfacial-enhanced iontronic dielectric and integrated with an acoustic recognition system using a deep learning classifier.
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Photo-Assisted Epitaxial Growth from Nanoparticles to Enhance Multi-Materialization for Advanced Surface Functionalization

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03112A, Paper
Masayuki Fukuda, Yuuki Kitanaka, Tomohiko Nakajima
To meet the requirements of freeform objects, a wide range of highly designable resin-based materials has been created, highlighting the need for low-temperature ceramic deposition methods for surface functionalization. Photo-assisted...
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xi

Quantifying the polar skyrmion motion barrier in an oxide heterostructure

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03686G, Paper
Lizhe Hu, Yuhui Huang, Yong Jun Wu, Zijian Hong
Exotic polar topologies such as polar skyrmions have been widely observed in the ferroelectric superlattice system. The dynamic motion of the polar skyrmion under external forces holds promise for applications...
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Expression of concern: Iron oxide magnetic nanoparticles with versatile surface functions based on dopamine anchors

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR90209B, Expression of Concern
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mykola Mazur, Alexandre Barras, Victor Kuncser, Andrei Galatanu, Vladimir Zaitzev, Kostiantyn V. Turcheniuk, Patrice Woisel, Joel Lyskawa, William Laure, Aloysius Siriwardena, Rabah Boukherroub, Sabine Szunerits
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Bioinspired ginsenoside Rg3 PLGA nanoparticles coated with tumor-derived microvesicles to improve chemotherapy efficacy and alleviate toxicity

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00159A, Paper
Shulei Zhang, Bo Zheng, Yiqi Wei, Yuhao Liu, Lan Yang, Yujiao Qiu, Jing Su, Mingfeng Qiu
Breast cancer, a pervasive malignancy affecting women, demands a diverse treatment approach including chemotherapy, radiotherapy, and surgical interventions.
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Bioactivity of cerium dioxide nanoparticles as a function of size and surface features

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Published On ::

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D3BM01900D, Paper
Veronika Sarnatskaya, Yuliia Shlapa, Denis Kolesnik, Olexandra Lykhova, Dmytro Klymchuk, Serhii Solopan, Svitlana Lyubchyk, Iuliia Golovynska, Junle Qu, Yurii Stepanov, Anatolii Belous
Nano-dispersed cerium dioxide is promising for use in medicine due to its unique physicochemical properties, low toxicity, the safety of in vivo usage, active participation in different redox processes occurring in living cells, and its regenerative potential.
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Macrophage membrane-camouflaged nanoclusters of ultrasmall iron oxide nanoparticles for precision glioma theranostics

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00357H, Paper
Bin Zhang, Rui Yang, Hongwei Yu, Yamin Peng, Haoyu Huang, Meera Moydeen Abdul Hameed, Han Wang, Guixiang Zhang, Mohamed EL-Newehy, Mingwu Shen, Xiangyang Shi, Shaojun Peng
Macrophage membrane-camouflaged nanoclusters of ultrasmall iron oxide nanoparticles can be developed to cross the blood–brain barrier for magnetic resonance imaging and chemo/chemodynamic therapy.
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Enhancing antioxidant properties of CeO2 nanoparticles with Nd3+ doping: structural, biological, and machine learning insights

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, 12,2108-2120
DOI: 10.1039/D3BM02107F, Paper
Oscar Ceballos-Sanchez, Diego E. Navarro-López, Jorge L. Mejía-Méndez, Gildardo Sanchez-Ante, Vicente Rodríguez-González, Angélica Lizeth Sánchez-López, Araceli Sanchez-Martinez, Sergio M. Duron-Torres, Karla Juarez-Moreno, Naveen Tiwari, Edgar R. López-Mena
The antioxidant capabilities of nanoparticles are contingent upon various factors, including their shape, size, and chemical composition.
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Type I and Type II Chemical Biology Toolbox to Overcome the Hypoxic Tumour Microenvironment for Photodynamic Therapy

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4BM00319E, Review Article
Minzi Ju, Lu Yang, Guowei Wang, Feng Zong, Yu Shen, Shuangshuang Wu, Xuna Tang, Decai Yu
Photodynamic therapy (PDT) is a minimally invasive therapeutic modality employed for the treatment of various types of cancers, localized infections, and other diseases. Upon illumination, the photo-excited photosensitizer generates singlet...
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Lipid sulfoxide polymers as potential inhalable drug delivery platforms with differential albumin binding affinity

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D3BM02020G, Paper
Gayathri Ediriweera, Neville Butcher, Ashok Kothapalli, Jiacheng Zhao, Joanne Therese Blanchfield, Christopher N. Subasic, James Lynden Grace, Changkui Fu, Xiao Tan, John F. Quinn, David Ascher, Michael R Whittaker, Andrew Whittaker, Lisa Kaminskas
Inhalable nanomedicines are increasingly being developed to optimise the pharmaceutical treatment of respiratory diseases. Large lipid-based nanosystems at the forefront of the inhalable nanomedicines development pipeline, though, have a number...
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xi

Give in to some Leica lure! Xiaomi 14 review 

By www.thehindubusinessline.com
Published On :: Sun, 14 Apr 2024 09:10:16 +0530

The flagship smartphone has a lot of allure, but what holds it back?


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iPhone 16 Pro - Unboxing

By www.thehindubusinessline.com
Published On :: Fri, 04 Oct 2024 14:58:11 +0530


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Engineering colleges anxious as companies cut campus recruitment

By www.thehindu.com
Published On :: Wed, 14 Jun 2023 14:43:59 +0530

Market trends may have forced firms to reduce recruitment, say placement officers; experts advise students, colleges to look beyond IT, ITeS firms


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Flexible employment for homemakers is gaining ground in corporate India

By www.thehindu.com
Published On :: Wed, 24 Jan 2024 09:23:43 +0530


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Timeboxing is the answer: An excerpt from Timeboxing: The Power of Doing One Thing at a Time by Marc Zao-Sanders

By www.thehindu.com
Published On :: Sat, 04 May 2024 16:14:58 +0530

How to deal with short attention spans, making decisions and allocate your energy and live a mindful life


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Flexible, and caring for the environment

By www.thehindu.com
Published On :: Fri, 12 Feb 2016 15:07:00 +0530

A look at the some of the architectural creations that related to location and culture, and won awards as well.


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A crop of new-age schools in India now boasts of seamless designs, flexible furniture, and collaborative spaces

By www.thehindu.com
Published On :: Fri, 14 Apr 2023 16:43:58 +0530

Meet the Indian designers doing away with cramped classrooms and dull walls and prioritising schools with flexible furniture, collaborative spaces, and interactive elements


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SA Test team controversy | This might be an inflexion point in the game, but we need to care

By www.thehindu.com
Published On :: Wed, 03 Jan 2024 00:30:00 +0530

Test cricket may be rushing to its end faster than we imagined, and in the next decade younger fans will need to be told what it was and why it no longer existed


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Asset-light approach: EV start-ups turn to micro-factories to cut costs, enhance flexibility

By www.thehindubusinessline.com
Published On :: Tue, 12 Nov 2024 15:59:28 +0530

Micro-factories are closer to the market, require less capital investment, and are faster to set up


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Maize research body seeks funding to undertake research on managing aflatoxin in DDGS

By www.thehindubusinessline.com
Published On :: Tue, 12 Nov 2024 20:26:20 +0530

IIMR says various technologies can be used to reduce the aflatoxin


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Leica love goes the distance: Xiaomi 14 CIVI review

By www.thehindubusinessline.com
Published On :: Thu, 20 Jun 2024 16:52:32 +0530

The photography-forward smartphone offers a unique aesthetic for enthusiasts


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Xiaomi to ship 70 crore devices in India over next ten years

By www.thehindubusinessline.com
Published On :: Mon, 08 Jul 2024 22:00:00 +0530

Currently, the company says it has shipped 35 crore devices in India, which includes 25 crore smartphones


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  • Mobiles & Tablets
xi

The gentle hum of anxiety

By www.thehindubusinessline.com
Published On :: Tue, 23 Sep 2014 17:05:57 +0530


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xi

The Hugo Barra factor in Xiaomi

By www.thehindubusinessline.com
Published On :: Wed, 20 May 2015 16:09:10 +0530


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xi

Cake-mixing ceremony ushers in the Christmas spirit in Madurai

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 18:54:14 +0530


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Xiaomi announces Redmi A4 5G powered by Snapdragon 4s Gen 2 processor at IMC 2024

By www.thehindu.com
Published On :: Wed, 16 Oct 2024 17:06:12 +0530

Xiaomi India President Muralikrishnan B said that the new Redmi A4 5G will be priced under ₹10,000 and will be launched commercially later this year


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