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Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02848A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sandur bypolls: Ballari Deputy Commissioner appeals to voters to exercise franchise




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CSK has been a great franchise to work for, says Bichel




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Kalinga look to stop Ranchi juggernaut

Both Delhi Waveriders and Jaypee Punjab Warriors will hope to reach their third final




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IPL’s business value rises to $16.4 billion in 2024, CSK most valuable franchise

The report highlights the league’s global appeal, strategic initiatives, and engagement with fans




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IPL player retention: Dhoni, Kohli, Rohit, ABD, stay with their franchises

The Indian Premier League player auction is to be held later this month




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Watch: Theft at Chitale Bandhu franchise on Pune’s Baner Road; probe underway




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Urging sex workers to exercise their franchise, PMC holds voter awareness rally in Budhwar Peth




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CSK CEO Kasi Viswanathan spells out franchises’ plan for Rishabh Pant at the IPL auctions




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CORNER KETCH RD BTWN BRANCH RD AND PINE HILL RD HAS INTERMITTENT LANE CLOSURES DUE TO CONSTRUCTION UNTIL 5PM




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SHARPTOWN RD BTWN BRANCH SCHOOL RD & HORSEY CHURCH RD WILL EXPERIENCE INTERMITTENT LANE CLOSURES UNTIL 5PM.




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Evaluating a franchise

For one who is contemplating becoming a self employed business person for the first time, there is more to consider than 'the franchise'.  The franchise is merely a method of establishing a business.  Of course one has to consider many ...




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Franchising Focus - Issue 17

Editorial Last year we devoted an issue of Franchising Focus to the international market place in view of the increasing interest in cross border franchising and in global growth by so many systems. There have been a number of changes in the la...




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Franchising Focus - Issue 18

Moldova We are providing more detail on Moldova as the provisions in many respects are quite unusual to an extent which makes one wonder how much the draftsman understood franchising.  Moldova's approach has been to provide a Chapter i...




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E-briefing - New China franchise regulations: replacement of approvals by registration?

Introduction The long-awaited regulations on the Administration of Commercial Franchise Operations (the 'New Regulations') were promulgated by the State Council of the PRC on 6 February 2007, and will take effect on 1 May 2007. They apply equally t...




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Franchising focus

Franchising is expanding Our franchising team is currently working on a number of exciting new instructions. Most of these have an international flavour and it is clear that franchising is now the major way to build brands in other countries. Our ...




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Restrictive covenants in franchise agreements

The courts continue to be asked by franchisees to limit the scope of their post termination restrictive covenants. It is becoming key for franchisors to show that the duration of their restrictions reflect the time that it would...




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Cousins to Prescott: Franchise tag 'can be your friend'

Kirk Cousins knows a thing or two about playing under the franchise tag, having done so in the 2016 and 2017 seasons before signing a lucrative three-year, $84 million contract with the Minnesota Vikings.




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'Jack Reacher: Never Go Back': Desperate Attempt To Replicate A Franchise

"Jack Reacher: Never Go Back"; Director: Edward Zwick; Cast: Tom Cruise, Cobie Smulders, Aldis Hodge, Danika Yarosh, Patrick Heusinger, Holt McCallany, Robert Knepper; Rating: **1/2




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The Branch Managar State Bank Of ... vs The Managing Director Nakoda ... on 21 January, 2020

>. Learned counsel for the appellants has also filed written notes of arguments and in reply a further written note of arguments has been filed by learned counsel for the respondent. The respondent, as an account holder in the State Bank of India (SBI), suffered a loss of Rs. 18,35 lakh through 20 internet transactions and the money was transferred to 20 accounts, all with the SBI. The account holder/complainant filed Petition No. 1 of 2013 before the leamed A.O./Secretary to Government, Information Technology, Electronics and Communications Department, Government of Andhra Pradesh. After hearing the parties in detail and taking into consideration the defence of the Bank, which is the appellants herein, and all the relevant documents, learned A.O. by the impugned order dated 12,3.2014 has allowed claim of the complainant who is respondent herein and directed SBI to pay the entire amount of Rs. 18.35 lakh with interest from the date of loss ie. 13.5.2012 till the date of payment along with the costs of Rs. 39,750.00. The rate of interest is 18% per annum. Admittedly, nothing has been paid by SBI so far.




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Western India Cashew Company vs The Branch Secretary on 5 May, 2020

2. Brief facts necessary to be noticed for deciding this petition are that in the above dispute raised under the provisions of the Industrial Disputes Act, 1947, the Labour court was called upon to adjudicate a reference wherein the issue was "whether the denial of employment of Smt.Ramani Amma, Smt.Geetha.G. and Geetha.R, who were employees of Western India Cashew Company, was justifiable and if it was found otherwise, the relief for which they were entitled to."

3. The case of the Union, which espoused the cause of the workers, was that the delinquent workers were employed by the management in their packing centre at Puthentheruvu, Karunagappally. Since 26.10.2012 was a public holiday owing to Bakrid, the factory was closed. On 27.10.2012, when the workers reached the factory, they were denied employment by the Management. The Union raised an industrial dispute and the matter reached the District Labour Officer, who convened a conference. In the meantime, a WP(C) No.12490/2018 3 show cause notice was issued to the workers and consequently on 2.11.2012, the workers were suspended from service pending enquiry. An enquiry officer was appointed who proceeded with the enquiry and submitted a report with the finding that the workers were guilty of all charges. Banking on the said report, the workers were dismissed from service with retrospective effect. According to the Union, the enquiry which was conducted was a farce and is therefore vitiated. The principles of natural justice were violated and the management failed to bring home the charge. They also contended that the punishment imposed was grossly disproportionate to the nature of charges levelled against the workers.




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The electrician, or, A practical treatise upon the science of electricity: considered in its various branches of atmospheric, frictional, thermo, galvanic, magneto and animal electricity, terrestial, inductive, and electro magnetism: with a descriptive vi

Archives, Room Use Only - TK144.F67 1846




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Cowboys rule out rescinding Dak Prescott franchise tag

The Cowboys have giveth, but they will not be taketh-ing away. The labor deal allowed the Cowboys to use the franchise tag to keep quarterback Dak Prescott from becoming a free agent in March. The labor deal also allows the Cowboys to rescind the franchise tender at any time before he accepts it. Appearing on [more]




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Transmission measurement at the Bernina branch of the Aramis Beamline of SwissFEL

The transmission of the optical components of the Bernina branch of the Aramis beamline at SwissFEL has been measured with an X-ray gas monitor from DESY and compared with a PSI gas detector upstream of the optical components. The transmission efficiencies of the Mo, Si and SiC mirror coatings of the Aramis beamline and the various other in-beam components were evaluated and compared with theoretical calculations, showing an agreement of 6% or better in all cases. The experiment has also shown the efficacy of the high-harmonic rejection mirrors at the Bernina branch of the Aramis beamline at SwissFEL, and characterized the transmission efficiency of the on-line spectrometer in the Aramis beamline. The theoretical transmission of the mirror coatings match the experimental data to within 7%. The accuracy of these measurements was checked against a radiative bolometer from a Japanese collaboration and found to agree to a level of 4% or better. Further comparisons with a diamond detector from a US-based inter-institute collaboration demonstrated a good agreement for the attenuator settings of the beamline.




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Crystal structure of an oxidized mutant of human mitochondrial branched-chain aminotransferase

This study presents the crystal structure of a thiol variant of the human mitochondrial branched-chain aminotransferase protein. Human branched-chain aminotransferase (hBCAT) catalyzes the transamination of the branched-chain amino acids leucine, valine and isoleucine and α-ketoglutarate to their respective α-keto acids and glutamate. hBCAT activity is regulated by a CXXC center located approximately 10 Å from the active site. This redox-active center facilitates recycling between the reduced and oxidized states, representing hBCAT in its active and inactive forms, respectively. Site-directed mutagenesis of the redox sensor (Cys315) results in a significant loss of activity, with no loss of activity reported on the mutation of the resolving cysteine (Cys318), which allows the reversible formation of a disulfide bond between Cys315 and Cys318. The crystal structure of the oxidized form of the C318A variant was used to better understand the contributions of the individual cysteines and their oxidation states. The structure reveals the modified CXXC center in a conformation similar to that in the oxidized wild type, supporting the notion that its regulatory mechanism depends on switching the Cys315 side chain between active and inactive conformations. Moreover, the structure reveals conformational differences in the N-terminal and inter-domain region that may correlate with the inactivated state of the CXXC center.




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DNA evidence is rearranging the branches of the avian family tree

When songwriter Oscar Hammerstein penned the lyrics “fish gotta swim, birds gotta fly,” he clearly did not have the ratites in mind. Large flightless birds, the ratites include ostriches, emus, rheas and cassowaries, along with kiwis and several extinct species.

The post DNA evidence is rearranging the branches of the avian family tree appeared first on Smithsonian Insider.




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Deadbeat ant species branched off as parasite inside its own colony

A newly-discovered species of ant supports a controversial theory of species formation. The ant, known to live only under a single eucalyptus tree on the […]

The post Deadbeat ant species branched off as parasite inside its own colony appeared first on Smithsonian Insider.




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Commonwealth Bank to shut down 114 branches amid coronavirus downturn

Australia-based Commonwealth Bank has announced the temporary shutdown of 114 branches to stave off coronavirus-related downturn.




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Years After The Gas Blowout, Recriminations Continue In Porter Ranch

Deirdre Bolona displayed a photo of her and her late father Matt Koenig at a state legislative oversight hearing about the Aliso Canyon natural gas disaster. ; Credit: Sharon McNary/KPCC

Sharon McNary

It’s been nearly four years since the smell and chemicals from a ruptured gas well at an underground storage field forced thousands of Porter Ranch residents to leave their neighborhood for months. The recriminations and protests have not stopped.

State legislators held a hearing in Porter Ranch Tuesday to review how gas field owner Southern California Gas and public officials responded to the blowout. 

This content is from Southern California Public Radio. View the original story at SCPR.org.




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Adidas India deploys mobility solution in its 15+ franchise stores

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Zillow Now Partners with over 250 Canadian Brokerages and Franchisors




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Walk-In Interviews in North Branch

38625 14th Avenue, Suite 100
North Branch, MN 55056
Thursday, May 28, 2020, 9am – 4pm

Every Thursday Residential Services, Inc (RSI) hosts walk-in interviews at our office in North Branch, hiring for the position of Direct Support Professional.

When: Thursdays from 9am-4pm
Where: 38625 14th Avenue, Suite 100


Qualifications:
-Must be 18 years of age (21 to work in child foster care settings)
-Must be able to pass a background check
Passionate about improving the lives of others

About the Job:
DSPs provide individualized services to people with disabilities and/or mental illness who are living in home settings. The people who receive services from RSI rely on their caregivers to provide a safe living environment and to help meet all of their physical, emotional, social, medical, spiritual, and recreational needs and wants. DSPs assist in a variety of day-to-day tasks based on the individual needs and goals of the people they are caring for, which could include medication administration, household duties, assistance with personal hygiene, and community activities such as shopping, concerts, going out to eat, movies, fitness, outdoor recreation, and more.

RSI is an Equal Opportunity Employer

Event type: Job and Career Fairs
Filter by Location: Greater Minnesota
Event Audience: For Job Seekers, For Veterans
Accommodation Request: 2187407621
CareerForce Sponsored Event: Other event
More infowww.rsi.jobs



  • 2020/05/28 (Thu)

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Walk-In Interviews in North Branch

38625 14th Avenue, Suite 100
North Branch, MN 55056
Thursday, May 21, 2020, 9am – 4pm

Every Thursday Residential Services, Inc (RSI) hosts walk-in interviews at our office in North Branch, hiring for the position of Direct Support Professional.

When: Thursdays from 9am-4pm
Where: 38625 14th Avenue, Suite 100


Qualifications:
-Must be 18 years of age (21 to work in child foster care settings)
-Must be able to pass a background check
Passionate about improving the lives of others

About the Job:
DSPs provide individualized services to people with disabilities and/or mental illness who are living in home settings. The people who receive services from RSI rely on their caregivers to provide a safe living environment and to help meet all of their physical, emotional, social, medical, spiritual, and recreational needs and wants. DSPs assist in a variety of day-to-day tasks based on the individual needs and goals of the people they are caring for, which could include medication administration, household duties, assistance with personal hygiene, and community activities such as shopping, concerts, going out to eat, movies, fitness, outdoor recreation, and more.

RSI is an Equal Opportunity Employer

Event type: Job and Career Fairs
Filter by Location: Greater Minnesota
Event Audience: For Job Seekers, For Veterans
Accommodation Request: 2187407621
CareerForce Sponsored Event: Other event
More infowww.rsi.jobs



  • 2020/05/21 (Thu)

ranch

Walk-In Interviews in North Branch

38625 14th Avenue, Suite 100
North Branch, MN 55056
Thursday, May 14, 2020, 9am – 4pm

Every Thursday Residential Services, Inc (RSI) hosts walk-in interviews at our office in North Branch, hiring for the position of Direct Support Professional.

When: Thursdays from 9am-4pm
Where: 38625 14th Avenue, Suite 100


Qualifications:
-Must be 18 years of age (21 to work in child foster care settings)
-Must be able to pass a background check
Passionate about improving the lives of others

About the Job:
DSPs provide individualized services to people with disabilities and/or mental illness who are living in home settings. The people who receive services from RSI rely on their caregivers to provide a safe living environment and to help meet all of their physical, emotional, social, medical, spiritual, and recreational needs and wants. DSPs assist in a variety of day-to-day tasks based on the individual needs and goals of the people they are caring for, which could include medication administration, household duties, assistance with personal hygiene, and community activities such as shopping, concerts, going out to eat, movies, fitness, outdoor recreation, and more.

RSI is an Equal Opportunity Employer

Event type: Job and Career Fairs
Filter by Location: Greater Minnesota
Event Audience: For Job Seekers, For Veterans
Accommodation Request: 2187407621
CareerForce Sponsored Event: Other event
More infowww.rsi.jobs



  • 2020/05/14 (Thu)

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Morgan Freeman turns ranch into a sanctuary for bees

Actor doesn't even wear a veil to protect himself because, clearly, all living things love Morgan Freeman.



  • Arts & Culture

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Move over, Old Faithful: Fly Ranch Geyser gets its moment in the sun

If you've ever wanted to visit this colorful, man-made geyser in Nevada, you may soon get your wish — thanks to the organizers of Burning Man!



  • Wilderness & Resources

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This bird with a haunting song can pretend to be a branch

The drab potoo bird uses its coloring to disguise itself as a tree limb.




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Simple tree branch water filter removes 99% of E. coli

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DARPA launches biotech security branch

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  • Research & Innovations

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40 horses saved from California ranch fire

Community works together to rescue dozens of horses from California wildfire.



  • Climate & Weather

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Branching Out: Women in Forestry

In honor of Women's History Month, Enviva honors and highlight the achievements of 3 remarkable female foresters.



  • Sustainable Business Practices

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Blog: Open or closed - the branch dilemma facing brokers

As the first working week of self-isolation comes to a close for many, Insurance Age content director Jonathan Swift looks at the stance brokers are taking in terms shutting up shop or keeping their branches open.




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7-Eleven and franchisees authorised to co-operate on store opening times

24 April 2020

7-Eleven and its franchisees have been granted conditional interim authorisation to discuss potential temporary store closures or reduced trading hours in light of reduced customer demand because of COVID-19 restrictions.

7-Eleven owns and operates stores in competition with its franchisees in some areas and therefore discussions and agreements between them risk breaching the competition laws.

“We recognise that 7-Eleven and its franchisees are facing difficult trading conditions due to the COVID-19 pandemic, and believe this co-operation could help the network and individual stores to remain viable,” ACCC Chair Rod Sims said.

“Importantly, franchisees are not required to temporarily close or reduce their store hours if they do not wish to. Our decision to grant interim authorisation does not force franchisees to agree to the terms offered by 7-Eleven.”

Franchisees that agree to close temporarily will receive an ex-gratia payment from 7-Eleven to cover certain unavoidable operational costs. For franchisees that agree to reduce their hours, the minimum guaranteed income that the franchisee receives from 7-Eleven would be pro-rata adjusted to reflect the temporary reduction in trading hours.

“Franchisees are strongly encouraged to seek independent legal and financial advice when considering whether to adopt these temporary measures,” Mr Sims said.

Interim authorisation is subject to a condition that requires 7-Eleven to notify the ACCC of arrangements reached with franchisees to provide some ACCC oversight.

“We are going to closely monitor the effect of these arrangements and when it is appropriate for this authorisation to be revoked,” Mr Sims said.

Having granted interim authorisation for the arrangements, the ACCC will seek feedback on 7-Eleven’s application for authorisation. 

Details on how to make a submission and more information, including the ACCC’s interim authorisation decision, is available at 7-Eleven Stores Pty Limited.

Background

Authorisation provides statutory protection from court action for conduct that might otherwise raise concerns under the competition provisions of the Competition and Consumer Act 2010.

The Franchising Code of Conduct will continue to apply to franchisees that operate non-fuel stores and the Oil Code will continue to apply to franchisees that operate fuel stores. Both codes contain a dispute resolution process.

Dispute resolution services are provided by the Australian Small Business and Family Enterprise Ombudsman (ASBFEO). More about resolving franchising disputes and oil code dispute resolution is available on the ACCC website.

Section 91 of the Act allows the ACCC to grant interim authorisation when it considers it is appropriate. This allows the parties to engage in the proposed conduct while the ACCC is considering the merits of the substantive application.

Release number: 
81/20
ACCC Infocentre: 

Use this form to make a general enquiry.

Media enquiries: 
Media team - 1300 138 917
Audience




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Bob Jane gives undertaking in relation to franchise agreements

30 April 2020

Bob Jane Corporation Pty Ltd (Bob Jane) has given the ACCC a court-enforceable undertaking to comply with its obligations under the Franchising Code of Conduct in relation to renewal and extension of franchising agreements.

The ACCC was concerned that Bob Jane failed to comply with its obligations under the Code relating to end of term and renewal of agreements. In particular, Bob Jane failed to notify some franchisees whether it intended to renew or extend their franchise agreements at least six months before the expiry of their agreements.

The ACCC was also concerned that it extended the term of certain franchise agreements without first providing required documentation to franchisees and obtaining a written statement that the franchisees had received, read and had an opportunity to understand certain documentation.

“Under the Franchising Code, franchisors must notify franchisees in writing whether they intend to extend or renew the agreement prior to the expiry of the agreement,” ACCC Deputy Chair Mick Keogh said.

“This is an important obligation as it allows franchisees to make informed decisions about the future direction of their business.”

“Franchisors must ensure they comply with their obligations under the Code. We took this action because we were concerned that Bob Jane failed to meet a number of its obligations,” Mr Keogh said.

Bob Jane has acknowledged that its conduct was likely to have contravened the Franchising Code of Conduct and section 51ACB of the Competition and Consumer Act 2010. 

As part of the undertaking, Bob Jane has agreed not to terminate any franchise agreements operating under interim arrangements without providing six months’ written notice.

As required by the Code, it will also obtain written notice from franchisees that they have received, read and had a reasonable opportunity to understand disclosure documents and the Code before entering into, renewing, transferring or extending the term or scope of franchise agreements.

Bob Jane has also undertaken to implement and maintain a compliance program for three years.

“Ensuring small businesses receive the protections of competition and consumer laws, with a focus on the Franchising Code, is a current compliance and enforcement priority for the ACCC,” Mr Keogh said. 

“Franchisors often have a stronger bargaining position in their dealings with franchisees, and we will continue to investigate and take action against franchisors where we believe there has been a potential breach of the Code.”

A copy of the undertaking can be found at Bob Jane Corporation Pty Ltd.

Background

Bob Jane, trading as Bob Jane T-Marts, operates a national network of franchised and company-owned tyre retail stores supplying tyres for a wide range of vehicles, and tyre and car maintenance-related services.

The Franchising Code of Conduct is a mandatory industry code across Australia that regulates the conduct of franchising participants towards each other. The ACCC regulates the Code and investigates alleged breaches.

In 2019, a Franchising Taskforce was established to provide advice to the Government to inform the Government’s response to the recommendations made to the Parliamentary Joint Committee Inquiry into franchising. 

On 11 November 2019, the Taskforce released a Consultation Regulation Impact Statement (RIS) for public consultation setting out identified problems with the franchising sector and possible options for government action.

The ACCC’s submission outlines the ACCC’s view that serious consideration should be given to a different regulatory model to address the fundamental concerns that persist in the franchising sector, rather than the incremental changes to the Code currently being considered by the Franchising Taskforce.

The ACCC’s submission in response the RIS can be found on the Department of Industry, Science, Energy and Resources website.

More information for the franchising sector can be found on the ACCC’s website.

Release number: 
86/20
ACCC Infocentre: 

Use this form to make a general enquiry.

Media enquiries: 
Media team - 1300 138 917
Audience




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How Turn A Franchise Agreement To Your Advantage

How to understand the terms of your franchise agreement and turn it to your advantage, before signing on the dotted line...




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California Incorporation – Look Out For the High Franchise Tax

California incorporation is simple on its face while being complex once you get into it...




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Tips to remember when choosing the best franchise.

How do you evaluate the various franchise opportunities that are out there to find the best fit for you?




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Dr. Helen Cadiz to Join Women Veterans In Crisis - Whispering Oaks Ranch as Director Clinical Services

Answering the President's Executive Order "National Roadmap to Empower Veterans and End Suicide," WVIC plan is a bold, shovel-ready therapeutic model for our nation.




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Human Trafficking Must Be Stopped And Everyone Has A Role To Play Says Monica Deller Of Trauma To Triumph Family Ranches

Monica Deller, an Amazon Bestselling author, hopes to bring more awareness to the issue of human trafficking and is compiling stories for a new book series on human trafficking and related subjects.




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Word Branch Publishing Re-Releases Lynny Prince's Native American Thriller, Scattered Leaves: The Legend of Ghostkiller

Forget everything you know about how the West was won ~ The Spirits have a story to tell.