pti

Engineering disease analyte response in peptide self-assembly

J. Mater. Chem. B, 2024, 12,10757-10769
DOI: 10.1039/D4TB01860E, Review Article
Open Access
Sihan Yu, Matthew J. Webber
The need to enhance the precision and specificity of therapeutic nanocarriers has led to the development of nanoscale peptide assemblies capable of sensing and responding to disease-related analytes.
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pti

Tuning the affinity of probes with transmembrane proteins by constructing peptide-conjugated cis/trans isomers based on molecular scaffolds

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01801J, Paper
Jing-Jing Hu, Juliang Yang, Yiheng Liu, Guangwen Lu, Zujin Zhao, Fan Xia, Xiaoding Lou
Peptide-conjugated cis/trans isomers were designed. cis-RTP interacts more stably with cell membranes than trans-RTP, and it has shown more excellent properties in inhibiting cell migration and killing cells.
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pti

Nanocrystalline alloy-mediated delivery of mosaic epitope peptides for universal influenza vaccine

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB00742E, Paper
Hongyu Wang, Han Fu, Liyan Zhai, Jiaqing Le, Bohan Guo, Yuyang Zhou, Chenlin Ji, Dapeng Li, Yue Zhang
Mosaic influenza antimicrobial peptide-like epitopes (Ampitopes) co-crystalize with poly(I:C), a TLR3 agonist, into nanocrystalline vaccine, which boosts immunogenicity via multivalent toll like receptor 3 (TLR3) binding and immune activation.
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pti

Enzymatic self-assembly of short peptides for cell spheroid formation

J. Mater. Chem. B, 2024, 12,11210-11217
DOI: 10.1039/D4TB01154F, Paper
Open Access
Jiaqi Guo, Weiyi Tan, Bing Xu
Biphenyl-capped phosphopeptides instruct cell aggregation into spheroids, with minimal effective concentrations below 10 μM. Key factors driving morphogenesis include the self-assembly ability and dynamic shapeshifting of the peptide assemblies.
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pti

Effect of supramolecular peptide hydrogel scaffold charge on HepG2 viability and spheroid formation

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01701C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yu Xin, Cosimo Ligorio, Marie O’brien, Richard Collins, Siyuan Dong, Aline F. Miller, Alberto Saiani, Julie E. Gough
Understanding how fibre charge in self-assembling peptide hydrogel networks affect HepG2 cell fate and spheroid formation.
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pti

Polycyclic aromatic polymer nanoparticles show potent infectious particle adsorption capability

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01793E, Paper
Yudai Oishi, Mako Toyoda, Nanami Hano, Chihiro Motozono, Takamasa Ueno, Makoto Takafuji
Nonspecific viral adsorption by polymer nanoparticles is more economical and superior in terms of operating cost and energy efficiency than viral adsorption using virus-specific antibodies and filtration techniques involving size...
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pti

A water playground for peptide re-assembly from fibrils to plates

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01727G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simone Adorinni, Marina Kurbasic, Ana M. Garcia, Slavko Kralj, Ottavia Bellotto, Erica Scarel, Paolo Pengo, Rita De Zorzi, Michele Melchionna, Attilivio V. Vargiu, Silvia Marchesan
Water plays a key role in the irreversible transition from peptide fibrils to plates.
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pti

Development of a Xanthene-Based NIR Fluorescent Probe for Accurate and Sensitive Detection of γ-Glutamyl Transpeptidase in Cancer Diagnosis and Treatment

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01841A, Paper
Chia-Kai Lai, KUPPAN MAGESH, Sivan Velmathi, Shu-Pao Wu
γ-Glutamyl transpeptidase (GGT) regulates glutathione (GSH), essential for cell functions and linked to cancer. High GGT levels in tumors make it a valuable cancer biomarker. Current GGT detection methods often...
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pti

Acoustic levitation and manipulation of columns of droplets with integrated optical detection for parallelisation of reactions

Analyst, 2024, 149,5546-5554
DOI: 10.1039/D4AN01096E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruchi Gupta, Nicholas J. Goddard
In this work, acoustically levitated droplets serve as wells of microtitre plates and are acoustically manipulated to perform chemical and biological reactions in a non-contact fashion.
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pti

Exploring gunshot residue detection in fingerprints by functionalized particle-coupled matrix-assisted laser desorption/ionization mass spectrometry

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01260G, Paper
Sunil S. Adav, Yan Wen Crystal Tan, Choon Teck Low, Song Wei Loo, Ridhwan Yusoff, Archana Gautam, Yuk Lin Yong, Chiew Yung Yang, Chin Chin Lim, Kee Woei Ng
In firearm forensic investigations, detecting gunshot residue (GSR) is crucial for linking firearms to suspects and determining firing distance for forensic reconstruction.
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pti

Magneto-optical properties of heavily Fe-doped GaAs: a density functional approach

Phys. Chem. Chem. Phys., 2024, 26,27510-27518
DOI: 10.1039/D4CP03101F, Paper
J. Zarpellon, D. H. Mosca, J. Varalda
Heavily Fe-doped GaAs, investigated using a DFT approach, reveals a spin polarized electronic band structure correlated with magnetic circular dichroism and complex Kerr and Faraday rotation angles in agreement with some previous experiments.
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pti

Structural and sorption characteristics of an aerogel composite material loaded with flufenamic acid: insights from MAS NMR and high-pressure NOESY studies

Phys. Chem. Chem. Phys., 2024, 26,27301-27313
DOI: 10.1039/D4CP03217A, Paper
Valentina V. Sobornova, Valeriya V. Mulloyarova, Konstantin V. Belov, Alexey A. Dyshin, Peter M. Tolstoy, Mikhail G. Kiselev, Ilya A. Khodov
The structural and sorption characteristics of a composite material consisting of a silica aerogel loaded with flufenamic acid were investigated using a variety of nuclear magnetic resonance techniques.
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pti

First-principles study on the lithiation process of amorphous SiO anode for Li-ion batteries with Bayesian optimization

Phys. Chem. Chem. Phys., 2024, 26,27561-27566
DOI: 10.1039/D4CP02533D, Paper
Ryoya Shintaku, Tomoyuki Tamura, Shogo Nogami, Masayuki Karasuyama, Takakazu Hirose
Bayesian optimization allows theoretical investigation of the lithiation process of amorphous SiO anode materials for lithium (Li) ion batteries (LIBs).
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pti

Exploring the valleytronic, optical, and piezoelectric properties of Janus MoBXY2 (X = N, P; Y = S, Se, Te) monolayers for multifunctional applications

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03793F, Paper
Luogang Xie, Lingli Wang, YanDong Ma, Hongyan Lu, Yang Yang
Unveiling novel Janus MoBXY2 monolayers with unique valleytronic, optical, and piezoelectric properties for multifunctional applications.
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pti

Optimization of preparation conditions and design of device configurations for Cu3AsS4 solar cells: a combined study of first-principles calculations and SCAPS-1D device simulations

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03392B, Paper
Yi Huang, Changqing Lin, Yang Xue, Bingyuan Huang, Dan Huang
Former studies have investigated the band structure and optoelectronic properties of Cu3AsS4 and suggested that it is a promising photovoltaic (PV) absorber. However, its power conversion efficiency (PCE) from experiments...
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pti

Influence of symmetry breaking on the absorption spectrum of crystal violet: from isolated cations at 5 K to room temperature solutions

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03825H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alexander Schäfer, Samuele Giannini, Dmitry Strelnikov, Theresa Mohr, Fabrizio Santoro, Javier Cerezo, Manfred M. Kappes
Theoretical and experimental spectroscopy of crystal violet resolves the influence of temperature and symmetry breaking on absorption properties in different environments.
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pti

Effects of surface oxygen vacancy on CO2 adsorption and its activation towards C2H4 using metal (Cu, Pd, CuPd) cluster-loaded TiO2 catalysts: A first principles study

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03507K, Paper
Sajjad Hussain, Lina Zhang, Zhengzheng Xie, Jianjun Yang, Qiuye Li
The conversion of the highly selective CO2 reduction reaction (CO2RR) into desired value-added multicarbon compounds, like C2H4, is crucial, but it is mainly constrained by high energy barrier for C-C...
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pti

First-principles study on stability, electronic and optical properties of 2D SbXY (X=Se/Te, Y=I/Br)Janus layers

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP04077E, Paper
Anjana E Sudheer , Amrendra Kumar, Tejaswini G, Muthu Vallinayagam, Matthias Posselt, Matthias Zschornak, Chinnathambi Kamal, D. Murali
Motivated by the exceptional optoelectronic properties of 2D Janus layers (JLs), we explore the properties of group Va antimony-based JLs SbXY (X=Se/Te, Y=I/Br). From the Bader charges, the elec-tric dipole...
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pti

Water adsorption at the (010) and (101) surfaces of CuWO4

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02699C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xuan Chu, David Santos-Carballal, Nora H. de Leeuw
The copper tungstate CuWO4 surfaces tend to remain either dry or fully hydrated, depending on specific environmental conditions.
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pti

Morphology optimization via pre-aggregation and miscibility matching in PM6:L8-BO ternary organic solar cells

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03206C, Paper
Chuyue Wei, Junwei Zhang, Jing Deng, Xiangyan Yang, Jiahui Luo, Zixiao Xu, Lin Zhang, Shuaishuai Yuan, Weihua Zhou
Pre-aggregation and miscibility matching accounting for morphology optimization in ternary organic solar cells based on a PM6:L8-BO system.
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pti

Deciphering nonlinear optical properties in functionalized hexaphyrins via explainable machine learning

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03303E, Paper
Eline Desmedt, Michiel Jacobs, Mercedes Alonso, Freija De Vleeschouwer
The NLO response of hexaphyrins is traced back to its driving forces using kernel ridge regression and explainable machine learning. Orbital and charge-transfer based features play a key role, as opposed to aromaticity and geometrical descriptors.
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pti

It’s fixed: floating rate is the better option

Study the pros and cons well before choosing your home loan. By Balaji Rao




pti

PIX: Palak-Mithoon's Wedding Reception

While the wedding was an intimate affair featuring only family and close friends, the couple hosted a grand reception for industry folk.




pti

The Importance of Title Tags: Tips and Tricks to Optimize for SEO

When it comes to on-page SEO, there’s one element that plays a pivotal role in both search engine rankings and user engagement: the HTML title tag. Often overlooked, this small but mighty piece of code can have a significant impact on how your website is perceived by search engines like Google and by potential visitors browsing the search engine results pages.




pti

Recent advances in super-resolution optical imaging based on aggregation-induced emission

Chem. Soc. Rev., 2024, 53,3350-3383
DOI: 10.1039/D3CS00698K, Review Article
Feng-Yu Zhu, Li-Jun Mei, Rui Tian, Chong Li, Ya-Long Wang, Shi-Li Xiang, Ming-Qiang Zhu, Ben Zhong Tang
From aggregation-induced emission to super-resolution imaging: the significance of reversible dynamic interaction.
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pti

Sixty years of electrochemical optical spectroscopy: a retrospective

Chem. Soc. Rev., 2024, 53,3579-3605
DOI: 10.1039/D3CS00734K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chao-Yu Li, Zhong-Qun Tian
After sixty years of development, electrochemical optical spectroscopy has evolved from the early phase of proof-of-concept to an advanced phase with various spectroscopic modes and has contributed significantly to the field of electrochemistry.
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pti

Peptide hydrogen-bonded organic frameworks

Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review
Open Access
Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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pti

Peptide-based self-assembled monolayers (SAMs): what peptides can do for SAMs and vice versa

Chem. Soc. Rev., 2024, 53,3714-3773
DOI: 10.1039/D3CS00921A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Carlos Redondo-Gómez, Paula Parreira, M. Cristina L. Martins, Helena S. Azevedo
Self-assembled monolayers (SAMs) based on peptides represent a reproducible platform for screening and studying peptide functions and facilitating their translation into multidisciplinary applications.
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pti

Vettel would be amazing option for Mercedes, says Hamilton

“I would love for Seb to come back and I think he would be an amazing option for the team,” Hamilton, who joins Ferrari next season, told a press conference at the Suzuka Circuit ahead of the Japanese Grand Prix




pti

Mahindra Racing cautiously optimistic for 2024-25 season




pti

Pakistan hockey’s long and arduous journey towards redemption and past glory

Among the many factors that point towards the downward spiral since the Asian Games gold in 2010, the structural changes in the feeder system and frequent changes in coaching staff stand out, the ACT bronze might be the first step of a nation trying to dominate a sport it once had




pti

Will an aptitude certificate help?

Is it time to say good bye to character certificates and replace them with a system that helps students find their calling?




pti

More options with IB, IGCSE

These curricula prepare students for a university experience at home and abroad.




pti

Market disruption takes intimate turn

How India launched 60-plus Internet-first innerwear brands, more than any other country except the US




pti

Fostering the digital adoption drive in India

Why 8i Ventures backs startups that are digitising the economy




pti

Loss of fluorine during crosslinking by the biarylitide P450Blt proceeds due to restricted peptide orientation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication
Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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pti

Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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pti

Extended polyene formation by a cryptic iterative polyketide synthase from Rhodococcus

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04963B, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Panward Prasongpholchai, Sam Tucker, Charles Burgess, Robert Jenkins, Ina Wilkening, Christophe Corre, Lijiang Song, Manuela Tosin
Investigations of the workings of a newly identified iterative polyketide synthase from Rhodococcus erythropolis PR4 reveal its ability to synthesise extended polyenes.
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pti

Endosomolytic Peptides Enable the Cellular Delivery of Peptide Nucleic Acids

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05214E, Communication
Open Access
JoLynn B. Giancola, Ronald T. Raines
Precision genetic medicine enlists antisense oligonucleotides (ASOs) to bind to nucleic acid targets important for human disease. Peptide nucleic acids (PNAs) have many desirable attributes as ASOs but lack cellular...
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pti

Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
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pti

Making your open source project sponsor-ready, Part 3: Accepting sponsorships

In the previous two posts in this series, I described why companies sponsor open source projects1 and how following some basic project hygiene can help attract sponsors2. Now that your project is functioning at a high level and is attractive to companies, it’s time to talk specifics about accepting sponsorships from companies. Making it easy...




pti

Selective mineralization at hydrogel interface induced by fusion between peptide hydrogels

Mol. Syst. Des. Eng., 2024, 9,1107-1115
DOI: 10.1039/D4ME00112E, Paper
Yongbaek Kim, Hiroto Isobe, Keishi Nishio, Kazuki Murai
Biomineralization has garnered attention not only for its fundamental role in understanding the mechanisms of biomineral formation but also as a method for fabricating next-generation functional materials.
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pti

Interruption volontaire de grossesse médicamenteuse

24,00 €

Philippe Faucher, Danielle Hassoun
4e édition
octobre 2024
160 pages
Un guide simple et concis pour bien prescrire l'IVG médicamenteuse
Livre
Nouveau
978-2-311-66541-3
Toutes les informations utiles - La prise en charge - La législation à jour
Disponible
Livre




pti

Temperature-dependent structural and optical properties of Sb-doped SnO2 nanoparticles and their electrochemical analysis for supercapacitor application

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00918E, Paper
Towseef Ahmad, Mohd Zubair Ansari
Transparent conducting oxides (TCOs) play an important role in advanced energy harvesting and storage systems, as well as cutting-edge display technology.
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pti

Structural optimization of icaritin for advanced cancer: novel carbamates via oral administration

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05723B, Paper
Fengxiao Li, Weiping Wang, Jiaqi Fan, Yixiu Zhai, Jiaming Zhang, Tianhong Zhang, Qikun Jiang
Carbamates of icaritin (3N-Me and 3N-Et) are synthesized first to overcome the challenge of the phase II metabolism of ICT. 3N-Me has potential as a novel advanced cancer treatment agent via oral administration in the future.
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pti

A boron nitride–carbon composite derived from ammonia borane and ZIF-8 with promises for the adsorption of carbon dioxide

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00643G, Paper
Open Access
Carlos A. Castilla-Martinez, Christophe Charmette, Jim Cartier, Umit B. Demirci
In the present study, we report the synthesis, characterization and assessment of the carbon dioxide adsorption capacity of a composite made of boron nitride and carbon.
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pti

Peptide-linked perylenebisimide and ferrocene dicarboxylic acid conjugates with tunable optoelectronic properties

New J. Chem., 2024, 48,7225-7234
DOI: 10.1039/D3NJ05809C, Paper
Biswanath Hansda, Soumyajit Hazra, Niladri Hazra, Purnadas Ghosh, Arindam Banerjee
Peptide linked perylenebisimide and ferrocene dicarboxylic acid conjugates display wonderful and tunable optoelectronic properties.
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pti

Efficient elimination of Hg(II) from water bodies with acid-modified magnetic biomass spent tea leaves: conditional optimization and application

New J. Chem., 2024, 48,7413-7429
DOI: 10.1039/D4NJ00576G, Paper
Dingli Cheng, Yiwen Li, Xinyu Zheng, Yongfu Guo
To effectively enhance the resource utilization of biomass waste, a acid-modified magnetic biomass spent tea leaves (NiFe2O4/STLs) was prepared via the pyrolysis and co-precipitation methods and used to eliminate mercury (Hg(II)) from water bodies.
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pti

Adsorption behavior of chloramphenicol on an activated carbon from pomelo peel using KHCO3 activator

New J. Chem., 2024, 48,7081-7091
DOI: 10.1039/D3NJ05838G, Paper
Haixia Li, Hai Zhu, Junqiang Qiu, Danning Zheng, Lifang Gao, Dan Zhou, Dan Xu
The pomelo peel-based activated carbon as a high-performance adsorbent for chloramphenicol is synthesized by KHCO3 activator through a solid pyrolysis method.
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