Apparatus and methods are disclosed for rapidly counteracting a transient low-pressure condition, that can occur intermittently in the exhaust section of a power plant or other such industrial facility upstream of exhaust fans as a result of an event that interrupts the generation and/or flow of exhaust gases, using jet nozzles disposed in the exhaust section and connected to a source of pressurized air or other suitable momentum material. By orienting the jet nozzles in a direction generally opposite to the flow of exhaust gas and actuating the system to release a burst of compressed air, for example in the event of a power plant interruption, the low-pressure condition can be ameliorated preventing damage to the exhaust section.

A coal nozzle assembly for a pulverized coal burner includes a diffuser. A flow conditioner also may be used with the assembly. The assembly conditions the coal/air flow before the coal/air flow is introduced to the furnace. The flow conditioner directs the coal into the diffuser where it is swirled to form a fuel rich outer ring disposed about an air rich inner portion before the fuel is delivered to the coal nozzle.

A waste disposal plant includes a combustion chamber (2) inside which waste laid on a combustion grate (3) is burnt, which permits the entrance of an adequate quantity of combustion air in the chamber. The combustion grate includes at least a handling group formed by of fire bars or plates (7), which move alternatively one with respect to the other by advancing the waste on the grate. A handling group permits the alternate movement of the fire bars (7) which are divided in movable fire bars (7a) and fixed fire bars (7b), alternately disposed one with respect to the other, on transversal rows resting one upon the other according to a longitudinal placement with alternate steps.

A fluidized bed reactor includes a bottom portion, a roof portion, and side walls vertically extending between the bottom portion and the roof portion, forming a reaction chamber of the reactor. At least one side wall of the reaction chamber forms at least one vertical indentation in the reaction chamber, which indentation extends from the plane of the at least one side wall towards the reaction chamber. The indentation extending from the plane of the at least one side wall towards the reaction chamber is formed of a portion of the at least one side wall, protruding from the plane of the at least one side wall towards the reaction chamber, and the portion of the at least one side wall includes at least two substantially vertical indenting wall portions deviating from the plane of the at least one side wall at vertical lines within a distance from each other.

A two stage refuse gasification combustion system for processing refuse is disclosed. The system may contain features such as an advancer, a first and second gasifier, a gas regulator, and a post combustor. Additionally, methods for regulating gas and advancing refuse through a two stage refuse gasification combustion system are disclosed.

A leading end located in a two-stage entrained-flow bed coal gasifier has a double-walled structure including an outer cylinder and an inner cylinder, and cooling water for cooling the leading end is supplied through an interior of the inner cylinder to cool the leading end and is then returned to a base end through a space formed between the outer cylinder and the inner cylinder. The space formed between the outer cylinder and the inner cylinder has a smaller channel area than the interior of the inner cylinder, and a swirling flow along a guide formed on an outer circumferential surface of the inner cylinder and a substantially linear flow in a longitudinal direction of the outer cylinder and the inner cylinder are applied to the cooling water returned to the base end through the space formed between the outer cylinder and the inner cylinder.

A combustion device in the form of an elevated fixed-grate that includes arcuately shaped solid refractory brick with ribs placed thereunder so as to allow horizontal air flow for fuel combustion. The brick are arranged atop one another in a stacked concentric configuration that forms a central fuel passageway and allows cascading of a fuel pile throughout the combustion stages. The device provides the benefit of proper de-ashing online while distributing the underfire air radially around the fuel pile. The elevated design of the bricks allows the air to be evenly distributed throughout the fuel pile and further allows the isolation of overfire and underfire air. Segregating overfire and underfire air in an evenly distributed manner allows the burner to combust a wide range of fuel moisture contents without modifying the mechanical components of the burner.

The invention relates to solid fuel units having a fuel supply chamber wherein the fuel to be sent for combustion to the combustion region found in the body is placed and the feed mechanism carrying the solid fuel found in the chamber forward. It is characterized in that it includes a main burning block having a fuel and air cell connected to the solid fuel supply chamber and air outlet vents formed on the external wall surface. A preventive surface is positioned on the main burning block external wall surface in a way that it would form a closed volume in a certain distance.

Methods of combustion include metering a substantially explosible powder into an oxidizing gas using a positive displacement powder dispersion device to suspend the powder in the gas and directing the powder in the gas to form a controlled stream of a moving explosible powder dispersion. In some embodiments, the method further includes igniting the dispersion with an ignition source to produce a stationary deflagrating combustion wave and sustaining combustion by continuing to meter the powder into the gas. In other embodiments, the method further includes adjusting a nozzle velocity of the dispersion to reflect properties of the dispersion to create a sustainable flame and igniting the dispersion to produce a stationary deflagrating wave of the dispersion. In other embodiments, the method further includes igniting the dispersion in a combustion area to produce a stationary deflagrating wave such that a conductive heat transfer from combustion brings the powder to combustion temperature.

A premix burner arrangement for safely oxygen-enriching a premix air-fuel combustion system is disclosed. In the disclosed burner arrangement, a first conduit is arranged and disposed to provide a first gas stream. The first gas stream is a self-reactive or self-flammable premixture comprising air and a combustible gas. At least one second conduit is arranged and disposed to provide a second gas stream circumferentially around the first gas stream. The second gas stream includes oxygen. The premix burner arrangement is configured to combust or react the first stream at a temperature at least 1000° F. greater than the temperature of the second stream. A method and combustion system including the premix burner arrangement are also disclosed.

A burner system for consumption of waste fuel comprises a screw conveyor having a longitudinal hollow interior for air distribution and radially disposed air intake orifices connecting the hollow interior to a plurality of combustion chambers, which includes a first combustion chamber disposed centrally around the screw conveyor and at least one orifice; a second combustion chamber disposed concentrically around the first combustion chamber, receiving burning waste fuel from the first combustion chamber, and in fluid communication with the air intake orifice to provide air from an air blower through the orifice; and a third combustion chamber disposed concentrically around the second combustion chamber, receiving waste fuel from the second combustion chamber, and in fluid communication with the air intake orifice to provide air from the air blower.

A method for starting a burner for combusting synthesis gases is provided. The burner includes first and second fuel passages, the first fuel passage encompasses the second fuel passage in a substantially concentric manner and the gas transferred to the burner is mixed with combusting air and is combusted. In order to start the burner, the second fuel passage is first loaded with a synthesis gas to a predefined burner power at a first starting phase and the first fuel passage is loaded with the synthesis gas at a second starting phase.

A system and techniques for waste oil combustion are provided. The techniques include straining waste oil, separating contaminants from the strained waste oil to produce segregated layers of waste oil, selectively drawing a segregated layer of the waste oil, entraining the drawn waste oil to a burner for combustion, and regulating flow rate to produce a controllable amount of heat output. The system includes a container for straining waste oil, a storage drum for separating contaminants from the strained waste oil via gravity separation to produce segregated waste oil, an oil uptake channel for entraining the waste oil from the storage drum, a fuel regulator for controlling rate of flow of the waste oil from the storage drum to a burner head via the oil uptake channel, and a burner head control for repositioning a burner head under the input stream to produce a controllable amount of heat output.

A hydrogen vacuum furnace (100) is provided with a process chamber (1) wherein a subject (10) to be heated is stored; a heating chamber (2) wherein a heater lamp (25) is stored; and a crystal board (3) for separating the subject (10) and the heater lamp (25) one from the other. In the hydrogen vacuum furnace (100), the subject (10) is heated by a radiant ray applied from the heater lamp (25). The process chamber (1) and the heating chamber (2) are provided with gas feed ports (11, 21) and exhaust ports (12, 22), respectively, for feeding and exhausting a gas. When the subject (10) is being heated, atmospheric pressure in each chamber is adjusted so that the heating chamber (2) is under positive pressure to the process chamber (1) by feeding or exhausting the gas.

A grate bar for an incinerator having a grate bar base body and a high temperature resistant cover plate covering the grate bar base body at least on a surface portion which in operation points to a combustion chamber. The cover plate is separated from the grate bar base body by a thermal insulating material. In the grate bar base body a cavity is inserted in a side pointing to the cover plate and/or in the cover plate in the side pointing to the grate bar base body, which cavity is at least partially filled with a ceramic fiber insulating material. The invention further relates to a method for producing such a grate bar.

The burner preferably exclusively burns substantially explosible solid fuels and preferably has instant ON-OFF thermostat control, wastes no energy preheating the enclosure or external air supply, achieves stable combustion the moment the powder-air mix is ignited in our burner, is used in the upward vertical mode except for oil burner retrofits, burns a solid fuel in a single-phase regime as if it were a vaporized liquid or gas, is designed to complete combustion within the burner housing itself rather than in a large, high temperature furnace enclosure which it feeds, has an ultra-short residence time requirement, is a recycle consuming burner with self-contained management of initially unburned particles, is much smaller, simpler and lower cost, has a wider dynamic range/turndown ratio, is more efficient in combustion completeness and thermal efficiency, and operates with air-fuel mix approximately at the flame speed.

A gasification reactor for processing organic waste in batches comprises a primary gasification reactor (62) that includes a primary gasification chamber (18) and a surrounding combustion chamber (19), a secondary gasification chamber (21), a synthesis gas decontamination unit (42) and a combustible gas selector (41). The waste is loaded into the primary gasification chamber through a latched opening and heated from the combustion of a fuel in the combustion chamber (19) to convert the waste to a synthesis gas. The gasification chamber (18) has an intake (20) for introducing pre-heated process air (1) therein. The combustion chamber operates either with a conventional fuel (9) or with the produced synthesis gas (6). The secondary gasification chamber (21) thermally treats the synthesis gas (2) to eliminate tars. The decontamination unit (42) scrubs the synthesis gas of contaminants including particulates and acid gases. The clean synthesis gas (6) is directed to the combustible gas selector (41) which selectively feeds either the combustible fluid (9) or the synthesis gas (6) to the burner (40).

Improved silicon solar cells, silicon image sensors and like photosensitive devices are made to include strained silicon at or sufficiently near the junctions or other active regions of the devices to provide increased sensitivity to longer wavelength light. Strained silicon has a lower band gap than conventional silicon. One method of making a solar cell that contains tensile strained silicon etches a set of parallel trenches into a silicon wafer and induces tensile strain in the silicon fins between the trenches. The method may induce tensile strain in the silicon fins by filling the trenches with compressively strained silicon nitride or silicon oxide. A deposited layer of compressively strained silicon nitride adheres to the walls of the trenches and generates biaxial tensile strain in the plane of adjacent silicon fins.

Methods and apparatus for converting electromagnetic radiation, such as solar energy, into electric energy with increased efficiency when compared to conventional solar cells are provided. A photovoltaic (PV) device generally includes a window layer; an absorber layer disposed below the window layer such that electrons are generated when photons travel through the window layer and are absorbed by the absorber layer; and a plurality of contacts for external connection coupled to the absorber layer, such that all of the contacts for external connection are disposed below the absorber layer and do not block any of the photons from reaching the absorber layer through the window layer. Locating all the contacts on the back side of the PV device avoids solar shadows caused by front side contacts, typically found in conventional solar cells. Therefore, PV devices described herein with back side contacts may allow for increased efficiency when compared to conventional solar cells.

Disclosed is a photovoltaic device. The photovoltaic device includes: a substrate; a first electrode placed on the substrate; a second electrode which is placed opposite to the first electrode and which light is incident on; a first unit cell being placed between the first electrode and the second electrode, and including an intrinsic semiconductor layer including crystalline silicon grains making the surface of the intrinsic semiconductor layer toward the second electrode textured; and a second unit cell placed between the first unit cell and the second electrode.

A method of connecting two solar cells is disclosed. In one embodiment, the method comprises gripping an interconnect with a head of positioning device, heating the interconnect with the head of the positioning device to between two predetermined temperatures, where one is higher than the other, positioning the interconnect so as to overlay two adjacent solar cells, coupling the interconnect to each of the two adjacent solar cells, and releasing the interconnect from the head.

A semiconductor device, in particular a solar cell, comprises a semiconductor substrate having a semiconductor substrate surface and a passivation composed of at least one passivation layer which surface-passivates the semiconductor substrate surface, wherein the passivation layer comprises a compound composed of aluminum oxide, aluminum nitride or aluminum oxynitride and at least one further element.

The present invention provides a solar-cell-integrated gas production device that can generate a first gas and a second gas by utilizing an electromotive force of a solar cell, and that can supply power to an external circuit by utilizing the same solar cell. The solar-cell-integrated gas production device according to the present invention comprises: a photoelectric conversion part having a light acceptance surface and its back surface; a first electrolysis electrode provided on the back surface of the photoelectric conversion part so as to be capable of being immersed into an electrolytic solution; a second electrolysis electrode provided on the back surface of the photoelectric conversion part so as to be capable of being immersed into the electrolytic solution; and a changeover part, wherein the first electrolysis electrode and the second electrolysis electrode are provided to be capable of electrolyzing the electrolytic solution to generate a first gas and a second gas by utilizing an electromotive force generated by irradiating the photoelectric conversion part with light, and the changeover part makes a changeover between a circuit that outputs the electromotive force, generated by irradiating the photoelectric conversion part outputs the electromotive force, generated by irradiating the photoelectric conversion part with light, to the first electrolysis electrode and the second electrolysis electrode.

This disclosure relates to electroconductive paste formulations useful in solar panel technology. In one aspect, the disclosure relates to an inorganic reaction system for use in electroconductive paste compositions, wherein the inorganic reaction system comprises a lead containing matrix composition and a tellurium containing matrix composition. In another aspect, the disclosure relates to an electroconductive paste composition comprising a conductive metal component, an inorganic reaction system and an organic vehicle. Another aspect of the disclosure relates to a solar cell produced by applying an electroconductive paste composition of the invention to a silicon wafer. Yet another aspect relates to a solar cell module assembled using solar cells produced by applying an electroconductive paste composition to a silicon wafer, wherein the electroconductive paste composition comprises an conductive metal component, an inorganic reaction system and an organic vehicle.

This invention is directed to a flexible solar cell photovoltaic module with high light transmittance based on modified substrate, which belongs to the field of thin-film solar cell technology. The objective of the present invention to provide a technical solution for a transparent flexible solar cell module and its fabrication method. Technical features include using a stainless steel template to mold a modified polyimide PI substrate (the PI substrate). The PI substrate has light-passing through-holes, including draining holes and convergence holes, through and distributed on the PI substrate, a conductive film layer, and various stacked photoelectric conversion film layers. The creativeness of the present invention is obvious, such as reducing the short circuit and current leakage due to crystallization of the photoelectric layer interface caused by a subsequent process of laser etching the conductive film layer, reducing the composition on the surface of the solar cell, reducing steps of the fabrication process, and lowering the production cost. Further, the present invention significantly increases the conversion efficiency and load capacity of the solar cell and the quality-cost ratio. The transparent flexible solar cell photovoltaic module also has a broad range of applications.

A photoelectric conversion element comprising a substrate, a first electrode, a photoelectric conversion layer comprising a semiconductor and a sensitizing dye, a hole transport layer and a second electrode, wherein the hole transport layer comprises a polymer having a repeat unit represented by Formula (1) or (2),

The present teachings relate to new semiconducting polymers. The polymers disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.

Accordingly, a method of forming a metal chalcogenide material may comprise introducing at least one metal precursor and at least one chalcogen precursor into a chamber comprising a substrate, the at least one metal precursor comprising an amine or imine compound of an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, or a metalloid, and the at least one chalcogen precursor comprising a hydride, alkyl, or aryl compound of sulfur, selenium, or tellurium. The at least one metal precursor and the at least one chalcogen precursor may be reacted to form a metal chalcogenide material over the substrate. A method of forming a metal telluride material, a method of forming a semiconductor device structure, and a semiconductor device structure are also described.

An optoelectronic semiconductor component includes a radiation emitting semiconductor chip having a radiation coupling out area. Electromagnetic radiation generated in the semiconductor chip leaves the semiconductor chip via the radiation coupling out area. A converter element is disposed downstream of the semiconductor chip at its radiation coupling out area. The converter element is configured to convert electromagnetic radiation emitted by the semiconductor chip. The converter element has a first surface facing away from the radiation coupling out area. A reflective encapsulation encapsulates the semiconductor chip and portions of the converter element at side areas in a form-fitting manner. The first surface of the converter element is free of the reflective encapsulation.

Photo-field-effect transistor devices and associated methods are disclosed in which a photogate, consisting of a quantum dot sensitizing layer, transfers photoelectrons to a semiconductor channel across a charge-separating (type-II) heterointerface, producing a sustained primary and secondary flow of carriers between source and drain electrodes. The light-absorbing photogate thus modulates the flow of current along the channel, forming a photo-field effect transistor.

A resin composition, a multi-layered film, a backsheet for photovoltaic modules, a method thereof, and a photovoltaic module are provided. The multi-layered film including a coating layer including a fluorine-based polymer has an excellent durability and weather resistance, and also exhibits high interfacial adhesive strength to a substrate since the multi-layered film is formed by coating a cured product of the resin composition including the fluorine-based polymer, an acrylic polymer including a thermosetting functional group, and a heat-curing agent on the substrate. In addition, drying can be performed at a low temperature during the manufacture of the multi-layered film so that the manufacturing costs can be decreased, productivity can be increased, and the deterioration of the product due to heat modification, heat shock, and the like, can be prevented. The multi-layered film can be effectively used as a backsheet for various photovoltaic modules.

Disclosed are molecular and polymeric compounds having desirable properties as semiconducting materials. Such compounds can exhibit desirable electronic properties and possess processing advantages including solution-processability and/or good stability.

Novel photoactive polymers, as well as related photovoltaic cells, articles, systems, and methods, are disclosed.

An organic compound and a photoelectric conversion device containing the organic compound are disclosed. The organic compound and device realize high photoelectric conversion efficiency, low dark current and high-speed responsivity. It has been found that when this organic compound and an n-type semiconductor are used in combination, high-speed responsivity can be realized while maintaining high heat resistance, an aspect of which has not been seen when the connection part between a donor part and an acceptor part is a phenylene group.

An improved method and apparatus for thermal-to-electric conversion involving relatively hot and cold juxtaposed surfaces separated by a small vacuum gap wherein the cold surface provides an array of single charge carrier converter elements along the surface and the hot surface transfers excitation energy to the opposing cold surface across the gap through Coulomb electrostatic coupling interaction.

In one embodiment, harmful solar cell polarization is prevented or minimized by providing a conductive path that bleeds charge from a front side of a solar cell to the bulk of a wafer. The conductive path may include patterned holes in a dielectric passivation layer, a conductive anti-reflective coating, or layers of conductive material formed on the top or bottom surface of an anti-reflective coating, for example. Harmful solar cell polarization may also be prevented by biasing a region of a solar cell module on the front side of the solar cell.

A layered compound-metal particle composite 3 is obtained by the addition, to an organically modified layered compound 1 formed by the intercalation of organic ions between layers of a layered compound, of both an aqueous colloidal metal solution 2 in which metal particles are dispersed as a metal colloid in water, and a nonaqueous solvent which is a poor solvent for the metal colloid and has an excellent ability to swell the organically modified layered compound 1.

[Problem] To provide a photovoltaic device capable of generating power whether day or night, without affecting the appearance of a structure or reducing lighting or other functions, and able to inhibit rises in room temperature by converting thermal radiation into electrical energy. [Means to Solve Problems] Provide a photoelectric conversion element 3 with a photovoltaic device 1 on structural members 2a-2d facing the outside of a house or other structure. Power generated by the photoelectric conversion element 3 is extracted via a power extraction unit 4. The power conversion element 3 includes a semiconductor layer 11, conductive layer 20, a metal nanostructure 30 having multiple periodic structures 33, a first electrode 41 and a second electrode 42. The first and second electrodes 41, 42 are separated in the direction of the surface of the photoelectric conversion element 1 with the terminals 71, 81 of the power extraction unit 4 respectively connected.

The present invention provides a dye-sensitized solar cell which enhances an area of a photo electrode by arranging metal wires on a surface of a transparent substrate or a transparent conductive layer without degrading a transparency of the solar cell, allowing the metal wires to act as a collector electrode exclusively or together with a metal electrode.

A crack resistant solar cell module includes a protective package mounted on a frame. The protective package includes a polyolefin encapsulant that protectively encapsulates solar cells. The polyolefin has less than five weight percent of oxygen and nitrogen in the backbone or side chain. In other words, the combined weight percent of oxygen and nitrogen in any location in the molecular structure of the polyolefin is less than five. The polyolefin also has a complex viscosity less than 10,000 Pa second at 90° C. as measured by dynamic mechanical analysis (DMA) before any thermal processing of the polyolefin. The protective package includes a top cover, the encapsulant, and a backsheet. The solar cell module allows for shipping, installation, and maintenance with less risk of developing cracks on the surfaces of the solar cells.

A back electrode type solar cell in which a no-electrode-formed region where no electrode is placed is provided in a part of a peripheral portion of a back surface of the back electrode type solar cell such that a line connecting end portions of a plurality of electrodes to one another includes a partially inwardly recessed region and the no-electrode-formed region is located adjacent to each of an electrode for n-type and an electrode for p-type adjacent to each other, a solar cell module, a method of manufacturing a back electrode type solar cell with interconnection sheet, and a method of manufacturing a solar cell module are provided.

A PV panel uses an array of small silicon sphere diodes (10-300 microns in diameter) connected in parallel. The spheres are embedded in an uncured aluminum-containing layer, and the aluminum-containing layer is heated to anneal the aluminum-containing layer as well as p-dope the bottom surface of the spheres. A phosphorus-containing layer is deposited over the spheres to dope the top surface n-type, forming a pn junction. The phosphorus layer is then removed. A conductor is deposited to contact the top surface. Alternatively, the spheres are deposited with a p-type core and an n-type outer shell. After deposition, the top surface is etched to expose the core. A first conductor layer contacts the bottom surface, and a second conductor layer contacts the exposed core. A liquid lens material is deposited over the rounded top surface of the spheres and cured to provide conformal lenses designed to increase the PV panel efficiency.

A separate connection device (40) intended to be inserted between a metal frame (3), of an electrical component (1), and a metal supporting structure (20) in order to connect, electrically and separately, the frame to the supporting structure. The connection device (40) comprises a metal blade manufactured from spring steel which comprises two self-connecting end areas (45, 46) arranged in separate planes and comprising a set of sharp teeth (47) arranged in order to be embedded within the metal material and formed on a folded section of the metal blade so that the sets of teeth (37, 47) extend in opposite directions and in planes intended to intersect the planes of the frame (3) and of the supporting structure (20) when the connection device is mounted.

A light guide apparatus includes a light guide layer having a top surface and a bottom surface, and a transversely oriented side-end surface that forms an output aperture of the light guide, characterized by an index of refraction, n1, and further characterized by a length dimension in an intended light propagation direction towards the output aperture, where the intended light propagation direction is a z-axis direction of a Cartesian coordinate system; and a plurality of light injection elements disposed in the form of at least one linear strip in at least one of the top and bottom surfaces of the light guide layer, wherein some of the plurality of light injection elements are disposed on one lateral side of the strip and some other of the plurality of light injection elements are disposed on an opposing lateral side of the strip at a rotation angle Δz about the y-axis.

The present disclosure relates to gel-type polymer electrolyte for a dye-sensitized solar cell, a dye-sensitized solar cell comprising the gel-type polymer electrolyte, and a method for manufacturing the dye-sensitized solar cell.

The present invention provides a photoelectric conversion material comprising a fullerene derivative represented by the formula C60(R1)5(R2), wherein each R1 independently represents an organic group having a substituent; and R2 represents a hydrogen atom or a substituted or unsubstituted C1-C30 hydrocarbon group. Further, the present invention also provides a photoelectric conversion device having a self-assembled monomolecular film of the photoelectric conversion material, and a solar cell having the photoelectric conversion device.

A conductive paste may include a conductive component and an organic vehicle. The conductive component may include an amorphous metal. The amorphous metal may have a lower resistivity after a crystallization process than before the crystallization process, and at least one of a weight gain of about 4 mg/cm2 or less and a thickness increase of about 30 μm or less after being heated in a process furnace at a firing temperature.

According to example embodiments, a conductive paste includes a conductive component that contains a conductive powder and a titanium (Ti)-based metallic glass. The titanium-based metallic glass has a supercooled liquid region of about 5K or more, a resistivity after crystallization that is less than a resistivity before crystallization by about 50% or more, and a weight increase by about 0.5 mg/cm2 or less after being heated in a process furnace at a firing temperature. According to example embodiments, an electronic device and a solar cell may include at least one electrode formed using the conductive paste according to example embodiments.

A method of photoplating a metal contact onto a surface of a cathode of a photovoltaic device is provided using light induced plating technique. The method comprises: a) immersing the photovoltaic device in a solution of metal ions, where the metal ions are a species which is to be plated onto the surface of the cathode of the photovoltaic device; and b) illuminating the photovoltaic device, using a light source of time varying intensity. This results in nett plating which is faster in a direction normal to the surface of the cathode than in a direction in a plane of the surface of the cathode.

A method for fabricating a photovoltaic device includes depositing a p-type layer at a first temperature and depositing an intrinsic layer while gradually increasing a deposition temperature to a final temperature. The intrinsic layer deposition is completed at the final temperature. An n-type layer is formed on the intrinsic layer.