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Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02594D, Paper
Xuemei Zhou, Linxiao Chen, George E. Sterbinsky, Debangshu Mukherjee, Raymond R. Unocic, Steven L. Tait
Metal–ligand coordination stabilizes single atom Pt on pristine and defective TiO2 supports to impact local coordination and catalytic hydrosilylation activity.
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
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Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00707B, Paper
Miguel González-Lainez, M. Victoria Jiménez, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Compound [IrBr(CO)2(κC-tBuImCH2PyCH2OMe)] featuring a flexible pyridine/OMe functionalized NHC ligand κ1C coordinated efficiently catalyzes the selective N-monomethylation of nitroarenes using methanol as both the reducing agent and the C1 source. A...
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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CO activation and methanation mechanism on hexagonal close-packed Co catalysts: effect of functionals, carbon deposition and surface structure

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00499E, Paper
Hai-Yan Su, Changlin Yu, Jin-Xun Liu, Yonghui Zhao, Xiufang Ma, Jie Luo, Chenghua Sun, Wei-Xue Li, Keju Sun
Regardless of the functionals used and the presence of graphitic carbon, the CO methanation rate on Co(0001) is mainly controlled by CHO decomposition.
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Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
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Impact of edge structures on interfacial interactions and efficient visible-light photocatalytic activity of metal–semiconductor hybrid 2D materials

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00420K, Paper
Open Access
Deobrat Singh, Pritam Kumar Panda, Nabil Khossossi, Yogendra Kumar Mishra, Abdelmajid Ainane, Rajeev Ahuja
The present work systematically investigates the structural, electronic, and optical properties of MoS2/Si2BN heterostructures based on first-principles calculations.
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Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
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Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
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Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
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From cellulose to 1,2,4-benzenetriol via catalytic degradation over a wood-based activated carbon catalyst

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00424C, Paper
Qiong Wu, Baozheng Zhao, Shiwei Liu, Shitao Yu, Lang Huang, Arthur J. Ragauskas
1,2,4-Benzenetriol was obtained from cellulose hydrothermal degradation using phosphoric acid-activated wood-based AC as the catalyst.
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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
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Does the structure of CuZn hydroxycarbonate precursors affect the intrinsic hydrogenolysis activity of CuZn catalysts?

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00143K, Paper
Violetta Pospelova, Jaroslav Aubrecht, Kateřina Pacultová, Miloslav Lhotka, Oleg Kikhtyanin, David Kubička
A comparative study of the properties and activity of catalysts derived from single-phase CuZn precursors to elucidate the effect of the precursor structure on the catalyst activity in DMA hydrogenolysis and to examine replacement of CuCr catalysts.
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Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00092B, Paper
Xiao-Yun Wu, Hou-Ze Gui, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse
A convenient and efficient strategy for the synthesis of 3-pyrrolines containing an amino quaternary stereogenic center via phosphine-catalyzed formal [3 + 2] annulation of allenoates with 2-aminoacrylates is disclosed. A...
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Photocatalytic degradation of tetracycline hydrochloride over rugby-like β-Ga2O3 with a 3D hierarchically assembled porous structure for environmental remediation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00562B, Paper
Lingxing Zeng, Jiaqi Wang, Qingrong Qian, Qinghua Chen, Xin-Ping Liu, Yongjin Luo, Hun Xue, Zhaohui Li
A novel rugby ball-like β-Ga2O3 photocatalyst with a 3D hierarchically assembled porous structure was constructed via a facile precipitation–calcination method. The as-synthesized Ga2O3 exhibits a high photocatalytic efficiency compared to commercial Ga2O3 and Degussa P25.
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Photoswitchable catalysis using organometallic complexes

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00431F, Minireview
Zoraida Freixa
Photoswitchable catalysis using organometallic complexes: a ligand design perspective.
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Facet-Dependent Activity of Hematite Nanocrystals toward Oxygen Evolution Reaction

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00655F, Paper
Toshihiro Takashima, Shota Hemmi, Qingyu Liu, Hiroshi Irie
Electrocatalytic activity of hematite exposed with different facets toward the oxygen evolution reaction (OER) was investigated. Hematite nanoparticles with pseudo cubic, hexagonal bipyramid, and plate morphologies were prepared, which predominantly...
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Synthesis of FeCo-N@N-doped carbon oxygen reduction catalysts via microwave-assisted ammoxidation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00376J, Paper
Hung-Chih Kuo, Shou-Heng Liu, Yan-Gu Lin, Chao-Lung Chiang, Dan CW Tsang
A core-shell structured FeCo-N@N-doped carbon derived from biomass wastes (sugarcane and palm kernel shell) is facilely prepared by hydrothermal carbonization and NH3 microwave ammoxidation method. The fabricated carbons are thoroughly...
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Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
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Hierarchical Z-scheme 1D/2D architecture with TiO2 nanowires decorated by MnO2 nanosheets for efficient adsorption and full spectrum photocatalytic degradation of organic pollutants

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00419G, Paper
Jiejing Zhang, Yajie Hu, Hong Zheng, Pengyi Zhang
Constructing composite photocatalysts with efficient photocatalytic activity, wide optical response range and excellent stability has great significance for the removal of organic pollutants in water. Herein, we report a novel...
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tal

Horizontal Scroll in Firefox

Hi,

I’m playing with this horizontal scroll, but having trouble getting it to work with Firefox. Chrome and Safari handle it fine. I have no way to test IE. Any tips or ideas?

codepen https://codepen.io/sarcodes/pen/XWJoBGy




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Secondary component continues to dominate IPOs with 80% of total proceeds

For a third year in a row, exits accounted for over 80% of total proceeds




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Good talk: a memoir in conversations / Mira Jacob

Barker Library - PN6727.J334 G663 2018




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Tales from la vida: a Latinx comics anthology / edited by Frederick Luis Aldama

Barker Library - PN6725.T35 2018




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Freedom Hospital / Hamid Sulaiman ; translated by Francesca Barrie

Barker Library - PN6790.S953 S85 2018




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Pound for pound / Natalie Chaidez, writer ; Andy Belanger, art ; Daniela Miwa, color art ; Serge LaPointe, letterer ; Sebastian Girner, editor

Barker Library - PN6727.P68 2019




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High antimicrobial photodynamic activity of photosensitizer encapsulated dual-functional metallocatanionic vesicles against drug-resistant bacteria S. aureus

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00323A, Paper
Bunty Sharma, Gurpreet Kaur, Ganga Ram Chaudhary, Santosh L. Gawali, P. A. Hassan
Developments in the field of photodynamic therapy (PDT) are being made by investigating appropriate photosensitizers (PSs) and enhancing the penetration effect of light by developing new metallocatanionic vesicles.
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Nanozyme-catalyzed oxygen release from calcium peroxide nanoparticles for accelerated hypoxia relief and image-guided super-efficient photodynamic therapy

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00187B, Paper
Yuping Hu, Xuechun Wang, Peng Zhao, Hao Wang, Wei Gu, Ling Ye
The accelerated O2 release from CaO2 catalyzed by MnO2 nanozyme leads to a rapid and efficient hypoxia relief, an increased yield of 1O2, a down-regulated HIF-1α and VEGF, and eventually a super-efficient PDT.
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Protein cages and virus-like particles: from fundamental insight to biomimetic therapeutics

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00159G, Minireview
Nicole F. Steinmetz, Sierin Lim, Frank Sainsbury
Protein cages found in nature have evolved for a variety of purposes and this review focuses on how they are being co-opted for use in immunotherapy and therapeutic delivery.
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Multifunctional Antibacterial Dental Sealants Suppress Biofilms Derived from Children at High Risk of Caries

Biomater. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0BM00370K, Paper
Maria Salem Ibrahim, Isadora Martini Garcia, Taissa Vila, Abdulrahman A. Balhaddad, Fabricio Mezzomo Collares, Michael D Weir, Huakun Xu, Mary Anne Melo
Dental caries in children is a leading worldwide concern for oral health. Combining antibacterial and remineralizing additives within dental sealants is a promising approach for caries prevention. Saliva contains oral...
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Biodegradable nanocomposite fibrous scaffold mediated local delivery of vancomycin for the treatment of MRSA infected experimental osteomyelitis

Biomater. Sci., 2020, 8,2653-2665
DOI: 10.1039/D0BM00140F, Paper
Amit G. Krishnan, Raja Biswas, Deepthy Menon, Manitha B. Nair
The study shows the development of a biodegradable bi-functional composite scaffold that can reduce bacterial infection, while promotes bone regeneration in osteomyelitis, without the need for revision surgery.
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A multifunctional metal-biopolymer coordinated double network hydrogel combined with multi-stimulus responsiveness, self-healing, shape memory and antibacterial properties

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00425A, Paper
Kun Yan, Feiyang Xu, Chunyu Wang, Yingying Li, Yuanli Chen, Xiufang Li, Zhentan Lu, Dong Wang
A universal, straightforward macroscale assembly technology has been presented for fabrication of polysaccharide-based multifunctional DN gels based on metal coordination chemistry.
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A transport system based on a quantum dot-modified nanotracer is genetically and developmentally stable in pregnant mice

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00311E, Paper
Open Access
Hye Jin Kim, Ji Sun Park, Se Won Yi, Minyeon Go, Hye-Ryun Kim, Su Jin Lee, Jong Min Park, Dong Hyun Cha, Sung Han Shim, Keun-Hong Park
The use of nanoscale materials (NMs) could cause problems such as cytotoxicity, genomic aberration, but the impacts of NM exposure during pregnancy remain uncharacterized in the context of clinical applications.
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Surface engineering of titanium alloy using metal-polyphenol network coating with magnesium ions for improved osseointegration

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00566E, Paper
Sangmin Lee, Yun-Young Chang, Jinkyu Lee, Sajeesh Kumar Madhurakkat Perikamana, Eun Mi Kim, Yang-Hun Jung, Jeong-Ho Yun, Heungsoo Shin
Although titanium-based implants are widely used in orthopedic and dental clinics, improved osseointegration at the bone–implant interface is still required.
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Tin thiocarbonohydrazone complexes: synthesis, crystal structures and biological evaluation

Toxicol. Res., 2019, 8,862-867
DOI: 10.1039/C9TX00109C, Paper
Jin Wang, Yu-Ting Wang, Yan Fang, Yan-Li Lu, Ming-Xue Li
Three organotin thiocarbonohydrazone complexes have been synthesized, and growth inhibition assays indicated that complex 3 has the highest tumor cell selectivity.
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Ex vivo toxicological evaluation of experimental anticancer gold(I) complexes with lansoprazole-type ligands

Toxicol. Res., 2019, 8,885-895
DOI: 10.1039/C9TX00149B, Paper
Natalia Estrada-Ortiz, Elena Lopez-Gonzales, Ben Woods, Stefan Stürup, Inge A. M. de Graaf, Geny M. M. Groothuis, Angela Casini
Novel experimental anticancer gold-based compounds were studied for their mechanisms of toxicity in healthy rat kidney and liver tissues, using the Precision Cut Tissue Slices (PCTS) technique.
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Environmental distribution of the neurotoxin L-BMAA in Paenibacillus species

Toxicol. Res., 2019, 8,781-783
DOI: 10.1039/C9TX00203K, Viewpoint
Peter B. Nunn, Geoffrey A. Codd
The neurotoxic amino acid, 3-N-methyl-2,3-diaminopropanoic acid (BMAA), known in plants of the genus Cycas and in aquatic cyanobacteria and other organisms, is a component of antibiotic peptides in two species of Paenibacillus.
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Novel evaluation of sevoflurane anesthetic exposure on the testicular germ cells of neonatal male mice

Toxicol. Res., 2019, 8,988-993
DOI: 10.1039/C9TX00193J, Paper
Ali Raza Ebrahim Soltani, Abdolmohammad Kajbafzadeh, Maryam Ezzati, Zahra Ebrahim Soltani, Navid Hosseinifar, Anahid Maleki, Maryam Nezhad Sistani
Inhalatory anesthetics may impact spermatogenesis and sexual behavior.
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Tamil Nadu CM asks PM to keep Electricity Amendment Bill on hold till talks

Proposed Bill takes away certain powers of the State government, and seeks to bring in changes in the existing Electricity Act that would make power utilities in the public sector totally unviable




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Dy2@C79N: A New Member of Dimetalloazafullerenes with Strong Single Molecular Magnetism

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02519D, Paper
Yuanyuan Wang, Jin Xiong, Jie Su, Zi-Qi Hu, Fang Ma, Rong Sun, Xue-You Tan, Hao-Ling Sun, Bingwu Wang, Zujin Shi, Song Gao
Enhancing the exchange interaction between magnetic ions is a long-term target in molecular magnetism. Endohedral metallofullerenes (EMFs) provide a possibility for achieving such a goal by imprisoning multiple magnetic centers...
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A super stable assembled P nanowire with variant structural and magnetic/electronic properties via transition metal adsorption

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02176H, Paper
Sukai Wang, Jinxing Gu, Yinan Dong, Linwei Sai, Fengyu Li
By means of first-principles calculations, we systematically investigated the structure, stability, magnetic and electronic properties of one-dimensional P nanowire (1D-P10 NW) assembled by Pn subunits (n = 2, 8) and...
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Correction: Anomalous polarization dependence of Raman scattering and crystallographic orientation of black phosphorus

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR90098B, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jungcheol Kim, Jae-Ung Lee, Jinhwan Lee, Hyo Ju Park, Zonghoon Lee, Changgu Lee, Hyeonsik Cheong
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A three-dimensional Cu nanobelt cathode for highly efficient electrocatalytic nitrate reduction

Nanoscale, 2020, 12,9385-9391
DOI: 10.1039/C9NR10743F, Paper
Xiaodan Wang, Mengqi Zhu, Guoshen Zeng, Xun Liu, Chihhsiang Fang, Chuanhao Li
A three-dimensional Cu nanobelt cathode was developed to efficiently catalyze the electrocatalytic nitrate reduction process.
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Boosting the photocatalytic CO2 reduction of metal–organic frameworks by encapsulating carbon dots

Nanoscale, 2020, 12,9533-9540
DOI: 10.1039/D0NR01696A, Paper
Shumin Li, Kang Ji, Meng Zhang, Cangshuang He, Jin Wang, Zhengquan Li
Small carbon dots as cocatalysts were loaded in MOF particles for CO2 reduction and their location effect was explored.
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MOF-derived lithiophilic CuO nanorod arrays for stable lithium metal anodes

Nanoscale, 2020, 12,9416-9422
DOI: 10.1039/D0NR01091J, Paper
Lei Wei, Li Li, Teng Zhao, Nanxiang Zhang, Yuanyuan Zhao, Feng Wu, Renjie Chen
MOF-derived CuO nanorod arrays with lithiophilic groups were fabricated on a Cu foil current collector (CuO NAs/CF) to produce stable lithium metal batteries with uniform, dendrite-free Li deposition.
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Ionic liquid assisted preparation and modulation of the photoluminescence kinetics for highly efficient CsPbX3 nanocrystals with improved stability

Nanoscale, 2020, 12,9569-9580
DOI: 10.1039/D0NR00579G, Paper
Ting Chen, Yanqiao Xu, Zhixiang Xie, Weihui Jiang, Lianjun Wang, Wan Jiang
A facile approach was performed to synthesize CsPbBr3 NCs with the assistance of ionic liquid [Bmim]Br, which could modulate the surface property and enhace the stability of NCs effectively.
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Strong plasmon–exciton coupling between lithographically defined single metal nanoparticles and monolayer WSe2

Nanoscale, 2020, 12,9708-9716
DOI: 10.1039/D0NR01056A, Paper
Xiaohong Yan, Hong Wei
Strong coupling between monolayer WSe2 and lithographically defined single gold nanobowties is realized for the first time, and smaller nanobowties lead to larger coupling strength.
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Oxygen vacancy-rich amorphous porous NiFe(OH)x derived from Ni(OH)x/Prussian blue as highly efficient oxygen evolution electrocatalysts

Nanoscale, 2020, 12,9557-9568
DOI: 10.1039/D0NR00607F, Paper
Shuang Wang, Xingbo Ge, Chao Lv, Cun Hu, Hongtai Guan, Jing Wu, Zhengnan Wang, Xianhui Yang, Yan Shi, Jiangfeng Song, Zhi Zhang, Akira Watanabe, Jinguang Cai
Oxygen vacancy-rich amorphous porous NiFe(OH)x on carbon paper is prepared through a two-step electrochemical depostion of Prussian blue nanocrystal layer and Ni(OH)x layer followed by an alkaline etching process for efficient OER catalysis.
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