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Computational investigation of the ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02562F, Paper
Pan Li, Chaoren Shen, Jie Min, Jing-Yuan Mei, Huan Zheng, Lin He, Xinxin Tian
The ligand effect on the chemo/regioselectivity and reactivity of cobalt-catalysed hydroformylation has been discussed.
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Superior adsorption capability and excellent photocatalytic activity derived from the ferroelectric external screening effect in Bi3TiNbO9 single-crystal nanosheets

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02513H, Paper
Xiaofeng Yin, Yingjie Sun, Xiaojun Wu, Xiaoning Li, Huan Liu, Wen Gu, Wei Zou, Liuyang Zhu, Zhengping Fu, Yalin Lu
A new strategy based on the ferroelectric external screening effect was used to enhance dye adsorption and degradation activity.
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Oxidation of lignocellulosic platform molecules to value-added chemicals using heterogeneous catalytic technologies

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00240B, Minireview
Pedro L. Arias, Juan A. Cecilia, Iñaki Gandarias, José Iglesias, Manuel López Granados, Rafael Mariscal, Gabriel Morales, Ramón Moreno-Tost, Pedro Maireles-Torres
This minireview gives an overview about heterogeneous catalytic technologies for the oxidation of key platform molecules (glucose, 5-hydroxymethylfurfural, furfural and levulinic acid) into valuable chemicals.
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Hydrodeoxygenation of anisole to benzene over an Fe2P catalyst by a direct deoxygenation pathway

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00046A, Paper
Shuyuan Wang, Dan Xu, Yunlei Chen, Song Zhou, Di Zhu, Xiaodong Wen, Yong Yang, Yongwang Li
Fe2P catalyst was highly selective for the cleavage of C–O bond of anisole via direct deoxygenation pathway.
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Metal free alkene hydrogenation by B-doped graphitic carbon nitride

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00488J, Paper
Ashima Dogra, Ilaria Barlocco, Amritpal Singh, Ferenc Somodi, Alberto Villa, Neeraj Gupta
Metal free hydrogenation of styrene under mild conditions employing boron-doped carbon nitride catalysts is reported.
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Integrated design for electrocatalytic carbon dioxide reduction

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00453G, Minireview
Xin Zhao, Lijie Du, Bo You, Yujie Sun
We have summarized three novel strategies for electrocatalytic carbon dioxide reduction, including concurrent CO2 electroreduction, tandem CO2 electroreduction and hybrid CO2 electroreduction.
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Water-soluble NHC-stabilized platinum nanoparticles as recoverable catalysts for hydrogenation in water

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00481B, Paper
Andrea M. Ruiz-Varilla, Edwin A. Baquero, Bruno Chaudret, Ernesto de Jesús, Camino Gonzalez-Arellano, Juan C. Flores
Aromatic compounds have been hydrogenated in water using recoverable catalysts based on water-soluble platinum nanoparticles capped with NHC ligands.
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Recent advances and prospects of inkjet printing in heterogeneous catalysis

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00040J, Minireview
Open Access
Hesam Maleki, Volfango Bertola
This review provides an insight into inkjet printing technology in the context of heterogeneous catalysis.
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Molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) – metal and surface dependent structure and stability

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00504E, Paper
Fan Wang, Teng Li, Yun Shi, Haijun Jiao
The surface and metal-dependent morphologies and energies of molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) have been systematically investigated on the basis of periodic density functional theory computations.
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Deactivation and regeneration of carbon supported Pt and Ru catalysts in aqueous phase hydrogenation of 2-pentanone

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00163E, Paper
Jiajie Huo, Hien N. Pham, Yan Cheng, Hsi-Hsin Lin, Luke T. Roling, Abhaya K. Datye, Brent H. Shanks
Aqueous phase conversion of biomass-derived molecules requires development of catalysts and operating strategies that create viable operation for extended performance as necessitated for industrial applications.
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Seaweed bio-inspired ZnO piezoelectric cilia array applied in microreactors for enhanced photocatalytic performance

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Catal. Sci. Technol., 2020, 10,2337-2342
DOI: 10.1039/C9CY02509J, Paper
Yukai Chen, Jiaojiao Fang, Baoying Dai, Huimin Wei, Jiahui Kou, Chunhua Lu
A piezoelectric built-in electric field is believed to be an effective way to separate photoinduced carriers and enhance photocatalytic performance.
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Fine-tuning of the substrate binding mode to enhance the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase

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Catal. Sci. Technol., 2020, 10,2462-2472
DOI: 10.1039/C9CY02335F, Paper
Aipeng Li, Xue Li, Wei Pang, Qing Tian, Ting Wang, Lianbing Zhang
Fine-tuning of the substrate binding mode was successfully applied for enhancing the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase.
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Synergistic photocatalysis–Fenton reaction for selective conversion of methane to methanol at room temperature

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Catal. Sci. Technol., 2020, 10,2329-2332
DOI: 10.1039/D0CY00028K, Communication
Yi Zeng, Hang Chen Liu, Jing Sheng Wang, Xing Yang Wu, Song Ling Wang
Combining the photocatalysis and Fenton reaction highly promote the yield and selectivity of CH3OH from CH4 with solar light at room temperature, up to 471 μmol g−1 h−1 and 83%, respectively.
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Effect of ceria morphology on the performance of MnOx/CeO2 catalysts in catalytic combustion of N,N-dimethylformamide

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Catal. Sci. Technol., 2020, 10,2473-2483
DOI: 10.1039/C9CY02384D, Paper
Fengying Huang, Dongsheng Ye, Xiaohan Guo, Wangcheng Zhan, Yun Guo, Li Wang, Yunsong Wang, Yanglong Guo
MnOx/CeO2 catalysts were prepared by a deposition–precipitation method, through loading MnOx into ceria supports with different morphologies (nanorods (NRs), nanocubes (NCs) and nano-octahedrons (NOs)).
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Microemulsion solventing-out co-precipitation strategy for fabricating highly active Cu–ZnO/Al2O3 dual site catalysts for reverse water gas shift

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Catal. Sci. Technol., 2020, 10,2343-2352
DOI: 10.1039/C9CY02608H, Paper
Ziheng Zhen, Wenxiang Tang, Wei (Willy) Chu, Tao Zhang, Li Lv, Shengwei Tang
A new strategy for the preparation of dual site catalysts is introduced, which combines microemulsion technology and anti-solvent extraction technology.
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Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

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Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

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Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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Path of electron transfer created in S-doped NH2-UiO-66 bridged ZnIn2S4/MoS2 nanosheet heterostructure for boosting photocatalytic hydrogen evolution

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Catal. Sci. Technol., 2020, 10,2531-2539
DOI: 10.1039/D0CY00127A, Paper
Qi Ran, Zebin Yu, Ronghua Jiang, Lun Qian, Yanping Hou, Fei Yang, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang
This work introduces the synthesis of ZnIn2S4/NH2-UiO-66/MoS2 sheet heterostructure photocatalysts and their application to photocatalytic hydrogen evolution.
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Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

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Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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Hydroxyl groups attached to Co2+ on the surface of Co3O4: a promising structure for propane catalytic oxidation

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Catal. Sci. Technol., 2020, 10,2573-2582
DOI: 10.1039/D0CY00265H, Paper
Kun Chen, Wenzhi Li, Zean Zhou, Qifu Huang, Yang Liu, Qiuyan Duan
Co3O4 catalysts with three specific morphologies (nanocubes, nanosheets, and nanooctahedra) were prepared using simple preparation methods and tested for catalytic combustion of propane under the same reaction conditions.
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Trace amounts of Cu(OAc)2 boost the efficiency of cumene oxidation catalyzed by carbon nanotubes washed with HCl

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Catal. Sci. Technol., 2020, 10,2523-2530
DOI: 10.1039/C9CY02536G, Paper
Jie Deng, Yuhang Li, Yonghai Cao, Hongjuan Wang, Hao Yu, Qiao Zhang, Jiangliang Zuo, Feng Peng
Trace amounts of Cu(OAc)2 significantly improve the activity and selectivity of cumene oxidation catalyzed by HCl-washed carbon nanotubes.
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Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

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Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
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980 nm NIR light driven overall water splitting over a combined CdS–RGO–NaYF4–Yb3+/Er3+ photocatalyst

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Catal. Sci. Technol., 2020, 10,2389-2397
DOI: 10.1039/D0CY00256A, Paper
Wei Gao, Yuqi Wu, Gongxuan Lu
Infrared light (NIR) accounts for more than 50% of the energy donated by the Sun to the Earth, but most of this type of energy is not utilized in photocatalytic reactions.
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Single-step benzene hydroxylation by cobalt(II) catalysts via a cobalt(III)-hydroperoxo intermediate

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Catal. Sci. Technol., 2020, 10,2540-2548
DOI: 10.1039/C9CY02601K, Paper
Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan
Cobalt(II) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H2O2. The catalysis proceeds likely via cobalt(III)-hydroperoxo species.
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Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

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Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes

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Catal. Sci. Technol., 2020, 10,2583-2592
DOI: 10.1039/D0CY00471E, Paper
Chandran Rajendran, Govindaswamy Satishkumar, Charlotte Lang, Eric M. Gaigneaux
AlSBA-15 catalysts possessing Brønsted acid and Lewis acid–base bifunctionalities catalyze the direct arylation of benzyl alcohols to diarylmethanes with an 85% product yield through C–O bond activation.
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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

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Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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Construction of heterostructure based on hierarchical Bi2MoO6 and g-C3N4 with ease for impressive performance in photoelectrocatalytic water splitting and supercapacitor

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Catal. Sci. Technol., 2020, 10,2427-2442
DOI: 10.1039/D0CY00211A, Paper
C. Murugan, M. Karnan, M. Sathish, A. Pandikumar
This work demonstrates the formation of g-C3N4/Bi2MoO6 heterostructure for water splitting and supercapacitor; which shows highest PEC efficiency and symmetric device delivered a energy density and power density of 47 W h kg−1 and 4.5 kW kg−1.
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Highly-efficient Ru/Al–SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of p-phthalic acid

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Catal. Sci. Technol., 2020, 10,2443-2451
DOI: 10.1039/D0CY00047G, Paper
Cong Mao, Jingwei Zheng, Babasaheb M. Matsagar, Ranjith Kumar Kankala, Tansir Ahamad, Yucheng Yang, Kevin C.-W. Wu, Xueqin Zhang
A Ru/Al–SBA-15 catalyst with excess Lewis acid sites displayed excellent efficiency (100%), high cis-isomer selectivity (84%), and exceptional stability towards hydrogenation of p-phthalic acid in water.
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Carbon deposits during catalytic combustion of toluene on Pd–Pt-based catalysts

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Catal. Sci. Technol., 2020, 10,2452-2461
DOI: 10.1039/D0CY00101E, Paper
Yu Yang, Gang Wang, Peng Zheng, Falu Dang, Jiannian Han
Carbon is easily deposited on a catalyst during the catalytic combustion of toluene, resulting in catalyst deactivation.
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Gold-catalyzed domino cyclization enabling construction of diverse fused azaspiro tetracyclic scaffolds: a cascade catalysis mechanism due to a substrate and counterion

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Catal. Sci. Technol., 2020, 10,2415-2426
DOI: 10.1039/D0CY00120A, Paper
Yunhe Li, Xiang Zhao
The detailed mechanism and origins of gold-catalyzed domino cyclization to diverse fused azaspiro tetracyclic scaffolds by cooperative dual catalysis and cascade catalysis are systematically studied.
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Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

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Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
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Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

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Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

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Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
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Loop engineering of aryl sulfotransferase B for improving catalytic performance in regioselective sulfation

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Catal. Sci. Technol., 2020, 10,2369-2377
DOI: 10.1039/D0CY00063A, Paper
Yu Ji, Shohana Islam, Haiyang Cui, Gaurao V. Dhoke, Mehdi D. Davari, Alan M. Mertens, Ulrich Schwaneberg
Loop engineering of aryl sulfotransferase B improves catalytic performance in regioselective sulfation.
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Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

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Catal. Sci. Technol., 2020, 10,2615-2626
DOI: 10.1039/C9CY02407G, Paper
Dan Zhao, Guoqiang Zhang, Lifei Yan, Lingqi Kong, Huayan Zheng, Jie Mi, Zhong Li
The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.
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Aerobic oxidation of 1,6-hexanediol to adipic acid over Au-based catalysts: the role of basic supports

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Catal. Sci. Technol., 2020, 10,2644-2651
DOI: 10.1039/D0CY00183J, Paper
Open Access
Noemi Capece, Achraf Sadier, Camila Palombo Ferraz, Joëlle Thuriot-Roukos, Mariusz Pietrowski, Michał Zieliński, Sébastien Paul, Fabrizio Cavani, Robert Wojcieszak
1,6-Hexanediol is a relevant building blocks that could be obtained from biomass and transformed under base free conditions into adipic acid used for polymer synthesis.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

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Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase

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Catal. Sci. Technol., 2020, 10,2398-2406
DOI: 10.1039/D0CY00123F, Paper
Timothy E. Rosser, Juliana P. S. Sousa, Yasmine Ziouani, Oleksandr Bondarchuk, Dmitri Y. Petrovykh, Xian-Kui Wei, Jo J. L. Humphrey, Marc Heggen, Yury V. Kolen'ko, Andrew J. Wain
Al-doping of cobalt phosphide oxygen evolution catalysts results in enhanced performance which, based on in situ and operando analysis, is shown to result from a surface area increase associated with modified oxidation behaviour.
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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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Outstanding Reviewers for Catalysis Science & Technology in 2019

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Catal. Sci. Technol., 2020, 10,2328-2328
DOI: 10.1039/D0CY90032J, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Catalysis Science & Technology in 2019, as selected by the editorial team for their significant contribution to the journal.
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Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00188K, Paper
Margarida M. Antunes, Auguste Fernandes, Diogo Falcão, Martyn Pillinger, Filipa Ribeiro, Anabela A. Valente
Eco-friendly solid bases possessing hierarchical MFI structure for D-glucose isomerization to D-fructose. Optimizing catalyst synthesis and composition for enhanced stability.
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Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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MOFs based on 1D structural sub-domains with Brønsted acid and redox active sites as effective bi-functional catalysts

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00235F, Paper
José María Moreno, Alexandra Velty, Urbano Díaz
Low-dimensional MOF-type catalysts containing Brønsted acid and redox active sites, based on assembled 1D organic–inorganic nanoribbons, for one-pot two-step reactions.
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Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

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Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00593B, Paper
Marta Navarro, Luis F. Sánchez-Barba, Andrés Garcés, Juan Fernández-Baeza, Israel Fernández, Agustín Lara-Sánchez, Ana M. Rodríguez
The binuclear aluminum complexes [AlR2(κ2-NN';κ2-NN')AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles：Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

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Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
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