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Observation of cavitation dynamics in viscous deep eutectic solvents during power ultrasound sonication

Faraday Discuss., 2024, 253,458-477
DOI: 10.1039/D4FD00031E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ben Jacobson, Shida Li, Paul Daly, Christopher E. Elgar, Andrew P. Abbott, Andrew Feeney, Paul Prentice
We characterise the development of cavitation structure in three deep eutectic solvents of increasing viscosity, and water, via high-speed imaging and parallel acoustic detection..
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Deep eutectic solvents on a tightrope: balancing the entropy and enthalpy of mixing

Faraday Discuss., 2024, 253,273-288
DOI: 10.1039/D4FD00048J, Paper
Adriaan van den Bruinhorst, Chiara Corsini, Guillaume Depraetère, Nithavong Cam, Agílio Pádua, Margarida Costa Gomes
We quantified the balance between excess enthalpy (interactions) and excess entropy (structure/disorder) of mixing that determines large melting point depressions in deep eutectic solvents (DESs), reformulating the role of hydrogen bonding in DESs.
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Cationic micelles in deep eutectic solvents: effects of solvent composition

Faraday Discuss., 2024, 253,26-41
DOI: 10.1039/D4FD00045E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Iva Manasi, Stephen M. King, Karen J. Edler
The size of cationic micelles in a pTSA based deep eutectic solvent can be tuned by changing the solvent composition, which alters the surfactant–solvent interactions.
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Exploring the structure of type V deep eutectic solvents by xenon NMR spectroscopy

Faraday Discuss., 2024, 253,118-128
DOI: 10.1039/D4FD00083H, Paper
Open Access
Matteo Boventi, Michele Mauri, Franca Castiglione, Roberto Simonutti
Type V deep eutectic solvents thymol : camphor, menthol : thymol and eutectic mixtures based on menthol : carboxylic acids with variable chain length, are investigated to clarify the peculiar nanostructure of these materials..
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Amid threats of violent protests, Brampton Triveni temple cancels event

The authorities appologised to the community members, stating, "We apologize to all community members who were depending on the event. We are deeply saddened that Canadians now feel unsafe coming to Hindu Temples in Canada."




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Delhi to launch 'E-Detection' system: Here's how it will prevent polluting vehicles from entering

India to launch an e-detection system to identify old and polluting vehicles in Delhi before Diwali.




vent

We Should Definitely Have More Dancing : Or the Amazing Adventures of the Woman with a Fist in Her Head [Electronic book] / Clara Darcy & Ian Kershaw.

London : Methuen Drama, 2022.




vent

Seventeenth-century libraries : problems and perspectives [Electronic book] / edited by Robyn Adams, Jacqueline Glomski.

Leiden ; Boston : Brill, [2023]




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Preventing Dementia? : Critical Perspectives on a New Paradigm of Preparing for Old Age [Electronic book] / ed. by Silke Schicktanz, Annette Leibing.

New York; Oxford : Berghahn Books, [2020]




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Open Heritage : Community-Driven Adaptive Reuse in Europe: Best Practice [Electronic book] / ed. by Heike Oevermann, Levente Polyák, Hanna Szemzö, Harald A. Mieg.

Basel : Birkhäuser, [2023]




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The liturgical year. Volume one, Advent, Christmas, Epiphany [Electronic book] / by Adrien Nocent, OSB ; translated by Matthew J. O'Connell ; introduced, emended, and annotated by Paul Turner.

Collegeville, Minnesota : LiturgicaI Press, [2013]




vent

Humanitarian intervention in the long nineteenth century : Setting the precedent [Electronic book] / Alexis Heraclides, Ada Dialla.

Manchester : Manchester University Press, [2017]




vent

Human rights and humanitarian norms, strategic framing, and intervention : lessons for the responsibility to protect [Electronic book] / Melissa Labonte.

Abingdon, Oxon : Routledge, 2013.




vent

Health care in the information society. Vol. 1, From adventure of ideas to anarchy of transition [Electronic book] / David Ingram.

Cambridge : Open Book Publishers, [2023]




vent

Gerry & Sewell: A Purely Belter Adventure : Adapted from the novel The Season Ticket by Jonathan Tulloch [Electronic book] / Jamie Alexander Eastlake.

London : Methuen Drama, 2022.




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Fathers, Pastors and Kings : Visions of episcopacy in seventeenth-century France [Electronic book] / Alison Forrestal.

Manchester : Manchester University Press, [2010]




vent

Fabric and fiber inventions : sew, knit, print, and electrify your own designs to wear, use, and play with [Electronic book] / Kathy Ceceri.

San Francisco, California : Maker Media, Inc., 2017.




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Exploring Past Images in a Digital Age : Reinventing the Archive [Electronic book] / Nezih Erdogan, Ebru Kayaalp.

[s.l.] : Amsterdam University Press, 2023.




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A dramatic reinvention : German television and moral renewal after National Socialism, 1956-1970 [Electronic book] / Stewart Anderson.

New York : Berghahn, 2020.




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Art is a tyrant : the unconventional life of Rosa Bonheur [Electronic book] / Catherine Hewitt.

London, England : Icon Books, 2020.




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Alfred Fagon Selected Plays : Adventure Inside Thirteen [Electronic book] / Alfred Fagon.

London : Methuen Drama, 2022.




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A solvent-free neutral cobalt complex exhibiting macroscopic polarization switching induced by directional charge transfer

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01389A, Research Article
Zi-Qi Zhou, Shu-Qi Wu, Qi-Rui Shui, Wen-Wei Zheng, Akari Maeda, Xiao-Peng Zhang, Jing Chu, Shinji Kanegawa, Sheng-Qun Su, Osamu Sato
A solvent-free neutral cobalt complex featuring a non-centrosymmetric polar structure exhibits macroscopic polarization switching induced by charge transfer.
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Sulfonylcalix[4]arene-based Al4 clusters: three aluminum oxo clusters with different coordinated solvents for the CO2 cycloaddition reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02096K, Research Article
Xiao-Jie Liu, Long-Xue Guo, Wei Xu, Ya-Wen Wang, Yuan-Hang Tian, Li-Xing Zhao, Xiao-Yu Li, Jin-Hua Li, Guo-Ming Wang
By using a macrocyclic H4BTC4A-SO2 ligand, we successfully synthesized three Al4 clusters with different solvents, which exhibit different potentials to expose metal active sites for the catalytic reaction. of cycloaddition of carbon dioxide.
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Unusual solvent-regulated inversion of a metal stereocenter in an enantiopure Eu2L4 helicate: a new strategy for CPL inversion

Inorg. Chem. Front., 2024, 11,8093-8100
DOI: 10.1039/D4QI02276A, Research Article
Qing Ma, Sen Yin, Ziye Song, Ting Gao, Pengfei Yan, Yanyan Zhou, Hongfeng Li
The dinuclear helicate Eu2(LR)4 exhibits a solvent-regulated metal stereocenter Δ/Λ configurational inversion, independent of P/M helical conformational conversion. This reversal process is accompanied by an inversion of the CPL.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Investigation of air bubble behaviour after gas embolism events induced in a microfluidic network mimicking microvasculature

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00087K, Paper
Mohammad Mahdi Mardanpour, Ayyappasamy Sudalaiyadum Perumal, Zahra Mahmoodi, Karine Baassiri, Gala Montiel-Rubies, Kenneth M. LeDez, Dan V. Nicolau
This study conducted in vitro experimentation using microvascular tissue-like structures to examine the dynamics of interfacial forces leading to gas bubble cessation, with the objective of providing a medical guideline for preventing gas embolism.
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Conformational and static properties of tagged chains in solvents: effect of chain connectivity in solvent molecules

Soft Matter, 2024, 20,3073-3081
DOI: 10.1039/D3SM01473H, Paper
Hong-Yao Li, Bokai Zhang, Zhi-Yong Wang
The radius of gyration of tagged polymer chain: effect of chain length in solvent molecules.
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Self-assembly of rod–coil–rod block copolymers in a coil-selective solvent: coarse-grained simulation results

Soft Matter, 2024, 20,3131-3142
DOI: 10.1039/D4SM00251B, Paper
Chiraz Toujani, Luis A. Padilla, Nour Alhraki, Su-Mi Hur, Abelardo Ramírez-Hernández
Parameters that govern the self assembly of a symmetric triblock copolymer.
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Cosolvent incorporation modulates the thermal and structural response of PNIPAM/silyl methacrylate copolymers

Soft Matter, 2024, 20,3322-3336
DOI: 10.1039/D4SM00246F, Paper
Jason D. Linn, Fabian A. Rodriguez, Michelle A. Calabrese
The nanoscale structure formation and optical response of aqueous thermoresponsive polymers with reactive silane groups can be widely tuned via polymer architecture and organic cosolvent incorporation.
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Harnessing the power of natural deep eutectic solvents (choline chloride/sucrose) and polypropylene glycol in the formation of aqueous biphasic systems and the application of these systems in drug extraction

RSC Adv., 2024, 14,12349-12359
DOI: 10.1039/D3RA07066B, Paper
Open Access
Fariba Ghaffari, Mohammed Taghi Zafarani-Moattar, Hemayat Shekaari
In recent times, there has been considerable interest in utilizing aqueous biphasic systems (ABSs) containing natural deep eutectic solvents (NADESs) for the extraction of various substances.
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Ethyl acetate as an acetyl source and solvent for acetylation of alcohols by KOH

RSC Adv., 2024, 14,12574-12579
DOI: 10.1039/D3RA08717D, Paper
Open Access
Xiaodan Wang, Huilin Sun, Yao Cheng, Wenfei Yang, Xinmei Wang, Liting Xiong, Yiying Li, Jinhui Wang, Chunli Gan, Chunguang Lin, Huanjun Xu
A mild, efficient and convenient procedure for the acetylation of alcohols with EtOAc as acetyl source and solvent mediated by KOH was reported.
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The influence of hydrogen bonding on the structure of organic–inorganic hybrid catalysts and its application in the solvent-free epoxidation of α-olefins

RSC Adv., 2024, 14,12853-12863
DOI: 10.1039/D4RA01399A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hong-Bin Ju, Li-Zhi Zhang, De-Bao Li, Tao Geng, Ya-Jie Jiang, Ya-Kui Wang
Different reaction routes with the influence of hydrogen bonding and without hydrogen bonding.
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Tuning the photophysical properties of ESIPT active unsymmetrical azine dyes by the change in the substituent and solvent: TD-PBE0 and TD-CAM-B3LYP studies

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00039K, Paper
Hossein Roohi, Tahereh Pouryahya
The photophysical properties of the designed ESIPT active as well as donor–acceptor structured unsymmetrical azine dyes L1L5 were investigated at PBE0/6-31++G(d,p) and CAM-B3LYP/6-31++G(d,p) levels of theory in the gas phase and solvent media.
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Comment on “Limonene as a renewable unsaturated hydrocarbon solvent for living anionic polymerization of β-myrcene” by A. Dev, A. Rösler and H. Schlaad, Polym. Chem., 2021, 12, 3084

Polym. Chem., 2024, 15,4364-4365
DOI: 10.1039/D4PY00913D, Comment
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akhil Dev, Alexander Rösler, Helmut Schlaad
Polymyrcenyllithium chains in DL-limonene solution are present as dimeric associates and not as single chains.
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Solvent quality shape control in continuous flow block copolymer self-assembly

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01174K, Communication
Axel-Laurenz Buckinx, Lakshani J. Weerarathna, Anna Sokolova, Tanja Junkers
The influence of solvent quality on block copolymer self assembly is studied in detail using SANS online monitoring.
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Acrylate–methacrylate radical copolymerization kinetics of sparingly water-soluble monomers in polar and nonpolar solvents

Polym. Chem., 2024, 15,4542-4553
DOI: 10.1039/D4PY01015A, Paper
Noushin Rajabalinia, Fatemeh Salarhosseini, Robin A. Hutchinson
The influence of solvent on radical copolymerization kinetics is studied to provide insight to emulsion polymerization systems.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rapid lung ventilation MRI using parahydrogen-induced polarization of propane gas

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01029A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Md Raduanul H. Chowdhury, Clementinah Oladun, Nuwandi M. Ariyasingha, Anna Samoilenko, Tarek Bawardi, Dudari B. Burueva, Oleg G. Salnikov, Larisa M. Kovtunova, Valerii I. Bukhtiyarov, Zhongjie Shi, Kehuan Luo, Sidhartha Tan, Juri G. Gelovani, Igor V. Koptyug, Boyd M. Goodson, Eduard Y. Chekmenev
The feasibility of ultrafast (1.7 s) ventilation MRI with a 1 × 1 × 50 mm3 voxel size is demonstrated using hyperpolarized propane gas contrast agent in excised rabbit lungs on a 0.35 T clinical MRI scanner without any scanner modification.
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The efficient triplet states formation of Se-modified PDI dimers and tetramers in solvents

Phys. Chem. Chem. Phys., 2024, 26,27325-27331
DOI: 10.1039/D4CP00954A, Paper
Feijun Huang, Wenli Su, Yubo Yang, Hang Wang, Zhishan Bo, Pengfei Jing, Wenkai Zhang
The Se-modified PDI oligomers experience triplet states formation in the solvents, but there are differences in the efficiency of triplet state generation due to variations in molecular structure.
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Experimental and simulation study of reverse micelles formed by aerosol-OT and water in non-polar solvents

Phys. Chem. Chem. Phys., 2024, 26,27772-27782
DOI: 10.1039/D4CP03389B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angie Mat'usová, Georgina Moody, Peter J. Dowding, Julian Eastoe, Philip J. Camp
Small-angle neutron scattering and molecular dynamics simulations are used to characterise aerosol-OT reverse micelles. Simulations capture spontaneous self-assembly, compare favourably with experiments, and give microscopic information.
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Improved perovskite crystallization by antisolvent engineering in tin-perovskite photovoltaics

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02655A, Paper
Xin Zhang, Yu Liu, Xinyao Chen, Chunqian Zhang, Jigang Wang, Jin Cheng, Junming Li
By adding an appropriate proportion of DMS to the anti-solvent, the DMSO remaining in the tin-based perovskite films can be effectively extracted, resulting in films with better crystallography, and the devices have lower trap densities.
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Structure and dynamics of aqueous VOSO4 solutions in conventional flow through cell design: a molecular dynamics simulation study

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02934H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anwesa Karmakar
A theoretical model has been proposed to study the structure and dynamics of aqueous vanadyl sulfate (VOSO4) solution used in the conventional flow (CF) through cell design operating under varying thermodynamic conditions.
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Extraction mechanism of phenolic compounds by deep eutectic solvents: DFT and molecular dynamics studies

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03453H, Paper
Lan Yi, Jinwen Wang, Jixing Liu, Hao Luo, Xiaoqin Wu, Wen-Ying Li
The mechanism of a deep eutectic solvent consisting of choline chloride and glycerol (ChCl/GLY) for extracting phenolic compounds from coal tar was theoretically studied using density functional theory and molecular...
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Hyrox races launch in India with first event scheduled for 2025 in Mumbai

Hyrox, the world series of indoor hybrid fitness racing, launched in India on October 17 this year. The first race is scheduled for May 3, 2025, in Mumbai




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Riyadh Season 2024: As part of cultural diplomacy, Saudi Arabia celebrates Indian diversity in mega tourism event

The Indian diaspora in Saudi Arabia has grown over the years and with 2.4 million expat workers it has the second largest number of foreign workers in Saudi Arabia



  • Life & Style

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Entering into a joint venture



  • Q & A

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F1’s longest season set to kick off after an eventful off-season

Rain isn't a major concern in Bahrain so problem drains at two corners have simply been filled in with concrete.




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Formula One frenzy: an overview of events, past, present, and future




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Formula 4 race: organisers expect event to boost Chennai’s economy

A report on the economic impact of the race on the city will be submitted after a month, says Abhinandan B., co-founder, Racing Promotions Private Limited; the aim is to put Chennai on a global map, and boost its profileJ. Meghanatha Reddy, Member Secretary, SDAT




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HIL to return after 7 long years; women's event added for first time

While the men's competition will have eight teams, six sides will feature in women's event which is being held for the first time.




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Drop : an adventure through the water cycle / Emily Kate Moon

Moon, Emily Kate, author, illustrator




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The music of life : Bartolomeo Cristofori & the invention of the piano / by Elizabeth Rusch ; illustrated by Marjorie Priceman

Rusch, Elizabeth, author