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A high-entropy FeCoMnCuNi diselenide self-standing electrode with outstanding water-electrolysis performance in alkaline medium

Inorg. Chem. Front., 2024, 11,7936-7946
DOI: 10.1039/D4QI01835D, Research Article
Xinxin Guo, Mengmeng Zhou, Ziwu Liu, Shiheng Mu, Kaijia Wang, Huanqiang Shi, Fang Wang, Shijian Lu, Zhonghai Ni, Guiqing Liu
A self-standing high-entropy FeCoMnCuNiSe2 electrode exhibited superior HER activity and OWS performance due to high entropy, lattice distortion and tip-enhancement effects.
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A long-range synergistic effect between Ptn clusters and Zn1 single atoms for efficient selective hydrogenations

Inorg. Chem. Front., 2024, 11,7822-7830
DOI: 10.1039/D4QI02027H, Research Article
Haisheng Wei, Jing Li, Xiaorui Yan, Tiantian Liu, Kairui Li, Dan Feng, Yujing Ren
Benefiting from the long-range synergistic effect between Ptn clusters and Zn1 single atoms, Ptn@Zn1-N–C displays superior catalytic performance in selective hydrogenations.
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Ultrathin 2D NiCo-MOF bimetallic nanosheets as single-atom catalysts for chemoselective hydrogenation of nitroarenes

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02343A, Research Article
Yu-Xuan Zhang, Yi-Jie Ma, Yu-Jia Zhao, Zi-Yan Wang, Cai-Xia Yu, Xiaoqiang Li, Lei-Lei Liu
Exploration of non-noble-metal-based catalysts with high catalytic activity and selectivity is significant for driving innovation in green chemistry and technology. Herein, we report a facile synthesis of two-dimensional (2D) NiCo-MOF...
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Droplet microfluidic system for high throughput and passive selection of bacteria producing biosurfactants

Lab Chip, 2024, 24,1947-1956
DOI: 10.1039/D3LC00656E, Paper
Open Access
Klaudia Staskiewicz, Maria Dabrowska-Zawada, Lukasz Kozon, Zofia Olszewska, Lukasz Drewniak, Tomasz S. Kaminski
Novel microfluidic technique for functional selection of biosurfactant-producing microorganisms. Single bacterial cells are encapsulated into picoliter droplets for clonal cultivation and passively sorted at high throughput by interfacial tension.
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A self-assembly and cellular migration based fabrication of high-density 3D tubular constructs of barrier forming membranes

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00006D, Paper
Seyedaydin Jalali, Ponnambalam Ravi Selvaganapathy
A scalable method for creating perfusable 3D tissue constructs using self-assembly is introduced. Unlike conventional cell injection methods, here we leverage cell migration to form tissue barriers of low permeability, mimicking in vivo environments.
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Development of a self-contained microfluidic chip and an internet-of-things-based point-of-care device for automated identification of respiratory viruses

Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00933E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huynh Quoc Nguyen, Van Dan Nguyen, Vu Minh Phan, Tae Seok Seo
The COVID-19 pandemic greatly impacted the in vitro diagnostic market, leading to the development of new technologies such as point-of-care testing (POCT), multiplex testing, and digital health platforms.
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Dielectrophoretic characterization and selection of non-spherical flagellate algae in parallel channels with right-angle bipolar electrodes

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00165F, Paper
Xiaoming Chen, Shun Liu, Mo Shen, Jishun Shi, Chungang Wu, Zhipeng Song, Yong Zhao
We develop a microfluidic device with closed right-angle bipolar electrodes to realize dielectrophoretic characterization and selection of non-spherical flagellate algae.
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Bayesian-optimization-based design of highly active and stable Fe–Cu/SSZ-13 catalysts for the selective catalytic reduction of NOx with NH3

React. Chem. Eng., 2024, 9,3029-3037
DOI: 10.1039/D4RE00327F, Paper
Sanha Lim, Hwangho Lee, Hyun Sub Kim, Jun Seop Shin, Jong Min Lee, Do Heui Kim
Bayesian optimization approach facilitates an efficient optimization of multi-components catalyst for NH3-SCR reaction.
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Selective Separation of Li, Ni, Co and Mn from Model Spent Li Ion Battery Cathode by Dry Processing using Combination of Chlorination and Oxidation

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00328D, Paper
Naoto Tsubouchi, Yuuki Mochizuki
The volatilization of Li, Ni, Co, and Mn during chlorination treatment of LNO, LCO, and LMO (model materials for used LIB cathode material) was investigated with the aim of developing...
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Phenylboronate-salicylate ester cross-linked self-healing hydrogel composed of modified hyaluronan at physiological pH

Soft Matter, 2024, 20,2926-2936
DOI: 10.1039/D3SM01417G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ryotaro Miki, Tsutomu Yamaki, Masaki Uchida, Hideshi Natsume
A self-healing hydrogel can be easily prepared at physiological pH by using phenylboronic acid-modified hyaluronic acid and salicylic acid-modified hyaluronic acid.
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Self-adhesion of uncrosslinked poly(butadiene-co-acrylonitrile), i.e. nitrile rubber, an inhomogeneous and associative polymer

Soft Matter, 2024, 20,2978-2985
DOI: 10.1039/D3SM01630G, Paper
Valentine Hervio, Annie Brûlet, Costantino Creton, Gabriel E. Sanoja
The precursor of NBR, poly(acrylonitrile-co-butadiene), experiences thermodynamic forces for self-assembly and kinetic barriers for processing. We introduce three strategies to overcome such barriers and enable polymer self-adhesion in the bulk.
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Self-assembly of rod–coil–rod block copolymers in a coil-selective solvent: coarse-grained simulation results

Soft Matter, 2024, 20,3131-3142
DOI: 10.1039/D4SM00251B, Paper
Chiraz Toujani, Luis A. Padilla, Nour Alhraki, Su-Mi Hur, Abelardo Ramírez-Hernández
Parameters that govern the self assembly of a symmetric triblock copolymer.
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Mechanical guidance to self-organization and pattern formation of stem cells

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00172A, Paper
Wei-Hua Zhou, Lin-Ru Qiao, She-Juan Xie, Zhuo Chang, Xu Yin, Guang-Kui Xu
We introduce a mechanical model based on the dynamic balance between cell-ECM-culture environment, and demonstrate that it can capture specific phenomena in stem cell pattern formation experiments guided by geometric constraints.
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Can self-propelled objects escape from compression stimulation?

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00288A, Paper
Open Access
Masaki Yoshikai, Muneyuki Matsuo, Nobuhiko J. Suematsu, Hiraku Nishimori, Satoshi Nakata
We studied circular papers impregnated with camphor (CPs) and CPs with magnets (MCPs) as self-propelled objects floating on water under the compression of the water surface as an inanimate system for evacuation in an emergency.
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Divergent self-assembly propensity of enantiomeric phenylalanine amphiphiles that undergo pH-induced nanofiber-to-nanoglobule conversion

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00117F, Paper
Manas Kumar Pradhan, Nayanika Misra, Fathima Sahala, Nyaya Prakash Pradhan, Aasheesh Srivastava
Enantiomeric single phenylalanine derivatives demonstrate very different self-assembling propensity and thermodynamic parameters associated with self-assembly.
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Self-healing polyacrylates based on dynamic disulfide and quadruple hydrogen bonds

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00257A, Paper
Longjin Du, Yuting Zhong, Linying Zhao, Chengzhen Hu, Liang Shen, Yuping Yang, Jiang Zhong
Herein, a self-healing polyacrylate system was successfully prepared by introducing crosslinking agents containing disulfide bonds and monomers capable of forming quadruple hydrogen bonds through free radical copolymerization.
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The effect of structural changes on the self-assembly of novel green pyridinium-carboxylate gemini surfactants in Langmuir and Langmuir–Blodgett films

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01671D, Paper
Ala’a F. Eftaiha, Abdussalam K. Qaroush, Dina M. Foudeh, Ahmad S. Abo-shunnar, Suhad B. Hammad, Khaleel I. Assaf, Matthew F. Paige
The synthesis and interfacial characterization of a series of gemini surfactants based on pyridine-n-carboxylic acids, including picolinic, nicotinic, and isonicotinic acids, in Langmuir and Langmuir–Blodgett films have been reported.
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Surface charge density and induced currents by self-charging sliding drops

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00205A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pravash Bista, Aaron D. Ratschow, Amy Z. Stetten, Hans-Jürgen Butt, Stefan A.L. Weber
Sliding drops induce a bipolar current in subsurface electrodes beneath a hydrophobic substrate. We show how it depends on substrate properties and how it can be optimized for energy harvesting.
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Selenosalicylate; a little-studied heavy-element analogue of the versatile thiosalicylate ligand

RSC Adv., 2024, 14,12323-12336
DOI: 10.1039/D4RA00926F, Paper
Open Access
Simeon Atiga, Graham C. Saunders, William Henderson
Selenosalicylic acid was synthesised by reacting 2-carboxybenzenediazonium chloride with Na2Se2 followed by reduction of the resulting diselenide with zinc and acetic acid. The deprotonated acid reacted with metal precursors to form selenosalicylate complexes.
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A self-powered photodetector through facile processing using polyethyleneimine/carbon quantum dots for highly sensitive UVC detection

RSC Adv., 2024, 14,12360-12371
DOI: 10.1039/D3RA08538D, Paper
Open Access
Vo Pham Hoang Huy, Chung Wung Bark
Ultraviolet C (UVC) photodetectors have garnered considerable attention because the detection of UVC is critical for preventing skin damage in humans, monitoring environmental conditions, and detecting power aging in military applications.
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Preparation of N-MG-modified PVDF-CTFE substrate composite nanofiltration membrane and its selective separation of salt and dye

RSC Adv., 2024, 14,11992-12008
DOI: 10.1039/D4RA00359D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinyu Pan, Jian Pan, Zhuoqun Li, Wenqiang Gai, Guangshun Dong, Min Huang, Lilan Huang
N-Methylglucamine (N-MG) was introduced to poly(vinylidene fluoride-co-chlorotrifluoroethylene) (PVDF-CTFE) porous substrate membrane to enhance its hydrophilicity and permeability, leading to the preparation of a composite NF membrane with selective separation performance for many dyes and salts.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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Nickel-catalyzed γ-alkylation of cyclopropyl ketones with unactivated primary alkyl chlorides: balancing reactivity and selectivity via halide exchange

RSC Adv., 2024, 14,12883-12887
DOI: 10.1039/D4RA02616K, Paper
Open Access
Zheng-Ying Wang, Shi-Zheng Liu, Cong Guo, Yi-Zheng Cheng, Qiang Li, Jianmin Dou, Dacheng Li
Nickel-catalyzed cross-electrophile coupling of cyclopropyl ketones and alkyl chlorides. High reactivity and selectivity can be achieved with sodium iodide as a cocatalyst that generates a low concentration of alkyl iodide via halide exchange.
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Regioselective C(sp2)–H halogenation of pyrazolo[1,5-a]pyrimidines facilitated by hypervalent iodine(III) under aqueous and ambient conditions

RSC Adv., 2024, 14,13095-13099
DOI: 10.1039/D4RA02090A, Paper
Open Access
Abhinay S. Chillal, Rajesh T. Bhawale, Umesh A. Kshirsagar
An efficient and mild approach has been developed for the regio-selective direct C3 halogenation of pyrazolo[1,5-a]pyrimidines employing readily available potassium halide salts and a hypervalent iodine(III) reagent at ambient temperature.
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Self-supplying Cu2+ and H2O2 synergistically enhancing disulfiram-mediated melanoma chemotherapy

RSC Adv., 2024, 14,13180-13189
DOI: 10.1039/D4RA01075B, Paper
Open Access
Yingqian Gao, Xiaojun Cai, Weijuan Zou, Xiuzhen Tang, Lixian Jiang, Junnian Hao, Yuanyi Zheng, Xinhua Ye, Tao Ying, Ao Li
Disulfiram (DSF) can target and kill cancer cells by disrupting cellular degradation of extruded proteins and has therefore received particular attention for its tumor chemotherapeutic potential.
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A molecular-design approach for selective sulfate separation from competitive acidic and alkaline aqueous media

Mol. Syst. Des. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4ME00031E, Review Article
Arghya Basu, Sandeep Kumar Dey
Selective and efficient removal of sulfate from aqueous solution having a high concentration of other competing ions is an important aspect of separation science technology and has attracted considerable attention...
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Countryside caretaker of the dainty demoiselle

Meet Sevaram, who has made it his life’s mission to care for the migrant visitors to a Rajasthan hamlet every year




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Women collectives prove that self-help is the best help

SHGs in the villages of Uttar Pradesh offer food security during the ongoing Covid pandemic




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Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

Polym. Chem., 2024, 15,4255-4263
DOI: 10.1039/D4PY00781F, Paper
Xiuling Wang, Yang Wang, Zhonglei Qin, Liying Shen, Xiaochao Shi
Phenylthiol-functionalized rare-earth metal cationic species showed unparalleled stereoselectivity in the polymerization of isoprene and butadiene to respectively produce cis-1,4-polyisoprene and trans-1,4-polybutadiene.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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Synthesis of Asymmetric Imine Polymers for Highly Selective Sorting of Semiconducting Single-Walled Carbon Nanotubes by Two in One Strategy

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00607K, Paper
Ying Zhang, Yu Li, Yuchi Wan, Jun-Hao Wang, Yunzhen Chang, Sheng Zhu, Lan Bai, Yu Cao, Xuelei Liang, Gaoyi Han
By two in one strategy, we get three polymers of fluorene derivative with asymmetric structure functionalized with two types of arenes with different orientation and electronic properties. The polymers are...
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Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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Solvent quality shape control in continuous flow block copolymer self-assembly

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01174K, Communication
Axel-Laurenz Buckinx, Lakshani J. Weerarathna, Anna Sokolova, Tanja Junkers
The influence of solvent quality on block copolymer self assembly is studied in detail using SANS online monitoring.
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Constructing self-healing flexible supercapacitors via graphene oxide synergistic multi-network polymer-supramolecular hydrogel electrolyte

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00809J, Paper
Xiaoyan Li, Xiuting Shi, Anbai Li, Mengmeng Xun, Shuzhen Cui, Kanjun Sun, Hui Peng, Guofu Ma, Yuxi Xu
Hydrogels are increasing interest and have great potential as electrolytes for flexible supercapacitors (FSCs) in wearable and portable electronic devices. However, the hydrogel electrolytes for practical applications are hampered by...
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Structure, humidity adaptivity, and elasticity of hydrogen-bonded complexes formed by self-assembly of a triblock copolymer and a homopolymer

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00959B, Paper
Weijie Wang, Hanxin Jian, Hao Huang, Fengfeng Feng, Qingye Meng, Yuli Li, Gang Chen, Shuguang Yang
The tri-block copolymer polystyrene-b-poly(ethylene oxide)-b-polystyrene (SES) and the homopolymer poly(acrylic acid) (PAA) were applied to fabricate elastomers with multi-hierarchical architectures.
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Engineering disease analyte response in peptide self-assembly

J. Mater. Chem. B, 2024, 12,10757-10769
DOI: 10.1039/D4TB01860E, Review Article
Open Access
Sihan Yu, Matthew J. Webber
The need to enhance the precision and specificity of therapeutic nanocarriers has led to the development of nanoscale peptide assemblies capable of sensing and responding to disease-related analytes.
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Porous helical supramolecular columns self-organized via the fluorophobic effect of a semifluorinated tapered dendron

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01951B, Paper
Open Access
Dipankar Sahoo, Mihai Peterca, Mohammad R. Imam, Devendra S. Maurya, Virgil Percec
Fluorophobic effect enhances supramolecular microsegregation.
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Enzymatic self-assembly of short peptides for cell spheroid formation

J. Mater. Chem. B, 2024, 12,11210-11217
DOI: 10.1039/D4TB01154F, Paper
Open Access
Jiaqi Guo, Weiyi Tan, Bing Xu
Biphenyl-capped phosphopeptides instruct cell aggregation into spheroids, with minimal effective concentrations below 10 μM. Key factors driving morphogenesis include the self-assembly ability and dynamic shapeshifting of the peptide assemblies.
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Eco-Friendly Self-Clean Coatings: Fundamentals, Fabrication, Applications, and Sustainability

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01392A, Review Article
Tanaji K. Chavan, Sushanta Kumar K. Sethi
Eco-friendly self-clean coatings have garnered significant attention due to their potential to address environmental concerns while offering remarkable properties. This review explores the dynamic field of such coatings, focusing on...
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Bioinspired programmable coacervate droplets and self-assembled fibers through pH regulation of monomers

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01550A, Paper
Satyajit Patra, Sushmitha Chandrabhas, Subi J. George
Phase separation or phase transitions pervade the biological domain, where proteins and RNA engage in liquid-liquid phase separation (LLPS), forming liquid-like membraneless organelles. The misregulation or dysfunction of these proteins...
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'It is important to love yourself'

'I was scared during every Weekend Ka Vaar as I used to do something wrong every week and then I knew Salman sir would scold me.'




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Farmer’s Share: A celebration of self reliant minimalism

Ambrose Kooliyath’s permaculture farm on the banks of the Nila River thrives on local resources





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Who Should Play Vin Diesel's Sister?

The Hollywood actor wants suggestions.




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Selection of DNA aptamers for detecting metronidazole and ibuprofen: two common additives in soft drinks

Analyst, 2024, 149,5482-5490
DOI: 10.1039/D4AN01186D, Paper
Jin Wang, Xiangmei Li, Hongtao Lei, Juewen Liu
Using capture-SELEX, short aptamers for metronidazole and ibuprofen were isolated and they can be used for the detection of these drugs illicitly added to soft drinks.
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DFT rationalization of the mechanism and selectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01700E, Paper
Guowei Yan, Ji Ma, Simeng Qi, Alexander M. Kirillov, Lizi Yang, Ran Fang
The mechanism, regioselectivity, and chemoselectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols to give furan-3-carboxylate derivatives were explored by density functional theory (DFT).
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Self-Healing in Dielectric Capacitors: a Universal Method to Computationally Rate Newly Introduced Energy Storage Designs

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03988B, Paper
Nadezhda Andreeva, Vitaly V. Chaban
Metalized-film dielectric capacitors provide lump portions of energy on demand. While the capacities of various capacitor designs are comparable in magnitude, their stabilities make a difference. Dielectric breakdowns – micro-discharges...
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Radiolytic degradation of selective actinide extractants from the bis-1,2,4-triazine family in cyclohexanone solutions

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02623C, Paper
Adrian Sulich, Jan Grodkowski, Krzysztof Bobrowski
Absorption spectra of transients derived from bis-1,2,4-triazine ligands in cyclohexanone solutions mimicking the extraction system studied by pulse radiolysis. The addition of benzophenone and saturation by O2 protect ligands from radiation damage.
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Unlocking the potential of metal ligand cooperation for enantioselective transformations

Chem. Soc. Rev., 2024, 53,3216-3223
DOI: 10.1039/D3CS00998J, Viewpoint
Open Access
Tizian-Frank Ramspoth, Johanan Kootstra, Syuzanna R. Harutyunyan
Metal–ligand cooperation, (MLC) is a versatile catalysis concept. Herein, we discuss the historical context, mechanisms, and applications, suggesting exploring MLC for enantioselective transformations beyond (de)hydrogenative processes.
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Recent advances in Rh(I)-catalyzed enantioselective C–H functionalization

Chem. Soc. Rev., 2024, 53,3457-3484
DOI: 10.1039/D3CS00762F, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yue Zhang, Jing-Jing Zhang, Lujun Lou, Ruofan Lin, Nicolai Cramer, Shou-Guo Wang, Zhen Chen
This review aims to provide the most comprehensive and up-to-date summary of recent advances in Rh(I)-catalyzed enantioselective C−H functionalization highlighting diverse reaction development, chiral ligand design and mechanistic investigation.
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