meta

Heterobimetallic complexes from 0D clusters to 3D networks based on various polycyanometallates and [Cu(dmpn)2]2+ (dmpn = 2,2-dimethyl-1,3-diaminopropane): synthesis, crystal structures and magnetic properties

CrystEngComm, 2020, 22,2806-2816
DOI: 10.1039/D0CE00235F, Paper
Xiaoyun Hao, Jingwen Shi, Yong Dou, Tong Cao, Zhen Zhou, Lu Yang, Dacheng Li, Qingyun Liu, Jianzhuang Jiang, Daopeng Zhang
Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between FeIII/CrI ion and CuII ion.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Static disorder in a perovskite mixed-valence metal–organic framework

CrystEngComm, 2020, 22,2859-2865
DOI: 10.1039/D0CE00119H, Paper
Ines E. Collings, Paul J. Saines, Mirko Mikolasek, Tiziana Boffa Ballaran, Michael Hanfland
Effects of A-site and M-site substitutions on the structural properties of perovskite dimethylammonium iron formate.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

New 2D layered structures with direct fluorine–metal bonds: MF(CH3COO) (M: Sr, Ba, Pb)

CrystEngComm, 2020, 22,2772-2780
DOI: 10.1039/D0CE00287A, Paper
S. Zänker, G. Scholz, M. Heise, F. Emmerling, E. Kemnitz
New coordination polymers with 2D network structures with fluorine directly coordinated to the metal ion were prepared both via mechanochemical synthesis and fluorolytic sol–gel synthesis.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Synthesis of all-silica hollow zeolites by selective demetallation

CrystEngComm, 2020, 22,2845-2848
DOI: 10.1039/D0CE00263A, Paper
Open Access
Teng Li, Frank Krumeich, Jeroen A. van Bokhoven
Exploiting the protective role of extra-framework aluminum species on the crystal rim, all-silica hollow zeolites are efficiently produced by demetallation.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Supramolecular association of M2+⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication
Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, Pt2+; L2 = dinaphthoylmethanido), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

A water-stable terbium metal-organic framework with functionalized ligands for the detection of Fe3+, Cr2O72- ions in water and picric acid in seawater

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00430H, Paper
Hai-Huan Yu, Jia-Qi Chi, Zhong-Min Su, Xiao Li, Jing Sun, Chen Zhou, Xiao-Li Hu, Qun Liu
The existence of Cr2O72- anions, excessive Fe3+ cations in water and picric acid in seawater have irreversible harm to human health and aquatic organism. Herein, a water-stable terbium metal-organic framework...
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Intrinsically porous molecular building blocks for metal organic frameworks tailored by the bridging effect of counter cations

CrystEngComm, 2020, 22,2889-2894
DOI: 10.1039/D0CE00397B, Communication
Open Access
Peng Yang, Buthainah Alshankiti, Niveen M. Khashab
Intrinsically porous molecular building blocks are used for the rational design and construction of molecular-level controlled porous materials.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

The different magnetic relaxation behaviors in [Fe(CN)6]3− or [Co(CN)6]3− bridged 3d–4f heterometallic compounds

CrystEngComm, 2020, 22,2998-3004
DOI: 10.1039/D0CE00039F, Paper
Ruirui Wang, Haili Wang, Juan Wang, Feifei Bai, Yue Ma, Licun Li, Qinglun Wang, Bin Zhao, Peng Cheng
For the isomorphic tetranuclear 3d–4f compounds constructed by [M(CN)6]3− linking LnIII-Schiff-base units, the diamagnetic CoIII ions in the system could suppress QTM effectively and obtain a field-induced SMMs behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

New pronounced progress in the synthesis of group 5 polyoxometalates

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00315H, Highlight
Joanna Dopta, Lisa K. Mahnke, Wolfgang Bensch
This highlight summarizes new developments made in group 5 polyoxometalate science of high nuclearity clusters with focus on synthetic approaches.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Open metal site (OMS) and Lewis basic site (LBS)-functionalized copper–organic framework with high CO2 uptake performance and highly selective CO2/N2 and CO2/CH4 separation

CrystEngComm, 2020, Advance Article
DOI: 10.1039/C9CE02005E, Paper
Cheng He, Chao Hou, Yu Min Wang, Xue Yong Gong, Hong Li Jiang, Yong Bin Sun, Kun Liu, Xiao Qun Cao
A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Halogen bonded metal bis(dithiolene) 2D frameworks

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00512F, Paper
Hadi Hachem, olivier Jeannin, Marc Fourmigue, Frederic Barriere, Dominique Lorcy
Halogenated metal dithiolene complexes have been designed together with halogen bond acceptor sites in order to favor halogen bonding interactions between these electroactive architectures. For the synthesis, we explored the...
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Strong stacking interactions at large horizontal displacements of tropylium and cyclooctatetraenide ligands of transition metal complexes: crystallographic and DFT study

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00501K, Paper
Dusan P Malenov, Snezana D Zaric
Cambrigde Structural Database search was performed in order to study stacking interactions of 7-membered tropylium ring and 8-membered cyclooctatetraenide (COT) ring, coordinated to transition metals via their π-electrons. The search...
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Metallic glass-based nanocomposites: molecular dynamics study of properties / Sumit Sharma

Online Resource




meta

Metal fatigue: effects of small defects and nonmetallic inclusions / Yukitaka Murakami

Online Resource




meta

Science, technology and applications of metals in additive manufacturing / Bhaskar Dutta, Sudarsanam Babu, Bradley Jared

Online Resource




meta

TMS 2020 149th Annual Meeting and Exhibition Supplemental proceedings The Minerals, Metals and Materials Society, editor

Online Resource




meta

Nanostructured metal oxides for advanced applications: symposium held April 1-5, 2013, San Francisco, California, U.S.A. / editors, Alberto Vomiero, Federico Rosei, Xiao Wei Sun, Juan Roman Morante

Hayden Library - TA418.9.N35 S9665 2013




meta

Asymmetric copper-catalyzed conjugate additions of organometallic reagents in syntheses of natural compounds and pharmaceuticals

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00278J, Review Article
Denisa Vargová, Ivana Nemethova, Radovan Sebesta
Stereoselective synthesis of complex molecular structures is needed in medicine as well as in crop-protection. Copper-catalyzed 1,4-additions of organometallic reagents is a robust C-C bond formation strategy applicable in a...
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums: facile access to arylazopyrrolines

Org. Biomol. Chem., 2020, 18,3149-3157
DOI: 10.1039/D0OB00346H, Paper
Jing Rong, Hao Jiang, Sijing Wang, Zhenni Su, Huiyan Wang, Chuanzhou Tao
A novel and facile approach to synthesize arylazopyrroline scaffolds via metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums has been developed, providing access to a variety of 4-arylazo-2-pyrrolines in a highly concise fashion.
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

Recent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00703J, Review Article
Yoichiro Kuninobu, Takeru Torigoe
Transition metal-catalysed C–H transformations are powerful tools to obtain functionalised organic molecules from simple starting materials. To control regioselectivity is one of the most important issues in C–H transformations. Since...
The content of this RSS Feed (c) The Royal Society of Chemistry




meta

[ASAP] Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries

ACS Energy Letters
DOI: 10.1021/acsenergylett.0c00700




meta

Gravitational Biology II: Interaction of Gravity with Cellular Components and Cell Metabolism / Wolfgang Hanke [and more]

Online Resource




meta

Encyclopedia of metagenomics / edited by Karen E. Nelson

Online Resource




meta

Plant-Metal Interactions

Online Resource




meta

Aldehyde Dehydrogenases: From Alcohol Metabolism to Human Health and Precision Medicine / Jun Ren, Yingmei Zhang, Junbo Ge, editors

Online Resource




meta

Hormones, Metabolism and the Benefits of Exercise.

Online Resource




meta

Genomics, proteomics, and metabolomics: stem cells monitoring in regenerative medicine / Babak Arjmand, editor

Online Resource




meta

[ASAP] Exposure to Trichloroethylene Metabolite <italic toggle="yes">S</italic>-(1,2-Dichlorovinyl)-L-cysteine Causes Compensatory Changes to Macronutrient Utilization and Energy Metabolism in Placental HTR-8/SVneo Cells

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00356




meta

[ASAP] Identifying Cysteine, <italic toggle="yes">N</italic>-Acetylcysteine, and Glutathione Conjugates as Novel Metabolites of Aristolochic Acid I: Emergence of a New Detoxification Pathway

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00488




meta

[ASAP] Analysis of the Different Metabolic Phenotypes of Metalaxyl Enantiomers in Adolescent Rat by Using <sup>1</sup>H NMR Based Urinary Metabolomics

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00011




meta

[ASAP] <italic toggle="yes">In Vitro</italic> Metabolism of Isopropylated and <italic toggle="yes">tert</italic>-Butylated Triarylphosphate Esters Using Human Liver Subcellular Fractions

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00002




meta

[ASAP] Comprehensive <italic toggle="yes">In Vitro</italic> Metabolism Study of Bisphenol A Using Liquid Chromatography-High Resolution Tandem Mass Spectrometry

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00042




meta

[ASAP] Synergy between Experiments and Computations: A Green Channel for Revealing Metabolic Mechanism of Xenobiotics in Chemical Toxicology

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00448




meta

[ASAP] Cellular Metabolism in High-Throughput <italic toggle="yes">In Vitro</italic> Reporter Gene Assays and Implications for the Quantitative <italic toggle="yes">In Vitro</italic>–<italic toggle="yes&

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00037




meta

[ASAP] Binding and Metabolism of Brominated Flame Retardant ß-1,2-Dibromo-4-(1,2-dibromoethyl)cyclohexane in Human Microsomal P450 Enzymes: Insights from Computational Studies

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00076




meta

[ASAP] In Vitro Phase I Metabolic Profiling of the Synthetic Cannabinoids AM-694, 5F-NNEI, FUB-APINACA, MFUBINAC, and AMB-FUBINACA

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.9b00466




meta

[ASAP] Particulate Matter Toxicity Is Nrf2 and Mitochondria Dependent: The Roles of Metals and Polycyclic Aromatic Hydrocarbons

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00007




meta

[ASAP] Effects of Arsenic on wnt/ß-catenin Signaling Pathway: A Systematic Review and Meta-analysis

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00019




meta

[ASAP] Correction to “Hemoglobin Adducts and Urinary Metabolites of Arylamines and Nitroarenes”

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00117




meta

[ASAP] Quadruply Stranded Metallo-Supramolecular Helicate [Pd<sub>2</sub>(hextrz)<sub>4</sub>]<sup>4+</sup> Acts as a Molecular Mimic of Cytolytic Peptides

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00061




meta

Engineer Builds Instruments for One-Man Metal Band

Tristan Shone designed, prototyped, and machined his "dub machines" and uses them to rage on songs like "Terrorbird."




meta

WIRED by Design - How Metaphors Make Us Love Some Designs and Not Others

Michael Hendrix at WIRED by Design, 2014. In partnership with Skywalker Sound, Marin County, CA. To learn more visit: live.wired.com




meta

Absurd Creatures | A Bird Impaling Its Victims Is So Metal I Can't Even Stand It

The shrike may look like a songbird but the only tunes it knows are METAL! The cute little bird kills its prey then impales them on spikes.




meta

Hands On with the Meta AR 2

The Meta 2 AR headset brings virtual objects into your real world and is designed to replace your computer monitor altogether.




meta

Scientist Explains How to Study the Metabolism of Ultra High Flying Geese

Bar-headed geese are the SR-71's of the avian world, soaring to 26,000 feet. To learn how their bodies function so well at altitude researchers raised a gaggle of geese, introduced them to a wind tunnel, strapped tiny masks to their beaks and sensor packs on their backs.




meta

Solar selective characteristics and local electronic bonding states of 3d transition metal oxide and metal nitride based thin film coatings / Mohammad Mahbubur Rahman

Rahman, Mohammad Mahbubur, author




meta

Transformation processes of metals in urban road dust: implications for stormwater reuse / Ayomi Jayarathne, Buddhi Wijesiri, Prasanna Egodawatta, Godwin A Ayoko, Ashantha Goonetilleke

Online Resource




meta

HP-UHP metamorphism and tectonic evolution of orogenic belts / edited by Lifei Zhang, Zeming Zhang, Hans-Peter Schertl and Chunjing Wei

Hayden Library - QE621.H48 2019




meta

Metamorphic geology: microscale to mountain belts / edited by S. Ferrero, P. Lanari, P. Goncalves, and E. G. Grosch

Hayden Library - QE475.A2 M473 2019




meta

Ultrafast assembly of swordlike Cu3(1,3,5-benzenetricarboxylate)n metal–organic framework crystals with exposed active metal sites

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00171F, Communication
Heba Ahmed, Xinci Yang, Yemima Ehrnst, Ninweh N. Jeorje, Susan Marqus, Peter C. Sherrell, Ahmed El Ghazaly, Johanna Rosen, Amgad R. Rezk, Leslie Y. Yeo
A new acoustomicrofluidic method for synthesizing copper-based metal–organic frameworks is shown to yield novel large aspect ratio elongated crystal morphologies with high active metal site density on their surfaces, leading to enhanced conductivity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry