pro Silicone rubber composition, silicone rubber molded article, and production method thereof By www.freepatentsonline.com Published On :: Tue, 10 Feb 2015 08:00:00 EST A UV curable silicone rubber composition is provided. The composition does not undergo curing failure, foaming, and other undesirable conditions even if a water-containing inorganic filler such as zeolite were added. A UV curable silicone rubber composition comprising (A) 100 parts by weight of an organopolysiloxane having at least 2 alkenyl groups per molecule represented by the average compositional formula (I): R1aSiO(4-a)/2 (I) (wherein R1 is independently a substituted or unsubstituted monovalent hydrocarbon group, and a is a positive number of 1.95 to 2.05); (B) 1 to 300 parts by weight of an inorganic filler having a water content of at least 0.5% by weight; (C) 0.1 to 50 parts by weight of an organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen atoms per molecule; and (D) a catalytic amount of a photoactive platinum complex curing catalyst. Full Article
pro Semi-cured product, cured product and method of manufacturing these, optical component, curable resin composition By www.freepatentsonline.com Published On :: Tue, 10 Feb 2015 08:00:00 EST A heat-resistant cured product is efficiently produced by obtaining a semi-cured product where a curable resin composition containing a (meth)acrylate monomer, a non-conjugated vinylidene group-containing compound and a thermal radical-polymerization initiator is processed by at least one of photoirradiation and heating to give a semi-cured product having a complex viscosity of from 105 to 108 mPa·s at 25° C. and at a frequency of 10 Hz; and putting the semi-cured product in a forming die for pressure formation therein, and heating it therein for thermal polymerization to give a cured product. Full Article
pro UV-curable coating compositions with self-healing capabilities, coating films, and methods of producing coating films By www.freepatentsonline.com Published On :: Tue, 10 Mar 2015 08:00:00 EDT The present invention is directed to a coating composition including a (meth)acrylate binder resin, a UV initiator, an organic solvent, and silica particles surface-treated with a (meth)acrylate compound, a coating film including a cured product of the coating composition, and a method of producing the coating film. The present invention makes it possible to provide a coating material having high transmittance and a low level of haze, and excellent scratch resistance and self-healing capabilities. Full Article
pro Scalable network security with fast response protocol By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT This disclosure provides a network security architecture that permits installation of different software security products as virtual machines (VMs). By relying on a standardized data format and communication structure, a general architecture can be created and used to dynamically build and reconfigure interaction between both similar and dissimilar security products. Use of an integration scheme having defined message types and specified query response framework provides for real-time response and easy adaptation for cross-vendor communication. Examples are provided where an intrusion detection system (IDS) can be used to detect network threats based on distributed threat analytics, passing detected threats to other security products (e.g., products with different capabilities from different vendors) to trigger automatic, dynamically configured communication and reaction. A network security provider using this infrastructure can provide hosted or managed boundary security to a diverse set of clients, each on a customized basis. Full Article
pro Providing indirect data addressing in an input/output processing system where the indirect data address list is non-contiguous By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT A method includes configuring a processing circuit to perform: receiving a control word for an I/O operation, forwarding a transport command control block (TCCB) from the channel subsystem to a control unit, gathering data associated with the I/O operation, and transmitting the gathered data to the control unit in the I/O processing system. Gathering the data includes accessing entries of a list of storage addresses that collectively specifying the data. Based on an entry of the list comprising a not-set first flag and a corresponding first storage address, gathering data from a corresponding storage location, and based on an entry of the list comprising a set first flag and a corresponding second storage address, obtaining a next entry of the list from a second storage location. Full Article
pro Multipass programming in buffers implemented in non-volatile data storage systems By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT The various implementations described herein include systems, methods and/or devices used to enable multipass programming in buffers implemented in non-volatile data storage systems (e.g., using one or more flash memory devices). In one aspect, a portion of memory (e.g., a page in a block of a flash memory device) may be programmed many (e.g., 1000) times before an erase is required. Some embodiments include systems, methods and/or devices to integrate Bloom filter functionality in a non-volatile data storage system, where a portion of memory storing one or more bits of a Bloom filter array may be programmed many (e.g., 1000) times before the contents of the portion of memory need to be moved to an unused location in the memory. Full Article
pro System and method to process event reporting in an adapter By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT Method and system for an adapter is provided. The adapter includes a plurality of function hierarchies, with each function hierarchy including a plurality of functions and each function being associated with an event. The adapter also includes a plurality of processors for processing one or more events generated by the plurality of functions. The adapter further includes a first set of arbitration modules, where each arbitration module is associated with a function hierarchy and receives interrupt signals from the functions within the associated function hierarchy and selects one of the interrupt signals. The adapter also includes a second set of arbitration modules, where each arbitration module receives processor specific interrupt signals and selects one of the interrupt signals for processing an event associated with the selected interrupt signal. Full Article
pro Interrupt control method and multicore processor system By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT In an interrupt control method of a multicore processor system including cores, a cache coherency mechanism, and a device, a first core detecting an interrupt signal from the device writes into an area prescribing an interrupt flag in the cache memory of the first core, first data indicating detection of the interrupt signal, and notifies the other cores of an execution request for interrupt processing corresponding to the interrupt signal, consequent to the cache coherency mechanism establishing coherency among at least cache memories of the other cores when the first data is written; and a second core different from the first core, maintaining the first data written as the interrupt flag, and notified of the execution request executes the interrupt processing, and writes over the area prescribing the interrupt flag written in the cache memory of the second core, with second data indicating no-detection of the interrupt signal. Full Article
pro Handling interrupts in a multi-processor system By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT A data processing apparatus has a plurality of processors and a plurality of interrupt interfaces each for handling interrupt requests from a corresponding processor. An interrupt distributor controls routing of interrupt requests to the interrupt interfaces. A shared interrupt request is serviceable by multiple processors. In response to the shared interrupt request, a target interrupt interface issues an interrupt ownership request to the interrupt distributor, without passing the shared interrupt request to the corresponding processor, if it estimates that the corresponding processor is available for servicing the shared interrupt request. The shared interrupt request is passed to the corresponding processor when an ownership confirmation is received from the interrupt distributor indicating that the processor has been selected for servicing the shared interrupt request. Full Article
pro Information processing apparatus, method thereof, and storage medium By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT An information processing apparatus includes a plurality of modules connected in a ring shape via a bus, and each module processes a packet flowing in a single direction on the ring in a predetermined order. The module includes a communication unit for transmitting a packet received from a first direction in the ring via the bus to a second direction, a discrimination unit for discriminating a packet from among the packets received from the first direction as a processing packet to be processed by the module, and a processing unit which is connected with the communication unit one by one and configured to process the processing packet. The communication unit transmits the packet processed by the processing unit at an interval equivalent to processing time or more for a processing packet processed by a module in a latter stage in the predetermined order among packets transmitted by the communication unit to the second direction. Full Article
pro Data transfer control apparatus, data transfer control method, and computer product By www.freepatentsonline.com Published On :: Tue, 18 Aug 2015 08:00:00 EDT A data transfer control apparatus includes a transferring unit that transfers data from a transfer source memory to a transfer destination memory, according to an instruction from a first processor; and a first processor configured to detect a process execute by the first processor, determine whether transfer of the data is urgent, based on the type of the detected process, and control the transferring unit or the first processor to transfer the data, based on a determination result. Full Article
pro Reducing cross queue synchronization on systems with low memory latency across distributed processing nodes By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT A method for efficient dispatch/completion of a work element within a multi-node data processing system. The method comprises: selecting specific processing units from among the processing nodes to complete execution of a work element that has multiple individual work items that may be independently executed by different ones of the processing units; generating an allocated processor unit (APU) bit mask that identifies at least one of the processing units that has been selected; placing the work element in a first entry of a global command queue (GCQ); associating the APU mask with the work element in the GCQ; and responsive to receipt at the GCQ of work requests from each of the multiple processing nodes or the processing units, enabling only the selected specific ones of the processing nodes or the processing units to be able to retrieve work from the work element in the GCQ. Full Article
pro Virtual machine provisioning based on tagged physical resources in a cloud computing environment By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT A cloud system may create physical resource tags to store relationships between cloud computing offerings, such as computing service offerings, storage offerings, and network offerings, and the specific physical resources in the cloud computing environment. Cloud computing offerings may be presented to cloud customers, the offerings corresponding to various combinations of computing services, storage, networking, and other hardware or software resources. After a customer selects one or more cloud computing offerings, a cloud resource manager or other component within the cloud infrastructure may retrieve a set of tags and determine a set of physical hardware resources associated with the selected offerings. The physical hardware resources associated with the selected offerings may be subsequently used to provision and create the new virtual machine and its operating environment. Full Article
pro Managing utilization of physical processors of a shared processor pool in a virtualized processor environment By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT Systems, methods and computer program products may provide managing utilization of one or more physical processors in a shared processor pool. A method of managing utilization of one or more physical processors in a shared processor pool may include determining a current amount of utilization of the one or more physical processors and generating an instruction message. The instruction message may be at least partially determined by the current amount of utilization. The method may further include sending the instruction message to a guest operating system, the guest operating system having a number of enabled virtual processors. Full Article
pro System, method and program product for cost-aware selection of stored virtual machine images for subsequent use By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT A system, method and computer program product for allocating shared resources. Upon receiving requests for resources, the cost of bundling software in a virtual machine (VM) image is automatically generated. Software is selected by the cost for each bundle according to the time required to install it where required, offset by the time to uninstall it where not required. A number of VM images having the highest software bundle value (i.e., highest cost bundled) is selected and stored, e.g., in a machine image store. With subsequent requests for resources, VMs may be instantiated from one or more stored VM images and, further, stored images may be updated selectively updated with new images. Full Article
pro Method and system for providing storage services By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT Method and system are provided for managing components of a storage operating environment having a plurality of virtual machines that can access a storage device managed by a storage system. The virtual machines are executed by a host platform that also executes a processor-executable host services module that interfaces with at least a processor-executable plug-in module for providing information regarding the virtual machines and assists in storage related services, for example, replicating the virtual machines. Full Article
pro Apparatus and methods for adaptive thread scheduling on asymmetric multiprocessor By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT Techniques for adaptive thread scheduling on a plurality of cores for reducing system energy are described. In one embodiment, a thread scheduler receives leakage current information associated with the plurality of cores. The leakage current information is employed to schedule a thread on one of the plurality of cores to reduce system energy usage. On chip calibration of the sensors is also described. Full Article
pro Converting dependency relationship information representing task border edges to generate a parallel program By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT According to an embodiment, based on task border information, and first-type dependency relationship information containing N number of nodes corresponding to data accesses to one set of data, containing edges representing dependency relationship between the nodes, and having at least one node with an access reliability flag indicating reliability/unreliability of corresponding data access; task border edges, of edges extending over task borders, are identified that have an unreliable access node linked to at least one end, and presentation information containing unreliable access nodes is generated. According to dependency existence information input corresponding to the set of data, conversion information indicating absence of data access to the unreliable access nodes is output. According to the conversion information, the first-type dependency relationship information is converted into second-type dependency relationship information containing M number of nodes (0≦M≦N) corresponding to data accesses to the set of data and containing edges representing inter-node dependency relationship. Full Article
pro Parallel computer system and program By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT There is provided a parallel computer system for performing barrier synchronization using a master node and a plurality of worker nodes based on the time to allow for an adaptive setting of the synchronization time. When a task process in a certain worker node has not been completed by a worker determination time, the particular worker node performs a communication to indicate that the process has not been completed, to a master node. When the communication has been received by a master determination time, the master node performs a communication to indicate that the process time is extended by a correction process time, in order to adjust and extend the synchronization time. In this way, it is possible to reduce the synchronization overhead associated with the execution of an application with a relatively large variation in the process time from a synchronization point to the next synchronization point. Full Article
pro Reconfigurable processor and method By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT Disclosed are a reconfigurable processor and processing method, a reconfiguration control apparatus and method, and a thread modeler and modeling method. A memory area of a reconfigurable processor may be divided into a plurality of areas, and a context enabling a thread process may be stored in respective divided areas, in advance. Accordingly, when a context switching is performed from one thread to another thread, the other thread may be executed by using information stored in an area corresponding to the other thread. Full Article
pro Information processing device and task switching method By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT Disclosed is an information processing device and a task switching method that can reduce the time required for switching of tasks in a plurality of coprocessors. The information processing device (30) includes a processor core (301); coprocessors (311 to 31n) including operation units (321 to 32n) that perform operation in response to a request from the processor core (301) and operation storage units (331 to 22n) that store the contents of operation of the operation units (321 to 32n), save storage units (351 to 35n) that store the saved contents of operation, a task switching control unit (302) that outputs a save/restore request signal when switching a task on which operation is performed by the coprocessors (311 to 31n), and save/restore units (341 to 34n) that perform at least one of saving of the contents of operation in the operation storage units (331 to 33n) to the save storage units (351 to 35n) and restoration of the contents of operation in the save storage units (351 to 35 n) to the operation storage units (331 to 33n) in response to the save/restore request signal. Full Article
pro ***WITHDRAWN PATENT AS PER THE LATEST USPTO WITHDRAWN LIST***Data transfer control apparatus, data transfer control method, and computer product By www.freepatentsonline.com Published On :: Tue, 30 Jun 2015 08:00:00 EDT A data transfer control apparatus includes a transferring unit that transfers data from a transfer source memory to a transfer destination memory, according to an instruction from a first processor; and a first processor configured to detect a process execute by the first processor, determine whether transfer of the data is urgent, based on the type of the detected process, and control the transferring unit or the first processor to transfer the data, based on a determination result. Full Article
pro Method and apparatus for continuously producing 1,1,1,2,3-pentafluoropropane with high yield By www.freepatentsonline.com Published On :: Tue, 10 Feb 2015 08:00:00 EST A method and apparatus for method of continuously producing 1,1,1,2,3-pentafluoropropane with high yield is provided. The method includes (a) bringing a CoF3-containing cobalt fluoride in a reactor into contact with 3,3,3-trifluoropropene to produce a CoF2-containing cobalt fluoride and 1,1,1,2,3-pentafluoropropane, (b) transferring the CoF2-containing cobalt fluoride in the reactor to a regenerator and bringing the transferred CoF2-containing cobalt fluoride into contact with fluorine gas to regenerate a CoF3-containing cobalt fluoride, and (c) transferring the CoF3-containing cobalt fluoride in the regenerator to the reactor and employing the transferred CoF3-containing cobalt fluoride in Operation (a). Accordingly, the 1,1,1,2,3-pentafluoropropane can be continuously produced with high yield from the 3,3,3-trifluoropropene using a cobalt fluoride (CoF2/CoF3) as a fluid catalyst, thereby improving the reaction stability and readily adjusting the optimum conversion rate and selectivity. Full Article
pro Fluoroalkyl iodide and its production process By www.freepatentsonline.com Published On :: Tue, 17 Feb 2015 08:00:00 EST A process for producing a fluoroalkyl iodide as a telomer Rf(CF2CF2)nI (wherein Rf is a C1-10 fluoroalkyl group, and n is an integer of from 1 to 6) by telomerization from a fluoroalkyl iodide represented by the formula RfI (wherein Rf is as defined above) as a telogen and tetrafluoroethylene (CF2CF2) as a taxogen, which comprises a liquid phase telomerization step of supplying a homogeneous liquid mixture of the telogen and the taxogen from the lower portion of a tubular reactor, moving the mixture from the lower portion towards the upper portion of the reactor in the presence of a radical initiator over a retention time of at least 5 minutes while the reaction system is kept in a liquid phase state under conditions where no gas-liquid separation will take place, so that the taxogen supplied to the reactor is substantially consumed by the reaction in the reactor, and drawing the reaction product from the upper portion of the reactor. Full Article
pro Optically active ammonium salt compound, production intermediate thereof, and production method thereof By www.freepatentsonline.com Published On :: Tue, 24 Feb 2015 08:00:00 EST An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality: where: R1 represents a halogen, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, C3-8 heteroaryl, linear, branched, or cyclic C1-8 alkoxy, or C7-16 aralkyl;R21 each independently represents hydrogen, halogen, nitro, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, linear, branched, or cyclic C1-8 alkoxy, or a C7-16 aralkyl;R3 represents hydrogen, or an optionally substituted: C6-14 aryl, a C3-8 heteroaryl, or a C7-16 aralkyl; andY2 represents a halogen, or an optionally substituted: C1-8 alkylsulfonyloxy, C6-14 arylsulfonyloxy, or C7-16 aralkylsulfonyloxy. Full Article
pro Diaryliodonium salt mixture and process for production thereof, and process for production of diaryliodonium compound By www.freepatentsonline.com Published On :: Tue, 10 Mar 2015 08:00:00 EDT Disclosed are: a diaryliodonium salt mixture which is a precursor of a BF4 salt or the like of a diaryliodonium compound, can be produced in the form of crystals at ambient temperature, can be purified in a simple manner, can be produced with high efficiency, and can be induced into a BF4 salt or the like salt that has excellent solubility in a monomer or the like; and a process for producing the diaryliodonium salt mixture. Also disclosed is a production process which can achieve good yield and can produce reduced amounts of byproducts, and is therefore applicable to the industrial mass production of a diaryliodonium compound. The diaryliodonium salt mixture is characterized by containing at least two specific diaryliodonium salts. Full Article
pro Process for producing 2,3,3,3-tetrafluoropropene By www.freepatentsonline.com Published On :: Tue, 10 Mar 2015 08:00:00 EDT The instant invention relates to a process and method for manufacturing 2,3,3,3-tetrafluoropropene by dehydrohalogenating a reactant stream of 2-chloro-1,1,1,2-tetrafluoropropane that is substantially free from impurities, particularly halogenated propanes, propenes, and propynes. Full Article
pro Method for producing pentafluoroethane By www.freepatentsonline.com Published On :: Tue, 10 Mar 2015 08:00:00 EDT The present invention aims in a method wherein tetrachloroethylene (PCE) is reacted with HF in a gas phase in the presence of a catalyst to obtain pentafluoroethane (HFC-125), to reduce production of undesirable by-products and maintain a catalytic activity at a high level over a long period of time while achieving a high conversion ratio of PCE and suppressing deterioration of the catalyst. In a method for producing pentafluoroethane wherein tetrachloroethylene is reacted with HF in a gas phase in the presence of a catalyst to obtain pentafluoroethane, characterized in that chromium oxyfluoride is disposed in a reactor as the catalyst, and oxygen is fed into the reactor together with tetrachloroethylene and HF, at a amount of 0.4-1.8% by mole with respect to tetrachloroethylene. Full Article
pro Method for purifying 2,3,3,3-tetrafluoropropene By www.freepatentsonline.com Published On :: Tue, 10 Mar 2015 08:00:00 EDT The present invention provides a method for purifying HFO-1234yf, comprising the steps of (1) cooling a liquid mixture containing HFO-1234yf and HF to separate the mixture into a upper liquid phase having a high concentration of HF and a lower liquid phase having a high concentration of 2,3,3,3-tetrafluoropropene; and (2) subjecting the lower liquid phase obtained in step (1) to a distillation operation to withdraw a mixture containing HFO-1234yf and HF from a top of a distillation column, thereby obtaining substantially HF-free HFO-1234yf from a bottom of the distillation column. According to the present invention, HF and HFO-1234yf contained in a mixture containing HF and HFO-1234yf can be separated under simple and economically advantageous conditions. Full Article
pro Process for producing 1,2-dichloro-3,3,3-trifluoropropene By www.freepatentsonline.com Published On :: Tue, 24 Mar 2015 08:00:00 EDT Disclosed is a process for producing 1,2-dichloro-3,3,3-trifluoropropene, which is characterized by that 1-halogeno-3,3,3-trifluoropropene represented by the general formula [1]: (In the formula, X represents a fluorine atom, chlorine atom or bromine atom.) is reacted with chlorine in a gas phase in the presence of a catalyst. It is possible by this process to produce 1,2-dichloro-3,3,3-trifluoropropene in an industrial scale with good yield by using 1-halogeno-3,3,3-trifluoropropene, which is available with a low price, as the raw material. Full Article
pro Production method for 1-chloro-3,3,3-trifluoropropene By www.freepatentsonline.com Published On :: Tue, 24 Mar 2015 08:00:00 EDT A production method of 1-chloro-3,3,3-trifluoropropene according to the present invention includes reaction of 1,1,1,3,3-pentachloropropane with hydrogen fluoride, characterized in that the concentrations of respective catalytic components in the 1,1,1,3,3-pentachloropropane as the raw material is controlled to a predetermined level or less. By controlling the concentrations of the respective catalytic components in the 1,1,1,3,3-pentachloropropane to the predetermined level or less, it is possible to improve the problems of shortening of catalyst life, retardation of reaction and scaling or corrosion of equipment in the production of the 1-chloro-3,3,3-trifluoropropene. In addition, the 1,1,1,3,3-pentachloropropane can be obtained selectively with high yield by telomerization reaction of carbon tetrachloride and vinyl chloride. The present invention is thus useful as the method for industrially advantageous, high-yield production of the 1-chloro-3,3,3-trifluoropropene. Full Article
pro Process for the manufacture of hydrochlorofluoroolefins By www.freepatentsonline.com Published On :: Tue, 24 Mar 2015 08:00:00 EDT The invention also relates a process for the manufacture of trans 1-chloro3,3,3-trifluoropropene. The process comprises an isomerization step from cis 1233zd to trans 1233zd. Full Article
pro Process for the manufacture of hydrochlorofluoroolefins By www.freepatentsonline.com Published On :: Tue, 24 Mar 2015 08:00:00 EDT The invention also relates a process for the manufacture of trans 1-chloro3,3,3-trifluoropropene. The process comprises an isomerization step from cis 1233zd to trans 1233zd. Full Article
pro Process for the reduction of RfCCX impurities in fluoroolefins By www.freepatentsonline.com Published On :: Tue, 24 Mar 2015 08:00:00 EDT The present disclosure relates to processes for reducing the concentration of RfC≡CX impurities in fluoroolefins. The process involves: contacting a mixture comprising at least one fluoroolefin and at least one RfC≡CX impurity with at least one amine to reduce the concentration of the at least one RfC≡CX impurity in the mixture; wherein Rf is a perfluorinated alkyl group, and X is H, F, Cl, Br or I. The present disclosure also relates to processes for making at least one hydrotetrafluoropropene product selected from the group consisting of CF3CF═CH2, CF3CH═CHF, and mixtures thereof and reducing the concentration of CF3C═CH impurity generated during the process. The present disclosure also relates to processes for making at least one hydrochlorotrifluoropropene product selected from the group consisting of CF3CCl═CH2, CF3CH═CHCl, and mixtures thereof and reducing the concentration of CF3C≡CH impurity generated during the process. Full Article
pro Process to make 1,1,2,3-tetrachloropropene By www.freepatentsonline.com Published On :: Tue, 31 Mar 2015 08:00:00 EDT Disclosed is a process for the synthesis of 1,1,2,3-tetrachloropropene (HCC-1230xa) using 1,1,3-trichloropropene (HCC-1240za) and/or 3,3,3-trichloropropene (HCC-1240zf) and Cl2 gas as the reactants, wherein the process takes place in a single reactor system. Before this invention, HCC-1230xa was made in a two-step process using HCC-1240za/HCC-1240zf and Cl2 gas, and the processing was conducted using two separate reactors. Full Article
pro Processes for separation of fluoroolefins from hydrogen fluoride by azeotropic distillation By www.freepatentsonline.com Published On :: Tue, 07 Apr 2015 08:00:00 EDT The present disclosure relates to a process for separating a fluoroolefin from a mixture comprising hydrogen fluoride and fluoroolefin, comprising azeotropic distillation both with and without an entrainer. In particular are disclosed processes for separating any of HFC-1225ye, HFC-1234ze, HFC-1234yf or HFC-1243zf from HF. Full Article
pro Methods for producing 1-chloro-3,3,3-trifluoropropene from 2-chloro-3,3,3-trifluoropropene By www.freepatentsonline.com Published On :: Tue, 07 Apr 2015 08:00:00 EDT The present invention provides processes for the production of HCFO-1233zd, 1-chloro-3,3,3-trifluoropropene, from the starting material, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf). In a first process, HCFO-1233zd is produced by the isomerization of HCFO-1233xf. In a second process, HCFO-1233zd is produced in a two-step procedure which includes (i) dehydrochlorination of HCFO-1233xf into trifluoropropyne; and (ii) hydrochlorination of the trifluoropropyne into HCFO-1233zd. Full Article
pro Integrated process for the production of 1-chloro-3,3,3-trifluoropropene By www.freepatentsonline.com Published On :: Tue, 07 Apr 2015 08:00:00 EDT The present invention is directed to processes for the production of 1233zd from 240fa and HF, with or without a catalyst, at a commercial scale. The 240fa and HF are fed to a reactor operating at high pressure. The resulting product stream comprising 1233zd, HCl, HF, and other byproducts is treated to one or more purification techniques including phase separation and one or more distillations to provide purified 1233zd, which meets commercial product specifications, i.e., having a GC purity of 99.5% or greater. Full Article
pro Catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene to produce 1-chloro-2,2-difluoroethane By www.freepatentsonline.com Published On :: Tue, 07 Apr 2015 08:00:00 EDT The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used. Full Article
pro Process for separating chlorinated methanes By www.freepatentsonline.com Published On :: Tue, 07 Apr 2015 08:00:00 EDT The present invention relates to a process for separating chlorinated methanes utilizing a dividing wall column. Processes and manufacturing assemblies for generating chlorinated methanes are also provided, as are processes for producing products utilizing the chlorinated methanes produced and/or separated utilizing the present process(es) and/or assemblies. Full Article
pro Process for purifying (hydro) fluoroalkenes By www.freepatentsonline.com Published On :: Tue, 21 Apr 2015 08:00:00 EDT The invention relates to a process for removing one or more undesired (hydro)halocarbon compounds from a (hydro)fluoroalkene, the process comprising contacting a composition comprising the (hydro)fluoroalkene and one or more undesired (hydro)halocarbon compounds with an aluminum-containing absorbent, activated carbon, or a mixture thereof. Full Article
pro Process for the preparation of dichlorofulvene By www.freepatentsonline.com Published On :: Tue, 21 Apr 2015 08:00:00 EDT The invention relates to a process for the preparation of formula (I) which process comprises pyrolyzing a compound of formula (II) wherein X is chloro or bromo, and to compounds which may be used as intermediates for the manufacture of the compound of formula I and to the preparation of said intermediates. Full Article
pro Reactor and agitator useful in a process for making 1-chloro-3,3,3-trifluoropropene By www.freepatentsonline.com Published On :: Tue, 28 Apr 2015 08:00:00 EDT Disclosed is a reactor and agitator useful in a high pressure process for making 1-chloro-3,3,3-trifluoropropene (1233zd) from the reaction of 1,1,1,3,3-pentachloropropane (240fa) and HF, wherein the agitator includes one or more of the following design improvements: (a) double mechanical seals with an inert barrier fluid or a single seal;(b) ceramics on the rotating faces of the seal;(c) ceramics on the static faces of seal;(d) wetted o-rings constructed of spring-energized Teflon and PTFE wedge or dynamic o-ring designs; and(e) wetted metal surfaces of the agitator constructed of a corrosion resistant alloy. Full Article
pro Process for the preparation of fluoroolefin compounds By www.freepatentsonline.com Published On :: Tue, 28 Apr 2015 08:00:00 EDT The subject of the invention is a process for the preparation of fluoroolefin compounds. It relates more particularly to a process for manufacturing a (hydro)fluoroolefin compound comprising (i) bringing at least one compound comprising from three to six carbon atoms, at least two fluorine atoms and at least one hydrogen atom, provided that at least one hydrogen atom and one fluorine atom are located on adjacent carbon atoms, into contact with potassium hydroxide in a stirred reactor, containing an aqueous reaction medium, equipped with at least one inlet for the reactants and with at least one outlet, in order to give the (hydro)fluoroolefin compound, which is separated from the reaction medium in gaseous form, and potassium fluoride, (ii) bringing the potassium fluoride formed in (i) into contact, in an aqueous medium, with calcium hydroxide in order to give potassium hydroxide and to precipitate calcium fluoride, (iii) separation of the calcium fluoride precipitated in step (ii) from the reaction medium and (iv) optionally, the reaction medium is recycled after optional adjustment of the potassium hydroxide concentration to step (i). Full Article
pro Methods to separate halogentated olefins from 2-chloro-1,1,1,2-tetrafluoropropane using a solid adsorbent By www.freepatentsonline.com Published On :: Tue, 28 Apr 2015 08:00:00 EDT The present invention provides a method for separating halocarbons. In particular, the invention provides a method for separating halogenated olefin impurities from 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) using a solid adsorbent, particularly activated carbon. More particularly the invention pertains to a method for separating 2-chloro-3,3,3-trifluoro-propene (HCFO-1233xf) from HCFC-244bb, which are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf). Full Article
pro Azeotropic or azeotrope-like composition, and method for producing 2,3,3,3-tetrafluoropropene or chloromethane By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT To provide a method for efficiently separating 2,3,3,3-tetrafluoropropene (HFO-1234yf) and chloromethane (R40) from a composition comprising HFO-1234yf and R40. An azeotrope-like composition comprising from 58 to 78 mol % of HFO-1234yf and from 22 to 42 mol % of R40, and a method for producing HFO-1234yf, which comprises steps of distilling an initial mixture containing HFO-1234yf in a content exceeding 63 mol % in the total amount of HFO-1234yf and R40, thereby to separate the initial mixture into a first fraction in which the content of HFO-1234yf in the total amount of HFO-1234yf and R40 is lower than the content of HFO-1234yf in the total amount of HFO-1234yf and R40 in the initial mixture, and a second fraction in which the content of HFO-1234yf in the total amount of HFO-1234yf and R40 is higher than the content of HFO-1234yf in the total amount of HFO-1234yf and R40 in the initial mixture, and then obtaining HFO-1234yf having a reduced R40 concentration, from the second fraction. Full Article
pro Method for producing fluorinated organic compounds By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT Provided is a process for making 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of hydrofluorinating 2-chloro-3,3,3-trifluoropropene in the presence of a catalyst selected from the group consisting of SbCl3, SbCl5, SbF5, TiCl4, SnCl4, Cr2O3, and fluorinated Cr2O3. Full Article
pro Process for 1-chloro-3,3,3-trifluoropropene from trifluoromethane By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides routes for HCFO-1233zd from inexpensive and commercially available trifluoromethane (HFC-23). Full Article
pro Process for 1-chloro-3,3,3-trifluoropropene from trifluoropropene By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides several routes for forming HCFO-1233zd from 3,3,3-trifluoropropene (FC-1234zf). Full Article
pro Method for producing fluorinated organic compounds By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT A method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3(—CX2X2)nCX1═H2 (I) to at least one compound of formula (II): CF3(CX2X2)nCX1═H2 (II), where X1 is Cl, Br or I, each X2 is independently selected from the group consisting of H, Cl, F, Br or J, and n is 0, 1, or 2. Full Article