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Tuning the phototherapeutic activity of Pt(IV) complexes for bladder cancer via modification of trans N-heterocyclic ligands

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Multistage construction of Gd-doped g-C3N4/Mo15S19 composites enabled both N2 activation and multiple electron transfer for an enhanced photocatalytic nitrogen reduction reaction

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02016B, Research Article
Xiaoyu Jiang, Boran Tao, Hongda Li
A multistage construction of the Gd-doped g-C3N4/Mo15S19 catalyst, with Gd3+ as redox centers and Mo15S19 as N2 activation sites, synergistically enhances its photocatalytic NRR performance.
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Tunable luminescence via Cr3+–Yb3+/Nd3+ energy transfer in Cr3+ and Yb3+/Nd3+ coactivated NIR phosphors for non-destructive analysis

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02260B, Research Article
Open Access
Xiaowei Zhang, Dashuai Sun, Pengcheng Luo, Luhui Zhou, Zheng Lu, Jia Liu, Congcong Fan, Xinyu Ye, Hongpeng You
Novel high-efficiency near-infrared phosphors with tunable luminescence via Cr3+–Yb3+/Nd3+ energy transfer for non-destructive analysis.
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A flexible electrode Array for genetic transfection of different layers of the retina by electroporation

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,1957-1964
DOI: 10.1039/D3LC01014G, Paper
Yu Zhang, Tao Peng, Yu Ge, Mengda Li, Chendi Li, Jiyu Xi, Zixi Li, Zewen Wei, Yuntao Hu
Stratified delivery into specific retinal layers was realized by a flexible electrode array that exhibited high compatibility with surgical procedures.
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Multifunctional cardiac microphysiological system based on transparent ITO electrodes for simultaneous optical measurement and electrical signal monitoring

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,1903-1917
DOI: 10.1039/D3LC00908D, Paper
Zhangjie Li, Kai Niu, Chenyang Zhou, Feifan Wang, Kangyi Lu, Yijun Liu, Lian Xuan, Xiaolin Wang
We developed a multifunctional cardiac microphysiological system on transparent electrodes, enabling simultaneous electrical signal monitoring and optical observations of cardiac tissue, holding promise for applications in cardiac drug development.
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Opto-combinatorial indexing enables high-content transcriptomics by linking cell images and transcriptomes

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,2287-2297
DOI: 10.1039/D3LC00866E, Paper
Arata Tsuchida, Taikopaul Kaneko, Kaori Nishikawa, Mayu Kawasaki, Ryuji Yokokawa, Hirofumi Shintaku
We introduce a simple integrated analysis method that links cellular phenotypic behaviour with single-cell RNA sequencing by utilizing a combination of optical indices from cells and hydrogel beads.
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Advanced sequencing-based high-throughput and long-read single-cell transcriptome analysis

By pubs.rsc.org
Published On ::

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00105B, Critical Review
Shanqing Huang, Weixiong Shi, Shiyu Li, Qian Fan, Chaoyong Yang, Jiao Cao, Lingling Wu
Cells are the fundamental building blocks of living systems, exhibiting significant heterogeneity. The transcriptome connects the cellular genotype and phenotype, and profiling single-cell transcriptome is critical for uncovering distinct cell...
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Combination of near-infrared spectroscopy and a transient flow method for efficient kinetic analysis of the Claisen rearrangement

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, 9,2975-2983
DOI: 10.1039/D4RE00301B, Paper
Yoshihiro Takebayashi, Kiwamu Sue, Sho Kataoka
An automated flow reactor with a rapid inline monitoring using a compact near-infrared spectrometer and a flow rate ramp control enabled high-density kinetic data acquisition.
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Transesterification or polymerization? Reaction mechanism and kinetics of 2-(diethylamino)ethyl methacrylate with methanol and the competitive effect on free-radical polymerization

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00406J, Paper
Judith Cabello-Romero, Román Torres-Lubián, Javier Francisco Enríquez-Medrano, Adrián Ochoa-Terán, Jesús Jara-Cortés, Iván Zapata-González
Transesterification of 2-(diethylamino)ethyl methacrylate (DEAEMA) with methanol leads to the formation of methyl methacrylate (MMA) and amino alcohol. This reaction significantly affects DEAEMA polymerization giving rise to poly(DEAEMA-co-MMA).
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Disorder-to-order transition of long fibers contained in evaporating sessile drops

By pubs.rsc.org
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Soft Matter, 2024, 20,3107-3117
DOI: 10.1039/D3SM01735D, Paper
S. Sannyamath, R. Vetter, H. Bonart, M. Hartmann, R. Ganguly, S. Hardt
We demonstrate self-organization of hydrophilic fibers, contained in a sessile droplet in a disordered initial configurations, to transform into an order deposit. Findings suggest new avenues to decorate solid surfaces with filamental structures.
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Form II to form I transition in solution-crystallized isotactic polybutene-1

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Published On ::

Soft Matter, 2024, 20,3191-3202
DOI: 10.1039/D4SM00152D, Paper
Peng Fu, Jiaxin Huo, Jingqing Li, Claudio De Rosa, Shichun Jiang
Different polymer chains in a solution or melt have different conformations with corresponding entropy at each moment, which would be confined after crystallization.
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Spatiotemporal Mapping of Nanotopography and Thickness Transitions of Ultrathin Foam Films

By pubs.rsc.org
Published On ::

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00048J, Tutorial Review
Chenxian Xu, Yiran Zhang, Vivek Sharma
Freshly formed soap films, soap bubbles, or foam films display iridescent colors due to thin film interference that changes as squeeze flow drives drainage and a steady decrease in film...
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Pinning–depinning transition of droplets on inclined substrates with a three-dimensional topographical defect

By pubs.rsc.org
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00081A, Paper
Ninad V. Mhatre, Satish Kumar
The influence of defect geometry on the critical inclination angle required for droplet depinning on inclined substrates is studied.
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Avalanche properties at the yielding transition: from externally deformed glasses to active systems

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Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01354E, Paper
Open Access
Carlos Villarroel, Gustavo Düring
We investigated the yielding phenomenon under different scenarios of deformation in the quasistatic limit using numerical simulations of soft particles.
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Temperature dependence of micelle shape transitions in copolymer solutions: the role of inter-block incompatibility

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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00331D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. J. Greenall, M. J. Derry
The incompatibility of the blocks in a copolymer strongly affects the temperature dependence of the micelle shape transitions in solution.
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Electric-field modulated energy transfer in phosphorescent material- and fluorescent material-codoped polymer light-emitting diodes

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12294-12302
DOI: 10.1039/D4RA00669K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling-Chuan Meng, Yan-Bing Hou
In this study, we find electric-field modulated energy transfer in phosphorescent material- and fluorescent material-codoped polymer that has never been reported.
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Quantitative analysis of the illegal addition of Atenolol in Panax notoginseng based on NIR–MIR spectral data fusion and calibration transfer

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12428-12437
DOI: 10.1039/D3RA08183D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Du, Zhengwei Huang, Chun Li, Ling Jiang
To address the issue of the common illegal addition of Atenolol in Panax notoginseng, we propose an approach that realizes multivariate calibration transfer between different particle sizes based on spectral data fusion.
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Surface modification of halide perovskite using EDTA-complexed SnO2 as electron transport layer in high performance solar cells

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12397-12406
DOI: 10.1039/D3RA08900B, Paper
Open Access
Nuno Marques, Santanu Jana, Manuel J. Mendes, Hugo Águas, Rodrigo Martins, Shrabani Panigrahi
The long-term performance of metal halide perovskite solar cells (PSCs) can be significantly improved by tuning the surface characteristics of the perovskite layers.
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In situ one step growth of amorphous tin oxide electron transport layer for high-performance perovskite solar cells

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12650-12657
DOI: 10.1039/D4RA01724B, Paper
Open Access
Wenlin Du, Zhe Wan, Jingyi Zhu, Xin Liu, Li Chen, Shuxia Li, Ning Kang, Chenglong Wang
Perovskite solar cells prepared by using amorphous Tin oxide as electron transport layer.
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‘TRANScend’ing to the mainstream

By www.thehindubusinessline.com
Published On :: Sat, 02 May 2020 06:46:00 +0530

An ambitious project fights for social inclusion of transgenders


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Influence of polyol impurities on the transesterification kinetics, molecular structures and properties of isosorbide polycarbonate

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4204-4220
DOI: 10.1039/D4PY00840E, Paper
Mingfa Guo, Yaning Wang, Zhenguang Li, Jielin Xu, Qian Chen, Jing Wu, Huaping Wang
A so-called “reverse-addition” model protocol based on two kinds of polyol impurities (glycerol and 2-deoxy-D-ribose) was established to systematically demonstrate their influence on the polymerization and properties of PIC.
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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4264-4280
DOI: 10.1039/D4PY00899E, Paper
Open Access
Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof Matyjaszewski
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.
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An efficient and economical degradation strategy for epoxy thermoset based on low cost transesterification catalyst

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01137F, Paper
Zhijun Yang, Shuhan Zhang, Huan Liang, Enjian He, Yixuan Wang, Ting Lei, Zhicheng Wu, Qiulin Chen, Fusheng Zhou, Yen Wei, Yan Ji
Epoxy thermoset materials are widely used in the field of electrical engineering, including gas-insulated enclosed switches and drytype transformers. It is a challenge to degrade and recycle traditional epoxy thermoset,...
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Sequence-defined structural transitions by calcium-responsive proteins

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00907J, Paper
Marina Chang, Winnie Huang, Gatha Shambharkar, Kenny Hernandez, Danielle Jamie Mai
Biopolymer sequences dictate their functions, and protein-based polymers are a promising platform to establish sequence–function relationships for novel biopolymers. To efficiently explore vast sequence spaces of natural proteins, sequence repetition...
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Intercellular lipid-cored, hectorite nanoplatelet-armored pickering emulsions with enhanced transdermal delivery and epidermal hydration

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01610F, Paper
Boryeong Lee, Lakshmishri Prabakaran, Minkyoung Jang, Song Hua Xuan, Kyounghee Shin, Sung Ho Lee, Jin Woong Kim
An intercellular lipid-cored, hectorite nanoplatelet-armored Pickering emulsion system is proposed to enhance dermal penetration and moisture retention.
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Tuning the affinity of probes with transmembrane proteins by constructing peptide-conjugated cis/trans isomers based on molecular scaffolds

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01801J, Paper
Jing-Jing Hu, Juliang Yang, Yiheng Liu, Guangwen Lu, Zujin Zhao, Fan Xia, Xiaoding Lou
Peptide-conjugated cis/trans isomers were designed. cis-RTP interacts more stably with cell membranes than trans-RTP, and it has shown more excellent properties in inhibiting cell migration and killing cells.
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Development of a Xanthene-Based NIR Fluorescent Probe for Accurate and Sensitive Detection of γ-Glutamyl Transpeptidase in Cancer Diagnosis and Treatment

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01841A, Paper
Chia-Kai Lai, KUPPAN MAGESH, Sivan Velmathi, Shu-Pao Wu
γ-Glutamyl transpeptidase (GGT) regulates glutathione (GSH), essential for cell functions and linked to cancer. High GGT levels in tumors make it a valuable cancer biomarker. Current GGT detection methods often...
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Three apps to transform your pictures into artworks

By www.thehindu.com
Published On :: Sun, 16 Oct 2016 17:00:23 +0530


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A transformative experience

By www.thehindu.com
Published On :: Sun, 13 Nov 2016 17:00:34 +0530

PARAS ARORA’S internship at Teach for India helped him become an activist.


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Radioactive — How Ushaben’s broadcasts transmitted the message of freedom

By www.thehindubusinessline.com
Published On :: Sun, 15 Aug 2021 09:42:39 +0530

The spirited 22-year-old woman, who earned the sobriquet Radioben, was an integral part of the underground radio service during the Quit India movement


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Participation of transition metal atoms in noncovalent bonds

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, 26,27382-27394
DOI: 10.1039/D4CP03716B, Paper
Steve Scheiner
All metals of the d-block are capable of forming σ and π-hole bonds to a nucleophile. Some of these bonds are typical of noncovalent bonds, but others are strong enough to be characterized as a covalent coordinate bond.
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Oxidation of fine aluminum particles: thermally induced transformations in particle shells and kinetics of oxide nucleation

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, 26,27602-27616
DOI: 10.1039/D4CP03355H, Paper
Andrey V. Korshunov
A submicron aluminum particle during oxidation is a shrinking spherical segment due to the growth of a single γ-Al2O3 nucleus.
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Impact of valley degeneracy on the thermoelectric properties of zig-zag graphene nanoribbons with staggered sublattice potentials and transverse electric fields

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, 26,27591-27601
DOI: 10.1039/D4CP03178D, Paper
David M. T. Kuo
This study investigates the band inversion of flat bands in zig-zag graphene nanoribbons (ZGNRs) using a tight-binding model.
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Ballistic transport in sub-10 nm monolayer InAs transistors for high-performance applications

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03789H, Paper
Tianruo Xie, Yuliang Mao
The modelling of double gate MOSFETs of monolayer InAsH2 is shown in (a). The corresponding transfer characteristics are shown for (b) n-type and (c) p-type, in which various doping concentrations are chosen.
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Structural Distortion Driven Polaronic Transport and Table-like Magnetocaloric Properties in Polycrystalline Tb0.7Sr0.3MnO3 compound

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03760J, Paper
Dipak Mazumdar, I. Das, Kalipada Das
This research mainly explores the structural, magnetic, magneto-transport, and magnetocaloric properties of the polycrystalline Tb0.7Sr0.3MnO3 compound. The results reveal a significant modification of the compound’s ground state with increasing the...
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Translational diffusion, molecular brightness, and energy transfer analysis of mEGFP-linker-mScarlet–I crowding biosensor using fluorescence correlation spectroscopy

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03850A, Paper
Sarah A. Mersch, Clint McCue, Alexandros Aristidou, Erin D. Sheets, Arnold J. Boersma, Ahmed A. Heikal
Fluorescence correlation spectroscopy (FCS) is used for molecular brightness, Förster resonance energy transfer (FRET), protein–protein interactions, diffusion, and size analysis of mEGFP-linker-mScarlet–I constructs in crowded environment.
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Transferring money overseas

By www.thehindu.com
Published On :: Fri, 15 May 2015 19:11:23 +0530

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm


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Unlocking the potential of metal ligand cooperation for enantioselective transformations

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, 53,3216-3223
DOI: 10.1039/D3CS00998J, Viewpoint
Open Access
Tizian-Frank Ramspoth, Johanan Kootstra, Syuzanna R. Harutyunyan
Metal–ligand cooperation, (MLC) is a versatile catalysis concept. Herein, we discuss the historical context, mechanisms, and applications, suggesting exploring MLC for enantioselective transformations beyond (de)hydrogenative processes.
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Thermally activated structural phase transitions and processes in metal–organic frameworks

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Published On ::

Chem. Soc. Rev., 2024, 53,3606-3629
DOI: 10.1039/D3CS01105D, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Celia Castillo-Blas, Ashleigh M. Chester, David A. Keen, Thomas D. Bennett
The structural knowledge of metal–organic frameworks is crucial for understanding and developing new efficient materials for industrial implementation.
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Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry

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Published On ::

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00185K, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lars J. C. van der Zee, Jelle Hofman, Joost M. van Gaalen, J. Chris Slootweg
Here, we discuss predicting thermal and photoinduced single-electron transfer (SET) in frustrated Lewis pairs (FLPs) and characterizing the resulting radical pair. We then extend these methods' application to main-group chemistry.
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Squaramide-based receptors in anion supramolecular chemistry: insights into anion binding, sensing, transport and extraction

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, 53,3952-3975
DOI: 10.1039/D3CS01165H, Review Article
Open Access
Giacomo Picci, Riccardo Montis, Vito Lippolis, Claudia Caltagirone
Squaramides are a class of extremely versatile receptors for anion recognition, sensing, transport and extraction.
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The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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On the fundamentals of quantum rate theory and the long-range electron transport in respiratory chains

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00662J, Tutorial Review
Paulo Roberto Bueno
The quantum rate concept v = E/h = c*/L implies relativistic electrodynamics, permitting the transport of electrons in long-range paths of length L and explaining the respiration mechanism if a suitable Boltzmannian statistical setting of E is applied.
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Let's build a dam! / written and translated by Daniel Fehr ; illustrated by Mariachiara Di Giorgio

By darius.uleth.ca
Published On ::

Fehr, Daniel, author, translator


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Pineshish the blue jay : an Algonquin story / written by Michel Noël ; illustrated by Camille Lavoie ; translated by Louis Anctil

By darius.uleth.ca
Published On ::

Noël, Michel, 1944-2021, author


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Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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Direct alkene functionalization via photocatalytic hydrogen atom transfer from C(sp3)–H compounds: a route to pharmaceutically important molecules

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05026F, Highlight
Hangqian Fan, Yuxin Fang, Jingbo Yu
Direct functionalization of alkenes with C(sp3)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.
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Polymeric membrane ion-selective electrode based on potential-modulated ion transfer: ultrasensitive measurement of oceanic pH

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Chem. Commun., 2024, 60,13404-13407
DOI: 10.1039/D4CC04807E, Communication
Lu Liu, Yuanxin Liu, Tianjia Jiang, Rongning Liang, Wei Qin
A simple approach to improve the precision of potentiometric sensors is proposed based on potential-modulated ion transfer without memory effects.
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Ultra-high Li+ transfer efficiency of in situ grown membrane for high-performance batteries

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Published On ::

Chem. Commun., 2024, 60,13412-13415
DOI: 10.1039/D4CC04546G, Communication
Jian Wang, Kang Ma, Yanbo Zhang, Jiawei Chen, Xin Song, Jianmin Zhang
Lewis acid effect of in situ grown nano-Al2O3 promotes lithium salt dissociation to improve Li+ transport efficiency.
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