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RFK Jr. asks Americans to suggest policies for new Trump administration: 'Transition team belongs to YOU'

Just a week after former President Trump won back the presidency, the new administration is quickly forming, and Robert F. Kennedy, Jr. is asking ordinary Americans to make suggestions about what policies and people should be put in place.



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Nevada volleyball star calls out trans inclusion in women's sports as she joins org: 'That is not fair!'

Sia Li'ili'i, the captain of the Nevada Wolf Pack women's volleyball team, has joined the Independent Women's Forum as an ambassador as she continues to fight for women's sports.



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Violent extortion threats forced him to transform his life. He wasn't alone




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University of Pittsburgh awarded $3.3 million to develop electrical transmission technology

The Swanson School of Engineering will develop an improved HVDC converter with the Department of Energy's funds.




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Candyman, Transformers Actor Tony Todd Dies at 69

Voiced The Faillen in Transformers: Revenge of the Fallen, Dreadwing in Transformers Prime




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Transcutaneous Spinal Cord Stimulation for Children With Acute Flaccid Myelitis

Acute Flaccid Myelitis (AFM) is an uncommon but severe neurological disorder that causes bsudden paralysis in children/b. Researchers at the International




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Transcutaneous Spinal Cord Stimulation for Children With Acute Flaccid Myelitis

Learn how Transcutaneous Spinal Cord Stimulation is revolutionizing treatment for children with Acute Flaccid Myelitis, offering improved mobility and hope.




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From Changing Diapers to Changing Lives: The Transition to Fatherhood

Men often face challenges during the transition to fatherhood due to a lack of information and emotional support tailored to their specific needs, suggests




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ONYX Hospitality Group Transforms Thailand’s The Tide Resort

ONYX Hospitality Group, a leading management company for hotels, resorts, serviced apartments, and luxury residences in Southeast Asia, has signed an agreement to manage Amari The Tide Bangsaen. This property, which is a significant transformation of The Tide Resort, and has been reimagined as Amari The Tide Bangsaen, is set to reveal its new look in the second quarter of 2025. Located in Thailand in the Chonburi Province, a region poised for significant economic growth, especially in tourism, this property reflects Amari’s commitment to delivering exceptional experiences in Thailand’s most promising destinations. With a focus on enhancing the guest experience to create memorable moments for Thai and international tourists, it is set to cater to a wide range of traveller needs and preferences across leisure and business segments On 7 November 2024, a signing ceremony for a business partnership agreement to manage Amari The Tide Bangsaen was held between Five Leader Group Co., Ltd. and...




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Sheraton Jumeirah Beach Resort Unveils a New Era of Modern Comfort with a Stunning Transformation

Sheraton Jumeirah Beach Resort is proud to announce its relaunch following an extensive revitalization, redefining the guest experience at this iconic destination. As the first hotel built in the Jumeirah Beach Residence (JBR) area, Sheraton Jumeirah Beach Resort has set the standard for excellence in hospitality for over two decades. This transformation ushers in a new era, blending modern design, amenities, and cutting-edge technology while preserving the resort’s rich history and cherished legacy. The reinvention of the Resort is driven by the vision of bringing people together through shared moments and spaces. The newly reimagined rooms and suites offer a sophisticated fusion of modern design and natural textures, with a color palette inspired by the serene beachfront setting. All rooms have been thoughtfully equipped to cater to the diverse needs of today’s travellers with the latest technologies, providing guests with a seamless blend of comfort and innovation. The bathrooms to...




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Transforming Enterprise Software Development with SAP BTP

Lakshmi Srinivasa Rao Gogula highlights that SAP Business Technology Platform (BTP) is revolutionizing enterprise software by enhancing agility, integration, security, developer empowerment, and sustainability beyond traditional ABAP.




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DNA-compatible functional group transformations via K2RuO4-mediated oxidation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00203B, Research Article
Pengyang He, Guixian Zhao, Mengping Zhu, Yangfeng Li, Gong Zhang, Yizhou Li
K2RuO4-mediated oxidation offers a DNA-compatible method for functional group transformations, enabling alcohol-to-carboxylic acid and amine-to-nitrile conversions valuable for DNA-encoded library synthesis.
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Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00396A, Review Article
Dong-Sheng Yang, Xiang-Long Chen, An-Xin Wu
The synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.
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Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00265B, Research Article
Shuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping Hui
An efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.
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Base-induced azofluoroalkylation of unactivated alkenes via halogen atom transfer

Org. Chem. Front., 2024, 11,2161-2170
DOI: 10.1039/D3QO02114A, Research Article
Jing Zhang, Yanchuang Zhao, Yu-Yi Zhu, Peng Lei, Hanru Liu, Chang-Sheng Wang, Shuya Xing, Yong Liu, Shao-Fei Ni, Thomas Castanheiro, Li-Wen Xu, Xinxin Shao
A base-induced three-components coupling employing unactivated alkenes, fluoroalkyl iodides and diazonium salts under mild reaction conditions has been developed.
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Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis

Org. Chem. Front., 2024, 11,2344-2350
DOI: 10.1039/D3QO01955A, Research Article
Linge Huai, Li Zhang, Zhentao Wang, Yewen Fang
N → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage

Org. Chem. Front., 2024, 11,2277-2282
DOI: 10.1039/D3QO01999C, Research Article
Yan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang Mo
We describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.
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Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis

Org. Chem. Front., 2024, 11,2269-2276
DOI: 10.1039/D4QO00073K, Research Article
Yujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang Lu
Two major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.
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Nickel/photoredox-catalyzed carbonylative transformations of α-phosphorus-, α-sulfur-, and α-boron-substituted alkyl halides

Org. Chem. Front., 2024, 11,2297-2305
DOI: 10.1039/D4QO00167B, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Le-Cheng Wang, Xiao-Feng Wu
A novel dual nickel/photoredox catalyzed direct amino- and alkoxycarbonylation of α-heteroatom substituted organohalides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Advancement in the C–H bond alkylation of (hetero)arenes catalyzed by the most abundant transition metal–iron

Org. Chem. Front., 2024, 11,2397-2417
DOI: 10.1039/D4QO00063C, Review Article
Chandini Pradhan, Benudhar Punji
Advancement in the direct C–H bond alkylation of arenes and heteroarenes using the catalysts based on the most abundant transition metal, iron, is summarized.
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Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00351A, Research Article
Fei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng Zhu
Lovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.
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A retro-Mannich mediated transformation of Morita–Baylis–Hillman ketones to saturated imidazo[1,2-a]pyridines

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00352G, Research Article
Sachin Sharma, Ajit Kumar Jha, Srinivasan Easwar
Two fruits felled with one stone! – a proof of mechanism and a synthetic method that delivers a privileged heterocyclic motif.
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Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00317A, Research Article
Guohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin Yin
Amine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.
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Photochemical [2 + 2 + 1] annulation of 2-vinyloxy arylalkynes with bromomalonates via energy transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00249K, Research Article
Shuo Tang, Jiupeng Liu, Min Zhang, Dan Wang, Yong Wang, Jingjing Zhao, Pan Li
A transition-metal-free, oxidant-free and base-free photochemical [2 + 2 + 1] radical annulation of 2-vinyloxy arylalkynes with bromomalonates has been developed.
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Synthesis of oxindole fused 1,3-oxazepanes via hydride transfer initiated ring expansion of pyrrolidine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00474D, Research Article
Peng He, Zongkang Wang, Qiongwen Kang, Nana Fei, Chengyu Wang, Yanzhong Li
An efficient B(C6F5)3 catalyzed protocol for the synthesis of oxindole fused 1,3-oxazepanes from pyrrolidine substituted aryl alkynones has been developed.
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Efficient Fully Textured Perovskite Silicon Tandems with Thermally Evaporated Hole Transporting Materials

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03899A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bhushan Kore, Oussama Er-raji, Oliver Fischer, Adrian Callies, Oliver Schultz-Wittmann, Patricia Samia Cerian Schulze, Martin Bivour, Stefaan De Wolf, Stefan W Glunz, Juliane Borchert
Fully textured perovskite silicon tandem solar cells effectively minimize the reflection losses and are compatible with industrial silicon production lines. To facilitate scalability and industrial deployment of perovskite silicon tandems...
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Design of Interfacial Dual Schottky Junctions to Modulate Charge Transfer for Enhanced Piezo-assisted Photocatalytic Degradation RhB Performances

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00619D, Paper
Xiaoqi Jiang, Shengdong Sun, Yuqiao Wang, Lebing Zhao, Fangzhi Huang, Shikuo Li
Regulating charge transfer is a great challenge to improving the efficiency of piezoelectric photocatalytic reactions. Herein, sandwich-like Bi2WO6@Ag/MXene nanoflower spheres (BWO@Ag/MXene) with piezoelectric/plasma dual characteristics were synthesized by a facile...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Origin of sputter damage during transparent conductive oxide deposition for semitransparent perovskite solar cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06654A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qing Yang, Weiyuan Duan, Alexander Eberst, Benjamin Klingebiel, Yueming Wang, Ashish Kulkarni, Andreas Lambertz, Karsten Bittkau, Yongqiang Zhang, Svetlana Vitusevich, Uwe Rau, Thomas Kirchartz, Kaining Ding
The origin of sputter damage during transparent conductive oxide deposition is ion bombardment rather than plasma radiation. Ion bombardment increased recombination, whereas plasma radiation reduced recombination.
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Bi-intercalated vanadium pentoxide synthesized via hydrogen peroxide-induced phase transition for highly stable cathode in aqueous zinc ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07984H, Paper
Jian-an Chen, Xuejun Hou, Xueli Wang, Chunxia Wang, Jiawei Wen, Yongjie Bu, Guoyong Huang, Tiantian Cao, Shengming Xu
Operating principle of aqueous zinc-ion batteries (ZIBs).
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The balancing act between high electronic and low ionic transport influenced by perovskite grain boundaries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA04458K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nadja Glück, Nathan S. Hill, Marcin Giza, Eline Hutter, Irene Grill, Johannes Schlipf, Udo Bach, Peter Müller-Buschbaum, Achim Hartschuh, Thomas Bein, Tom Savenije, Pablo Docampo
Grain size and orientation's impact on charge carriers is explored via a new solvent engineering method for MAPbI3 solar cells. Drift-diffusion simulations connect s-shaped JV curves to slower ions.
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Revolutionary SAMs: transforming inverted perovskite solar cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00962B, Highlight
Hongshi Li, ShunChang Liu
Revolutionary self-assembled monolayers, represented by xPACz, have propelled the rapid improvement in the performance of inverted perovskite solar cells.
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Cubic-to-hexagonal Structural Phase Transition in Metal Halide Compounds: A DFT Study

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06604E, Paper
Iván Ornelas-Cruz, Ramiro M. dos Santos, José E. González, Matheus Paes Lima, Juarez L. F. Da Silva
Phase transitions into photo-inactive structural phases have impacted the use of metal halide perovskites as photovoltaic materials. However, the chemical composition has been found to mitigate this issue. This study...
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Fluorophore branching boosted photo-induced energy transfer in UiO-66 for ultrasensitive and instant hydrazine sensing

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01549E, Paper
Ying Luo, Da Lei, Maohua Li, Yuansheng Ge, Jiguang Li, Baiyi Zu, Jun Yao, Xincun Dou
Metal organic frameworks (MOFs) have made great progress in the field of fluorescent sensing; however, whether the electronic structure and recognized sites can be adjusted by external functionalization still remains challenging.
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Plasticity tunable artificial synapses based on organic electrochemical transistors with aqueous electrolytes

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03569K, Paper
Ruhua Wu, Miao Xie, Yuhua Cheng, Dan Zhao, Liang-Wen Feng, Jianhua Chen, Wei Huang
By regulating ion transporting kinetics and ion diffusion distances in organic mixed ionic–electronic conductor channels, highly tunable short- and long-term plasticity are obtained in vOECTs with aqueous electrolytes.
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Phase transition induced hydrogen activation for enhanced furfural reductive amination over CoCu bimetallic catalyst

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05885B, Edge Article
Open Access
Yilin Wei, Zixu Ma, Beibei Liu, Jialin Yang, Dan Wu, Yongsheng Zhang, Yuexing Zhang, Charles Chunbao Xu, Renfeng Nie
The synthesis of primary amines from renewable biomass and its derivatives through reductive amination has garnered significant attention. How to construct efficient non-noble-metal catalysts that enable low-temperature catalysis still remains...
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Akashteer: Transforming India's air defence with cutting-edge technology




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Karnataka High Court dismisses Union Bank of India’s petition seeking transfer of Valmiki corporation case to CBI

‘Banking Regulations Act does not empower banks to seek transfer of probe into criminal cases registered by States to agency of its choice’




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Karnataka to roll out e-khatas for all properties in GPs, ULBs to avoid fictitious transactions




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Allison Transmission to double Chennai facility with $100 mn+ investment amid rising global demand

The expansion aims to double the facility’s size, creating 167 new jobs, and enhance production capacity for automatic transmissions in response to growing global demand




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Donald Trump meets Joe Biden in White House; both pledge smooth transition

In a brief meeting, the two leaders assured the nation of a peaceful transition of power on January 20, 2025.




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Tax evasion rampant as only 23% of transactions being traced, says Chief Commissioner of IT




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The green transition India needs




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Biden meets Trump, both pledge smooth transition

In the meeting, the two leaders assured the nation of a peaceful transition of power on January 20 next year.




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Ministry and Transitions - Frederica and Fr. Gregory Mathewes-Green

Fr. Barnabas Powell interviews Frederica and Fr. Gregory Mathewes-Green after they recently transitioned from full time parish ministry to "retirement." Of course, they remain as active as ever in continued outreach.




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Donald Trump triumphantly returns to White House as Joe Biden pledges 'smooth transition'

President-elect Donald Trump made his victorious return to Washington on Wednesday, meeting with jubilant House Republicans and then conferring with President Biden in the Oval Office, where they mutually pledged a smooth transfer of power after a bitter election in which they repeatedly disparaged each other.




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Transgender student bathroom bill clears Ohio legislature, heads to governor

The Ohio Senate on Wednesday approved a ban on transgender students using bathrooms that fit their gender identities and sent the measure to Republican Gov. Mike DeWine.




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Flexys partners with 10x Banking to accelerate digital transformation

Flexys has announced its partnership with cloud-native core...





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A quasi-annual record of time-transgressive esker formation: implications for ice-sheet reconstruction and subglacial hydrology

Livingstone, S J; Lewington, E L M; Clark, C D; Storrar, R D; Sole, A J; McMartin, I; Dewald, N; Ng, F. The Cryosphere vol. 14, issue 6, 2020 p. 1989-2004, https://doi.org/10.5194/tc-14-1989-2020




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Ancestral trans-North American Bell River system recorded in late Oligocene to early Miocene sediments in the Labrador Sea and Canadian Great Plains

Corradino, J I; Pullen, A; Leier, A L; Barbeau, D L, Jr; Scher, H D; Weislogel, A; Bruner, A; Leckie, D A; Currie, L D. Geological Society of America Bulletin 2021 p. 1-15, https://doi.org/10.1130/B35903.1
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20210427.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20210427.jpg" title="Geological Society of America Bulletin 2021 p. 1-15, https://doi.org/10.1130/B35903.1" height="150" border="1" /></a>