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Deoxygenation of N-heterocyclic N-oxides using isopropanol as a recyclable reductant

Org. Chem. Front., 2024, 11,2249-2268
DOI: 10.1039/D4QO00208C, Research Article
Ho Kyeong Ryu, Yun Do Song, Jun Hee Lee
An organic photoredox-based recyclable strategy that facilitates the chemoselective deoxygenation of various functionalised N-heterocyclic N-oxides is presented.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst

Org. Chem. Front., 2024, 11,2313-2318
DOI: 10.1039/D4QO00116H, Research Article
Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Assembly of ionic supramolecular polymers using a decacationic pillar[5]arene to noncovalently crosslink hyaluronic acid for short DNA delivery

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00447G, Research Article
Qian Li, Danying Ma, Yue-Yang Liu, Hui Wang, Wei Zhou, Dan-Wei Zhang, Zhan-Ting Li
A multicationic pillar[5]arene noncovalently crosslinks hyaluronic acid to afford ionic supramolecular polymers for intramolecular delivery of short DNA.
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Integrating continuous flow reaction and work-up: chiral amine resolution, separation and purification using a novel coalescing filter system

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00442F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bethan May Rowley, Lisa Alice Thompson, Luke Power, James Daglish, Emma Parks, James Birbeck, Stephen P Marsden, Nikil Kapur, John Blacker
To maximize the benefits of a continuous flow reaction, a continuous work-up is also needed. Herein, we present a process design and novel equipment for a continuous amine resolution reaction,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Inference with Gemma using Dataflow and vLLM

vLLM's continuous batching and Dataflow's model manager optimizes LLM serving and simplifies the deployment process, delivering a powerful combination for developers to build high-performance LLM inference pipelines more efficiently.




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Non-equilibrium defect chemistry in oxygen-rich zinc oxide nano-tetrapods synthesized using atmospheric pressure microplasma

J. Mater. Chem. A, 2024, 12,9212-9231
DOI: 10.1039/D3TA06821H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dilli babu Padmanaban, Paul Maguire, Davide Mariotti
We demonstrate the synthesis of zinc oxide (ZnO) nanoscale tetrapods (nTPs) using an atmospheric pressure microplasma with a metal wire as a sacrificial electrode.
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From scrap metal to highly efficient electrodes: harnessing the nanotextured surface of swarf for effective utilisation of Pt and Co for hydrogen production

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00711E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Madasamy Thangamuthu, Emerson C. Kohlrausch, Ming Li, Alistair Speidel, Adam T. Clare, Richard Plummer, Paul Geary, James W. Murray, Andrei N. Khlobystov, Jesum Alves Fernandes
Atomically deposited Pt and Co on nano-grooves result in active and stable electrocatalysts for hydrogen evolution and oxygen evolution reactions.
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Probing the potential of Al2CO/SiC heterostructures for visible light driven photocatalytic water splitting using first-principles strategies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00885E, Paper
Amina Shehbaz, Abdul Majid, Hira Batool, Mohammad Alkhedher, Sajjad Haider, Kamran Alam
Photocatalytic water splitting is a sustainable and eco-friendly method for renewable energy production. The fabrication of an efficient photocatalyst based on two-dimensional (2D) interfaces with suitable band offsets is at...
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Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg1/2Ti1/2)O3–PbTiO3 ferroelectric re-entrant relaxor

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00240G, Paper
Laijun Liu, Kaiyuan Chen, Dawei Wang, Manuel Hinterstein, Anna-Lena Hansen, Michael Knapp, Biaolin Peng, Xianran Xing, Yuanpeng Zhang, Jing Kong, Abhijit Pramanick, Mads Ry Vogel Jørgensen, Frederick Marlton
Local structure information of relaxor ferroelectrics is key to a clear understanding of their structure–property relationships. The size of polar nanoregions is determined based on the local atomic displacement and dielectric response.
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Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Lightweight, elastic and conductive pure PEDOT:PSS foam for dual-mode sensing

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01631A, Paper
Haibin Li, Rubai Luo, Jingbo Hu, Shisheng Zhou, Xing Zhou, Bin Du
Pure PEDOT:PSS foam with a multi-scale porous structure and dual-mode sensing characteristics.
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Insights into the Enhanced Cycling Stability of Cobalt-Free Single-Crystal Layered Oxide Cathodes at Elevated Voltage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA02135E, Paper
Tiancheng Liu, Ke Fan, Changsheng Chen, Mingxia Dong, Yanping Zhu, Gao Chen, Jiangtong Li, Zezhou Lin, Liuqing Li, Ye Zhu, Huangxu Li, Haitao Huang
Co-free single-crystal cathodes Li(NixMn1-x)O2 have been proposed as promising candidates due to remarkable thermal stability and low cost. Unfortunately, insufficient in-depth understanding on the failure mechanisms hinders the development of...
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Enhanced Hydrogen Production by Assisted Biomass Gasification Using Lithium Manganate as Bifunctional Material

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00224E, Paper
Open Access
Carlos Hernández-Fontes, Nan Wang, Nayeli Gómez-Garduño, Heriberto Pfeiffer
The rising energy demand, among other economic and technological factors, increases the greenhouse gas emissions. Therefore, it is crucial to develop technologies to produce clean energy, such as hydrogen (H2)...
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Fluorophore branching boosted photo-induced energy transfer in UiO-66 for ultrasensitive and instant hydrazine sensing

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01549E, Paper
Ying Luo, Da Lei, Maohua Li, Yuansheng Ge, Jiguang Li, Baiyi Zu, Jun Yao, Xincun Dou
Metal organic frameworks (MOFs) have made great progress in the field of fluorescent sensing; however, whether the electronic structure and recognized sites can be adjusted by external functionalization still remains challenging.
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Food prices rising due to failed policies of Modi govt., says Congress

Tomatoes, onions, and potatoes disappearing from common man’s plate, says Jairam Ramesh




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Try to stand on your own legs, Supreme Court tells NCP led by Ajit Pawar to stop using Sharad Pawar’s pictures, videos

The Bench asked the Ajit Pawar camp to circulate an online message among its leaders, party workers and representatives against using the pictures or video/audio clips of Sharad Pawar, whether old or new




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BJP accuses Congress of releasing election manifesto during “silence” period in Jharkhand

Mr. Patra claimed that the Congress wanted to give 4% reservation to the Muslim organisations and contractors in public tenders




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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri




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Rajnath Singh stresses on adaptive defence to cope with Age of Grey Zone, hybrid warfare




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Chemical synthetic approaches to mimic the TRAIL: promising cancer therapeutics

RSC Med. Chem., 2024, 15,3639-3651
DOI: 10.1039/D4MD00183D, Review Article
Abdullah-Al Masum, Shin Aoki, Md. Mahbubur Rahman, Yosuke Hisamatsu
TRAIL induced apoptosis signalling by death receptors (DR4/DR5).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Preventing SARS-CoV-2 infection using Fv-antibodies targeting the proprotein convertase (PPC) cleavage site

RSC Med. Chem., 2024, 15,3704-3710
DOI: 10.1039/D4MD00552J, Research Article
Jaeyong Jung, Jeong Soo Sung, Soonil Kwon, Hyung Eun Bae, Min-Jung Kang, Joachim Jose, Misu Lee, Jae-Chul Pyun
Fv-antibodies targeting the PPC region of SARS-CoV-2 to prevent infection, screened from an Fv-antibody library (displayed on outer membrane of E. coli cell).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stachydrine, a pyrrole alkaloid with promising therapeutic potential against metabolic syndrome and associated organ dysfunction

RSC Med. Chem., 2024, 15,3652-3673
DOI: 10.1039/D4MD00425F, Review Article
Semim Akhtar Ahmed, Prasenjit Manna, Jagat Chandra Borah
Metabolic syndrome is a multifaceted condition marked by interconnected risk factors, significantly increasing the risk of serious diseases like cardiovascular disease, type 2 diabetes, and stroke.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A photoswitchable CENP-E inhibitor with single blue-green light to control chromosome positioning in mitotic cells

RSC Med. Chem., 2024, 15,3795-3799
DOI: 10.1039/D4MD00458B, Research Article
Kazuya Matsuo, Takashi Kikukawa, Tomonori Waku, Akio Kobori, Nobuyuki Tamaoki
A photoswitchable centromere-associated protein E (CENP-E) inhibitor based on the 4-methylaminoazobenzene photoswitch is reported, which is characterized with cistrans photoisomerization with blue-green light and fast thermal relaxation.
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Advances in Detecting Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) Using Molecular Receptors and Nanostructured Assemblies

RSC Med. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4MD00661E, Review Article
Avijit Kumar Das
The detection and quantification of non-steroidal anti-inflammatory drugs (NSAIDs) are crucial due to their widespread use and potential impact on human health and the environment. This review provides a comprehensive...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Arvinder Singh Sahney is new chairman of Indian Oil 




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India’s office leasing soars 41% in 2024 amid rent hikes, supply crunch, and GCC growth: Cushman & Wakefield

In an interview to businessline, Cushman & Wakefield’s Veera talks about commercial space leasing outlook, trends, and rental and supply trends for the coming months




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Three youths go missing after coracle overturns in Sharavathi backwaters in Sagar taluk




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Allison Transmission to double Chennai facility with $100 mn+ investment amid rising global demand

The expansion aims to double the facility’s size, creating 167 new jobs, and enhance production capacity for automatic transmissions in response to growing global demand




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29th IFFK: organising committee formed




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Police arrest man for employing, abusing 11-year-old domestic help in Noida society




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Prioritising mental wellbeing can help in management of diabetes, say doctors




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Arvinder Singh Sahney to be new IndianOil Chairman

Arvinder Singh Sahney, who has around three decades of experience in the oil and gas sector, is currently the Executive Director (Business Development - Petrochemicals) of Indian Oil Corporation




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Kriti, Rashmika Are Obsessing Over...

Celeb-approved nail trends you need to try right now.




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IND vs SA: Ramandeep Singh achieves THIS feat on T20I debut, joins Suryakumar Yadav in elite list

India's rising star, Ramandeep Singh, received his cap from senior all-rounder Hardik Pandya just before the toss at SuperSport Park.




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Orthodox Evangelism and Using Media

Fr. Barnabas opens the lines tonight to talk about the use of media to spread the Orthodox Faith. Is it "anything goes?" or or there pitfalls?




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Revolut launches debit card vending machine in Singapore

UK-based fintech company Revolut has introduced a debit...




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CROSSING OVER LIMITED EDITION PRINT

CROSSING OVER LIMITED EDITION PRINT by Scott Kennedy is a(n) Limited Edition. The Edition is Limited to Limited to 750 pcs





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Participants of OSCE-supported discussion in Bosnia and Herzegovina called to unite efforts in addressing online content that incites violence

Addressing online content that incites violence was in the focus of a two-day OSCE-supported roundtable discussion that concluded today in Sarajevo, Bosnia and Herzegovina (BiH).




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High-resolution mapping of glacial landscapes in central mainland Nunavut using ArcticDEM data and Landsat 8 imagery

McMartin, I; Godbout, P -M; Campbell, J E; Tremblay, T; Behnia, P. 2020 NWT and Nunavut Geoscience Forum, presentations; 2020 p. 1, 1 sheet




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Analyzing spatial patterns of thermal alteration in the Stikine and Wrangell terranes of the Canadian Cordillera using the conodont color alteration index (CAI) to identify hot spots and cold spots

Lei, J Z X; Golding, M L; Husson, J M. Geological Survey of Canada, Open File 8746, 2020, 43 pages, https://doi.org/10.4095/327243
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_327243.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_327243.jpg" title="Geological Survey of Canada, Open File 8746, 2020, 43 pages, https://doi.org/10.4095/327243" height="150" border="1" /></a>




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High-resolution mapping of glacial landscapes in central mainland Nunavut using ArcticDEM data and Landsat 8 imagery

McMartin, I; Godbout, P -M; Campbell, J E; Tremblay, T; Behnia, P. GSA 2020 Connects Online - Geological Society of America Annual Meeting; Geological Society of America, Abstracts With Programs vol. 52, no. 6, 129-3, 2020 p. 1, https://doi.org/10.1130/abs/2020AM-354703
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200344.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200344.jpg" title="GSA 2020 Connects Online - Geological Society of America Annual Meeting; Geological Society of America, Abstracts With Programs vol. 52, no. 6, 129-3, 2020 p. 1, https://doi.org/10.1130/abs/2020AM-354703" height="150" border="1" /></a>




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Kimberlite indicator-mineral studies on Banks Island, Northwest Territories: assessing the potential for diamond-bearing kimberlite

Smith, I R. Geological Survey of Canada, Open File 8726, 2020, 45 pages, https://doi.org/10.4095/326157
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_326157.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_326157.jpg" title="Geological Survey of Canada, Open File 8726, 2020, 45 pages, https://doi.org/10.4095/326157" height="150" border="1" /></a>




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A multikinetic approach to apatite fission-track thermal modelling using elemental data: data and model results for a Permian and Devonian sample from northern Yukon

Issler, D R; McDannell, K T; Lane, L S; O'Sullivan, P B; Neill, O K. Geological Survey of Canada, Open File 8821, 2021, 158 pages, https://doi.org/10.4095/328844
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_328844.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_328844.jpg" title="Geological Survey of Canada, Open File 8821, 2021, 158 pages, https://doi.org/10.4095/328844" height="150" border="1" /></a>




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Evaluation and optimization of acid processing procedures for the extraction of conodont elements from calcareous rock

Gallotta, C; Gouwy, S A; Komaromi, L. Geological Survey of Canada, Open File 8792, 2021, 50 pages, https://doi.org/10.4095/328273
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_328273.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_328273.jpg" title="Geological Survey of Canada, Open File 8792, 2021, 50 pages, https://doi.org/10.4095/328273" height="150" border="1" /></a>




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Simulating sedimentary burial cycles: I. investigating the role of apatite fission track annealing kinetics using synthetic data

McDannell, K T; Issler, D R. Geochronology vol. 3, 2021 p. 321-335, https://doi.org/10.5194/gchron-3-321-2021
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200758.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200758.jpg" title="Geochronology vol. 3, 2021 p. 321-335, https://doi.org/10.5194/gchron-3-321-2021" height="150" border="1" /></a>




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Regional subglacial quarrying and abrasion belowhard-bedded palaeo-ice streams crossing the Shield-Palaeozoic boundary of central Canada: the importance of substrate control

Bukhari, S; Eyles, N; Sookhan, S; Mulligan, R; Paulen, R; Krabbendam, M; Putkinen, N. Boreas 2021 p. 1-25, https://doi.org/10.1111/bor.12522
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200742.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200742.jpg" title="Boreas 2021 p. 1-25, https://doi.org/10.1111/bor.12522" height="150" border="1" /></a>




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Assessment of the Amaruq gold deposit signature in glacial sediments using multivariate geochemical data analysis and indicator minerals

de Bronac de Vazelhes, V; McMartin, I; Côté-Mantha, O; Boulianne-Verschelden, N. Journal of Geochemical Exploration vol. 228, 106800, 2021 p. 1-17, https://doi.org/10.1016/j.gexplo.2021.106800
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20200684.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20200684.jpg" title="Journal of Geochemical Exploration vol. 228, 106800, 2021 p. 1-17, https://doi.org/10.1016/j.gexplo.2021.106800" height="150" border="1" /></a>




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High-resolution mapping of glacial landscapes in central mainland Nunavut using ArcticDEM data and Landsat 8 imagery

McMartin, I; Godbout, P -M; Campbell, J E; Tremblay, T; Behnia, P. Geological Survey of Canada, Scientific Presentation 121, 2021, 1 sheet, https://doi.org/10.4095/327853
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/gid_327853.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/gid_327853.jpg" title="Geological Survey of Canada, Scientific Presentation 121, 2021, 1 sheet, https://doi.org/10.4095/327853" height="150" border="1" /></a>




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Overpressure detection in the Beaufort-Mackenzie Basin, northern Canada, using an integrated approach

Hu, K; Issler, D R; Chen, Z; Dietrich, J R; Dixon, J. GeoConvention 2022, abstracts; 2022, 1 sheet
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20220002.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20220002.jpg" title="GeoConvention 2022, abstracts; 2022, 1 sheet" height="150" border="1" /></a>