salt Saltlake: স্কুল থেকে আর বাড়ি ফেরা হল না... সল্টলেকে বেপরোয়া বাসের রেষারেষিতে মৃত্যু একরত্তির! By Published On :: Tue, 12 Nov 2024 15:28:37 +0530 পড়ুয়াদেরকে নিয়ে বাড়ি ফিরছিলেন অভিভাবক। দুটি বাস রেষারেষি করতে গিয়ে স্কুটিকে ধাক্কা মারে। Full Article
salt Saltlake | Mamata Banerjee: বেপরোয়া বাসের ধাক্কায় মৃত্যু শিশুর! ক্ষুব্ধ মমতা, কড়া ব্যবস্থার পথে... By Published On :: Tue, 12 Nov 2024 17:09:07 +0530 Mamata Banerjee on saltlake incident: মর্মান্তিক পথ দুর্ঘটনায় মৃত্যু স্কুলপড়ুয়ার। সল্টলেকে ২ নম্বর গেটের সামনে দুর্ঘটনা। ঘটনার পর রীতিমত ধুন্ধুমার পরিস্থিতির সৃষ্টি হয়। এই দুর্ঘটনা নিয়ে ক্ষুব্ধ মুখ্যমন্ত্রী মমতা বন্দ্যোপাধ্যায়। পরিবহন মন্ত্রীকে ডাকার নির্দেশ মমতার। মুখ্যমন্ত্রী জানিয়েছেন, তিনি সব পক্ষকে নিয়ে বৈঠকে বসবেন। Full Article
salt Heterogeneous Li coordination in solvent-in-salt electrolytes enables high Li transference numbers By pubs.rsc.org Published On :: Faraday Discuss., 2024, 253,343-364DOI: 10.1039/D4FD00012A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anne Hockmann, Florian Ackermann, Diddo Diddens, Isidora Cekic-Laskovic, Monika SchönhoffUnusually high Li transference numbers (t+ > 0.7) in a bisolvent-in-salt electrolyte are explained by a heterogeneous Li solvation structure, which yields two distinctly different Li species with different transport behavior.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Speciation of the proton in water-in-salt electrolytes By pubs.rsc.org Published On :: Faraday Discuss., 2024, 253,478-492DOI: 10.1039/D4FD00027G, PaperKateryna Goloviznina, Alessandra Serva, Mathieu SalanneIn 21 m LiTFSI water-in-salt electrolyte, the proton forms species existing in bulk water (H3O+, H5O2+, etc.) as well as the HTFSI acid, known to be a superacid in water.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Electric field induced associations in the double layer of salt-in-ionic-liquid electrolytes By pubs.rsc.org Published On :: Faraday Discuss., 2024, 253,365-384DOI: 10.1039/D4FD00021H, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Daniel M. Markiewitz, Zachary A. H. Goodwin, Michael McEldrew, J. Pedro de Souza, Xuhui Zhang, Rosa M. Espinosa-Marzal, Martin Z. BazantWe have developed a theory for the electrical double layer of salt-in-ionic liquids accounting for the thermoreversible association of ions into Cayley tree aggregates. We find that the solution becomes more aggregated at moderate positive voltages.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Go home? : The politics of immigration controversies [Electronic book] / Hannah Jones, Yasmin Gunaratnam, Gargi Bhattacharyya, Roiyah Saltus, Sukhwant Dhaliwal, Kirsten Forkert, Emma Jackson, William Davies. By encore.st-andrews.ac.uk Published On :: Manchester : Manchester University Press, [2017] Full Article
salt Al-alkyl borate salt cocatalysts for olefin polymerization: exploration of N-donor ligand variations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,7872-7885DOI: 10.1039/D4QI01874E, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo BusicoThe stability and reactivity of {[iBu2(L)Al]2(μ-H)}+[B(C6F5)4]− (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Unveiling the dynamic CO2 capture performance of MgO promoted with molten salts and CaCO3 via fixed bed reactor experiments By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Advance ArticleDOI: 10.1039/D4RE00432A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Theodoros Papalas, Andy N. Antzaras, Angeliki A. LemonidouMgO promoted with molten alkali salts and CaCO3 displayed efficient CO2 capture activity in a fixed bed reactor, attaining 75% CO2 removal at 275 °C and stable cyclic performance, with the promoters providing an alternative carbonation mechanism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Strong, tough and conductive single-network hydrogels based on deswelling and the salting-out effect By pubs.rsc.org Published On :: Soft Matter, 2024, Advance ArticleDOI: 10.1039/D4SM00298A, PaperXingyue Sun, Haiyi Liang, Lina YeBy comparing the mechanical properties between salt-treated hydrogels and air-dried hydrogels, the synergistic effect in energy transfer and dissipation arising from increases in polymer fraction and cross-linking plays an indispensable role in toughening SN hydrogels.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Preparation of N-MG-modified PVDF-CTFE substrate composite nanofiltration membrane and its selective separation of salt and dye By pubs.rsc.org Published On :: RSC Adv., 2024, 14,11992-12008DOI: 10.1039/D4RA00359D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinyu Pan, Jian Pan, Zhuoqun Li, Wenqiang Gai, Guangshun Dong, Min Huang, Lilan HuangN-Methylglucamine (N-MG) was introduced to poly(vinylidene fluoride-co-chlorotrifluoroethylene) (PVDF-CTFE) porous substrate membrane to enhance its hydrophilicity and permeability, leading to the preparation of a composite NF membrane with selective separation performance for many dyes and salts.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Designing a novel paper-based microfluidic disc for rapid and simultaneous determination of multiple nutrient salts in water By pubs.rsc.org Published On :: Analyst, 2024, 149,5563-5571DOI: 10.1039/D4AN01127A, PaperZhentao Sun, Youquan Zhao, Yameng Liu, Chen Chen, Hao ChenA paper-based microfluidic disc is used for the rapid determination of various nutrients in water.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Molten salt synthesized Tb3+, Pr3+ or Dy3+ single doped CaTa4O11 with persistent luminescence By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, Accepted ManuscriptDOI: 10.1039/D4CP03989K, PaperYuhan Fan, Yongze Cao, Meiling Li, Sai Xu, Yichao Wang, Xizhen Zhang, Jinsu Zhang, B. J. ChenA series of Tb3+, Pr3+ and Dy3+ monodoped CaTa4O11(CTO) persistent luminescence (PersL) phosphors have been successfully synthesized by molten salt method with KCl flux. The PersL color is green and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation By pubs.rsc.org Published On :: Chem. Commun., 2024, Advance ArticleDOI: 10.1039/D4CC04764H, CommunicationPriyasha Harsha, Dinabandhu DasTwo-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Li2NbHO2: a new transition-metal oxyhydride with rock-salt-type structure By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC05503A, CommunicationF Takeiri, Keiko KUSUMOTO, Kosuke Kawai, Hiroshi Yaguchi, Takashi Saito, Kazuhiro Mori, Saburo Hosokawa, Masashi Okubo, Genki KobayashiTransition-metal oxyhydrides are an emerging class of functional materials; however, the known compounds have mostly been limited to perovskite-type structures. Here, we successfully synthesized Li2NbHO2, the first example of a...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Salt baked fish at its heart By www.thehindu.com Published On :: Thu, 17 Nov 2016 22:26:12 +0530 The Drawing Room charms with fancy seafood set to Bohemian décor Full Article Metroplus
salt A zwitterionic salt–cocrystal: in vitro insights from niraparib tosylate, an anti-cancer drug By pubs.rsc.org Published On :: CrystEngComm, 2024, Advance ArticleDOI: 10.1039/D4CE00114A, PaperRamesh Reddy Mudda, Ramesh Devarapalli, Arijit Das, Pulla Reddy Lakkireddy, C. Malla Reddy, Ramanaiah ChennuruSchematic representation showing nomenclature of different cocrystals.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Rock-salt Ti1−xO → rutile TiO2−x transformation twinning via pulsed laser deposition – implications for the dense (hkl)-specific phase change and optoelectronic properties By pubs.rsc.org Published On :: CrystEngComm, 2024, 26,1926-1939DOI: 10.1039/D3CE01091K, PaperChang-Ning Huang, Jian-Yu Chen, Yu-Xuan Lin, Pouyan ShenThe R + r intimate intergrowth was found to form a butterfly twin following the optimum crystallographic orientation relationship [101]R//[11̄]r by the close-packed (̄11)R and (011)r planes as the twin boundary and phase interface, respectively.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Introduction of new guest molecules into BEDT-TTF radical-cation salts with tris(oxalato)ferrate By pubs.rsc.org Published On :: CrystEngComm, 2024, 26,1962-1975DOI: 10.1039/D4CE00099D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Toby J. Blundell, Elizabeth K. Rusbridge, Rebecca E. Pemberton, Michael J. Brannan, Alexander L. Morritt, Joseph O. Ogar, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Lee MartinWe present the crystal structures of five new BEDT-TTF radical-cation salts with tris(oxalato)ferrate anions using solid or liquid additives toluene, phenol, benzaldehyde, 4-bromobenzaldehyde, and kojic acid.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Gefitinib salts/cocrystals with phenolic acids as a promising solid-state approach to improve solubility By pubs.rsc.org Published On :: CrystEngComm, 2024, 26,2112-2122DOI: 10.1039/D4CE00039K, PaperYao Zou, Xin Meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lu, Guanhua DuIn this study, we designed and synthesized a series of gefitinib (GEF) salts and cocrystals with phenolic acids, comprising two salts, one cocrystal, and two salt cocrystals. All these forms exhibited significant improvements in solubility compared to pure GEF.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Synthesis and structural trends in a series of simple tetraalkylphosphonium salts By pubs.rsc.org Published On :: CrystEngComm, 2024, Accepted ManuscriptDOI: 10.1039/D4CE00210E, PaperJakub Gawraczynski, Piotr J Leszczynski, Michal Ksawery Cyranski, Łukasz Dobrzycki, Wiktor Koźmiński, Karol J. Fijalkowski, Wojciech Grochala, Tomasz JarońA series of sulfates (S) and hydrogen sulfates (HS) containing tetramethylphosphonium (TMP), tetraethylphosphonium (TEP) and tetrabutylphosphonium (TBP) cations have been prepared from the respective bromides using ion metathesis reactions. The...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt BODIPY(aryl)iodonium salts in the efficient synthesis of diversely functionalized BODIPYs and selective detection of serum albumin By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00336E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bintu Kumar, Anindita Bhatta, Prakriti Saraf, Taur Prakash Pandurang, Krishnan Rangan, Madhushree Sarkar, Sivaprasad Mitra, Dalip KumarUsing readily available BODIPY and iodoarenes various BODIPY(aryl)iodonium salts were prepared and successfully utilized for the direct syntheses of functionalized BODIPYs, bis-BODIPYs and for the selective detection of serum protein.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Photoinduced decatungstate-catalyzed C(sp3)–H thioetherification by sulfinate salts By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00394B, PaperPengcheng Li, Jia-Lin Tu, Ao-Men Hu, Lin Guo, Chao Yang, Wujiong XiaA visible light photoinduced decatungstate-catalyzed C(sp3)–H thioetherification of hydrocarbons by sodium sulfite is herein reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Synthesis of alkynyl sulfides via base-promoted nucleophilic ring-opening of α-bromostyrene sulfonium salt By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, 22,2953-2957DOI: 10.1039/D4OB00203B, CommunicationJunqi Zhou, Ziyu Wang, Hanmiao Xu, Mengke Su, Jian WenAn effective method for synthesizing various alkynyl sulfides has been developed using tetramethylene sulfoxide as a sulfur source through base-promoted nucleophilic ring-opening reactions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Dissociating high concentration lithium salts in LLZTO-based high dielectric polymer electrolytes for low temperature Li metal batteries By pubs.rsc.org Published On :: Mater. Chem. Front., 2024, 8,3569-3576DOI: 10.1039/D4QM00625A, Research ArticleJiajun Gong, Zhicheng Yao, Qimin Peng, Huizi Tang, Wenhao Han, Shimou ChenA new composite electrolyte, combined with rigid fillers and high dielectric polymers, promotes the dissociation of lithium salts and the construction of multiple Li+ paths, improving Li metal batteries performances at room and low temperatures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Doctor explains why a low-salt diet may not be healthy for everyone By www.newkerala.com Published On :: Sun, 10 Nov 2024 09:10:31 +0530 Full Article
salt Segregative phase separation of strong polyelectrolyte complexes at high salt and high polymer concentrations By pubs.rsc.org Published On :: Soft Matter, 2024, 20,8505-8514DOI: 10.1039/D4SM00994K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Conner H. Chee, Rotem Benharush, Lexi R. Knight, Jennifer E. LaaserComplexes of strong polyelectrolytes prepared well above the binodal are shown to undergo hydrophobicity-driven segregative phase separation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Pyrrolylsulfonium salts: stable, accessible and versatile pseudohalides for Stille couplings By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01793E, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jodie L. Hann, Catherine L. Lyall, Gabriele Kociok-Köhn, Simon E. LewisPyrroles functionalised with a thianthrenium or diphenylsulfonium group undergo Stille couplings with aryl or alkynyl stannanes in good yields, avoiding the issues of instability that can hamper the use of the analogous pyrrolyl halides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01681E, Research ArticleLu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai ZhouTwo different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6573-6588DOI: 10.1039/D4QO01644K, Review ArticleZhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You HuangRecent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt A fluoride gradient, Zn-salt-rich hydrophobic interphase formed by a zincophilic, hydrophobic, anion-philic polymer “skin” for an anode-free solid Zn battery By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE01978D, PaperXinpeng Han, Jinpeng Han, Kang Ma, Jiaqi Wen, Lianpeng Li, Daliang Han, Jie SunA Zn2+·OC group-derived contact ion pair (CIP)/aggregate (AGG)-rich electrolyte is fabricated to generate a fluoride gradient, Zn-salt-rich hydrophobic solid electrolyte interface (SEI) layer with ultrahigh mechanical properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4EE04310C, PaperTengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua ChenBis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Asymmetric evaporation for efficient and simultaneous extraction of freshwater, salt, and electrical energy from seawater By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE04201H, PaperYitian Wu, Chaoliang Ma, Kangxin Zhu, Lizheng Jin, Lvfu Song, Lanze Li, Yingzhuo Lu, Yu Zheng, Yaoxin Zhang, Xin Zheng, Sai Wu, Yajun Pang, Zhehong Shen, Swee Ching Tan, Hao ChenThis study presents an asymmetric evaporation strategy that simultaneously achieves freshwater production, salt collection, and electrical energy generation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Salt Dissociation and Localized High-concentration Solvation by Interface of Fluorinated Gel and Polymer Solid Electrolyte By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4EE04078C, PaperDechao Zhang, Yuxuan Liu, Dedi Li, Shimei Li, Qi Xiong, Zhaodong Huang, Shixun Wang, Hu Hong, Jiaxiong Zhu, Haiming Lyu, Chunyi ZhiLow salt dissociation and unstable [Li(N, N-dimethylformamide (DMF))x]+ solvent structure in poly(vinylidene fluoride) (PVDF)-based solid polymer electrolyte (SPE) remarkably restricts the high throughput ion transport and interfacial stability. Here, we...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Self-assembled porous salt crystals for solar-powered crystallization By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4EE04741A, PaperJie Yu, Lenan Zhang, Jintong Gao, Wenyu Han, Ruzhu Wang, Zhenyuan XuThermally localized solar evaporation has been recognized as an efficient and suitable pathway for desalination and brine treatment. However, the annoying salt crystallization inside the porous evaporator brings challenges for...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Green synthesis of surfactant-free mesoporous silica with strong hydrophilicity via metal salt modifications for moisture adsorption By pubs.rsc.org Published On :: React. Chem. Eng., 2024, 9,816-824DOI: 10.1039/D3RE00513E, PaperPariyawalee Sangteantong, Kunpirom Chainarong, Waleeporn Donphai, Metta ChareonpanichIn this work, the green synthesis of mesoporous silica (MPS) was carried out using low-cost sodium silicate as a precursor.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Who do langurs drink salt water? By www.thehindu.com Published On :: Sat, 02 Nov 2024 21:10:00 +0530 Full Article Sci-Tech
salt Controllable tertiary amine-promoted photoactivation metal-free carbonylation of aryl sulfonium salts to aryl carboxylic acid derivatives By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC04502E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jiajun Zhang, Le-Cheng Wang, Yuanrui Wang, Xiao-Feng WuThis paper describes a new method for the activation of aryl radicals via EDA complexes without metals and photosensitizers for carbonylation with various nucleophilic reagents under visible light.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Ball milling-promoting difunctionalization of alkynyl sulfonium salts with sulfinic acids towards (Z)-1,2-disulfonylethenes By pubs.rsc.org Published On :: Green Chem., 2024, Advance ArticleDOI: 10.1039/D4GC04895D, PaperLi-Hua Yang, Bei Li, Lin Chen, Wen-Shi Yao, Han-Yue Peng, Sha Peng, Long-Yong XieA simple ball milling-mediated disulfonylation of alkynyl sulfonium salts with sulfinic acids for the stereoselective synthesis of various (Z)-1,2-disulfonylethenes has been developed under catalyst-, additive- and solvent-free conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
salt Recipe: Salted Peanut Butter Iced Latte By www.rediff.com Published On :: Tue, 12 Nov 2024 12:39:01 +0530 Give your cold coffee a delicious pep up with peanut butter! Full Article
salt Nancy Workman, Salt Lake County’s first mayor, dies at 79 By www.sltrib.com Published On :: Sun, 10 May 2020 04:55:14 +0000 Full Article
salt The Power of Salt By feedproxy.google.com Published On :: 2014-08-25T14:17:00Z Where the river meets the sea, there is the potential to harness a significant amount of renewable energy, according to a team of mechanical engineers at MIT. Full Article Hydropower Baseload
salt A new guidance is now available to facilitate the ecological risk assessment of organometallic and organic metal salt substances By www.oecd.org Published On :: Mon, 16 Feb 2015 11:30:00 GMT The OECD has published guidance to facilitate the ecological risk assessment of organometallic and organic metal salt substances. A strategy is presented based on key steps that first consider the fate of these substances in the environment, the identification of moieties of concern, and subsequently the selection of an appropriate path forward to either assess the inorganic moiety and/or the individual substance. Full Article
salt Schalke boss David Wagner reveals players will have individual salt and pepper sachets for meals By www.dailymail.co.uk Published On :: Sat, 09 May 2020 17:05:51 GMT The Bundesliga is restarting on May 16 and players will be isolated in hotels before matches. Among the rules for the Bundesligas return are detailed instructions for coaches. Full Article
salt Still can't make salt By indiatogether.org Published On :: Tue, 27 Jan 2009 00:00:00 +0000 Lalit Vachani's latest film places the Mahatma's historic Dandi March in perspective, juxtaposing it against the reality of the depriveations faced by the poor. Shoma Chatterji reviews the film. Full Article
salt Rochelle salt – a structural reinvestigation with improved tools. I. The high-T paraelectric phase at 308 K By journals.iucr.org Published On :: A novel sample cell with control of temperature and relative humidity permitted collection of data of excellent quality, enabling unrestrained refinement of all atomic parameters. One of the K atoms in the structure is disordered; very strong anisotropy in three of the four water O atoms indicates partial static disorder, which does not involve the bonded H atoms. Full Article text
salt Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O By scripts.iucr.org Published On :: 2019-09-06 The title compound, d-(+)-glucosammonium potassium tetrathiocyanatocobaltate(II) dihydrate, K(C6H14NO5)[Co(NCS)4]·2H2O or (GlcNH)(K)[Co(NCS)4]·2H2O, has been obtained as a side product of an incomplete salt metathesis reaction of d-(+)-glucosamine hydrochloride (GlcN·HCl) and K2[Co(NCS)4]. The asymmetric unit contains a d-(+)-glucosammonium cation, a potassium cation, a tetraisothiocyanatocobalt(II) complex anion and two water molecules. The water molecules coordinate to the potassium cation, which is further coordinated via three short K+⋯SCN− contacts involving three [Co(NCS)4]2− complex anions and via three O atoms of two d-(+)-glucosammonium cations, leading to an overall eightfold coordination around the potassium cation. Hydrogen-bonding interactions between the building blocks consolidate the three-dimensional arrangement. Full Article text
salt Structure and Hirshfeld surface analysis of the salt N,N,N-trimethyl-1-(4-vinylphenyl)methanaminium 4-vinylbenzenesulfonate By scripts.iucr.org Published On :: 2019-06-04 In the title compound, the asymmetric unit comprises an N,N,N-trimethyl-1-(4-vinylphenyl)methanaminium cation and a 4-vinylbenzenesulfonate anion, C12H18N+·C8H7O3S−. The salt has a polymerizable vinyl group attached to both the cation and the anion. The methanaminium and vinyl substituents on the benzene ring of the cation subtend angles of 86.6 (3) and 10.5 (9)° to the ring plane, while the anion is planar excluding the sulfonate O atoms. The vinyl substituent on the benzene ring of the cation is disordered over two sites with a refined occupancy ratio of 0.542 (11):0.458 (11). In the crystal, C—H⋯O hydrogen bonds dominate the packing and combine with a C—H⋯π(ring) contact to stack the cations and anions along the a-axis direction. Hirshfeld surface analysis of the salt and of the individual cation and anion components is also reported. Full Article text
salt An unexpected rhenium(IV)–rhenium(VII) salt: [Co(NH3)6]3[ReVIIO4][ReIVF6]4·6H2O By scripts.iucr.org Published On :: 2019-07-12 The title hydrated salt, tris[hexaamminecobalt(III)] tetraoxidorhenate(VII) tetrakis[hexafluoridorhenate(IV)] hexahydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octahedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetrahedral [ReVIIO4]− anions (Re site symmetry 1) and octahedral [ReIVF6]2− anions (Re site symmetries 1and overline{3}). The [ReF6]2− octahedral anions (mean Re—F = 1.834 Å), [Co(NH3)6]3+ octahedral cations (mean Co—N = 1.962 Å), and the [ReO4]− tetrahedral anion (mean Re—O = 1.719 Å) are slightly distorted. A network of N—H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin. Full Article text
salt Crystal structures of an imidazo[1,5-a]pyridinium-based ligand and its (C13H12N3)2[CdI4] hybrid salt By scripts.iucr.org Published On :: 2019-07-19 The monocation product of the oxidative condensation–cyclization between two molecules of pyridine-2-carbaldehyde and one molecule of CH3NH2·HCl in methanol, 2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridinium, was isolated in the presence of metal ions as bis[2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridin-2-ium] tetraiodocadmate, (C13H12N3)2[CdI4], (I), and the mixed chloride/nitrate salt, bis[2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridin-2-ium] 1.5-chloride 0.5-nitrate trihydrate, 2C13H12N3+·1.5Cl−·0.5NO3−·3H2O, (II). Hybrid salt (I) crystallizes in the space group P21/n with two [L]2[CdI4] molecules in the asymmetric unit related by pseudosymmetry. In the crystal of (I), layers of organic cations and of tetrahalometallate anions are stacked parallel to the ab plane. Antiparallel L+ cations disposed in a herring-bone pattern form π-bonded chains through aromatic stacking. In the inorganic layer, adjacent tetrahedral CdI4 units have no connectivity but demonstrate close packing of iodide anions. In the crystal lattice of (II), the cations are arranged in stacks propagating along the a axis; the one-dimensional hydrogen-bonded polymer built of chloride ions and water molecules runs parallel to a column of stacked cations. Full Article text
salt The fumarate salts of the N-isopropyl-N-methyl derivatives of DMT and psilocin By scripts.iucr.org Published On :: 2019-08-16 The solid-state structures of the salts of two substituted tryptamines, namely N-isopropyl-N-methyltryptaminium (MiPT) fumarate {systematic name: [2-(1H-indol-3-yl)ethyl](methyl)propan-2-ylazanium 3-carboxyprop-2-enoate}, C14H21N2+·C4H3O4−, and 4-hydroxy-N-isopropyl-N-methyltryptaminium (4-HO-MiPT) fumarate monohydrate {systematic name: [2-(4-hydroxy-1H-indol-3-yl)ethyl](methyl)propan-2-ylazanium 3-carboxyprop-2-enoate monohydrate}, C14H21N2O+·C4H3O4−·H2O, are reported. Both salts possess a protonated tryptammonium cation and a 3-carboxyacrylate (hydrogen fumarate) anion in the asymmetric unit; the 4-HO-MiPT structure also contains a water molecule of crystallization. Both cations feature disorder of the side chain over two orientations, in a 0.630 (3):0.370 (3) ratio for MiPT and a 0.775 (5):0.225 (5) ratio for 4-HO-MiPT. In both extended structures, N—H⋯O and O—H⋯O hydrogen bonds generate infinite two-dimensional networks. Full Article text