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Bayesian-optimization-based design of highly active and stable Fe–Cu/SSZ-13 catalysts for the selective catalytic reduction of NOx with NH3

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React. Chem. Eng., 2024, 9,3029-3037
DOI: 10.1039/D4RE00327F, Paper
Sanha Lim, Hwangho Lee, Hyun Sub Kim, Jun Seop Shin, Jong Min Lee, Do Heui Kim
Bayesian optimization approach facilitates an efficient optimization of multi-components catalyst for NH3-SCR reaction.
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“25 years of The Netherlands' Catalysis and Chemistry Conference (NCCC)” themed collection – A personal invitation Aromatization of n-alkanes: a mini review on catalysts and reactants

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00384E, Minireview
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hongqi Wang, Raveendran N. Shiju
The catalytic aromatization of n-alkanes is an important process in the chemical industry, especially for the production of valued-added aromatics from the abundant and unreactive small alkanes. This mini review...
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CO2 hydrogenation to light olefins over Fe–Co/K–Al2O3 catalysts prepared via microwave calcination

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00428K, Paper
Nutkamaithorn Polsomboon, Thanapha Numpilai, Kulpavee Jitapunkul, Kajornsak Faungnawakij, Metta Chareonpanich, Xingda An, Le He, Günther Rupprechter, Thongthai Witoon
Microwave calcination optimizes the Fe–C/Fe3O4 ratio to 0.34, enhancing CO2 conversion and light olefin yield.
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Ammonia Decomposition over Low-loading Ruthenium Catalyst Achieved through “Adiabatic” Plasma Reactor

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper
Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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Rice husk valorisation by in situ grown MoS2 nanoflowers: a dual-action catalyst for pollutant dye remediation and microbial decontamination

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RSC Adv., 2024, 14,12192-12203
DOI: 10.1039/D4RA00862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rahul Ranjan, Smruti B. Bhatt, Rohit Rai, Sanju Kumari Sharma, Rishabh Ranjan, Ankit Bharti, Prodyut Dhar
In this study, we carried out valorization of rice husk through in situ growth of MoS2 nanoflowers for simultaneous pollutant dye remediation and microbial decontamination.
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Optimizing methanol synthesis from CO2 using graphene-based heterogeneous photocatalyst under RSM and ANN-driven parametric optimization for achieving better suitability

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RSC Adv., 2024, 14,12496-12512
DOI: 10.1039/D4RA00578C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ramesh Kumar, Jayato Nayak, Somnath Chowdhury, Sashikant Nayak, Shirsendu Banerjee, Bikram Basak, Masoom Raza Siddiqui, Moonis Ali Khan, Rishya Prava Chatterjee, Prashant Kumar Singh, WooJin Chung, Byong-Hun Jeon, Sankha Chakrabortty, Suraj K. Tripathy
Assessment of the performance of linear and nonlinear regression-based methods for estimating in situ catalytic CO2 transformations employing TiO2/Cu coupled with hydrogen exfoliation graphene (HEG) has been investigated.
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Significantly enhanced catalytic performance of Pd nanocatalyst on AlOOH featuring abundant solid surface frustrated Lewis pair for improved hydrogen activation

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RSC Adv., 2024, 14,12593-12599
DOI: 10.1039/D4RA01852D, Paper
Open Access
Junwei Li, Hongshuai Yin, Sisi Liu, Chaofa Xu, Zhixiong Cai
The superior catalytic performance of Pd nanocatalysts in AlOOH-80 is attributed to solid surface frustrated Lewis pairs (ssFLP), which enhance hydrogen gas dissociation, improve Pd nanocatalyst hydrogenation, and result in high catalytic activity of Pd/AlOOH-80.
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Fabrication of MoS2/rGO hybrids as electrocatalyst for water splitting applications

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RSC Adv., 2024, 14,12742-12753
DOI: 10.1039/D4RA00697F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Shahzeb Khan, Tayyaba Noor, Erum Pervaiz, Naseem Iqbal, Neelam Zaman
Environmental degradation and energy constraint are important risks to long-term sustainability in the modern world.
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The untold story of starch as a catalyst for organic reactions

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RSC Adv., 2024, 14,12676-12702
DOI: 10.1039/D4RA00775A, Review Article
Open Access
Masoud Sadeghi
Starch as catalyst for organic reactions.
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The influence of hydrogen bonding on the structure of organic–inorganic hybrid catalysts and its application in the solvent-free epoxidation of α-olefins

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RSC Adv., 2024, 14,12853-12863
DOI: 10.1039/D4RA01399A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hong-Bin Ju, Li-Zhi Zhang, De-Bao Li, Tao Geng, Ya-Jie Jiang, Ya-Kui Wang
Different reaction routes with the influence of hydrogen bonding and without hydrogen bonding.
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An efficient and economical degradation strategy for epoxy thermoset based on low cost transesterification catalyst

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01137F, Paper
Zhijun Yang, Shuhan Zhang, Huan Liang, Enjian He, Yixuan Wang, Ting Lei, Zhicheng Wu, Qiulin Chen, Fusheng Zhou, Yen Wei, Yan Ji
Epoxy thermoset materials are widely used in the field of electrical engineering, including gas-insulated enclosed switches and drytype transformers. It is a challenge to degrade and recycle traditional epoxy thermoset,...
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Axial-phenyl Constrained Bis(imino)acenaphthene-Nickel Precatalysts Enhancing Ethylene Polymerization

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01110D, Paper
Quanchao Wang, Qiuyue Zhang, Yizhou Wang, Song Zou, Yanping Ma, Tongling Liang, Wen Hua Sun
To enhance the performance of the bis(imino)acenaphthene-nickel precatalyst, the axial phenyl group is introduced on the acenaphthenyl backbone forming five analogues, bis(aryl)imino-5-phenylacenaphthene nickel bromides (aryl: 2,6-dimethylphenyl, Ni1; 2,6-diethylphenyl, Ni2; 2,6-diisopropylphenyl,...
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A highly active zinc-based catalyst system for lactide homo- and copolymerization under industrially relevant conditions

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01034E, Paper
Zisheng Zhang, Yi Zhou, Shuang Liu, Baixue Li, Rui Qu, Yanan Gu, Hongyi Suo, Yusheng Qin
A guanidine-based zinc catalyst with a rigid backbone exhibited excellent activity in the ring-opening polymerization and copolymerization of lactide.
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Dibenzobarrelene-Derived Pd-NHCs: Efficient Precatalysts for the Suzuki-Miyaura Polycondensations of Dichloroarenes Monomers

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01026D, Paper
Yuman Guo, Hao Wu, Meng-Jiao Zhang, Feng-Shou Liu
The Pd-catalyzed Suzuki-Miyaura polycondensations (SMPs) has emerged as a powerful method for synthesizing conjugated polymers (CPs). While numerous reports have utilized dibromoarene and diiodoarene derivatives as monomers, research on the...
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Revealing the heterogeneous catalytic kinetics of PtRu nanocatalysts at the single particle level

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Analyst, 2024, 149,5184-5190
DOI: 10.1039/D4AN01017E, Paper
Open Access
Bowei Zhang, Dezheng Zhang, Jinpeng Bao, Ce Han, Ping Song, Weilin Xu
The difference in kinetic information among PtRu bimetallic nanocatalysts, Pt and Ru monometallic nanocatalysts is revealed by the single-molecule fluorescence technique.
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α-MnO2 catalysts with efficient ozone-catalyzed decomposition under high humidity conditions

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Analyst, 2024, Accepted Manuscript
DOI: 10.1039/D4AN01095G, Paper
Jiafan Ji, Qianqian Yan, Yi Chen, Gaosheng Zhao, Bin Jia, Li Xu, Ping Cheng
Ground-level ozone pollution poses significant risks to both ecosystems and human health, necessitating the implementation of effective control strategies. This investigtion concentrated on a monolithic ozone degradation catalyst composed of...
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Strategy for predicting catalytic activity of catalysts with hierarchical nanostructures

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Phys. Chem. Chem. Phys., 2024, 26,27371-27381
DOI: 10.1039/D4CP03102D, Paper
Zidi Zhu, Daoming Huan, Jingchao Yuan, Dan Zhang, Aijun Li, Jiujun Zhang
This study constructs a multiphysics model that successfully replicates experimental results, introducing an improved Thiele modulus to enhance the prediction of catalytic activity in hierarchical nanostructured SOFC electrodes.
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A theoretical investigation on the OER and ORR activity of graphene-based TM–N3 and TM–N2X (X = B, C, O, P) single atom catalysts by density functional theory calculations

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03779K, Paper
Jiaxiang Wu, Erjun Kan, Cheng Zhan
Promising ORR/OER single atom catalysts have been designed in the form of TM–N2X via DFT simulation.
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Unveiling the potential of aluminum-decorated 3D phosphorus graphdiyne as a catalyst for N2O reduction

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Phys. Chem. Chem. Phys., 2024, 26,27677-27683
DOI: 10.1039/D4CP02686A, Paper
Shehzad Ahmed, Adnan Ali Khan, Danish Khan, Awais Ghani, Rashid Ahmad, Tian Xiaoqing, Imran Muhammad
This study reveals the exceptional reactivity and efficiency of 3D-Al/PGDYN catalysts for the reduction of N2O and CO with minimal energy barriers.
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Effects of surface oxygen vacancy on CO2 adsorption and its activation towards C2H4 using metal (Cu, Pd, CuPd) cluster-loaded TiO2 catalysts: A first principles study

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03507K, Paper
Sajjad Hussain, Lina Zhang, Zhengzheng Xie, Jianjun Yang, Qiuye Li
The conversion of the highly selective CO2 reduction reaction (CO2RR) into desired value-added multicarbon compounds, like C2H4, is crucial, but it is mainly constrained by high energy barrier for C-C...
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Advances in morphology-controlled alumina and its supported Pd catalysts: synthesis and applications

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00776F, Review Article
Yanpeng Yang, Chenglin Miao, Ruoyu Wang, Rongxin Zhang, Xiaoyu Li, Jieguang Wang, Xi Wang, Jiannian Yao
This review highlights the preparation and regulation strategies of alumina materials from different dimensions and summarizes the preparation, metal–support interaction, and application of Pd/Al2O3 catalysts on important industrial catalysis.
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The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Sulfonated hierarchical ZSM-5 zeolite monoliths as solid acid catalyst for esterification of oleic acid

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Chem. Commun., 2024, 60,13356-13359
DOI: 10.1039/D4CC05044D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Binhang Zhao, Pan Yang, Nan Zhang, Donald R. Inns, Elena F. Kozhevnikova, Alexandros P. Katsoulidis, Ivan V. Kozhevnikov, Alexander Steiner, Haifei Zhang
Sulfonated hierarchical H-ZSM-5 monoliths were synthesized via ice-templating as solid acid catalysts for biodiesel production.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Copper nanoclusters: emerging photoredox catalysts for organic bond formations

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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Revealing the Influencing Mechanism of CO2 on SCR of NOx with NH3 over FeW Mixed Oxides Catalyst

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01468E, Paper
Hui Wang, Yujie Qiao, Xiang Li, Zhenping Qu
The effect of CO2, another major component of the exhaust gas, on the elimination of NOx over FeW oxides catalyst has been studied. It reveals that the presence of CO2...
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Ni–Co alloys via controlled pyrolysis of NiCo–MOF as heterogeneous hydrogenation catalysts

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00664J, Paper
Lidan Deng, Xingwang Liu, Chong Chen, Lu Wang, Fan Liu, Jie Zhang
The pyrolysis in H2 at lower temperatures can obtain MNP/MOF with more complete MOFs structure and dispersed Ni–Co alloy nanoparticles, which display significantly better activity for the hydrogenation of toluene to methylcyclohexane.
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From byproducts to NLO-active dyes: catalyst-free transfer hydrogenation in the modular synthesis of merocyanines

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00820K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Zou, Yi Pan, Di Zhang, Jie Zhang, Weilong Chen, Hongyan Sun, Kai-Chung Lau, Jingdong Luo
Direct transfer hydrogenation from a strong electron donor to highly polarizable hemicyanines was discovered in the synthesis of push–pull chromophores. The reaction mechanism and experimental results were elucidated using DFT calculations.
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Magnesium(II) complexes supported by indole- and pyrrole-containing Schiff-base ligands: syntheses, structures, and applications as precatalysts in the hydroboration of nitriles and alkynes

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New J. Chem., 2024, 48,7125-7133
DOI: 10.1039/D4NJ00492B, Paper
Mengxiang Wu, Ling Chen, Xiaohan Yang, Yahong Li
Five magnesium compounds were synthesized. They are active precatalysts for the hydroboration of nitriles and alkynes. The catalytic reactions feature mild reaction conditions, excellent functional group tolerance, and high yields.
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Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

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New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
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High proficiency Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst for the actuation of C(OH)–H bond

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New J. Chem., 2024, 48,7430-7438
DOI: 10.1039/D4NJ00395K, Paper
Fereshteh Zolfi, Mahdieh Ghobadifard, Sajjad Mohebbi
Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst was prepared for the actuation of the C(OH)–H bond with a mechanistic point of view.
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Catalytic decomposition of hydrazine nitrate and hydroxylamine nitrate in radioactive nitric acid waste liquid using Ru/AC catalyst

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00916A, Paper
Deyan Yu, Baole Li, Zhi Cao, Qi Chen, Chen Zuo, Tiansheng He, Taihong Yan, Weifang Zheng
The 5 wt% Ru/AC catalysts were prepared using the impregnation method.
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A cubic Sm@CdS Q-dot glass as a photocatalyst for solar H2 generation

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00050A, Paper
Vijay B. Autade, Rajendra P. Panmand, Sandeep A. Arote, Reshma S. Ballal, Sonali D. Naik, Milind V. Kulkarni, Baharat B. Kale
Under natural sunlight, thermally stable cubic Sm@CdS QDs – glass matrix shows increase of 42.5% in the hydrogen evolution with respect to the CdS-glass with a similar heat treatment temperature.
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Constructing a core–shell Pt@MnOx/SiO2 catalyst for benzene catalytic combustion with excellent SO2 resistance: new insights into active sites

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00071D, Paper
Dan Yang, Fang Dong, Jie Wang, Zhicheng Tang, Jiyi Zhang
The construction of a core–shell Pt@MnOx/SiO2 protective structure catalyst can protect the active Pt site well from SO2 toxicity.
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Magnetically recyclable nanophotocatalysts in photocatalysis-involving processes for organic pollutant removal from wastewater: current status and perspectives

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00906H, Critical Review
Open Access
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Zexiao Zheng, Juhua He, Zuyao Zhang, Ashutosh Kumar, Musharib Khan, Cheuk Wai Lung, Irene M. C. Lo
The critical review covers the applications, associated mechanisms, challenges, and prospects of magnetically recyclable nanophotocatalysts in photocatalysis-related processes.
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Critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst systems

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00911D, Paper
Yang Luo, Hong Li, Hailan Yang, Zhiming Yang, Chuang Li, Shaoheng Liu, Qiang Chen, Weihua Xu, Wei Zhang, Xiaofei Tan
The critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst system was studied.
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A novel CuAl2O4/MoS2/BaFe12O19 magnetic photocatalyst simultaneously coupling type I and Z-scheme heterojunctions for the sunlight-driven removal of tetracycline hydrochloride

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00970J, Paper
Mengjun Han, Shifa Wang, Xinmiao Yu, Xianlun Yu, Huajing Gao, Xianju Zhou, Dengfeng Li, Leiming Fang, Jagadeesha Angadi V., Mohd Ubaidullah, Bidhan Pandit
A novel CuAl2O4/MoS2/BaFe12O19 photocatalyst is synthesized that simultaneously couples type I and Z-scheme heterojunctions and exhibits high photocatalytic activity for the degradation of TC under simulated sunlight irradiation.
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Carbon nanotubes as a nanocatalyst and nanoreactor for the efficient treatment of pharmaceutical wastewater via CaSO3 activation

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00026A, Paper
Haoqi Wang, Xiaohong Liu, Yanlan Wang, Yiqun Tian, Yingping Huang, Di Huang, Xiang Liu
Herein, carbon nanotubes (CNTs) are reported as an efficient catalyst and nanoreactor for activating CaSO3 for water decontamination.
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Real-time assessment of the impacts of polystyrene and silver nanoparticles on the hatching process and early-stage development of Artemia using a microfluidic platform

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00116H, Paper
Preyojon Dey, Terence M. Bradley, Alicia Boymelgreen
Development of real-time in situ monitoring techniques is crucial for a mechanistic understanding of the impacts of pollution on the marine environment.
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Facile fabrication of Z-scheme g-C3N5/Gd-MOF/silver nanocubes composite as new generation visible light active photocatalyst for abatement of persistent toxic pollutants

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00913K, Paper
Varsha UshaVipinachandran, Susanta Kumar Bhunia
Some of the persistent hazardous contaminants that readily dissolve in water with a recognizable hue are hexavalent chromium and neomycin antibiotic. Herein, a Z-scheme g-C3N5/Gd-MOF/silver nanocubes (CNGdAg) ternary composite was...
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Interfacial catalytic degradation mechanism of n-hexane over polyhedral Co3O4 nanocatalysts derived from topotactic condensation of ZIF-67

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00101J, Paper
Yunlong Guo, Meicheng Wen, Guiying Li, Jiejing Kong, Shengnan Song, Qiuxia Liu, Taicheng An
A progressive transition from the L–H model to MvK model is observed, where a polyhedral Co3O4 nanocatalyst enabled by topotactic condensation of ZIF-67 is synthesized for catalytic degradation of n-hexane.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

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Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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TiO2−x prepared by radio-frequency thermal plasma: optical switching of hydrophilicity and hydrophobicity used in the efficient recovery of photocatalysts

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Environ. Sci.: Nano, 2024, 11,1693-1700
DOI: 10.1039/D4EN00033A, Paper
Chang Liu, Huacheng Jin, Zongxian Yang, Yuge Ouyang, Fei Ding, Baoqiang Li, Fangli Yuan
A TiO2−x catalyst synthesized using radio-frequency thermal plasma can switch between hydrophilic and hydrophobic properties. Its dispersion and agglomeration can thus be adjusted so that it is dispersed evenly or forms floating balls, which is convenient for recycling.
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Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

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Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
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Selective metal recovery by mucin: turning gold from wastewater into a peroxymonosulfate-activated catalyst

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Environ. Sci.: Nano, 2024, 11,1487-1498
DOI: 10.1039/D3EN00699A, Paper
Open Access
Shira Gavriely, Shachar Richter, Ines Zucker
This study explores mucin's ability to selectively recover gold (Au) from metal wastewater. The Au, in the form of a nanoparticle, was utilized in peroxymonosulfate activation for the degradation of bisphenol A.
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Zeolite-like ion-exchanged Cu-attapulgite catalysts for promoted selective oxidation of ammonia

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00157E, Paper
Xuebin Zhang, Tianwei Lan, Qiuying Yi, Yufei Wang, Danhong Cheng, Dengsong Zhang
Zeolite-like ion-exchanged Cu-attapulgite catalysts have been developed for selective catalytic oxidation of ammonia.
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Enhanced photocatalytic activity of single-atom Au1/TiO2 catalysts prepared using cold plasma

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CrystEngComm, 2024, 26,2103-2111
DOI: 10.1039/D4CE00171K, Paper
Zikun Yang, Jingxuan Zheng, Mengge Shi, Zhao Wang
Single-atom Au1/TiO2-DBD catalysts were synthesised using DBD plasma and glow plasma, and the synergistic effect of single-atom Au and oxygen vacancies improved the degradation performance.
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DMSO promoted catalyst-free oxidative C–N/C–O couplings towards synthesis of imidazoles and oxazoles

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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00383G, Paper
Debasish Bera, Rajib Sarkar, Tiyasa Dhar, Pinaki Saha, Prasanta Ghosh, Chhanda Mukhopadhyay
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C–N coupling and C–O coupling under oxidant-free conditions are outlined.
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