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American tourist, 60, found 'beaten to death' at 5-star hotel in Ireland frequented by celebrities

A 60-year-old American man was found "beaten to death" at Ballyfin Demesne, a luxurious five-star hotel in Ireland. Police said a suspect is in custody.



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Six Israeli soldiers killed, six killed by Israeli jets in Lebanon







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Chris Cuomo stuns podcast host by revealing who he voted for – and it wasn’t Trump or Harris

Ex-CNN host shared that rather than choosing between Kamala Harris or Donald Trump, he wrote in an alternative candidate on his ballot




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In Lebanon, residents fear Hezbollah could be hiding among people displaced by war

A neighborhood watch group in a Christian Beirut neighborhood is on the lookout for militant operatives, which could make the area a target for Israeli airstrikes.




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The USS Edsall, sunk by Japanese forces in World War II, has been found

The USS Edsall was overpowered by a Japanese fleet in the Indian Ocean but fought valiantly to the end, the U.S. Navy said. It was found in deep waters south of Australia's Christmas Island.




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King Charles celebrates 76th birthday by opening food hubs

LONDON — UK's King Charles will celebrate his 76th birthday on Thursday (Nov 14) by opening two food distribution hubs which are part of his project designed to cut waste and support charities that help those who are hungry. Last year, the king, an outspoken campaigner on environmental issues and supporter of a sustainable economy, launched the 'Coronation Food Project', his mission to 'bridge the gap between food waste and food need'. On Thursday, the monarch will open the initiative's first two food hubs — distribution centres which are designed to save and circulate tonnes of surplus food. He will visit one of the hubs in south London which will host a 'surplus food festival' making meals created from food which would have gone to waste, as well as virtually opening the other site in northern England. Their aim is to make it easier for food charities such as FareShare and the Felix Project to provide support for those in need, Buckingham palace said. It said since the launch of the scheme, the project had helped save an additional 940 tonnes of surplus food which was to the equivalent of more than 2.2 million meal portions.




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Using phone? Jaywalker hit and sent flying by taxi in Orchard

A woman was sent flying after she was hit by a car on Wednesday (Nov 13) morning. The incident occurred at the junction of Orchard Road and Handy Road. In a video posted to the SG Kaypoh Facebook group, the woman is seen crossing the road while the traffic light was not in her favour.   She appears to be looking down at her phone. The driver involved in the accident did not notice her till it was too late and collided with her head-on. In the video, the woman is sent flying and lands several metres in front of the car upon impact. She manages to sit up after landing, and looks stunned from the impact.   The driver and his passenger also rush out of the vehicle to assist.  Speaking to AsiaOne, the Singapore Civil Defence Force said that the female pedestrian was conveyed conscious to Tan Tock Seng Hospital. When contacted, the police said they were alerted to an accident involving a taxi and a pedestrian at the junction of Orchard Road and Handy Road on Nov 13 at about 3.15am.





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Bandai Namco Filmworks Releases 2nd Aura Battler Dunbine 'Experimental Video' With New Theme Song by MindaRyn

MindaRyn performs "Remaining Story" theme song, specifically written for video





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Presidents Roasting By An Open Fire

President-elect Trump meets President Biden in the Oval Office.




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Baby red panda died from firework stress, says zoo

Three-month-old Roxie choked on her own vomit as fireworks were being set off across Edinburgh on Bonfire Night.




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Baby milk prices 'punish those who don't breastfeed'

Parents say they feel penalised by the high cost of formula, which cannot be discounted under the law.




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KE Hotels Expands UK Portfolio With Management of Three Hampton by Hilton Hotels

KE Hotels is pleased to announce the expansion of its UK portfolio with the addition of three Hampton by Hilton hotels under new Hotel Management Agreements (HMA) as of October 2024. The properties now under KE Hotels’ management are Hampton by Hilton Newcastle, Hampton by Hilton Birmingham Broad Street, and Hampton by Hilton Sheffield.




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Tharaldson Hospitality Management Celebrates Opening of Hampton Inn & Suites by Hilton Porter Ranch Los Angeles

Tharaldson Hospitality Management proudly announces the grand opening of their 88th hotel, the Hampton Inn & Suites by Hilton Porter Ranch Los Angeles. This milestone marks another significant achievement in THM’s continued expansion and commitment to delivering exceptional hospitality experiences. Located in the vibrant and rapidly growing area of Porter Ranch, CA, the new Hampton Inn & Suites by Hilton boasts 100 modern and beautifully designed guest rooms, providing visitors with the perfect blend of comfort and convenience. Guests can enjoy premium amenities, including complimentary breakfast, free Wi-Fi, a state-of-the-art fitness center, and a refreshing outdoor pool. The opening of this new hotel comes thanks to the hard work and dedication of the entire THM team, who have worked tirelessly to ensure a seamless and successful launch. THM extends sincere gratitude to every team member for their unwavering commitment and efforts. The Hampton Inn & Suites by Hilton Porter Ranch Lo...




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San Diego’s Revered CH Projects to Open Second Hotel, Baby Grand, in Coronado in Winter 2025

Acclaimed San Diego hospitality group CH Projects today announces its second hotel, Baby Grand, opening in early 2025. Situated across from the iconic Hotel Del Coronado in the town center on Orange Avenue, the hotel will be the first design hotel of its kind in two decades in the popular Southern California destination. The $17 million project by award-winning Brooklyn design firm Post Company will feature 31 keys and three new restaurant concepts. The design will thematically reference the area’s coastal setting paired with CH Projects’ signature maximalism, striving to progress the social landscape of San Diego’s distinctive neighborhoods and cultures. CH Projects is behind some of the city’s most acclaimed restaurant and bar destinations, including Morning Glory, Youngblood, Born & Raised and more, as well as the trailblazing Lafayette Hotel and Club, the team’s first hotel project in North Park. "Coronado is such a unique element of San Diego’s layered persona. We wanted to creat...




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Radisson Hotel Group opens Kuwait’s first Park Inn by Radisson Hotel

Radisson Hotel Group is pleased to announce the opening of its second hotel in Kuwait - Park Inn by Radisson Hotel & Apartments Kuwait. The new hotel is located in the bustling Mahboula district, just south of Kuwait City, and offers easy access to key locations, including the Warehouse Mall and Kuwait Towers. The hotel is conveniently situated 30 minutes from Kuwait International Airport, with the famous Al Kout Mall only a 10-minute drive away. Kuwait has a dynamic blend of rich history and modern development, offering visitors a unique cultural experience. From the traditional charm of Souq Al-Mubarakiya to the architectural marvel of Kuwait Towers, the city effortlessly merges its heritage with contemporary advancements. Visitors can explore the vibrant cityscape, indulge in world-class shopping at The Avenues Mall, or experience the tranquility of the Arabian Gulf coastline. The country’s strategic location at the crossroads of global business makes it a key destination for corpo...




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K'taka bypolls: 26.33 pc voting till 11 A.M. on three Assembly seats

The voting for the bye-elections held for three Assembly constituencies in Karnataka on Wednesday is witnessing a good turnout as 26.33 per cent of voting was recorded till 11 A.M.




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Bengal bypolls: Trinamool leader injured in shootout dies in hospital

The first casualty in the bypolls for six Assembly constituencies in West Bengal has been reported, as a Trinamool Congress leader who was severely injured in a shootout at Jagatdal adjacent to Naihati Assembly constituency in North 24 Parganas district, died on Wednesday.




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K'taka bypolls: EC reports good turnout on three Assembly seats

The bye-elections held for three Assembly constituencies in Karnataka on Wednesday witnessed a good turnout as 45.02 per cent of voting was reported by the Election Commission of India.




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Karnataka by-polls: Congress will win all three seats, claims CM Siddaramaiah

Karnataka Chief Minister Siddaramaiah on Wednesday expressed confidence that Congress party would win by-elections in all three constituencies of the state.




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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report

India accounts for per cent of the global total carbon dioxide (CO2) emissions, and it is expected to increase by 4.6 per cent in 2024, according to a new report released on Wednesday, ahead of the UN climate conference in Baku, Azerbaijan.




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'Mahavatar' first look: Vicky Kaushal as Parashurama takes Bollywood by storm; fans in awe

Vicky was last seen in Bad Newz. He will now be seen in Chhava. The film, another Dinesh Vijan production, will see Vicky play the role of Chhatrapati Sambhaji. He will then be seen in Love and War alongside Ranbir Kapoor.







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Jharkhand Phase-I Assembly poll records over 65% turnout; Wayanad bypoll 64.72% - The Hindu

  1. Jharkhand Phase-I Assembly poll records over 65% turnout; Wayanad bypoll 64.72%  The Hindu
  2. Watch: MS Dhoni casts his vote in Ranchi for Jharkhand Assembly Elections  The Times of India
  3. First phase of polling ends in Jharkhand with 64.86% turnout of voters  The Hindu
  4. Situation in West Asia matter of deep concern: Jaishankar  The Economic Times
  5. Jharkhand Assembly elections: High voter turnout recorded in Maoist-hit pockets  Telegraph India




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She Became CEO of Her Whole Company By Raising Her Hand and Saying This

Nobody cares what you want unless you speak up to tell them. That's how Tracy Panase became CEO of Just Between Friends.




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Wayanad Chelakkara Byelection 2024: ചേലക്കരയിൽ പോളിം​ഗ് ശതമാനത്തിൽ റെക്കോഡ് വർധനവ്; വയനാട്ടിൽ പോളിങ് കുത്തനെ ഇടിഞ്ഞു

തെരഞ്ഞെടുപ്പ് കമ്മീഷന്‍റെ അന്തിമ കണക്ക് പ്രകാരം വയനാട്ടിൽ 64.53 ആണ് പോളിങ് ശതമാനം.  




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Actor John Krasinski named 'Sexiest Man Alive 2024' by People magazine

Krasinski's win adds him to an esteemed group of past honourees like George Clooney, Brad Pitt, Idris Elba, and Michael B. Jordan.




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Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00228H, Research Article
Ekaterina V. Malakhova, Vladislav S. Kostromitin, Vitalij V. Levin, Alexander D. Dilman
Commodity chemicals are used as alkylating and reducing agents for radical addition to alkenes. The method is based on activation of the strong C–Cl bond by the radical anion of carbon dioxide.
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Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00421C, Research Article
Carina Mützel, Kazutaka Shoyama, Ana-Maria Krause, Frank Würthner
A doubly helical boron-doped polycyclic aromatic hydrocarbon was synthesized, which showed a low LUMO level, a high absorption coefficient and fluorescence (ΦF = 0.73), combined with a one-dimensional π–π stacking interaction in the solid state.
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Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00002A, Research Article
Shu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong Liu
A chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.
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Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00305E, Research Article
Chen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong Ma
Herein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.
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Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00311J, Research Article
Pei-Ting Li, Zi-Fa Shi, Wei Yu
Two triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.
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Nickel metallaphotoredox-catalyzed C–O bond activation/Csp2–Csp3 coupling enabled by phosphine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00310A, Research Article
Jiaxi Fang, Ziheng Jian, Huan Liu, Yuting Wang, Xianbo Yu, Zehuai Mou, Huifei Wang
A novel and general nickel/photoredox dual catalysis platform for benzyl alcohol C–O bond activation/Csp2–Csp3 cross coupling of benzothiazolyl bromide and free alcohol, enabled by the catalytic generation of an alkyl radical, is reported.
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Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis

Org. Chem. Front., 2024, 11,2344-2350
DOI: 10.1039/D3QO01955A, Research Article
Linge Huai, Li Zhang, Zhentao Wang, Yewen Fang
N → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.
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Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis

Org. Chem. Front., 2024, 11,2171-2177
DOI: 10.1039/D3QO02029K, Research Article
Rong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo Han
An asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.
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Advancement in the C–H bond alkylation of (hetero)arenes catalyzed by the most abundant transition metal–iron

Org. Chem. Front., 2024, 11,2397-2417
DOI: 10.1039/D4QO00063C, Review Article
Chandini Pradhan, Benudhar Punji
Advancement in the direct C–H bond alkylation of arenes and heteroarenes using the catalysts based on the most abundant transition metal, iron, is summarized.
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Efficient Synthesis of Benzophosphole Oxides by Ag-Promoted Radical Cycloisomerization

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00552J, Research Article
Open Access
Liyao Ma, Sonia Mallet-Ladeira, Julien MONOT, Blanca Maria MARTIN VACA, Didier Bourissou
Cycloisomerization reactions involving C–P bond formation have been overlooked to prepare P-heterocycles. We discovered here a simple, efficient and versatile route to benzophosphole oxides by reacting ortho-alkynyl secondary phosphine oxides...
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NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00347K, Research Article
Zhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping Hui
A novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...
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Palladium-catalyzed and ligand-controlled divergent cycloadditions of vinylidenecyclopropane-diesters with para-quinone methides enabled by zwitterionic π-propargyl palladium species

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00368C, Research Article
Jia-Hao Shen, Yong-Jie Long, Min Shi, Yin Wei
A palladium-catalyzed and ligand-controlled divergent synthesis of spiro-cyclohexadienones from p-quinone methides and VDCP-diesters was realized via zwitterionic π-propargyl palladium species and the mechanism was clarified by DFT calculations.
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Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00412D, Research Article
Chengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling Song
A deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.
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Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00481G, Research Article
Jia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin Liao
Three typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.
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Wayanad bypoll turns out to be a reunion for landslides survivors

Their tearful reunion touches many, as they witness the heartbreak of lost connections. We celebrated the previous election, but many who participated then are no longer with us, says a survivor. District administration designated three polling stations for the survivors, two at Neelicappu and one at Meppadi




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Chelakkara records 72.77% turnout in bypoll




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PDA will defeat BJP in bypolls, says Akhilesh

Welcoming the Supreme Court’s direction on bulldozer ‘justice’, the SP chief says from now onwards, the bulldozer will remain parked in garage forever