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Theoretical Insights into the Vibrational Spectra and Chemical Bonding of Ln(III) Complexes with a Tripodal N4O3 Ligand Along the Lanthanide Series

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03677H, Paper
Francielle C Machado, Mateus M Quintano, Carlos Vital dos Santos Junior, Albano Carneiro Neto, Elfi Kraka, Ricardo Luiz Longo, Renaldo Tenorio Moura Jr.
{This study provides new theoretical insights into the vibrational spectra of Ln(III) complexes, along the lanthanide series by utilizing the LModeAGen protocol and integrating cutting-edge topological ideas. It provides a...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Intermolecular Hydrogen Bonding Delineates Stability of Non-canonical Adenine Base Pairs: A First-Principles Study

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP02875A, Paper
Nicholas Adu-Effah, Nabanita Saikia
Non-canonical nucleobase pairs differ from canonical Watson-Crick (WC) pairs in their hydrogen bonding patterns. This study uses density functional theory with empirical dispersion correction to examine the stability and electronic...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective C(aryl)–O bond cleavage in biorenewable phenolics

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00570D, Review Article
Gilles De Smet, Xingfeng Bai, Bert U. W. Maes
Selective removal of the hydroxy, methoxy or both groups in biorenewable oxygenated arenes (derived from lignin depolymerization) provides, respectively, anisoles, phenols and benzenes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Peptide hydrogen-bonded organic frameworks

Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review
Open Access
Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bond investment 101: Create a login ID

Higher interest. Bond investment platforms buzz with users drawn by the user-friendly interface, zero cost, jargon-free guidance




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Ti3C2Tx MXene bonded perylene diimide as a robust charge host for seawater electrolytes

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05059B, Communication
Sreelakshmi P., Soujanya H. Goudar, Soumyaranjan Behera, Kotagiri Venkata Rao, Ambika S., Narendra Kurra
MXene bonded perylene diimide redox electrode as a robust host for seawater electrolytes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mn and Mo co-doped NiS nanosheets induce abundant Ni3+–O bonds for efficient electro-oxidation of biomass

Chem. Commun., 2024, 60,13392-13395
DOI: 10.1039/D4CC04818K, Communication
Pengfei Ren, Zixuan Wang, Wenchao Zhang, Fang Duan, Shuanglong Lu, Mingliang Du, Han Zhu
MnMo–NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 μmol h−1 cm−2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rapid identification of P–C bonds in phosphorus–carbon anode materials

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03317E, Communication
Yadong Ye, Qiang Xiao, Huanyu Xie, Hongchang Jin, Hengxing Ji
This work presents a simple, rapid, and convenient spectroscopic analysis method for characterizing the bonding state in phosphorus-carbon composites.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Copper nanoclusters: emerging photoredox catalysts for organic bond formations

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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Construction of amide-bonded supramolecular multifunctional fillers towards boosted self-healing, thermal conductivity and dielectric properties

Mol. Syst. Des. Eng., 2024, 9,1167-1178
DOI: 10.1039/D4ME00114A, Paper
Junlong Yao, Zongqiang Fu, Huan Yang, Lin Gao, Xueliang Jiang, Wei Nie, Zhengguang Sun, Haolan Lu, Meiyun Lin, Jinglou Xu
The two modified fillers effectively improved the self-healing efficiency, dielectric properties and thermal conductivity of the supramolecular composites by forming a synergistic effect of amide bonds.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Elucidating the interplay between entropy-driven and patch-mediated bonding in directing nanoscale assemblies

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00153B, Paper
Kireeti Akkunuri, Xiangyu Zhang, Thi Vo
The interplay between directional patchy attraction and shape-driven entropic forces sculpts the spatial and orientational orderings between anisotropic building blocks, giving rise to symmetry breaking of pre-programmed interactions between particles.
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Hydrogen-bonded organic frameworks with extended conjugate systems for boosted photocatalytic degradation

New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper
Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
The content of this RSS Feed (c) The Royal Society of Chemistry




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High proficiency Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst for the actuation of C(OH)–H bond

New J. Chem., 2024, 48,7430-7438
DOI: 10.1039/D4NJ00395K, Paper
Fereshteh Zolfi, Mahdieh Ghobadifard, Sajjad Mohebbi
Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst was prepared for the actuation of the C(OH)–H bond with a mechanistic point of view.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Incisive analysis of hydrogen-bonded supramolecular architectures in designer polycyclitols: observation of some interesting self-assembly patterns

CrystEngComm, 2024, 26,1952-1961
DOI: 10.1039/D4CE00010B, Paper
Showkat Rashid, Ahmad Husain, Bilal A. Bhat, Goverdhan Mehta
This article examines C–H⋯O and O–H⋯O hydrogen-bonded patterns in polyoxygenated decalins, showcasing varied supramolecular architectures influenced by oxyfunctionalisation and surrogate carbonate groups.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Shortening CN⋯Br–Csp3 halogen bonds via π-stacking

CrystEngComm, 2024, 26,2131-2135
DOI: 10.1039/D4CE00307A, Communication
Open Access
Kamil Kupietz, Rosa M. Gomila, Thierry Roisnel, Antonio Frontera, Rafael Gramage-Doria
An extremely short N⋯Br distance between a nitrile group and a Csp3-linked bromine atom was encountered in the solid-state and rationalized by DFT calculations, which emphasized the role of π-stacking for bringing both partners at close proximity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A highly stable hydrogen-bonded organic framework for hydrogen storage

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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Federal Bank mops up ₹1,500 crore via maiden issue of 10-year infra bonds

Federal Bank’s infrastructure bond issuance comprised a base issue of ₹750 crore and a greenshoe option of similar amount



  • Money & Banking

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Synthesis of Asp-based lactam cyclic peptides using an amide-bonded diaminodiacid to prevent aspartimide formation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00472H, Communication
Wen-Jie Li, Jun-You Chen, Hui-Xia Zhu, Yi-Ming Li, Yang Xu
A diaminodiacid (DADA) containing an amide bond can be used in Fmoc solid-phase peptide synthesis (SPPS) of an Asp-based lactam cyclic peptide with no aspartimide formation.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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DFT investigation of the DDQ-catalytic mechanism for constructing C–O bonds

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00346B, Paper
Xiu-Fang Zheng, Da-Gang Zhou, Li-Jun Yang
The DDQ-catalytic mechanisms for constructing C–O bonds via H2O and CH3OH as oxygen sources have been investigated with DFT.
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Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Additive-free oxychlorination of unsaturated C–C bonds with tert-butyl hypochlorite and water

Org. Biomol. Chem., 2024, 22,3080-3085
DOI: 10.1039/D4OB00003J, Paper
Duyi Shen, Chaoyue Sun, Yun Han, Zhen Luo, Ting Ren, Qin Zhang, Wenting Huang, Jianru Xie, Ying Jia, Mianran Chao
A facile oxychlorination of various alkynes and alkenes with tBuOCl as an alternative chlorine source and H2O as a green oxygen source.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Coordination-bond-assisted fabrication of robust composite photonic crystal films through melt-compression

Mater. Chem. Front., 2024, 8,3624-3633
DOI: 10.1039/D4QM00566J, Research Article
Jiahao Li, Tongling Yu, Chengcai Wu, Qianyao Fang, Xin Su
Robust photonic crystal films with vivid colors are fabricated through coordination-bond assisted melt compression and recombined into multicolor patterns.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tailoring the adsorption properties of imidazole-based halogen bonded organic frameworks for anionic dye removal

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00735B, Research Article
Shumeng Wang, Hongqiang Dong, Guanfei Gong, Siyi Lin, Jiahao Zhao, Zhennan Tian, Ya Lu, Xuguan Bai, Meimei Zhang, Lu Wang, Kang-Da Zhang, Shigui Chen
A novel class of [N⋯I⋯N]+ halogen-bonded XOFs were synthesized using imidazole ligands. XOF-TIB showed strong adsorption capacity and selectivity for anionic dyes, with excellent stability and reusability for environmental remediation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Multiple hydrogen bonding in crosslinked graphene oxide films with improved stretchability and toughness

Mater. Chem. Front., 2024, 8,3724-3730
DOI: 10.1039/D4QM00571F, Research Article
Mengling Yang, Chunyu Wang, Wenbin Wang, Li Yang, Shaolei Qu, Zhaoming Zhang, Xuzhou Yan
The UPy-rich polymers have been utilized to toughen and strengthen graphene oxide films through quadruple hydrogen-bonding, which offered a promising route for developing high-performance two-dimensional materials.
The content of this RSS Feed (c) The Royal Society of Chemistry




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“Delocalized π-bond” guided pyramidal nanocrystal superstructures for excellent light trapping in SERS

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00576G, Research Article
Yang Shang, Bo Ren, Xiaotian Wang, Jie Lin
A 2D CuI pyramidal superstructure is self-assembled in a manner similar to a delocalized π-bond, which effectively traps light and exhibits a remarkable SERS performance.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Each and Every - Every James Bond Car Explained

Aston Martin Chief Creative Officer Marek Reichman talks about all the Aston Martin cars that appear in the James Bond movies. Marek talks about the popularity brought to the DB5 after Goldfinger, all the awesome gadgets they've fit into the cars throughout the years, and how the Aston Martin has grown with the Bond series.




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Modulating the band gap of a pyrazinoquinoxaline-based metal–organic framework through orbital hybridization for enhanced visible light-driven CN bond construction

J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper
Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sovereign Gold Bond Scheme SGB 2016-17 Series III Final Redemption On November 16: How Much Money Will You Get?

Sovereign Gold Bond Scheme 2016 Final Redemption: How Much Money Will You Get? Check Details.




bond

Lessons from electoral bonds saga

Electoral funding needs to be made more transparent



  • From the Viewsroom

bond

Poor response to Dredging Corp tax-free bonds




bond

Daily quiz | On James Bond film series

On October 5, 1962, Dr. No, the first film of the James Bond series was released in the United Kingdom. A quiz on the film series based on the books written by Ian Fleming




bond

Enhanced magnetic properties and spin–phonon coupling in Ni-substituted α-Cu2V2O7: the role of bond length, bond angles, and distorted polyhedral structures

J. Mater. Chem. C, 2024, 12,17519-17532
DOI: 10.1039/D4TC02838D, Paper
A. Das, A. Banerjee, A. Tayal, S. Bandyopadhyay
Ni-Doped Cu2V2O7 exhibits enhanced magnetic hysteresis, zero-field exchange bias, and strong spin–phonon coupling, making it a promising candidate for spintronics applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solidifying the role of hydrogen bonds in conjugated polymers for wearable electronics

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03666B, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Megan M. Westwood, Bob C. Schroeder
The functionalisation of conjugated polymers with hydrogen bonding motifs, to impart self-healing or stretchability for wearable electronic applications. Through refinement of characterization techniques in recent years, the effect of these...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanism and stereoselectivity in metal and enzyme catalyzed carbene insertion into X–H and C(sp2)–H bonds

Chem. Soc. Rev., 2024, 53,11004-11044
DOI: 10.1039/D4CS00742E, Review Article
Reena Balhara, Ritwika Chatterjee, Garima Jindal
This review provides a mechanistic overview of asymmetric Fe, Cu, Pd, Rh, Au and heme-based enzymes catalyzed carbene insertion reactions to construct  C–X (X = O, N, S, etc.) and C–C bonds, focusing on the stereochemical models.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chemical bonding in Swedish upper secondary school education: a force-based teaching model for enhanced understanding

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00258J, Paper
Catalin Koro Arvidsson
This study investigates if a force-based teaching approach, based on quantum mechanical principles and developed in a lesson study, would enhance the understanding of chemical bonding among upper secondary school...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sovereign credit and exchange rate risks: Evidence from Asia-Pacific local currency bonds [electronic journal].

National Bureau of Economic Research




bond

Sovereign Bonds since Waterloo [electronic journal].

National Bureau of Economic Research




bond

Risk-Taking, Competition and Uncertainty: Do CoCo Bonds Increase the Risk Appetite of Banks? [electronic journal].




bond

The Rise in Foreign Currency Bonds: The Role of US Monetary Policy and Capital Controls [electronic journal].




bond

Procyclical Asset Management and Bond Risk Premia [electronic journal].




bond

Prices and Inflation when Government Bonds are Net Wealth [electronic journal].




bond

Municipal Bond Markets [electronic journal].




bond

Make-Wholes in Sovereign Bonds (Not sure why they are there, but they may be free) [electronic journal].




bond

Informed Trading in Government Bond Markets [electronic journal].




bond

ECB interventions in distressed sovereign debt markets: The case of Greek bonds [electronic journal].




bond

Corporate Foreign Bond Issuance and Interfirm Loans in China [electronic journal].

National Bureau of Economic Research




bond

Corporate Bond Liquidity During the COVID-19 Crisis [electronic journal].

National Bureau of Economic Research




bond

Common shocks in stocks and bonds [electronic journal].




bond

The Bond Lending Channel of Monetary Policy [electronic journal].